CH3CH2CH=CH2 + HI CH3CH2CH CH2 (100%)

I H

H3PO4/SiO2
CH3CH=CH2 + HOH CH3CH CH3 (95%)
250oC, 40atm
OH

I
KI, H3PO4
CH3 (80%)
CH3

A
H+ vao C bac thap A
H3C C CH3 H3C C CH3
(1) Nhanh
CH3 CH3
H A (Carbocation ben) (San pham chinh)
H3C C CH2 -A
Cham
CH3
H H A
H+ vào C bac cao A
H3C C CH2 H3C C CH2
(2) Nhanh
CH3 CH3
(Carbocation kem ben) (San pham phu)

Br
H+ vao C bac thap CF3 C CH3 + Br CF3 C CH3
H
H
(kem ben) (san pham phu)

CF3 C CH2 + - Br
BrH
H

H2 H2 Br
H+ vào C bac cao CF3 C CH2 + Br CF3 C CH2
(ben hon) (san pham chinh)

Bac cao Bac thap Bac cao Bac thap

C C + E Nu C C
Nu E