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52

Q.1 Indicate whether each of the following structure has the R configuration or the S-configuration. [21]

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j) (k) (l)

(m) (n) (o) (p)

CH2CH3
CH3 H
(q) (r) (s) (t) Br CH3
CH2CH 3

(u)

Q.2 Assign priority number to the following groups as per Cahn, Ingold, Prelog sequence rule [7]
(a) –CH2OH, –CH3, –CH2CH2OH, –H
(b) –Cl, –Br, –CH=CH2, –CH3
O
||
(c) C H –OH, –CH3, –CH2OH
(d) –CH(CH3)2, –CH2CH2Br, –Cl, –CH2CH2CH2Br

(e) –CH=CH2, –CH2CH3 , –CH3

CH 3 CH 3
| |
(f) –CH=CH2, –C CH CH CH 2 C— CH
| | | |
CH 3 CH 3 CH 3 CH 3
(g) –CH2CH2CH2I CH CH CH 3 CH CH 2 CH 3 –F
| |
Br Cl

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