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ME 8391 Engineering Thermodynamics MCQ 2020
ME 8391 Engineering Thermodynamics MCQ 2020
Answer: c
UNIT I BASIC CONCEPTS
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Explanation: The above formula gives the
AND FIRST LAW macroscopic potential energy of the fluid
element by virtue of its position.
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TOPIC 1.1 BASIC CONCEPTS - 5. Which of the following types of energy can
CONCEPT OF CONTINUUM, be present in molecules?
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COMPARISON OF a) translational and rotational kinetic energy
b) electronic energy and vibrational energy
MICROSCOPIC AND
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c) chemical energy and nuclear energy
MACROSCOPIC APPROACH. d) all of the mentioned
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1. Energy is a Answer: d
a) point function Explanation: The molecules may be
b) property of the system subjected to rotation as well as vibration due
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c) extensive property to a collision.
d) all of the mentioned
6. The total internal energy of the system is
Answer: d given by
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Explanation: Energy has a definite value for a) U=N/ɛ
every state of the system. b) U=Nɛ
c) U=ɛ/N
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c) E=constant Answer: a
d) all of the mentioned Explanation: For two reversible paths, dQ/T
doesn’t depend on the path taken.
Answer: c
Explanation: For an isolated system, 2. Integral of dQ/T of a reversible path is
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dQ=dW=0 and hence, dE=0 by first law. given by
a) Si-Sf
9. A perpetual motion machine of first kind b) Sf-Si
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a) is a fictitious machine c) Si+Sf
b) can supply mechanical work without d) -Si-Sf
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dissipating energy
c) violates first law Answer: b
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d) all of the mentioned Explanation: Integral of dQ/T is = Sf-Si
where i=initial equilibrium state and f=final
Answer: d equilibrium state.
Explanation: There cannot be any machine
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which would continuously supply mechanical 3. Entropy is a
energy without other form of energy being a) path function, intensive property
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dissipated. b) path function, extensive property
c) point function, intensive property
10. The limitation of the first law is d) point function, extensive property
a) does not indicate the possibility of a
spontaneous process proceeding in a definite Answer: d
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direction Explanation: Fact about entropy and unit of
b) it assigns a quality to different forms of entropy is J/K.
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energy
c) indicates the direction of any spontaneous 4. Specific entropy is given by( where m is
process the mass)
d) none of the mentioned a) Sm
b) m/S
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Answer: a c) S/m
Explanation: This is the main limitation of d) none of the mentioned
first law and the second law overcomes it.
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Answer: c
Explanation: s=S/m with unit J/kg K.
TOPIC 1.2 PATH AND POINT
FUNCTIONS. INTENSIVE AND 5. For any process which is undergone by a
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Explanation: For a reversible process, dQ/T AND PROCESS. QUASI-STATIC,
is equal to the net change in entropy. REVERSIBLE AND
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7. For an irreversible process, IRREVERSIBLE PROCESSES.
a) dS=dQ/T
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b) dS>dQ/T 1. A reversible process is performed in such a
c) dS<dQ/T way that
a) at the conclusion of process, both system
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d) none of the mentioned
and surroundings can be restored to their
Answer: b initial states without producing any change
Explanation: For a irreversible process, b) it should not leave any trace to show that
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change in entropy is greater than dQ/T. the process had ever occurred
c) it is carried out infinitely slowly
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8. For two different paths between same two d) all of the mentioned
points, entropy change is
a) depends on path taken Answer: d
b) different Explanation: These are some basic concepts
c) same
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of a reversible process.
d) none of the mentioned
2. A reversible process coincides with a
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Explanation: For heat transfer to be b) false
reversible, heat must be transferred through
an infinitesimal temperature difference. Answer: b
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Explanation: Friction lakes the process
5. All actual heat transfer processes are irreversible.
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a) irreversible
b) take place through a finite temperature 10. Which of the following is irreversible?
a) stirring work
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difference
c) both of the mentioned b) friction work in moving devices
d) none of the mentioned c) current flowing through a wire
d) all of the mentioned
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Answer: c
Explanation: An infinitesimal temperature Answer: d
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difference is not easy to attain. Explanation: All these processes includes a
particular cause of irreversibility.
6. Free expansion is irreversible.
a) true 11. A process will be reversible if it has
b) false a) no dissipative effects
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b) dissipative effects
Answer: a c) depends on the given conditions
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a) friction, viscosity
b) inelasticity 12. Irreversibility can be distinguished in how
c) electrical resistance, magnetic hysteresis many types?
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dissipative effects.
Answer: c
8. The continual motion of a movable device Explanation: Tow types of irreversibility are
in the complete absence of friction is known internal and external irreversibility.
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as
a) PMM2 13. Internal irreversibility is caused by
b) PMM3 a) internal dissipative effects
c) PMM1 b) friction, turbulence
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system boundary. b) negative
a) true c) zero
b) false d) varies according to situation
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Answer: a Answer: a
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Explanation: This mainly includes heat Explanation: In thermodynamics, work done
interaction with the surroundings due to a by a system is take to be positive.
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finite temperature gradient.
3. Work done on a system is taken to be
15. Which of the following is true? a) positive
a) mechanical irreversibility is due to finite b) negative
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pressure gradient c) zero
b) thermal irreversibility is due to finite d) varies according to situation
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temperature gradient
c) chemical irreversibility is due to finite Answer: b
concentration gradient Explanation: In thermodynamics, work done
d) all of the mentioned on a system is take to be negative.
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Answer: d 4. Work is a
Explanation: These are some other a) point function
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b) exact differentials
Answer: b c) all of the mentioned
Explanation: The work is done by a force as d) none of the mentioned
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7. In the equation dV=(1/p)dW, (1/p) is c) it may exist in one or more phases
known as d) all of the mentioned
a) volume factor
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b) pressure factor Answer: d
c) differential factor Explanation: These are some of the
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d) integration factor properties of a pure substance.
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Answer: d 2. For water, as temperature increases,
Explanation: Used to convert inexact volume always increases?
differential dW into exact differential dV. a) true
b) false
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8. Cyclic integral of a property is always
a) zero Answer: b
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b) one Explanation: From 0 degree Celsius to 4
c) infinite value degree Celsius as temperature increases,
d) none of the mentioned volume of water decreases which is a
peculiarity of water.
Answer: a
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Explanation: The initial and final states of 3. A saturation state is a state from which a
the system for a cyclic process are the same. change of phase may occur
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Explanation: Isobaric and isopiestic means Celsius and at 100 degree Celsius.
pressure being constant.
4. In which of the following state does water
10. Work done in a quasi-static process exist?
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Answer: a Answer: d
Explanation: This is because work done is a Explanation: Water exists in these states at 0
path function. degree Celsius and at 100 degree Celsius.
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Answer: d Answer: a
Explanation: The p-V diagram for water has Explanation: At critical point, all the
all these three lines. quantities like pressure, temperature and
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volume attain their critical values.
6. The triple point is a line on the p-V
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diagram, where all the three phases, solid, 10. The greater the temperature, the ____ is
liquid and gas exist. the vapour pressure.
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a) true a) lower
b) false b) higher
c) depends on the substance
Answer: a d) none of the mentioned
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Explanation: At triple point, all these three
phases exists in equilibrium. Answer: b
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Explanation: The vapour pressure mainly
7. At a pressure below the triple point line, depends on the temperature.
a) the substance cannot exist in the liquid
phase 11. Phase change occurs at
b) the substance when heated transforms from a) constant pressure
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solid to vapour b) constant temperature
c) both of the mentioned c) constant pressure and temperature
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Answer: c Answer: c
Explanation: This phenomenon is known as Explanation: For phase change, pressure and
sublimation and takes place by absorbing the temperature must be constant like water at 0
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latent heat of sublimation from the degree Celsius and at 100 degree Celsius.
surroundings.
12. Which of the following statement is true?
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TEMPERATURE SCALES. b) triple point of water
c) boiling point of water
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d) none of the mentioned
1. It is necessary to have a temperature
difference to obtain work of any cycle. Answer: a
a) true
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Explanation: The smallest possible value of
b) false Q which is the amount of heat supply is zero
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Answer: a and the corresponding temperature is zero.
Explanation: It comes from the second law
6. At absolute zero, an isotherm and an
of thermodynamics.
adiabatic are identical.
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a) true
2. The absolute thermodynamic temperature
b) false
scale is also known as
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a) celsius scale
Answer: a
b) kelvin scale
Explanation: At absolute zero, there is no
c) fahrenheit scale
heat transfer.
d) none of the mentioned
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7. A definite zero point ___ on the absolute
Answer: b
temperature scale but this point ___ be
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a) isotherms, increases
b) isotherms, decreases c) third law of thermodynamics
c) adiabatics, increases d) none of the mentioned
d) adiabatics, decreases Answer: c
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d) Internal Energy=Heat added plus work
Answer: a done
Explanation: This is a fact about third law of
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thermodynamics. Answer: d
Explanation: It is a thermodynamic
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10. The Kelvin temperature is numerically expression which gives a relationship
equal to the _____ and may be measured by between internal energy, heat and work done.
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means of a _____ Work done on the system is positive, and
a) gas temperature, liquid thermometer work done by the system is negative. The
b) ideal gas temperature, gas thermometer standard unit of all these quantities is Joule.
c) ideal gas temperature, liquid thermometer
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d) none of the mentioned 3. During a fluid flow, the temperature is
developed due to________
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Answer: b a) Increase in density
Explanation: θ=T=273.16K . b) Change in pressure
c) Translational Kinetic Energy
TOPIC 1.7 FIRST LAW OF d) Fluid level
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THERMODYNAMICS - Answer: c
APPLICATION TO CLOSED Explanation: When there is a high rate of
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AND OPEN SYSTEMS - STEADY fluid flow, the molecules tend to collide with
AND UNSTEADY FLOW each other. At this state, the average
translational kinetic energy of the particles
PROCESSES. increases. The temperature developed due to
.B
Answer: c
Explanation: First law corresponds to the law Answer: b
of conservation of energy. It states that energy Explanation: The equation for kinetic energy
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can neither be created nor destroyed, but can is 0.5mv2, where m= mass and v= velocity.
be transformed from one form to the other. It This equation corresponds to 1.5 KT, where
follows the principle of heat transfer and K=Boltzmann’s constant and R= Gas
energy transfer. constant.
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Explanation: When the temperature measurement of energy in a thermodynamic
increases, the amount of molecular system. It is equal to the internal energy plus
interactions also increases. Using the equation the product of volume and pressure. Thus,
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from the first law of thermodynamics, giving a unit of Joule/kg.
internal energy also increases with the
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increase in temperature. Thus, increase in 9. Which among this is not an exothermic
enthalpy leads to an increase in internal reaction?
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energy. a) Combustion reaction
b) Neutralization reaction
6. Entropy occurs due to _______ c) Thermite reaction
a) Change in macroscopic variables d) Evaporating liquid water
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b) Volumetric changes only
c) Mass changes only Answer: d
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d) Temperature only Explanation: Exothermic reaction is a
reaction that releases energy by either light or
Answer: a heat. It is the opposite of endothermic
Explanation: Entropy is related to a number reactions. In this case, evaporating liquid
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of microscopic configurations. It can have water is an endothermic reaction.
some of the most specified macroscopic Endothermic reaction is a reaction in which
variables. These macroscopic variables the system absorbs heat from its
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SOURCE AND SINK. HEAT
ENGINE, REFRIGERATOR, Answer: a
HEAT PUMP. Explanation: This is the basic concept of
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cycle heat engine.
1. The first law of thermodynamics doesn’t
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tell us whether a thermodynamic process is 5. Boiler, turbine, condenser and pump
feasible or not. together constitute a heat engine.
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a) true a) true
b) false b) false
Answer: a Answer: a
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Explanation: The second law of Explanation: It is an example for a cyclic
thermodynamics provides criterion as to the heat engine.
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probability of a process.
6. In a heat engine cycle, which of the
2. According to Joule’s experiments, following process occurs?
a) heat can be completely converted into a) heat is transferred from furnace to boiler
b) work is produced in turbine rotor
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work
b) work can be completely converted into c) steam is condensed in condenser
heat d) all of the mentioned
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Answer: b
Explanation: Work transfer -> internal
7. The function of a heat engine cycle is to
energy increase -> heat transfer.
_____ continuously at the expense of _____
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a) small heat capacity
CYCLE, PERFORMANCE.
b) large heat capacity
c) infinite heat capacity CLAUSIUS INEQUALITY.
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d) none of the mentioned
1. Carnot cycle is a reversible cycle.
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Answer: c a) true
Explanation: Basic fact about TER. b) false
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10. Processes inside a thermal energy Answer: a
reservoir are quasi-static. Explanation: A reversible cycle is an ideal
a) true hypothetical cycle in which all processes are
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b) false reversible.
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Answer: a 2. A reversible cycle has following processes.
Explanation: The changes taking place in a) 4 isothermal processes
TER are very slow and minute. b) 4 adiabatic processes
c) 2 isothermal and 2 adiabatic processes
11. A TER which transfers heat to system is
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d) none of the mentioned
called ____ and one which receives heat is
called ____ Answer: c
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Answer: b Explanation: Efficiency=1-(Q2/Q1) and
Explanation: In reversed heat engine, the T2,T1 are temperatures at which heat is
magnitude of energy transfers remains same rejected and received.
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and only directions change.
9. For a reversible refrigerator, Coefficient of
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5. Example of reversed heat engine is Performance is given by
a) heat pump a) T2/(T1-T2)
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b) refrigerator b) T1/(T1-T2)
c) both of the mentioned c) T2/(T2-T1)
d) none of the mentioned d) T1/(T2-T1)
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Answer: c Answer: a
Explanation: Heat pump and refrigerator are Explanation: For a reversible refrigerator,
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the types of reversed heat engine. (Q1/Q2)=(T1/T2).
6. According to Carnot’s theorem, all heat 10. For a reversible heat pump, COP is given
engines operating between a given constant by
temperature source and sink, none has a a) T2/(T1-T2)
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higher efficiency than a reversible engine. b) T1/(T1-T2)
a) true c) T2/(T2-T1)
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b) false d) T1/(T2-T1)
Answer: a Answer: b
Explanation: This is the statement of Explanation: For a reversible heat pump we
Carnot’s theorem . have, (Q1/Q2)=(T1/T2).
.B
Answer: d
Explanation: This statement is a corollary of
Carnot’s theorem. 1. Which of the following is true?
a) for an isolated system, dS>=0
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Answer: d maximum
Explanation: For an isolated system which c) both of the mentioned
does not undergo any energy interaction with d) none of the mentioned
the surroundings, dQ=0 and also dS>=dQ/T.
Answer: c
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2. The entropy of an isolated system can Explanation: These two statements were
never ____ given by Clausius.
a) increase
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b) decrease 6. The entropy of an isolated system always
c) be zero ____ and becomes a ____ at the state of
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d) none of the mentioned equilibrium.
a) decreases, minimum
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Answer: b b) increases, maximum
Explanation: The entropy of an isolated c) increases, minimum
system always increases and remains constant d) decreases, maximum
only when the process is reversible.
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Answer: b
3. According to entropy principle, the entropy Explanation: If entropy of an isolated system
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of an isolated system can never decrease and varies with some parameter, then there is a
remains constant only when the process is certain value of that parameter which
reversible. maximizes the entropy.
a) true
7. Entropy principle is the quantitative
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b) false
statement of the second law of
Answer: a thermodynamics.
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Explanation: (T1+T2)/2 is the temperature Answer: a
when there is no delivery of work and Explanation: This statement can be proved
sqrt(T1*T2) is the temperature with by the second law of thermodynamics.
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maximum delivery of work.
4. Which of the following is an example of
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10. Which of the following processes exhibit low grade energy?
external mechanical irreversibility? a) heat or thermal energy
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a) isothermal dissipation of work b) heat from nuclear fission or fusion
b) adiabatic dissipation of work c) heat from combustion of fossil fuel
c) both of the mentioned d) all of the mentioned
d) none of the mentioned
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Answer: d
Answer: c Explanation: These are few examples of low
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Explanation: These processes exhibit grade energy.
external mechanical irreversibility.
5. The part of ____ available for conversion
is referred to ____
TOPIC 2.4 APPLICATIONS OF II a) high grade energy, available energy
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LAW. HIGH AND LOW GRADE b) low grade energy, available energy
ENERGY. c) low grade energy, unavailable energy
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Answer: c
a) minimum work output, available energy
Explanation: These are two types in which
b) maximum work output, available energy
the sources of energy can be divided into.
c) minimum work input, unavailable energy
2. Which of the following is an example of d) none of the mentioned
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a) true
8. The lowest practicable temperature of heat b) false
rejected is the
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a) given temperature Answer: a
b) 0K Explanation: The exergy is mainly lost due
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c) temperature of surroundings to irreversible heat transfer through a finite
d) 273K temperature difference.
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Answer: c 13. When considering a finite energy source,
Explanation: Work done and hence its working fluid expands,
efficiency will be maximum when heat is a) reversibly
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rejected at the temperature of surroundings. b) adiabatically
c) reversibly and adiabatically
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9. The available energy is known as ____ and d) none of the mentioned
the unavailable energy is known as ____
a) energy, exergy Answer: c
b) exergy, energy Explanation: For a finite energy source,
c) both are called exergy expansion of working fluid is reversibly and
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d) both are called energy adiabatically.
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Answer: b
Explanation: Rant was the one who coined TOPIC 2.5 AVAILABLE AND
these terms. NON-AVAILABLE ENERGY OF
A SOURCE AND FINITE BODY.
10. Whenever heat is transferred through a
.B
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work is impossible. Answer: a
a) true Explanation: U.E.=T0*(change in entropy).
b) false
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8. The lowest practicable temperature of heat
Answer: a rejected is the
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Explanation: This statement can be proved a) given temperature
by the second law of thermodynamics. b) 0K
T.
c) temperature of surroundings
4. Which of the following is an example of d) 273K
low grade energy?
a) heat or thermal energy Answer: c
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b) heat from nuclear fission or fusion Explanation: Work done and hence
c) heat from combustion of fossil fuel efficiency will be maximum when heat is
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d) all of the mentioned rejected at the temperature of surroundings.
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interaction)+dS(due to internal irreversibility)
12. Energy is said to be degraded each time it c) dS=-dS(due to external heat interaction)-
flows through a finite temperature difference.
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dS(due to internal irreversibility)
a) true d) dS=-dS(due to external heat
b) false interaction)+dS(due to internal irreversibility)
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Answer: a Answer: b
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Explanation: The exergy is mainly lost due Explanation: Total entropy increase of the
to irreversible heat transfer through a finite system is the sum of these two entropies.
temperature difference.
3. The entropy increase due to internal
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13. When considering a finite energy source, irreversibility is also called entropy
its working fluid expands, production or entropy generation.
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a) reversibly a) true
b) adiabatically b) false
c) reversibly and adiabatically
d) none of the mentioned Answer: a
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Explanation: This entropy is generated
Answer: c during the process within the system.
Explanation: For a finite energy source,
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expansion of working fluid is reversibly and 4. Which of the following statement is true?
adiabatically. a) if the isentropic process is reversible, it
must be adiabatic
b) if the isentropic process is adiabatic, it
TOPIC 2.6 ENERGY AND
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irreversibilities b) pdV+dW
c) both of the mentioned c) -pdV-dW
d) none of the mentioned d) pdV*dW
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Answer: c Answer: a
Explanation: These two processes increase Explanation: The lost work d(LW) indicates
the entropy of a closed system. the work that is lost due to irreversibility.
6. The amount of entropy generation is given 10. In an open system, there is a transfer of
by which of the following quantity?
a) S2+S1+∫(dQ/T) a) mass
b) S2-S1+∫(dQ/T) b) energy
c) S2-S1-∫(dQ/T) c) entropy
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d) none of the mentioned d) all of the mentioned
Answer: c Answer: d
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Explanation: Here (S2-S1) is the entropy Explanation: In an open system, there is a
change of the system and ∫(dQ/T) is the transfer of all these three quantities.
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entropy transfer.
11. The rate of entropy increase of the control
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7. Any thermodynamic process is volume ____ or ____ the net rate of entropy
accompanied by entropy generation. transfer to it.
a) true a) exceeds or is less than
b) false b) exceeds, is equal to
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c) is less than, or equal to
Answer: a d) none of the mentioned
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Explanation: This comes from the second
law. Answer: b
Explanation: The difference is the entropy
8. Which of the following statement is false? generated within the control volume due to
a) for a reversible process, entropy generation
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irreversibility.
is zero
b) the entropy generation does not depend on 12. Mass and energy are conserved quantities,
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the path the system follows but entropy is generally not conserved.
c) for an irreversible process, entropy a) true
generation is greater than zero b) false
d) none of the mentioned
Answer: a
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path that system follows. 13. The rate at which entropy is transferred
out must ____ the rate at which entropy
9. If the path A causes more entropy enters the control volume.
generation than path B, then a) be less than
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Answer: c
Answer: c Explanation: The difference is the rate of
Explanation: The amount of entropy entropy generated within the control volume
generation quantifies the intrinsic owing to irreversibilities.
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which is at 50°C to 25°C air. How much 1S2(gen2) = [Q(out,2) / T(air)] – [Q(out,1) /
entropy is generated in the chip? T(surf)] = (2/298.15) – (2/323.15) = 0.519
J/K.
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TOPIC 2.7 ENERGY BALANCE
AND ENTROPY GENERATION.
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1. The entropy of any closed system can
a) 4.19 J/K increase in which if the following way?
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b) 5.19 J/K a) by heat interaction in which there is
c) 6.19 J/K entropy transfer
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d) 7.19 J/K b) dissipative effects or internal
irreversibilities
Answer: c c) both of the mentioned
Explanation: C.V.1 Chip with surface at
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d) none of the mentioned
50°C, we assume chip state is constant.
U2 – U1 = 0 = 1Q2 – 1W2 = W(electrical,in) Answer: c
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– Q(out,1) Explanation: These two processes increase
S2 – S1 = 0 = – [Q(out,1)]/[T(surf)] + the entropy of a closed system.
1S2(gen1)
1S2(gen1) = [Q(out,1)]/[T(surf)] = 2. Entropy increase dS of the system can be
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W(electrical,in) / T(surf) expressed as
= 2/323.15 = 6.19 J/K. a) dS=dS(due to external heat interaction)-
dS(due to internal irreversibility)
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Answer: b
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b) false
Answer: b
Explanation: C.V.2 From chip surface at Answer: a
50°C to air at 25°C, assume constant state. Explanation: This entropy is generated
U2 – U1 = 0 = 1Q2 – 1W2 = Q(out,1) – during the process within the system.
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Q(out,2)
S2 – S1 = 0 = [Q(out,1) / T(surf)] – [Q(out,2) 4. Which of the following statement is true?
/ T(air)] + 1S2(gen2) a) if the isentropic process is reversible, it
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d) all of the mentioned Explanation: Entropy generation is not a
thermodynamic property and depends on the
Answer: d path that system follows.
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Explanation: An adiabatic process need not
be isentropic, since entropy can also increase 9. If the path A causes more entropy
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due to friction. generation than path B, then
a) path A is more irreversible than path B
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5. Lost work is given by b) path A involves more lost work
a) pdV-dW c) both of the mentioned
b) pdV+dW d) none of the mentioned
c) -pdV-dW
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d) pdV*dW Answer: c
Explanation: The amount of entropy
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Answer: a generation quantifies the intrinsic
Explanation: The lost work d(LW) indicates irreversibility of the process.
the work that is lost due to irreversibility.
10. In an open system, there is a transfer of
6. The amount of entropy generation is given which of the following quantity?
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by a) mass
a) S2+S1+∫(dQ/T) b) energy
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b) S2-S1+∫(dQ/T) c) entropy
c) S2-S1-∫(dQ/T) d) all of the mentioned
d) none of the mentioned
Answer: d
Answer: c Explanation: In an open system, there is a
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Explanation: Here (S2-S1) is the entropy transfer of all these three quantities.
change of the system and ∫(dQ/T) is the
entropy transfer. 11. The rate of entropy increase of the control
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entropy.
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out must ____ the rate at which entropy
enters the control volume.
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a) be less than
b) equal to a) 0.419 J/K
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c) exceed b) 0.519 J/K
d) none of the mentioned c) 0.619 J/K
d) 0.719 J/K
Answer: c
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Explanation: The difference is the rate of Answer: b
entropy generated within the control volume Explanation: C.V.2 From chip surface at
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owing to irreversibilities. 50°C to air at 25°C, assume constant state.
U2 – U1 = 0 = 1Q2 – 1W2 = Q(out,1) –
14. A chip dissipates 2 kJ of electric work and Q(out,2)
rejects it as heat transfer from its surface S2 – S1 = 0 = [Q(out,1) / T(surf)] – [Q(out,2)
which is at 50°C to 25°C air. How much
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/ T(air)] + 1S2(gen2)
entropy is generated in the chip? 1S2(gen2) = [Q(out,2) / T(air)] – [Q(out,1) /
T(surf)] = (2/298.15) – (2/323.15) = 0.519
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J/K.
Explanation: C.V.1 Chip with surface at Explanation: First law efficiency = output
50°C, we assume chip state is constant. energy / input energy.
U2 – U1 = 0 = 1Q2 – 1W2 = W(electrical,in)
– Q(out,1)
SE
energies available at different temperatures 6. Second law efficiency can also be given as
d) all of the mentioned a) 1 / ( first law efficiency * Carnot
efficiency)
Answer: d b) Carnot efficiency * first law efficiency
Explanation: It is the second law which c) Carnot efficiency / first law efficiency
M
provides a means of assigning a quality index d) first law efficiency / Carnot efficiency
to energy.
Answer: d
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3. With the concept of exergy available, Explanation: First law efficiency = W/Q1 =
which of the following is possible? (W/Wmax)*(Wmax/Q1) = second law
C
a) to analyse means of minimizing the efficiency * Carnot efficiency.
consumption of available energy to perform a
T.
given process 7. If work is involved, Amin= ____ and if
b) to ensure most efficient possible heat is involved, Amin= ____
conversion of energy a) w, Q(1+To/T)
c) both of the mentioned b) W, Q(1-To/T)
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d) none of the mentioned c) Q(1+To/T), W
d) Q(1-To/T), W
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Answer: c
Explanation: These statements tell us why Answer: b
the concept of exergy is so important. Explanation: This is because, Wmax=Q1(1-
To/T).
4. Second law efficiency is defined as
G
a) actual exergy intake / minimum exergy 8. If solar energy Qr is available at a reservoir
intake storage temperature of Tr and if quantity of
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b) minimum exergy intake / actual exergy heat Qa is transferred by the solar collector at
intake temperature Ta, then which of the following
c) actual exergy intake / maximum exergy is true?
intake a) first law efficiency = Qa/Qr
.B
d) maximum exergy intake / minimum exergy b) second law efficiency = exergy output /
intake exergy input
c) second law efficiency = (first law
Answer: b efficiency)*(1-To/Ta)/(1-To/Tr)
17
and second law efficiency = Qa*(1- b) fusion curve and sublimation curve
To/Ta)/Wi. c) vaporization curve and sublimation curve
d) fusion curve and vaporization curve and
10. Both first law efficiency and second law sublimation curve
efficiency indicate how effectively the input
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has been converted into the product. Answer: d
a) true Explanation: At triple point, all these three
b) false curves meet.
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Answer: a 2. The slopes of sublimation and vaporization
C
Explanation: First law of efficiency does this curves for all substances are
on energy basis and second law efficiency a) negative
T.
does it on exergy basis. b) positive
c) zero
11. For proper utilization of exergy, it is d) none of the mentioned
desirable to make first law efficiency ____
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and the source and use temperatures should Answer: b
____ Explanation: This is true for all substances.
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a) as close to unity, be different
b) as close to unity, match 3. The slope of the fusion curve for water is
c) as close to zero, match a) negative
d) as close to zero, be different b) positive
c) zero
G
Answer: b d) none of the mentioned
Explanation: If first law efficiency is close to
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function of pressure.
PURE SUBSTANCE AND a) true
STEAM POWER CYCLE b) false
-R
Answer: a
TOPIC 3.1 FORMATION OF Explanation: The slope of the fusion curve is
STEAM AND ITS small.
SE
1. Which of the following curves meet at pressure, it gets transformed into vapour
triple point? directly
a) fusion curve and vaporization curve d) all of the mentioned
Answer: d c) zero
Explanation: The solid CO2 absorbs the d) infinity
latent heat of sublimation from the
surroundings which gets cooled. Answer: c
Explanation: As pressure increases, there is a
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6. The equation which forms the basis of the decrease in Hg-Hf and at critical pressure its
Mollier diagram is value becomes zero.
a) Tds=-dh+vdp
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b) Tds=dh+vdp 10.In the Mollier diagram, the constant
c) Tds=dh-vdp pressure lines diverge from one another.
C
d) none of the mentioned a) true
b) false
T.
Answer: c
Explanation: This equation form the basis of Answer: a
the h-s diagram of a pure substance also Explanation: As the pressure increases, the
called the Mollier diagram. saturation temperature also increases,
O
increasing the slope of the isobar.
7. Which of the following statements is true?
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a) the slope of an isobar on h-s coordinates is
equal to the absolute saturation temperature at
TOPIC 3.2 P-V-T SURFACE.
that pressure
b) is the temperature remains constant, the 1. Which of the following is a property of a
pure substance?
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slope will also remain constant
c) if the temperature increases, the slope of a) it has constant chemical composition
the isobar will also increase throughout its mass
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enthalpy of the saturated vapour and Hf is the volume of water decreases which is a
specific enthalpy of the saturated water. peculiarity of water.
M
Explanation: For example, water at 0 degree
Celsius and at 100 degree Celsius. 8. Which of the following statement is true?
a) to the left of saturated solid line is the solid
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4. In which of the following state does water region
exist? b) between saturated solid line and saturated
C
a) saturated solid state liquid line with respect to solidification there
b) saturated liquid state exists the solid-liquid mixture region
T.
c) saturated vapour state c) between two saturated liquid lines is the
d) all of the mentioned compressed liquid region
d) all of the mentioned
Answer: d
O
Explanation: Water exists in these states at 0 Answer: d
degree Celsius and at 100 degree Celsius. Explanation: These statements come from
SP
the p-V diagram for a pure substance.
5. Which of the following exists in a p-V
diagram for water? 9. The isotherm passing through the critical
a) saturated solid line point is called the critical isotherm.
b) saturated liquid lines
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a) true
c) saturated vapour line b) false
d) all of the mentioned
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Answer: a
Answer: d Explanation: At critical point, all the
Explanation: The p-V diagram for water has quantities like pressure, temperature and
all these three lines. volume attain their critical values.
.B
6. The triple point is a line on the p-V 10. The greater the temperature, the ____ is
diagram, where all the three phases, solid, the vapour pressure.
liquid and gas exist. a) lower
17
a) true b) higher
b) false c) depends on the substance
d) none of the mentioned
Answer: a
-R
a) the substance cannot exist in the liquid 11. Phase change occurs at
phase a) constant pressure
b) the substance when heated transforms from b) constant temperature
solid to vapour c) constant pressure and temperature
C
Answer: c Answer: a
Explanation: For phase change, pressure and Explanation: This is arbitrarily chosen and
temperature must be constant like water at 0 form the basic assumptions for steam tables.
degree Celsius and at 100 degree Celsius.
4. When a liquid and its vapour are in
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12. Which of the following statement is true? equilibrium at a certain pressure and
a) saturation temperature is a function of temperature, then which of the following is
pressure required to identify the saturation state.
O
b) saturation pressure is a function of a) pressure
temperature b) temperature
C
c) both of the mentioned c) both pressure and temperature
d) none of the mentioned d) pressure or temperature
T.
Answer: c Answer: d
Explanation: At saturation temperature, a Explanation: If one of the quantity is given,
pure liquid transforms into vapour and at then other gets fixed.
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saturation pressure, the liquid boils.
5. Saturated liquid or the saturated vapour has
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how many independent variables?
TOPIC 3.3 USE OF STEAM a) one
TABLE AND MOLLIER CHART. b) two
c) three
G
1. The properties of water are arranged in the d) none of the mentioned
steam tables as functions of
a) pressure Answer: a
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Answer: c
Explanation: The properties of water are is normally accurate.
arranged in steam tables as functions of both a) true
pressure and temperature. b) false
17
b) 0 provided.
c) -1
d) infinity 7. For a liquid-vapour mixture, which of the
following can give us all the properties of the
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Answer: b mixture?
Explanation: This value is arbitrarily chosen. a) p or t and the quality of the mixture are
given
3. The entropy of saturated water is chosen to b) p or t and any one of the property is given
C
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d) none of the mentioned
8. When does a vapour become superheated?
a) when the temperature of vapour is less than Answer: c
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the saturation temperature at given pressure Explanation: This is the reason why
b) when the temperature of vapour is more properties are taken from the saturation tables
C
than the saturation temperature at given at the temperature of the compressed liquid.
pressure
T.
c) when the temperature of vapour is equal to 12. Which of the following statement is true?
the saturation temperature at given pressure a) a subcooled liquid is one which is cooled
d) none of the mentioned below its saturation temperature at a certain
pressure
O
Answer: b b) subcooling is the difference between the
Explanation: For a superheated vapour, saturation temperature and the actual liquid
SP
temperature of vapour must be greater than temperature
the saturation temperature. c) both of the mentioned
d) none of the mentioned
9. The superheat or degree of superheat is
G
given by Answer: c
a) difference between the temperature of Explanation: This is what a subcooled liquid
saturated liquid and saturation temperature means.
LO
Answer: d Answer: b
Explanation: The heat rate in terms of Explanation: With reheat, the area under the
M
kJ/kWh is given by the expression, curve increases in comparison to what it was
Heat Rate = (3600/n) kJ/kWh without reheat. Hence, Net Work output of
where, n = efficiency. the plant increases.
O
3. What is the effect of reheat pressure on 6. Which of the following problems are posed
C
mean temperature of heat addition Tml? by increasing the number of reheats?
a) Reheat pressure is directly proportional to a) Cost & Fabrication problems arise
T.
Tml b) Heat transfer problems arise
b) Reheat pressure is inversely proportional to c) Frictional losses arise
Tml d) None of the mentioned
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c) Reheat pressure is equal to Tml Answer: a
d) Tml is independent of reheat pressure Explanation: Higher the number of Reheats,
SP
still higher steam pressures could be used, but
Answer: a mechanical stresses increase at a higher
Explanation: As cycle efficiency is reduced proportion than the increase in pressure,
with a decrease in reheat pressure. Hence, the because of the prevailing high temperature.
G
mean temperature of heat addition also The cost & fabrication difficulties will also
decreases. increase.
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4. Why is the steam not allowed to expand 7. What is the effect of decrease of reheat
deep into the two phase region before it is pressure on the quality of steam at turbine
taken to reheating? exhaust?
a) to control flow rate a) decreases
.B
Answer: c Answer: b
Explanation: The steam is not allowed to Explanation: For too low a reheat pressure,
expand deep into the two phase region before the exhaust steam may even be in the
it is taken to reheating, because the moisture superheated state which isn’t good.
-R
a) decreases
b) increases Answer: c
Explanation: The efficiency increases as the
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a) 0.99 decrease in Vg-Vf and at critical point its
b) 0.77 value becomes zero.
c) 0.66
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d) 0.88 3. Above the critical point, the isotherms are
continuous curves.
C
Answer: d a) true
Explanation: The dryness fraction of the b) false
T.
exhaust steam is in the range of 0.86-0.88 for
modern turbines. Answer: a
Explanation: These continuous curves
10. For pressure ratio = 1, efficiency = 0, approach equilateral hyperbolas at large
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then? volumes and low pressures.
a) reheat is used
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b) reheat is not used 4. A rigid tank contains 50 kg of saturated
c) only reheat is used liquid water at 90°C. Determine the pressure
d) none of the mentioned in the tank and the volume of the tank.
a) 0.0518 m3
Answer: b
G
b) 0.0618 m3
Explanation: There cannot be any reheat
cycle employed when the cycle efficiency is c) 0.0718 m3
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Answer: a
TOPIC 3.5 APPLICATION OF I Explanation: P = [email protected] C =
AND II LAW FOR PURE 70.183 kPa
.B
Answer: d
a) two Explanation: T = [email protected] =
b) one 138.86°C
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6. A rigid tank contains 10 kg of water at 9. An 80 litre vessel contains 4 kg of R-134a
90°C. If 8 kg of the water is in the liquid form at a pressure of 160 kPa. Determine the
and the rest is in the vapour form, determine quality.
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the pressure in the tank. a) 0.127
a) 60.183 kPa b) 0.137
b) 70.183 kPa c) 0.147
C
c) 80.183 kPa d) 0.157
d) 90.183 kPa
T.
Answer: d
Answer: b Explanation: v = V/m = 0.080 m3/4 kg =
Explanation: P = [email protected]°C = 0.02 m3/kg
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70.183 kPa.
@ 160kPa, vf = 0.0007437 m3/kg; vg =
7. A rigid tank contains 10 kg of water at 0.12348 m3/kg.
SP
90°C. If 8 kg of the water is in the liquid form vf < v < vg
and the rest is in the vapour form, determine x = (v –vf)/ vfg = 0.157.
the volume of the tank.
10. An 80 litre vessel contains 4 kg of R-134a
a) 1.73 m3
G
at a pressure of 160 kPa. Determine the
b) 2.73 m3 volume occupied by the vapour phase.
c) 3.73 m3 a) 0.0775 m3
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d) 4.73 m3 b) 0.0575 m3
Answer: d c) 0.0975 m3
Explanation: P = [email protected]°C = d) 0.0375 m3
.B
70.183 kPa
Answer: a
@ 90°C, vf = 0.001036 m3/kg and vg =
Explanation: v = V/m = 0.080 m3/4 kg =
2.3593 m3/kg
17
0.02 m3/kg
V = Vf + Vg = mf vf + mg vg = 4.73 m3.
@ 160kPa, vf = 0.0007437 m3/kg; vg =
8. An 80 litre vessel contains 4 kg of R-134a 0.12348 m3/kg
at a pressure of 160 kPa. Determine the vf < v < vg
-R
c) -15.60°C
d) -19.60°C 11. Determine the specific volume of R-134a
at 1 MPa and 50°C, using ideal gas equation
Answer: c of state.
Explanation: v = V/m = 0.080 m3/4 kg = a) 0.022325 m3/kg
C
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Explanation: v = RT/P = (0.0815 kJ/kg.K)*
cooling water is low, which increases
(323 K)/(1000 kPa)
Condenser’s efficiency.
= 0.026325 m3/kg.
O
4. Rankine cycle comprises of ___________
TOPIC 3.6 IDEAL AND ACTUAL a) two isentropic processes and two constant
C
volume processes
RANKINE CYCLES b) two isentropic processes and two constant
T.
pressure processes
1. What is the unit of Heat rate? c) two isothermal processes and two constant
a) kJ/KW pressure processes
b) KW/kJ d) none of the mentioned
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c) kJ
d) KW Answer: b
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Explanation: Rankine cycle is a reversible
Answer: a cycle which have two constant pressure and
Explanation: Heat rate is the rate of input two constant temperature processes.
required to produce unit shaft output.
5. In Rankine cycle, the work output from the
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2. Rankine cycle operating on low pressure turbine is given by ___________
limit of p1 and high pressure limit of p2 a) change of internal energy between inlet and
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___________ outlet
a) has higher thermal efficiency than the b) change of enthalpy between inlet and
Carnot cycle operating between same outlet
pressure limits c) change of entropy between inlet and outlet
b) has lower thermal efficiency than Carnot
.B
Explanation: Area under P-V curve for improvement of efficiency of Rankine cycle
Rankine will be more as compared to Carnot in a Thermal Power Plant?
cycle. a) reheating of steam at intermediate stage
b) regeneration use of steam for heating
SE
temperature, by reducing the addition of heat 10. A simple Rankine cycle operates the
from the Boiler/fuel source at the relatively Boiler at 3 MPa with an outlet temperature of
low feedwater temperatures that would exist 350°C and the Condenser at 50 kPa.
without regenerative feedwater heating. Assuming ideal operation and processes, what
is the thermal efficiency of this cycle?
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7. Match the following: a) 7.7
b) 17.7
i) Boiler A. reversible a
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c) 27.7
diabatic expansion of steam
ii) turbine B. constant pre d) 37.7
ssure heat heat addition
C
iii) Condenser C. reversible a Answer: c
diabatic compression Explanation: Fixing the states; h1 = 340.5
T.
iv) pump D. constant pre kJ/kg, h2 = h1 + v1 (P2 – P1) = 343.5 kJ/kg,
ssure heat rejection
h3 = 3115.3 kJ/kg, s3 = 6.7428 kJ/kg – K, x4
a) i-B ii-A iii-D iv-C = 0.869, and h4 = 2343.9 kJ/kg. Thus, η = 1 –
Qout / Qin = 1 – (h4 – h1) / (h3 – h2) =
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b) i-A ii-C iii-D iv-A
27.7%.
c) i-B ii-D iii-C iv-A
d) i-A ii-D iii-B iv-C
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11. A simple Rankine cycle produces 40 MW
of power, 50 MW of process heat and rejects
Answer: a
60 MW of heat to the surroundings. What is
Explanation: Working fluid in Rankine cycle
the utilization factor of this co generation
undergoes 4 processes, expansion in turbine,
G
cycle neglecting the pump work?
heat addition in Boiler, heat rejection in
a) 50
Condenser and compression in pump.
b) 60
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Answer: c
Explanation: The TIT(Turbine Inlet
Temperature) is of the range 500-570C. TOPIC 3.7 CYCLE
IMPROVEMENT METHODS -
-R
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high, the reheating of steam is adopted. Explanation: Their difference is known as
the terminal temperature difference of heater.
2. Why both reheating and regeneration is
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used together? 6. Which of the following is true for an open
a) the effect of reheat alone on efficiency is heater?
C
very small a) it is simple, has low cost and low heat
b) regeneration has a marked effect on transfer capacity
T.
efficiency b) a pump is required at each heater
c) both of the mentioned c) both of the mentioned
d) none of the mentioned d) none of the mentioned
O
Answer: c Answer: b
Explanation: Thus a modern steam power Explanation: The open heater has high heat
SP
plant has both reheating and regeneration. transfer capacity.
3. How many types of feedwater heaters are 7. Deaerator is a type of open heater.
present? a) true
a) one b) false
G
b) two
c) three Answer: a
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heater?
4. Which of the following statement is true? a) it requires a single pump regardless of the
a) open heater is also known as contact-type number of heaters
17
heater b) it is costly
b) in an open type heater the extracted or bled c) both of the mentioned
steam is allowed to mix with the feedwater d) none of the mentioned
c) in a closed heater, the fluids are not
-R
Answer: b Answer: a
Explanation: The cycle efficiency varies Explanation: The major exergy destruction
M
according to the number of heaters. due to irreversibility takes place in the steam
generation.
10. If n heaters are used, the greatest gain in
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efficiency occurs when overall temperature
rise is ____ times the difference between
C
condenser and boiler saturation temperatures.
a) (n-1) / n UNIT IV IDEAL AND
T.
b) (n+1) / n
c) n / (n-1)
REAL GASES,
d) n / (n+1) THERMODYNAMIC
RELATIONS
O
Answer: d
Explanation: This gives us the greatest gain
SP
in efficiency. TOPIC 4.1 PROPERTIES OF
11. The efficiency gain follows the law of IDEAL GAS- IDEAL AND REAL
diminishing return with the increase in the GAS COMPARISON-
number of heaters. EQUATIONS OF STATE FOR
G
a) true IDEAL AND REAL GASES-
b) false
REDUCED PROPERTIES.
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Answer: a
Explanation: This is because the cycle 1. For the ideal gas equation, what
efficiency is proportional to the temperature assumptions are made?
rise of feedwater.
.B
c) at low pressure and temperature 6. Real gases conform more closely with the
d) at high pressure and temperature van der Waals equation of state than the ideal
gas equation of state.
Answer: b a) true
Explanation: At low pressure and high b) false
M
temperature, the intermolecular attraction and
the volume of the molecules compared to the Answer: a
total volume of the gas are not of much Explanation: This happens particularly at
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significance. higher pressures.
C
3. The real gases deviate from the ideal gas 7. The following also gave two-constant
equation when the pressure increases. equations of state.
T.
a) true a) Berthelot
b) false b) Dieterici
c) Redlich-Kwong
Answer: a d) all of the mentioned
O
Explanation: With increase in pressure, the
intermolecular forces of attraction and Answer: d
SP
repulsion increase, and also the volume of the Explanation: These are also two-constant
molecules becomes appreciable compared to equations of state other than the van der
the gas volume. Waals equation.
c) (RT/pv)2
c) (p-a/(v2))(v+b)=RT
d) (pv/RT)2
d) (p+a/(v2))(v-b)=RT
Answer: b
Answer: d
.B
the molecules
b) the term a/(v2) is called the force of Answer: c
cohesion Explanation: For an ideal gas, pv=RT hence
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Answer: d behaviour.
Explanation: These coefficients were also a) true
introduced by van der Waals. b) false
M
TOPIC 4.2 COMPRESSIBILITY
a) (p+a/(v2))(v+b)=RT
FACTOR-.PRINCIPLE OF
b) (p-a/(v2))(v-b)=RT
CORRESPONDING STATES. -
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c) (p-a/(v2))(v+b)=RT
GENERALISED
d) (p+a/(v2))(v-b)=RT
C
1. For the ideal gas equation, what Answer: d
assumptions are made? Explanation: The two correction terms were
T.
a) there is little or no attraction between the introduced by van der Waals.
molecules of the gas
b) the volume occupied by the molecules is 5. Which of the following statement is true
O
negligibly small compared to the volume of about the correction terms?
the gas a) the coefficient a was introduced to account
SP
c) both of the mentioned for the existence of mutual attraction between
d) none of the mentioned the molecules
b) the term a/(v2) is called the force of
Answer: c cohesion
Explanation: The ideal gas equation pv=RT
G
c) the coefficient b was introduced to account
is established from the postulates of the for the volumes of the molecules and is
kinetic theory of gases considering these two known as co-volume
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3. The real gases deviate from the ideal gas 7. The following also gave two-constant
equation when the pressure increases. equations of state.
a) true a) Berthelot
b) false b) Dieterici
C
c) Redlich-Kwong
Answer: a d) all of the mentioned
Explanation: With increase in pressure, the
intermolecular forces of attraction and
Answer: d Answer: a
Explanation: These are also two-constant Explanation: Compressibility = PV/nRT, but
equations of state other than the van der for ideal gases PV = nRT, => Compressibility
Waals equation. = 1.
M
8. Compressibility factor Z is given by 2. Which of the following is true about
a) RT/pv compressibility of real gases?
b) pv/RT a) Z = 1
O
c) (RT/pv)2 b) Z < 1
c) Z > 1
d) (pv/RT)2
C
d) Both Z < 1 and Z > 1
Answer: b View answer
T.
Explanation: This ratio is known as
Answer: d
compressibility factor.
Explanation: For any value of
compressibility except 1, the gas is real.
O
9. For an ideal gas, Z has the value
a) 0
3. What is the pressure of CO2 gas with
b) 2
SP
c) 1 compressibility z = 0.8, if the ideal gas
d) infinity pressure of CO2 is 10 Pa, all other variables
are same?
Answer: c a) 5
G
Explanation: For an ideal gas, pv=RT hence b) 8
Z=1. c) 10
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d) 14
10. The magnitude of Z at a particular View answer
pressure and temperature indicates the extent
of deviation of the gas from the ideal gas Answer: b
behaviour. Explanation: Pressure of CO2 = 0.8*10 = 8
.B
a) true Pa.
b) false
4. What is the pressure of H2 with
17
Answer: a
compressibility 0.6, molar volume 5
Explanation: This is a basic fact about the
compressibility factor. liter/mole at 27oC?
a) 2.9 atm
b) 5.4 atm
-R
d) 4
5. At what temperature, does SO2 with
View answer
compressibility 2 has pressure 5 atm and
molar volume 10 mole/s?
M
c) 39.6
d) 44.1
Answer: b View answer
Explanation: T = PV/zR = 5*10/(2*0.0821)
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= 304.5 K. Answer: a
Explanation: z = PM/dRT =
C
6. What is the compressibility factor of water 500*16/(10*0.0821*300) = 32.5.
with density 1 g/liter at 27oC and 1 atm?
T.
a) 0.25 10. What is the compressibility of neon
b) 0.59 (molar mass = 20) with density 20 g/liter at
c) 0.73 27oC and 100 atm?
d) 0.91
O
a) 2.1
View answer b) 3.5
c) 4
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Answer: c d) 6.8
Explanation: z = PM/dRT = View answer
1*18/(1*0.0821*300) = 0.73.
Answer: c
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7. What is the compressibility factor of a Explanation: z = PM/dRT =
liquid of molar mass 90 g and density 10 100*20/(20*0.0821*300) = 4.
g/liter at 27oC and 2 atm?
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View answer
b) 51.7oC
Answer: d c) 76.9oC
d) 103.5oC
17
Explanation: z = PM/dRT =
2*90/(10*0.0821*300) = 0.73. View answer
Answer: d c) 40.6 g
Explanation: P = 5*5*0.0821*300/10 = 61.5 d) 50.8 g
atm. View answer
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13. What is the volume of 21 g of propane (z
then z may be expressed as a function of x
= 1.9) at 1 atm and 27oC?
and y as, dz=Mdx+Ndy .
a) 23.4 liter
a) true
O
b) 37.5 liter
b) false
c) 42.1 liter
d) 59.6 liter
C
Answer: a
View answer Explanation: Here, M,N and z are functions
of x and y.
T.
Answer: a
Explanation: V = 1.9*0.5*0.0821*300/1 = 2. A pure substance which exists in a single
23.4 liter. phase has ____ independent variables.
O
a) zero
14. 1 mole of cyclohexane (z = 1.2) is filled
b) one
in a container at 27oC and 4 atm, what is the
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c) two
volume of container? d) three
a) 3.8 liter
b) 4.4 liter Answer: c
c) 5.6 liter Explanation: Of all the quantities, any one
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d) 7.4 liter can be expressed as a function of any two
View answer others.
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d) (∂V/∂T) = -(∂S/∂p) thermodynamic variables, p,V and T.
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Explanation: The correct equation is (∂T/∂p) entropy to be a function of T and V and also
= (∂V/∂S). of T and p.
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a) true
6. The condition for exact differential is b) false
T.
a) (∂N/∂y) = (∂M/∂x)
b) (∂M/∂y) = (∂N/∂x) Answer: a
c) (∂M/∂y) = -(∂N/∂x) Explanation: For first TdS equation, we
d) all of the mentioned assume entropy as a function of T and V and
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for second TdS equation, we assume entropy
Answer: b as a function of T and p .
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Explanation: This is the condition for perfect
or exact differential and here M and N are the
functions of x and y.
TOPIC 4.5 JOULE-THOMSON
COEFFICIENT, CLAUSIUS
7. The first TdS equation is CLAPEYRON EQUATION,
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a) TdS=Cv*dT + T(∂T/∂p)dV PHASE CHANGE PROCESSES.
b) TdS=Cv*dT – T(∂p/∂T)dV
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c) TdS=Cv*dT + T(∂p/∂T)dV
d) TdS=Cv*dT – T(∂T/∂p)dV 1. During phase transitions like vaporization,
melting and sublimation
Answer: c a) pressure and temperature remains constant
Explanation: This equation comes when b) volume and entropy changes
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d) dT/dp = l / T(vf-vi) d) p = 101.325 exp (88/R)(1-Tb/T)
Answer: b Answer: d
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Explanation: Here vf is the final specific Explanation: Here Tb is the boiling point at
volume and vi is the initial specific volume 1.013 bar and this relation comes from the
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and l is the latent heat. latent heat of vaporization and Trouton’s rule.
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4. Water ____ on melting and has the fusion 8. At the triple point, l(sublimation) =
curve with a ____ slope. l(vaporization) – l(fusion).
a) contracts, negative a) true
b) contracts, positive b) false
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c) expands, negative
d) expands, positive Answer: b
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Explanation: At the triple point,
Answer: a l(sublimation) = l(vaporization) + l(fusion),
Explanation: Unlike other substances which where l is the latent heat.
expands on melting, water contracts on
9. The slope of sublimation curve is ____ the
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melting and hence the slope of the fusion
curve is negative. slope of the vaporization curve at triple point.
a) equal to
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Answer: b Answer: d
Explanation: This is the statement of Explanation: This is the expression for
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b) 0.0098 kPa -13 442 kPa/K
c) 0.0068 kPa at P = 30 MPa, T = 0.01 + (30 000-0.6)/(-13
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d) 0.0088 kPa 442) = = -2.2°C.
Answer: b
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Explanation: The lowest temperature for R-
12 is -90°C, so it must be extended to -140°C
UNIT V GAS MIXTURES
T.
using the Clapeyron equation.
at T1= -90°C = 183.2 K, P1 = 2.8 kPa
R = 8.3145/120.914 = 0.068 76 kJ/kg K AND PSYCHROMETRY
ln P/P1 = (hfg/R)(T-T1)/(T*T1)
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= (189.748/0.068 76)[(133.2 – 183.2)/(133.2 TOPIC 5.1 MOLE AND MASS
× 183.2)] = -5.6543
FRACTION, DALTON'S AND
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P = 2.8 exp(-5.6543) = 0.0098 kPa.
AMAGATS LAW.
12. Ice (solid water) at −3°C and 100 kPa, is
compressed isothermally until it becomes 1. The expression which represents the
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liquid. Find the required pressure. pressure exerted by a gas is
a) 20461 kPa a) nVRT
b) 30461 kPa b) nRT/V
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Explanation: Water, triple point T = 0.01°C, Explanation: This expression comes from the
P = 0.6113 kPa, vf = 0.001 m^3/kg, gas equation where V is the volume occupied
hf = 0.01 kJ/kg, vi= 0.001 0908 m^3/kg, hi = by the gas at temperature T.
-333.4 kJ/kg
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dPif/dT = (hf – hi)/[(vf – vi)T] = 2. The expression nRT/V is called the partial
333.4/(-0.0000908 × 273.16) = -13442 kPa/K pressure of a gas.
∆P = (dPif/dT)*∆T = -13442(-3 – 0.01) = a) true
40460 kPa b) false
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Answer: c Answer: d
Explanation: According to the Dalton’s law Explanation: these relations come from the
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of partial pressures, p=p1+p2+p3+…..+pc. Dalton’s law and the gas equation.
4. Which of the following relation is correct? 8. The total entropy of a mixture of gases is
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a) mole fraction of the Kth gas = moles of the the ____ of the partial entropies.
Kth gas / total number of moles of gas a) average
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b) partial pressure of Kth gas = (mole fraction b) weighted mean
of the Kth gas)*(sum of the partial pressures) c) sum
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c) sum of mole fractions of all the gases is d) difference of the highest and the lowest
unity
d) all of the mentioned Answer: c
Explanation: This is given by the Gibbs
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Answer: d theorem.
Explanation: All these statements come from
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the Dalton’s law of partial pressures. 9. When gases which are at equal pressure
and temperature are mixed adiabatically
5. The gas constant of the mixture is the ____ without work, then
of the gas constants of the components. a) internal energy of the gaseous system
a) average remains constant
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b) weighted mean b) heat transfer of the gaseous system remains
c) sum constant
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d) difference of the highest and the lowest c) entropy of the gaseous system remains
constant
Answer: b d) all of the mentioned
Explanation: It can be found from the
Dalton’s law and gas equation. Answer: a
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PSYCHROMETRIC CHARTS. in summer air conditioning.
a) true
b) false
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1. Which of the following statement is true?
a) the chart is plotted for pressure equal to Answer: a
760mm Hg
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Explanation: This is a common process in
b) the constant wbt line represents adiabatic summer air conditioning.
saturation process
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c) the constant wbt line coincides with 6. Heating and humidification is done in
constant enthalpy line a) summer air conditioning
d) all of the mentioned b) winter air conditioning
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c) both of the mentioned
Answer: d d) none of the mentioned
Explanation: All these come from the
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psychrometric chart. Answer: b
Explanation: This is opposite to summer air
2. In sensible heating or cooling, conditioning.
a) work done remains constant
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b) dry bulb temperature or air remains 7. Which of the following is an absorbent?
constant a) silica gel
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be humidified. dehumidification.
4. Air can be cooled and dehumidified by 9. In adiabatic evaporative cooling, heat
a) circulating chilled water in tube across air transfer between chamber and surroundings is
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flow ____
b) placing evaporator coil across air flow a) zero
c) spraying chilled water to air b) high
d) all of the mentioned
c) low Answer: b
d) none of the mentioned Explanation: Complete dry air does not exist
in nature.
Answer: a
Explanation: No heat transfer takes place 3. Which of the following is true?(here
M
between chamber and surroundings in pa=partial pressure of dry air, pw=partial
adiabatic evaporative cooling. pressure of water vapour, p=atmospheric
pressure)
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10. The cooling tower uses the phenomenon a) p=pw
of evaporative cooling to cool warm water b) p=pa
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above the dbt of air. c) p=pw + pa
a) true d) all of the mentioned
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b) false
Answer: c
Answer: b Explanation: This comes by Dalton’s law of
Explanation: The cooling tower uses the partial pressures.
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phenomenon of evaporative cooling to cool
warm water below the dbt of air. 4. In a mixture of dry air and water vapour,
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a) mole fraction of dry air = pa/p
11. Cooling towers are rated in terms of b) mole fraction of water vapour = pw/p
a) approach c) both of the mentioned
b) range d) none of the mentioned
c) both of the mentioned
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d) none of the mentioned Answer: c
Explanation: This comes from the concepts
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Answer: d
1. Dry air consists of Explanation: Mostly partial pressure of water
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Answer: b
2. Complete dry air exists in nature. Explanation: Here pw is the partial pressure
a) true of water vapour and ps is the saturation
b) false
pressure of pure water at same temperature of 11. The degree of saturation varies between
mixture. -1 and 0.
a) true
7. For saturated air, relative humidity is 0%. b) false
a) true
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b) false Answer: b
Explanation: The degree of saturation varies
Answer: b between 0 and 1.
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Explanation: For saturated air, relative
humidity is 100%. 12. Which of the following statement is true?
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a) dew point temperature is the temperature at
8. If water is injected into a container with which water vapour starts condensing
has unsaturated air,
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b) dry bulb temperature is recorded by
a) water will evaporate thermometer with dry bulb
b) moisture content of air will decrease c) wet bulb temperature is recorded by
c) pw will decrease thermometer when bulb is covered with a
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d) all of the mentioned cotton wick which is saturated with water
d) all of the mentioned
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Answer: a
Explanation: The moisture content of air will Answer: d
increase and pw will increase. Explanation: These are the definitions of
dew point temperature, dry bulb temperature
9. Humidity ratio is given by the ratio of
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and wet bulb temperature.
a) (mass of dry air per unit mass of water
vapour)^2 13. The wet bulb temperature is the ____
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b) 1/(mass of dry air * mass of water vapour) temperature recorded by moistened bulb.
c) water vapour mass per unit mass of dry air a) lowest
d) mass of dry air per unit mass of water b) highest
vapour c) atmospheric
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temperature.
10. The degree of saturation is the ratio of
a) (saturated specific humidity / actual 14. At any dbt, the ____ the difference of wbt
specific humidity)^2 reading below below dbt, ____ is the amount
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15. When unsaturated air flows over a sheet 3. When humidity ratio of air ____ air is said
of water in an insulated chamber to be dehumidified.
a) specific humidity of air decreases a) increases
b) the water evaporates b) decreases
c) both air and water are cooled during c) remains constant
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evaporation d) none of the mentioned
d) all of the mentioned
Answer: b
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Answer: a Explanation: when it increases, air is said to
Explanation: The specific humidity of air be humidified.
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increases during this process.
4. Air can be cooled and dehumidified by
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a) circulating chilled water in tube across air
TOPIC 5.4 PSYCHROMETRIC flow
PROCESS - ADIABATIC b) placing evaporator coil across air flow
SATURATION, SENSIBLE c) spraying chilled water to air
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HEATING AND COOLING, d) all of the mentioned
HUMIDIFICATION,
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Answer: d
DEHUMIDIFICATION, Explanation: These are the ways of cooling
EVAPORATIVE COOLING AND and dehumidifying air.
ADIABATIC MIXING.
5. Cooling and dehumidification of air is done
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in summer air conditioning.
1. Which of the following statement is true? a) true
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M
c) dbt of air increases above the dbt of air.
d) all of the mentioned a) true
b) false
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Answer: d
Explanation: This process is called chemical Answer: b
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dehumidification. Explanation: The cooling tower uses the
phenomenon of evaporative cooling to cool
9. In adiabatic evaporative cooling, heat
T.
warm water below the dbt of air.
transfer between chamber and surroundings is
____ 11. Cooling towers are rated in terms of
a) zero a) approach
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b) high b) range
c) low c) both of the mentioned
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d) none of the mentioned d) none of the mentioned
Answer: a Answer: c
Explanation: No heat transfer takes place Explanation: These are the two factors
considered.
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