(903113639 TREL - PiO-4q| &- Butyl Alcohol (TBA) is an inportané octane enchancer Hat 1s used to replace lead addiBves in gasoline. TBA was prodvcect by He liquid phase hydra- normally + | Dianti Lita Les tari tion (W) oF Bobutene C1) over an Ambertyst =F catlgst Hee ryctem nalbphase mainte oF hydrocarbon, water , ard solve cabmlgsts. However, Ht te oF cosolvents or excess TRA cm achieve reasonabce miscibility. The renchon mechanism 13 believed to be bas = ls wts = Ws W.S + 1.5% TBA. SHS TRA.s =* TBA+S i Derive a rate lms assuming ~ o A. The tepace reaction IS rate - limi tn b. The sArorpton oF isobutene iS limiting . c- the racton follows Eley- Ridral Lineker listwW —>7TBA-s and the curface reachon is Kmiting 4. Lobviene (1) and water (w) are adforbed on Mippereat BtFS- [4 eS wtS2 = WwW. Ss, _ TBA Is not onthe surface, and tbe curpace reacton is rate-limiting. What generals 2atien Can yor mabe by Comparing the rate laws lerived in parts (a) though ch)? What can yee learn promth ag is problem ond the process plow sheet 2. N WS 42.5 2 BASH fi shel Cus Cog Gms | ” «, As wer 7 prs eels = toon ® Far OyCy - Cue «Kr : wits ws -Sapw * kaw Gy Cy = cs | L Rw | 3 TRA .s = TBA +S 3 Cra © Fol rams 7 apn ox} a. qurpace reacton limited. foro Crs rk crCy Cos = Kw Pw Cy Tapw sO ka ky bso Cons” Ctea- Gv = Kron Crea Cv, face + > Krpa. kp Kp 2: vit Cris + Cw.s + Crops = (v(t KiCrt kwlw + Kren Copa) Cn Petes ke kw 7 [exGw= =) Cl tke Grt KuCw + Kroa Cron) iv ‘Come Cray Co Borage _ Crs > Gy Cons Ca-p + Crea Kren Cy lee Cw kw Bs Kar = . on — — ke [b- on opt = Traore Fal cy - Gon ley i (tm) i(e to b : - gle Kaw Ako} | 4 C. Eley - Rideal Kine fics: _ : Creas ts Teter waa | — _ s ens = Ks ly Crea. 5 = Kren Crea Cv ok [ewes - Crea | - ana = Ka! + where ke brkt Ca and Ew = Kr ks ; Le key +kres Crea Krea_ d Wea tS SP TRAt SHS, % “Cus Crs = Concncn | s Cy = Cut Cress Cra = Cye tCwese. spekt CsCw- Cn = Cv (t+ &: Cr) 6* Roly ~On,= Coa Che Ree)ne lau eLange depending. spon the rate lmiting Step. the clanges tak Oceor are primarily inthe denominator (adsorpsn grip) an tin the kine Beton stant ——Flewsheet Aapat Aelchak pala Figure Pi0-s. I Miran Ca diyurg meronjvthan bahwo ade reals; (ain yang, terjach: didckam ve actin Bs tower pertama, C4 q dipsabkan | Bogie lon bso Bk iheh menara_ ify &igvretan univ memisahlean TBA TBA lebih venclah darspecke,_ KEK didth ar awa Fewer yang bertanca AC sebagan be ipikean 200, a ged ket ater hampir Helak ala iobvtena han TBA bersblet mentoba untrk menjaga bensen brass air tetop thy dan bonsentrag; [sobvtenak TBA vendah. Pola konsen ini lapst membanh mentofeat kan laje pode _(b) dom (