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UnitTestFR02andFR03 - D09 Aug 2023
UnitTestFR02andFR03 - D09 Aug 2023
1. Choose the correct option for the total pressure (in atm.) in a mixture of 4g O2 and 2g H2 (confined
in) a total volume of one litre at 0°C. [Given R = 0.082 L atm mol–1 K–1, T = 273 K]
(A) 25.18 (B) 26.02 (C) 2.518 (D) 2.602
2. What is Gay-Lussac’s formula ?
(A) p µ T (B) pT–1 = K (C) p1T2 = p2T1 (D) All of these
3. Equation for Boyle’s law is....
dp dV dp dV 2 2 2
d p dV d p d V
(A) =– (B) =+ (C) =– (D) =+
p V p V p dT p dT
4. Constainers A and B have same gas. Pressure, volume and tempreature of A are all twice that of B.
Then the ratio of the number of molecules of A and B are...
(A) 1 : 2 (B) 2 : 1 (C) 1 : 4 (D) 4 : 1
5. A certain sample of a gas has a volume of 0.21 measured at 1 atm. pressure and 0o C. At the same
pressure but 273o C, its volume will be...
(A) 0.4 L (B) 0.8 L (C) 27.8 L (D) 5.6 L
6. A plot of volume (V) versus temperature (T) for a gas at constant pressure is a straight line passing
through the origin. The plots at different values of pressure are shown in Fig. Which of the following
order of pressure is correct for this gas ?
(B) P1 = P2 = P3 = P4
p3
(C) P1 < P2 < P3 < P4 p4
(D) P1 < P2 = P3 < P4
Temperature (K)
7. The pressure of a 1 : 4 mixture of dihydrogen and dioxygen enclosed in a vessel is one atmosphere.
What would be the partial pressure of dioxygen ?
(A) 0.8 × 105 atm (B) 0.008 Nm–2 (C) 8 × 104 Nm–2 (D) 0.25 atm
8. London force is ......
1
(A) directly proportional to .
r6
(B) directly proportional to r6.
(C) Inversely proportional to pressure of barometer.
(D) All of these
9. Which of the following graph is related to Boyle’s law ?
V1
(A) (B) V2
V3
Pressure V4
Volume P
V
Cl CN OH SH
(A) Only (c) (B) (c) and (d) (C) Only (a) (D) (a) and (b)
13. The vapour pressure of acetone at 20ºC is 185 torr. When 1.2 g of a non-volatile substance was
dissolved in 100 g of acetone at 20ºC, its vapour pressure was 183 torr. The molar mass (g mol–1) of
the substance is :
(A) 32 (B) 64 (C) 128 (D) 488
14. Equal moles of hydrogen and oxygen gases are placed in a container with a pin-hole through which
both can escape. What fraction of the oxygen escapes in the time required for one-half of the
hydrogen to escape ?
1 3 1 1
(A) (B) (C) (D)
4 8 2 8
15. Given Van der waal's constant for NH3, H2, O2 and CO2 are respectively 4.17, 0.244, 1.36 and 3.59,
which one of the following gases is most easily liquified ?
(A) CO2 (B) NH3 (C) O2 (D) H2
16. The correction factor ‘a’ to the ideal gas equation corresponds to....
(A) forces of attraction between the gas molecules.
(B) density of the gas molecules.
(C) electric field present between the gas molecules.
(D) volume of the gas molecules.
17. Which of the following equation is known as Van der waal's equation ?
PV æ an 2 ö
(B) ç P + (v + nb ) = nRT
v ÷ø
(A) = nRT
K è
æ an 2 ö æ an 2 ö
(C) ç P – ÷ (v – nb ) = nRT (D) ç P + 2 ÷
(v – nb ) = nRT
PV æ an 2 ö
(A) = nRT (B) ç P + v ÷ (v + nb ) = nRT
K è ø
æ an 2 ö æ an 2 ö
(C) ç P – (v – nb ) = nRT P + ÷ (v – nb ) = nRT
è v ÷ø (D) ç
è v2 ø
18. The rate of diffusion of two gases at same volume are 8 and 12 sec. respectively. If gas A’s molecular
weight is 81 g/mol so what will be the molecular weight of gas B ?
(A) 48.50 g/mol (B) 182.25 g/mol (C) 36 g/mol (D) 72.0 g/mol
19. Gases possess characteristic critical temperature which depends upon the magnitude of
intermolecular forces between the particles. Following are the critical temperatures of some gases.
Gases H2 He O2 N2
Critical temperature in Kelvin 33.2 5.3 154.3 126
From the above data what would be the order of Liquifaction of these gases ? Start writing the order
from the gas liquifying first
(A) H2, He, O2, N2 (B) He, O2, H2, N2 (C) N2, O2, He, H2 (D) O2, N2, H2, He
B
(C) E and F
(D) A and B
0 p
23. In Van der waal’s equation of state of the gas law the constant ‘b’ is a measure of.....
(A) intermolecular repulsion. (B) intermolecular attraction.
(C) volume occupied by the molecules. (D) intermolecular collisions per unit volume.
24. Choose the correct option for graphical representation of Boyle's law, which shows a graph of
pressure vs. volume of a gas at different temperatures :
Pressure (P) ®
Pressure (P) ®
0K
K
0
20
40 0 K
(bar)
(bar)
60 600 K
400 K
(A) (B) 20 0 K
Pressure (P) ®
(bar)
(bar)
2 00 K
(C) 40 0 K (D)
600 K
Volume (V ) ® Volume (V) ®
(dm3) (dm3)
25. Two closed bulbs of equal volume(V) containing an ideal gas initially at pressure pi and temperature
T1 are connected through a narrow tube of negligible volume as shown in the figure below. The
temperature of one of the bulbs is then raised to T2. The final pressure pf is :
T1 T1 T1 T2
pi, V pi, V pf ,V pf ,V
T1 are connected through a narrow tube of negligible volume as shown in the figure below. The
temperature of one of the bulbs is then raised to T2. The final pressure pf is :
T1 T1 T1 T2
pi, V pi, V pf ,V pf ,V
æ TT ö æ TT ö æ T1 ö æ T2 ö
(A) 2pi ç 1 2 ÷ (B) pi ç 1 2 ÷ (C) 2pi ç (D) 2pi ç
è T1 + T2 ø è T1 + T2 ø è T1 + T2 ÷ø è T1 + T2 ÷ø
Aakash Institute Jabalpur
Chapter=state of matter Std 11 : Chemistry Date : 09/08/23
Total Marks :100 Unit Test FR02 and FR03 Time : 1.5 HOUR
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