CLASSICA 7.

The number of acetylinic bonds in the given

1. The hybrid state of C-atomns which are attached compound is/are :
to a single bond with each other in the
following
structure are : CH,-CHCCH
(1) sp", sp (2) sp', sp (1) 2 (2) 3 (3) 1 (4) 4
(3) sp', sp (4) sp', sp NCO007
NCO001
3. The number of C-atoms in second member of an
2. The third member of the homologouS series of ester is//are:
aliphatic aldehydes has the structure : (1) 2 (2) 3 (3) 4 (4) 5
NCO008
(1) CH,CH,CHO (2) CHCH),CHO
(3) CH,COCHCH, (4) CH,COCH, 9. Which of the following is an example of
NCO002 syrmmetrical or simple ether :
3. Molecular formula C,H,0, represents
(1) An acid only
(2) An ester only (2) CH, 0-CH CH,
(3) An alcohol only (3) CH,-CH, 0-CH-CH, CH,
(4) An acid and an ester also
NCO003 H, CH,
NCO009
4. The higher homologue of dimethylamine
(CH,-NH-CH) has the structure : 10. The number of hetero atoms present in the
(1) CH,N-CH, following compound is/are:
H,
(2) CH,-CH,-CH-NH,
(3) CH,-NH-CH-CH,
(1) 2 (2) 3 (3) 1 (4) 4
(4) CH-ÇH-CH, NCO010
NH,
NCO004 11. Which of the following compound has
sp-hybridised carbon atom :
5 The third member of the family of alkenynes has
the molecular formula : (1) CH,COOH
(2) CH, (2) CH,COCH,
(1)CH,
(3) CH, (4) C,H, (3) CH,CH,CN
NCO005 (4) CH,-CH-CH-CH,
NCOO12
6. The number of olefinic bonds in the given
compound is/are : 12. In compound HC=C -CH-CH-CH-CH, the
CC, bond is the type of i
(1) sp-sp (2)sp-sp
(3) sp- sp (4) sp-sp
(1) 2 (2)3 (3) 1 (4) 4 NCOO13
NCO006
13. Which of the following pair of compounds are 19. A primary amine has amino group (-NH)
homologues attached to:
(1) 1-Propanol &2-Propanol (1) A primary carbon atom only
(2) Ethanol &Propanal (2) Asecondary carbon atom only
(3) Acetone &Acetaldehyde (3) A tertiary carbon atom only
(4) Acetic acid & Butyric acid (4) Aprimary, secondary or tertiary carbon atom
NCO015 NCO023

14. Which of the following homologous series has 20. Which of the following are secondary radicals -
incorect general fomula ;
(1)Alkyne
(2) Alkanol
CHg wCH-CH GH, 6) CH--cCH,
CH,0 () CH,-CH () (CH),CH
(3) Alkanal CH0 (2) a, d, c
(1) a, b, c
(4) Carboxyic acid CH,0, (3) b, c, d (4) a, b, d
NC0016
NCO024
15. Minimum number of carbon atoms present in a
21. Examine the following structures -
carboxylic acid anhydride.
(1) 2 (2) 1 (3) 4 (4) 3
NCO126 (A) CH,COH : B) CH,-NH,
16. Which of the following has general formula CH
H,
(1) Only Alkyne Which of the following statement is correct :
(2) Only Alkane (1) A is tertiary alcohol while B is tertiary amine
(3) Aromatic hydrocarbon (2) A is primary alcohol while B is primary amine
(4) Alkene & cycloalkane (3) A is tertiary alcohol while B is primary amine
NCO019
(4) A is primary alcohol while B is tertiary amine
NCO025

17. Which of the following are tertiary radicals - 22. Which of the following is not a corect match

wo H,
(b) CH-ÇH
CH, H,
’ Neopentyl

CH, ÇH,
() CH,-CH ’ Neobutyl
H,
CH,
(1) a and b (2) bandc
(3) a and c (4) bandd (3) HC=C-CH, » Propargyl
NCO021
(4) CH,-CH-CH- Allyl
NC0026
18. Common name of the given compound is :
CH-¢-o-CH-CH,
(1) vinyl acetate 23. The IUPAC name for isobutyl chloride is :
(2) acryl acetate (1) 2-Methy+-2-chlorobutane
(3) methyl acrylate (2) 2-Chloro-2-methylbutane
(4) Vinyl ethanoate (3) 1-Chkoro-2-methylpropane
NCO022 (4) 2-Methyl-3-chloropropane
24. The IUPAC name of given The IUPAC name of CH,CH,-NH-CH, Is ;
compound is : 29.
CH,CH-Ç-CH,CH,
OOH
(1) Methylethylamine
(2) 1-methylaminoethane
(1) 3-Carboxy-2-pentene (3) N-methylethanamine
(2) 2-Ethylidenebutanoic acid (4) N-ethylmethanamine
(3) 2-Ethyl-2-butenoic acid NCO034
(4) 3-Ethyl-2-buten-4-oic acid
NCO028 30. The IUPAC name for the compound is

25. The IUPAC name for the given structure is :

CH, (1) Cyclohexanoyl chloride
CH,-CH- CH-H-CHCH, (2) Cyclohexane carbonyl chloride
H,C H-CH, (3) 1-Chloro cyclohexanal
(1) 3-Isopropyl-4-methylhexane (4)Chloro cyclohexyl methanal
NCO035
(2) 4-lsopropy-3-methylhexane
(3) 3-Ethy-2,5-dimethyihexane 31. The IUPAC name of HC=C-C=CH-CH,
(4) 2-Ethy-3-isopropylpentane
NCO029
is
26. The UPAC name for
(1) 3-Methyl-2-penten-4yne
and (2) 3-Methyl-3-penten-1-yne
(3) 3-Methyl4-penty-1-ene
(1) 1-Amino-1-oxo ethane, 1-chloro ethanal (4) 3-Methyl pentenyne
(2) 1-Amino ethanal, acetoyl chloride NCO036
(3) 1-Oxoethanamine, ethanoyl chloride
32. The IUPAC name of the structure is :
(4) Ethanamide, Ethanoyl chloride
NCO030
CH,-CH=Ç-CH-¢-CH,-CH,
27. The number of carbon atoms in the principle CH,-CH-CH, H,
chain of the given compound are :
CH-CH,-CHÇ-COOH (1) 3-Isopropyl-5,5-dimethylhept-2-ene
OHC- CH,-CH, (2) 5-Ethyl-3,3,6-trimethylhept-2-ene
(1) 7 (2) 5 (3) 4 (4) 6 (3) 3,3-Dimethy-5-isopropylhept-5-ene
NCO031
(4) 3-Ethyl-2,5,5-trimethylhept-2-ene
NCO037
28. The UPAC name of given compound is :
CH,
33. has the IUPAC name :
CH,-Cc¢CH,
CH, cH,
(1)Methyltertiarybutyl acetylene (1) 3-Chloro-1-ethy-2-methylcyclopentane
(2) t-Butylpropyne (2) 1-Chloro-3-ethy-2-methylcyclopentane
(3) 4,4-Dimethy-2-pentyne (3) 4-Chloro-1-ethyl-5-methylcyclopentane
(4) 1,3,3,3-Tetramethylethyne (4) Al are corect

NCO032 NCO038
 ÇH, 40. Wrong IUPAC name ls :
(1)CH,CH,CONH, Propanamlde
34. The IUPAC name of ||CH,CH, Is:
(2) CH,CH,COoCH, Methyl propanoole
(1) 1-Methy-5-ethylcyclohex-2-ene
(13) CH-CH-CH-CH-CH, 2-Methyl pent-3-ene
(2)5-Ethyt 3-methylcyclohex-1-ene
(3) 4-Ethyl-6-methylcyclohex-1-ene 2-Ethoxy butane
(4) 1-Ethy5-methylcyclohex-3-ene H, CH,
NCO039 NCO047
35. The IUPAC name for the compound Is :
41. The IUPAC name 0s :

(1) 2-Acetyl prop-1-ene (2) Pent- 1-en-4-one (1) Acatlc anhydride

(2) Formyl ethanoate
(3) Pent-4-en-2-one (4) Formyl propene
(3) Butane-2, 4-dlone
NC0041
(4) Ethanolc methanolc anhydride
36. Which is incorrect IUPAC name : NCO049
(1) 3-Pentyne
42. The IUPAC name of glven compound Is:
(2) 3-Methy-2-butanone OH
(3) 2-Cthyl-3-methy-1-butene
(4) 3-Ethyl 2-methyl pentane
NC0042 CH/ CH,
(1) 3,3-Dimethyl-1-hydroxycyclohexane
37. The IUPAC name of (2) 1,1-Dimethyl-3-hydroxycyclohexane
(3) 3,3-Dimethyl-1-cycohexanol
(1) 1-Methoxy 4-aminobenzene (4) 1,1-Dimethyl-3-cycohexanol
(2) Aminophenyl methyl ether NCO050
(3) 4-Methoxy aniline
(4) None of the above 43. UPAC name of (CH),CHCH(CH), 0s :
NCO043 (1) 2,2-Dimethylbutane (2) 2,3-Dimethylbutane
(3) 2,4-Dimethylbutane (4) 1-Methylpentane
38. The IUPAC name of the given compound is : NC0051

ÇH-CN 44. IUPAC name of CH,-CH--CH,-Cl is -

H-CN (1) Allylchlorlde
H,-CN (2) 1-Chloro-3-propene
(3) 3-Chloro-1-propene
(1) 1,2,3-Tricarbonitrilepropane
(4) Vinyl chlorlde
(2)Propane-1,1,1-tricarbylamine NCO052
(3) Propane-1,2,3-tricarbonitrile
(4) 3-Cyano pentane dicyanide 45. The IUPAC name of the following group
NCO045 0s :

39. Number of carbon atoms in the principle carbon CH,

chain in the given compound are (1) Isopropenyl
(2) 1-Methylethenyl
CH,-CHfo0OH (3) 2-Methylethylnyl
H, (4) None of the above
(1) 4 (2) 3 (3) 2 (4) 5
NCO053
NCO046
46. CH-CH-CH-C-CH has IUPAC name : 50. Incorrect statement is :
(1) Pent-2-en-4yne
(2) Pent-4-yn-2-ene
(3) Pent-1-yn-3-ene (2) C
Br
(4) Pent-3-en-1yne
NCO054 lodine atom is away from observer and -Cl is
on the plane of paper
47. The IUPAC name of the following compound (2) Alicyic are those compounds which have
CH,CH,-ÇHCH-CH, similar properties of aliphatic compounds
CH,CH,-H-CH,-CH,
(3) is benzenoid structure
(1) 3, 4 - Dimethyloctane
(2) 3-sec pentylpentane
(3) 3, 4 - Diethylhexane
(4) 3,4- Dimethylhexane (4) Naphthalene is example of fused benzene ring
NCO055 NCO113
51. Which of the following is non-benzenoids ?
48. Corect IUPAC name is :
(1) 3-Methy-2-ethylpentane
(2) 2-Ethyl-3-methylpentane (2)
(3) 3-Ethy-2-methylpentane
(4) 2-Ethyt2-methyipentane NCO056
49. Which is hetero alicyclic ?
(4)

NCO114

OH
(c) (d)

NH,

Correct choice is :
(1) a ,b, d and e (2) c and e
(3) d ande (4) only f
NCO112
1. The general molecular formula, which represents
6. The correct TUPAC name of the compound
the homologous series of alkanols is
(1) CH,0, (2) CH_O
(3) CH0 (4) CH0
NCO057 is

2. The IUPAC name

is : (1)4-Ethy-3-propylhex-l-ene
(1) 3,4-Dimethylpentanoyl chloride (2)3-Ethyt4-ethenylheptane
(2) 1-Chloro-1-oxo-2,3-
dimethylpentane
(3) 2-Ethyl-3-methylbutanoyl chloride (3) 3-Ethyl4propylhex-5ene
(4) 2,3-Dimethyipentanoyl chloride (4) 3{1-ethyl propylhex-l-ene
NCO058
NC0062
APMT-2008
3. In the hydrocarbon
CH, - CH =CH-CH,-C= CH 7.
6 5 4
Which nomenclature is not according to IUPAC
3 2 1
The state of hybridization of carbons 1, 3 and 5 system?
are in the following sequence (1) CH, -CH-ÇH-CH,CH,
(1) sp, sp', sp
(2) sp', sp, sp
(3) sp', sp, sp' HO
(4) sp, sp', sp 2-Methyl-3-phenylpentane
NCO059

4 The IUPAC name of the compound having the 5-Oxohexanoic acid

formula CH =C-CH= CH, is
(1) 1-buten-3-yne (3) Br-CH,- CH = CH,
(2)3-buten-1-yne
(3) 1-butyn-3-ene 1-Bromo-prop-2-ene
(4) but-1-yn-3-ene
NCO060
(4 CH-CHHHCH,
Br H,
5 The UPAC name of the
CH,CH-CHC-CH is -
Compound
4-Bromo-2,4-dimethylhexane
(1) Pent-3-en-l-yne NC0063
(2) Pent-2-en-4-yne
(3) Pent-1-yn-3-ene
(4) Pent-4-yn2-ene
8. Structure of the compound whose UPAC narme is 12. The pair of electron in the given carbanion.
3-Ethy-2-hydroxy-4-methylhex-3-en-S-ynoic
acld is : CH,C= C®, is present in which of the following
orbitals ?
(1 COOH
(1) 2p (2) sp3 (3) sp² (4) sp
OH
OH NCO068
(2) ~cOOH

QH
(3) COOH 13. In which of the following molecules, al atoms are
coplanar ?

(4) COOH CN
(1)
CN
NCO064

9. Which of the following organic compounds has (3) (4

same hybridization as its combustion product
CO,?
(1) Ethane (2) Ethyne NCO069
(3) Ethene (4) Ethanol
NCO065

14. The UPAC name of the compound

10. The total number of -bond electrons in the
following structure is :
is :
HC
H,C (1) 5-fornylhex-2-en-3-one
H,C H CH, (2) 5-methyl-4-oxohex-2-en-5-al
(1) 8 (2) 12 (3) 16 (4)4 (3) 3-keto-2-methylhex-5-enal
NCO066
(4) 3-keto-2-methylhex-4-enal
11. The enolic form of ethyl acetoacetate as below
has: NCO071

HC H
NEETUG) 2018
OH 15. Which of the following molecules represents the
Enolic Ketonic order of hybridisation sp', sp, sp, sp from left to
right atoms ?
(1) 16 sigma bonds and l pi - bond (1) HC = C-C= CH
(2) 9 sigma bonds and 2 pi bonds (2) CH, = CH-C= CH
(3) 9 sigma bonds and 1 pi bond (3) CH, = CH-CH= CH,
(4) 18 sigma bonds and 2 pi - bonds (4) CH, -CH = CH- CH,
NCO067 NCO073=