FIITJEE – JEE (Main)

B
A
Physics, Chemistry & Mathematics
T QP Code:

C
H
E
Time Allotted: 3 Hours Maximum Marks: 300

S
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
–
20
22 Important Instructions

-
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.

24
A. General Instructions

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log tables, slide
rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall
/ room.

B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.

C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each and only
one correct option. Each question carries +4 marks which will be awarded for every correct answer and -1 mark
will be deducted for every incorrect answer.

(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________
Enrolment Number :___________________________________________________

SECTION – I
 PHYSICS
PART– A
This part contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

1. A body is moved along a straight line by a machine delivering constant power. The distance
moved by the body in time t is proportion to
1/2 3/4 3/2 2
(a) t (b) t (c) t (d) t

!
F = −K(yiˆ + xj)
ˆ
2. A force where K is a positive constant, acts on a particle moving in the xy plane.
Starting from the origin, the particle is taken along the positive x-axis to the point (a, 0) and then
parallel to the y-axis up to point (a, a). The total work done by the fore on the particle is
2 2 2 2
(a) -2 Ka (b) 2 Ka (c) – Ka (d) Ka

3. Find the acceleration of 3 kg mass when acceleration of 2 kg

mass is 2 ms–2 as shown in figure.
(a) 3 ms–2 (b) 2 ms–2
(c) 0.5 ms–2 (d) zero

4. A body of mass m falls freely through a height h from the top of a tower. The velocity just before
3
gh
touching the ground is 2 . The air drag is

(A) mg (B) mg/2

(C) mg/3 (D) mg / 4

5. Two particles A and B are connected by a rigid rod Y

AB. The rod slides along perpendicular rails as shown.
↑B
The velocity of A to the left is 10 m/sec when a = 300,
then what is the velocity of B ?

α
A X

(A) 5.8 m/s (B) 17.3 m/s

(C) 9.8 m/s (D) 10 m/s

µ = 0.4 2k F 1= 2
F2=µ s = 0.3 g 2N a = 2m/s
k
20N 4k
1 kg
g 6. A particle is thrown at an angle a to the horizontal with y
a velocity ‘V’. The acceleration and rate of change of
Smooth speed at t = 0 have values (magnitude only )
v
(A) (g cos a, g)
(B) (g, g sin a)
(C) (–g, -g)
(D) (-g, - g cos a) α
x
O

Space for rough work

7. The plot of velocity versus time is shown in the figure. A ν

varying force acts on the body. The correct statement B C
among the following is
(A) in moving from A to B, work done on the body is A D
negative. t
(B) in moving from B to C work is done on the body. E

(C) in moving from C to D, work done by the force on the body is positive.

(D) in moving from D to E, work done by the force on body is positive.

8. A particle of mass m is moving in a circular path of constant radius r such that its centripetal
2 2
acceleration ac is varying with time t as ac = K .r.t , where k is a constant. The power delivered to
the particle by the forces acting on it is

(a) 2 p mK .r .t
2 2
(b) mK .r t
2 2 4
(c) mK .r .t /3
2 5
(d) zero

A force acting on the body is given by F = x y î + yx ĵ , where x and y are coordinates.

2 2
9.
Then that force is

(A) Conservative force (B) Non-Conservative force

(C) Can’t say (D) none of these

Space for Rough Work

10. A uniform rope of length L, resting on frictionless L

horizontal surface is pulled at one end by a force F. Find T T F

the tension in the rope at distance !from the end where
force F is applied. L−! !

F! F (L − !
)
(A) L (B) L
F! F!
L
(C) + ! (D) − 1
L

11. A body starts from rest with constant acceleration, what is the ratio of the distance
th rd
travelled by the body during the 4 and 3 second?
(A) 7/5 (B) 5/7
(C) 7/3 (D) 3/7

12. A block A is able to slide on the frictionless incline of angle q and length !, kept inside
an elevator going up with uniform velocity v. Find the time taken by the block to slide
down the length of the incline if released from rest. What would be the time taken if the
elevator is accelerated at a ms . - 2

2! 2 ! 2! 2 !
, ,
gsin θ (g + a )sin θ gsin θ (g − a )sin θ
(A) (B)
2! 2 !
,
(C) g sin θ g sin θ (D) none of these

13. A ball is projected at such an angle that the horizontal range is three times the
maximum height the angle of projection of the ball is,
(A) - 1
sin (3/4) - 1
(B) sin (4/3)

cos- (4/3) (D) tan- (4/3)

1 1
(C)

! ! ˆ ˆ !
!
ˆ ˆ
14. What is the value of linear velocity, if ω = 3 i - 4j + k and r = 5 i - 6j + 6k ?
!
(A) 6 i + 2jˆ - 3kˆ (B) -18 ˆi - 13i + 2kˆ
 ! !
(C) 4 i - 13jˆ + 6kˆ (D) 6 i - 2jˆ + 8kˆ

15. One end of a spring of natural length ! and spring m

constant k is fixed at the ground and the other is fitted with a
smooth ring of mass m which is allowed to slide on a ! k
horizontal rod fixed at a height !as shown. Initially, the 60
o

spring makes an angle of 60o with the vertical when the

P
system is released from rest. Find the speed of the ring
when the spring becomes vertical.
k k 2!
!
(A) m (B) m
2
k ! 2 2
k!
2
2
(C) m (D) m

Space for rough work

ˆ ˆ ˆ ˆ
16. Given vector A = 2i + 3 j and B = i + j . The component of vector A along vector B is
ˆi + ˆj
( ) 5
ˆi + ˆj ( )
(A) 2 (B) 2
13 ˆ ˆ 7
2
i+j ( ) 2
(ˆi + ˆj )
(C) (D)

17. As situation shown in figure, an object of mass m is tied to a string

of length L and a variable horizontal force is applied on it show that L
its moves slowly until the string makes an angle q with the vertical. F
Work done by the variable force F is:
q
(A) mgL(1-sin ) (B) mgL

(C) mgL(1-cosq) (D) mgL(1+cos ) q

18. A particle is moving in a circle of radius r = 1m and angular displacement with respect to centre
t3
θ = 3 rad/sec (where t in second). What will be its total acceleration at t = 1 sec?

(A) 5 m/s2 (B) 2 5 m/s

2

(C) 4 m/s
2
(D) 5 Ö2 m/s 2

19. A circular disc of radius R is rotating about its axis O with a P

uniform angular velocity w rad/s as shown in the figure. P and Q
are two points on the disc. At any instant of time the magnitude of R/2 ω
the relative acceleration of P with respect to Q is • • ω
O Q
Rω2
(A) 0 (B) 2
Rω2 5Rω2
3
(C) 2 (D) 2

l
20. Two ends A and B of a smooth chain of mass m and length l are situated at a distance 3 as
shown in the figure. If we pull A till in comes to same level of B, work done by external agent is:
 mgl mgl mgl
(A) 36 (B) 18 (C) 9 (D) none of these

(PART – B)
(Integer Type)
Part-C (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

1. The velocity v versus t graph of body v (m/s)

in a straight line is as shown in figure
then displacement in 6 sec
2
will be (in m)

1
0.5
t(s)
0
1 2 3 4 6

−1

−2

2. A projectile is thrown horizontally from a big tower with a speed of 20 ms . If - 1

- 2
wg = 10 ms , find the speed of the projectile after 5 second to the nearest integer (in
-
ms ),
1

3. Find the horizontal velocity of the particle when it reach the point Q. Assume there is no
2
friction. Take g = 9.8 m/s .
m=2kg

1m
Q
0.5m

5m

4. In the arrangement shown in the figure, coefficient of friction

1
µ=
between the two blocks is 2 . The force of friction acting
between the two blocks is (in N)
5. A block of mass 1 kg is placed on the rough horizontal
surface of a car moving with a constant acceleration a
2
= 2m/s starting from rest as shown. The net work done
by frictional force on the block relative to ground in first
4 sec is (in Joule)

Section – II (CHEMISTRY)
PART– A
This part contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

1. If the radius of first orbit of hydrogen atom is a0, which of the following cannot be the
radius of any other orbit of hydrogen?
(A) 4 a0 (B) 6 a0

(C) 16 a0 (D) 25 a0

2. The formula of the chloride of a non-transition element(E) is ECl3. The probable group
number(s) of the element may be:
(A) 12 or 16 (B) 13 or 15
(C) 14 or 15 (D) 15 or 17

3. Overlapping between which of the following half-filled atomic orbitals, results in the
formation of the strongest sigma covalent bond?
(A) 2s and 2s (B) 2p and 2p
(C) 3p and 3p (D) 2p and 3p

4. Which of the following property of an ideal gas decreases by increasing temperature?

(A) R.M.S velocity (B) Average kinetic energy
(C) Rate of effusion (D) No. of collisions

5. Boiling of hard water in a boiler is accompanied with formation of scales on the inner
surface of the boiler. The scales are produced due to deposition of:
(A) Ca(HCO3)2 (B) CaCO3

(C) CaSO4 (D) CaCl2

6. Which contains the strongest B – F bond?

F F
(A) B (B) B
F F F F
F
H H
(C) B (D) B
F Cl F F

7. The correct graph for an ideal gas is:

(A) V
(in L )

–273 0 T (in K)

P
(in atm)
(B)

0
–273 0 t (in C)

V
(in L )
(C)

273 P (in mm of Hg)

T
(in K )
(D)

273 P (in mm)

8. P
Q
R
S

Pressure
o
Above graph represents the behavior of four gases at 0 C. Which of the following gas
will most likely represent curve ‘Q’?
(A) NH3 (B) SO2

(C) H2 (D) CO2

9. Which has the highest value of dipole moment?

Cl F
F Cl
(A) (B)

Cl Cl
Cl Cl
F
(C) (D)

F Cl Cl
10. At which of the following condition of temperature and pressure, an ideal gas will have
maximum density?
(A) High temperature and high pressure (B) Low temperature and low pressure
(C) High temperature and low pressure (D) Low temperature and high pressure

11. The van der Waal’s equation for one mole of a gas is given as:
⎛ a ⎞
⎜ P + V 2 ⎟ (V − b ) = RT
⎝ ⎠

Which of the following term represents the volume which is used for expansion and
compression of the real gas?
(A) V (B) b
a
2
(C) (V - b) (D) V
12. The incorrect statement regarding PF2Cl3 is:

(A) It has zero dipole moment

(B) The axial atoms are more electronegative than the equatorial atoms
o o o
(C) Bond angles of 90 , 120 and 180 are observed in the molecule
(D) It contains both sigma and pi-bonds

13. Which of the following orbital has double dumb bell shape?
(A) 4 pz (B) 4 dxy
5 dz2
(C) (D) 5 py

14. Which of the following element can form maximum number of covalent bonds?
(A) Carbon (B) Phosphorus
(C) Sulphur (D) Chlorine

15. Which ion has no resonating structure due to absence of p-bond?

2− 3−
CO BO
(A) 3 (B) 3

NO3− SO32−
(C) (D)

16. Ideal gas Ideal gas

NO2 NO2
(2 mole) (2 mole)
(I) ( II )
V=5L V=5L
P = 4 atm P = 6 atm
Which of the following property of the gases in the above two vessels is given in correct
order?
(A) Kinetic energy: I > II
(B) RMS velocity: I > II
(C) No. of collisions: II > I
(D) No. of molecules having most probable velocity: II > I

17. At which of the following position in an atom, the probability of finding electrons is
zero?
(A) Nucleus (B) Orbit
 (C) Orbital (D) Infinity

18. Which has more covalent character than MgCl2?

(A) NaCl (B) KCl

(C) BeCl2 (D) CaCl2

19. If the volume of a molecule of a monoatomic real gas is Vm. How much minimum
volume is needed to accommodate two molecules of the gas?
(A) 4 Vm (B) 8 Vm

(C) 2 Vm (D) 6 Vm

20. Which of the following is most soluble in water?

(A) BeO (B) MgO
(C) CaO (D) BaO

(PART – B)
(Integer Type)
Part-C (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

1. What is the equivalent mass of NH3 in the following reaction? [Mol. Mass of NH3 = 17]
NH3 + H+ ⎯⎯
→ NH+4

2. How many gram of magnesium can be completely dissolved in 400 mL of 0.1 M HCl
solution?
Mg + 2HCl ⎯⎯
→ MgCl2 + H2

O
H-O -N
3.
O

How many electron(s) is/are present in the hybrid orbitals of nitrogen in the above
molecule?

4. What is the average oxidation number of sulphur in the following ion?

O
O
HO − S − O − O − S − O
O
O

5. How many quantum number(s) is/are needed to distinguish the electrons of helium?

Space for Rough Work

SECTION – III
MATHEMATICS

PART– A
This part contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

log20 3
1. The number lies in the interval
⎛ 1 1⎞ ⎛ 1 1⎞
⎜ , ⎟ ⎜ , ⎟
(A) ⎝ 4 3 ⎠ (B) ⎝ 3 2 ⎠
⎛1 3⎞ ⎛3 4⎞
⎜ , ⎟ ⎜ , ⎟
(C) ⎝ 2 4 ⎠ (D) ⎝ 4 5 ⎠

dy
x = a (t − sin t ) y = a (1 − cos t )
2. If , , then dx is equal to
1 − cos t 1 + cos t
(A) sin t (B) sin t
cos t cos t
(C) 1 − sin t (D) 1 + sin t
dx
∫ x (x =
3.
7
)
+1

1 ⎛ x7 ⎞ 1 ⎛ x7 ⎞
ln ⎜ ⎟+c − ln ⎜ 7 ⎟+c
7 ⎝ x7 + 1⎠ 7 ⎝ x + 1⎠
(A) (B)
⎛ x7 ⎞
ln ⎜ 7 ⎟+c
x + 1⎠
(C) ⎝ (D) none of these

4. If A = tan 6° tan 42° and B = cot 66° cot 78°, then

1
A= B
(A) A = 2B (B) 3

(C) A = B (D) 3A = 2B

5. The locus of the point such that the tangents drawn from it to the circle
x 2 + y 2 − 6x − 8y = 0 are perpendicular to each other, is
2 2 2 2
(A) x + y − 6x − 8y − 25 = 0 (B) x + y + 6x − 8y − 5 = 0
2 2 2 2
(C) x + y − 6x + 8y − 5 = 0 (D) x + y − 6x − 8y + 25 = 0

6. The equation of the circle passing through the points (2, 0) and (0, 4) and having the
minimum possible radius is
2 2 2 2
(A) x + y + x + y = 3 (B) x + y − 2x − 4y = 0
2 2
(C) x + y − 7x − y + 8 = 0 (D) none of these

7. If the area of the triangle formed by the points (2a,b ), (a + b, 2b + a )

and (
2b, 2a )
be
λ , then the area of the triangle having vertices at (a + b, a − b ), (3b − a, b + 3a ) and
(3a − b, 3b − a ) is
3
λ
(A) 2 (B) 3λ
(C) 4λ (D) none of these
8. If log4 5 = a and
log5 6 = b,
then
log3 2=

1 1
(A) 2a +1 (B) 2b +1
1
(C) 2ab + 1 (D) 2ab −1

sin (cos x )
9. The maximum value of is equal to
(A) sin1 (B) 1
 ⎛ 1 ⎞ ⎛ 3⎞
sin ⎜ sin ⎜
⎟ ⎜ 2 ⎟⎟
(C) ⎝ 2⎠ (D) ⎝ ⎠

10. The reflection of the point (4, –13) in the line 5x + y + 6 = 0 is

(A) (–1, –14) (B) (3, 4)
(C) (1, 2) (D) (–4, 13)

11. The coordinates of the middle point of the chord cut off by the line 2x − 5y + 18 = 0 on
2 2
the circle x + y − 6x + 2y − 54 = 0 are
(A) (1, 4) (B) (2, 4)
(C) (4, 1) (D) (1, 1)

12. The medians AD and BE of the triangle with vertices A (0, b), B (0, 0) and C (a, 0) are
mutually perpendicular if
(A) b = 2a (B) a = 2b
(C) b = − 2a (D) a = 5 2b

3π
π < 2θ < ,
13. If 2 then 2 + 2 + 2 cos 4θ is equal to

(A) −2 cos θ (B) −2 sin θ

(C) 2 cos θ (D) 2 sin θ

14. The number of positive integral values of ‘m’ for which the x-coordinate of the point of
intersection of the lines 3x + 4y = 9 and y = mx + 1 is an integer, is
(A) 0 (B) 1
(C) 2 (D) infinitely many

15. If the point (α, β ) lies on the line 2x + 3y = 6 , the smallest value of α 2 + β2 is

36 6 13
(A) 13 (B) 13
(C) 6 (D) 13

2
16. The maximum value of 12 sin θ − 9 sin θ is equal to
(A) 3 (B) 4
(C) 21 (D) none of these

17. Let PQ and RS be tangents at the extremities of the diameter PR of a circle of radius r.
If PS and RQ intersect at a point X on the circumference of the circle, then 2r equals
PQ + RS
PQ.RS 2
(A) (B)
2PQ.RS PQ2 + RS2
(C) PQ + RS (D) 2

18. The equation of the pair of straight lines parallel to y – axis and which are tangents to
2 2
the circle x + y − 6x − 4y − 12 = 0 , is
2 2
(A) x − 4x − 21 = 0 (B) x − 5x + 6 = 0
2
(C) x − 6x − 16 = 0 (D) none of these

2 2 2 2
19. The common chord of the circles x + y − 4x − 4y = 0 and x + y = 16 subtends at
 the origin an angle equal to
π π
(A) 6 (B) 4
π π
(C) 3 (D) 2

a,b
If a circle passes through the point ( ) and cuts the circle x + y = p
2 2 2
20.
orthogonally, then the equation of the locus of its center is
2ax + 2by − (a2 + b2 + p2 ) = 0 2ax + 2by + (a2 + b2 + p2 ) = 0
(A) (B)

(C)
(
x 2 + y 2 − 3ax − 4by + a2 + b2 − p2 = 0) (D)
2 2
x + y − 2ax − 3by + a + b − p ( 2 2 2
) =0

Space for Rough Work

(PART – B)
(Integer Type)
Part-C (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

λx 2 + µy 2 + (λ + µ − 4 ) xy − λx − µy − 20 = 0
1. If represents a circle, then the radius of the
circle is

2 2
2. The pair of straight lines joining the origin to the common points of x + y = 4 and
y = 3x + c are perpendicular if c 2 is equal to

1
x 4 sin + x2
lim x =
3. x →∞ 1 + x3

4. The sum of the squares of the length of the chord intercepted by the line x + y = n, n ∈ N
2 2
on the circle x + y = 4 is

2 2
5. The number of common tangents to the circles x + y − 6x − 14y + 48 = 0 and
x 2 + y 2 − 6x = 0 is

Space for Rough Work

FIITJEE INTERNAL TEST

PHASE – I
BATCHES: Two Year CRP (224)_PT-1_A Lot
ANSWERS - JEE MAINS
QP CODE: (Set-A)

SR. NO PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE

1 C P110502 B C110103 B M110201
2 C P110409 B C110702 B M110201
3 B P110310 B C110306 A M120701
4 D P110502 C C111301 C M120701
5 B P110409 B C111106 A M120701
6 B P110310 C C110305 B M110802
7 D P110310 B C111201 C M110708
 8 B P110504 C C111203 D M110202
9 B P110501 D C110304 A M110202
10. B P110403 D C111201 A M110202
11. A P110301 C C111204 A M110202
12. A P110303 D C110306 B M110202
13. D P110310 B C110107 D M110202
14. B P110310 D C110302 A M110202
15. A P110503 B C110308 A M110202
16. B P110503 C C111205 B M110202
17. C P110507 A C110113 A M110806
18. A P110301 C C110306 C M110808
19. D P110303 B C111204 D M110808
20 A P110310 D C110301 A M110808
Part B Part B
1 3 P110310 17 C111101 3.24 M110808
2 54 P110311 0.48 C111102 20 M110808
3 3.13 P110503 4 C110305 1 M110201
4 8 P110311 6 C110204 22 M110201
5 32 P110503 1 C110107 4 M110201

Hints & Solutions

Physics
1. Power P = F.v = constant
dv
m .v = c
dt
1
dv
v = c ⇒ v α t2
dt
3
⇒ x α t2

!! !
dw = F.dr and dr = dxiˆ + dyjˆ
2.

= - K(ydx + xdy)
(a,a)
w = −k ∫ (ydx + xdy)
(0,0)

= −K[xy](a,a)
(0,0) = −Ka
2

10. B P110403
M
Mʹ = M
(L − !)
Sol: Let L be mass per unit length. Then mass of length (L - !) is L .
F M (L − !) F (L − )!
T = Mʹ × = × = F
M L M L

11. A P110301
1
Sn = u + (2n − 1)a
Sol: 2
a
S4 = 0 + ×7
2
a
S3 = 0 + ×5
2
S4
=7/5
S3

12. A P110303
1 2!
g sin θt 2 = ! or t=
Sol: Case (i) 2 g sin θ

1 2!
(g + a) sin θt 2 = ! or t=
2 (g + a )sin θ
Case (ii)
13. D P110310
v 2 sin 2θ v 2 sin2 θ
=3
Sol: g 2g

Þ 2 ´ 2 sin q cos q = 3 sin q 2

Þ 4cos q = 3 sin q
\ tan q = 4/3
\ q = tan- (4/3)
1

14. B P110316
!
Sol:
!
v = tangentially velocity = ω ´!
r
ˆ ˆ ˆ
!
v = (3i − 4 j + k) ´ (5iˆ − 6ˆj + 6k)ˆ = −18iˆ + 13ˆj + 2kˆ

15. A P110503
!
−!
Sol: Initial extension in the spring x = cos 60o = !
1 2 1
k!= mv 2
\ 2 2

k
!
\v= m

16. B P110205
! ! ˆi + ˆj
A ⋅B
=
5 ( )
Sol: A cos q = B 2 , unit vector = 2

17. C P110507
Sol: Work done by the external force = D E of the system (object)
= DPE (!ΔKE = 0 ) L cos θ θ L
m
= mgh = mg (L – L cos q) = mgL (1 – cos q).
h B
m
A

PART – B (NUMERICAL )

1. 3
Sol: Area under the curve gives the displacement with proper sign
1 1
d = × 3 × 2 − × 1× 2 + 1× 1
2 2

=3 -1+1=3m
2. 54
Sol: vx = v = 20 ms - 1

vy = uy + ayt = 0 + gt = 10 ´ 5 = 50 ms- 1

v 2x + v 2y = 202 + 502 ≈ 54ms−1

\v = .

3. 3.13
 m=2kg

1m
Q
0.5m

5m

⎛ 1⎞ 1 g v2
⎜1 − 2 ⎟ g
Sol: mg ⎝ ⎠ = 2 mv
2
Þ 2 = 2 Þ v= @ 3.13 m/s

Chemistry

1. B (Concept Code: C 110103)

n2
r = a0
Sol. z

Where n = 1, 2, 3, ………
\6a 0
is not the radius of any orbit of H atom.

2. B (Concept Code: C 110702)

Sol. The elements of gr-13 and gr-15 display +3 oxidation states.

3. B (Concept Code: C 110306)

Sol. p-orbitals overlap better than s-orbitals. p-orbitals of lower value of ‘n’ overlap in a better
way than that with higher value of ‘n’.

4. C (Concept Code: C 111301)

1
α
Sol. Effusion T , other properties a temperature.

5. B (Concept Code: C 111106)

Sol. Hard water contains Ca(HCO3)2 which on heating produces insoluble CaCO3.

6. C (Concept Code: C 110305)

Sol. Due to strongest p p - pp back bond in (C).

7. B (Concept Code: C 111201)

o
Sol. At –273 C (–273 + 273 = 0 K), the pressure becomes zero as volume becomes zero.

8. C (Concept Code: C 111203)

o
Sol. H2 shows only positive deviation at 0 C.

9. D (Concept Code: C 110304)

Sol. In(D), the resultant vector of tow C – Cl and is intensified by C – F bond.
10. D (Concept Code: C 111201)
PM P
d= ⇒dα
Sol. RT T

11. C (Concept Code: C 111204)

Sol. (V - b) represents the free volume for expansion and compression.

12. D (Concept Code: C 110306)

Sol. It contains no p-bonds.

13. B (Concept Code: C 110107)

Sol.

4 dxy is

14. D (Concept Code: C 110302)

Sol. Max. no. of covalent bonds formed by the given elements is C = 4, P = 5, S = 6 and Cl =
7.

15. B (Concept Code: C 110308)

BO33 − –
Sol. contains B – O bonds

16. C (Concept Code: C 111205)

Sol. No. of collision becomes less for a gas at low pressure.

17. A (Concept Code: C 110113)

Sol. y = 0 only at Nucleus.
2

y ¹ 0 at infinity
2

18 C (Concept Code: C 110306)

2+
Sol. Be has most polarizing power.

19. B (Concept Code: C 111204)

Sol. For one molecule, the volume is 4 Vm. For two molecules, it is 2 ´4V m
= 8 Vm

20. D (Concept Code: C 110301)

Sol. L.E order: BeO > MgO > CaO > BaO

Numerical Type
1. 17
+
Sol. One molecule can absorb one H ion.

2. 0.48 g
400 × 0.1
Moles of HCl = = 0.04
Sol. 1000

\ Moles of Mg to be dissolved = 0.02 mole

Mass of Mg = 0.02 ´ 24 = 0.48 g

3.
Sol.

N
2s 2p

sp2 -hybridization

4.
Sol. It contains peroxy linkage.

5.
⎛ 1 1 ⎞
He → 1s2 ⎜ s = + and s = − ⎟
Sol. ⎝ 2 2 ⎠

l
n, , m ® same

Mathematics
PART-A
1. B M110201
1
log20 3 =
Sol. log3 20
⇒ 2 < log3 20 < 3
Now, 9 < 20 < 27

2. B M120510
dy
dy dt a sin t sin t 1 + cos t 1 + cos t
= = = × =
dx dx a (1 − cos t ) 1 − cos t 1 + cos t sin t
Sol. dt

3. A M120701
dx dx
∫ x (x =∫
7
)
+1 8⎛ 1⎞
x ⎜1 + 7 ⎟
Sol. ⎝ x ⎠

1
1+ =t
Put x7 .
4. C M111412
A
= tan 6° tan 42° tan 66° tan 78°
Sol. B
tan 6° tan (60° − 6° )tan (60° + 6° ) tan18° tan (60° − 18° )tan (60° + 18° )
= ×
tan 54° tan18°
tan (3 × 6° ) tan (3 × 18° )
= × =1
tan 54° tan18°

5. A M110825
2 2

Sol. Given circle is (x − 3 ) + (y − 4 ) = 25

.
The locus of the point of intersection of two perpendicular tangents is the director circle,
2 2
x − 3 ) + (y − 4 ) = 50
whose equation is (
⇒ x 2 + y 2 − 6x − 8y − 25 = 0

6. B M110802
Sol. The required circle is the one having (2, 0) and (0, 4) as the end-points of a diameter.

7. C M110708
Sol. The area of the triangle formed by joining the mid-points of any triangle is one fourth of
that the triangle.

8. D M110202
1
ab = log4 6 ⇒ 2ab = log2 6 = log2 3 + 1 ⇒ log3 2 =
Sol. 2ab − 1

9. A M111411
−1 ≤ cos x ≤ 1 ⇒ − sin1 ≤ sin (cos x ) ≤ sin1
Sol.

10. A M110722
Q (x1, y1 )
Sol. Let be the reflection of P (4, –13) in the line 5x + y + 6 = 0 .
x1 − 4 y1 + 13 −2 (20 − 13 + 6 )
= =
Then, 5 1 25 + 1 = −1

∴ x 1 = −1, y 1 = −14

11. A M110826
Sol. Let the coordinates of the mid-point of AB be
D (h, k). Since D lies on 2x − 5y + 18 = 0 ,
B
2h − 5k + 18 = 0 ...(i)
Equation of CD is
5
y + 1 = − (x − 3 )
2 A
C (3, –1)
or 5x + 2y − 13 = 0 ...(ii)
D lies on CD.
∴ 5h + 2k − 13 = 0 ...(iii)
Solving Equations (i) and (iii), we get
h = 1, k = 4
12. B M110720
Sol. slope of AD x slope of BE = –1
⇒ a2 = 2b2

∴ a = ±b 2

13. D M111409
2 + 2 + 2 cos 4θ = 2 + (2 )(2 cos2 2θ ) = 2 + 2 cos 2θ = 2 − 2 cos 2θ
Sol.
= (2 )(2 sin2 θ ) = 2 sin θ = 2 sin θ

14. A M110725
5
x=
Sol. 4m + 3

There is no positive integral value of m for which the value of x is an integer.

15. A M110718
2 2
Sol. The smallest value of α + β is the square of the perpendicular distance of the origin
from the line.

16. B M111411
2 2
12 sin θ − 9 sin θ = 4 − (3 sin θ − 2 )
Sol.

17. A M110806

Sol. From the figure, Q S

RS RS
tan α = =
PR 2r .…(i)
⎛π ⎞ PQ PQ X
tan ⎜ − α ⎟ = =
and ⎝2 ⎠ PR 2r ….(ii)
Multiplying (i) and (ii), we get
RS. PQ
tan α cot α = 2 π
(2r ) α 2
−α
P R
∴
2r = (RS )(PQ )

18. C M110808
3−λ
= ±5
Sol. If x = λ be the equation of the tangent, then 1 (condition of tangency)
⇒ λ = 3 ± 5 = −2, 8

The equation of the pair of lines is (x + 2 )(x − 8 ) = 0 2

or x − 6x − 16 = 0 .
19. D M110820
C2 ≡ (0,0 )
Sol. . Equation of AB is given by S1 − S2 = 0 , i.e. x + y = 4 .
0+0−4
C2P = =2 2
12 + 12
2 2 1 π π
∴ cos θ = = ⇒θ= ⇒ 2θ =
4 2 4 2

20. A M110824
 2 2
Sol. Let the equation of the required circle be x + y + 2gx + 2fy + c = 0 . According to the
given conditions, we have
2 2
a + b2 + 2ga + 2fb + c = 0 and 2g (0 ) + 2f (0 ) = c − p ⇒ c = p
2

2 2 2
Hence, a + b + 2ga + 2fb + p = 0 . Replace −g by x and −f by y to get the equation
of the locus of the center.

PART-C

2
Since the given equation represents a circle, coefficient of x = coefficient of y .
2
1. Sol.
⇒ λ=µ

and coefficient of xy = 0 ⇒ λ + µ − 4 = 0 ⇒ λ = µ = 2
2 2
Thus, the equation of the circle becomes x + y − x − y − 10 = 0
2 2
⎛ 1⎞ ⎛ 1⎞
= ⎜ ⎟ + ⎜ ⎟ + 10 = 21 = 42
whose radius is ⎝2⎠ ⎝2⎠ 2 2
2
⎛ y − 3x ⎞
x2 + y2 = 4 ⎜ ⎟
2. Sol. Homegeneous equation is ⎝ c ⎠

⇒ (
c 2 x 2 + c 2 y 2 = 4 y 2 + 9x 2 − 6xy )
The lines are perpendicular.
∴ c 2 − 36 + c 2 − 4 = 0

∴ c 2 = 20
1
sin
x +1
1 1 1 1 x
x 4 sin + x2 x sin +
x x x = lim x 1+ 0
lim = lim = =1
x →∞ 1 + x3 x →∞ 1 x →∞ 1 0 +1
+1 +1
3. Sol. x3 x 3

4.
B
⎛ n2 ⎞
AB2 = 4AM2 = 4 ⎜ 4 −
2
⎟ = 2 8−n(2
) M
Sol. ⎝ ⎠
Hence, required sum A
(0, 0) O 2
(
= 2 8 − 12 + 8 − 22 = 22 )

5.
C1 ≡ (3,7 ), C2 ≡ (3,0 ), r1 = 10, r2 = 3
Sol.
C1C2 = 7 > r1 + r2

Hence, 4 common tangents.

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