SAFETY DATA SHEET

No. 002

1 .- IDENTIFICATION OF THE PRODUCT AND THE COMPANY

SUPPLIER: Linde Gas Chile SA

PRODUCT
ADDRESS: Paseo Pdte. Errázuriz E. 2631 – P3
CONTACT: 9 800 800 242
PHONES: EMERGENCY: 9 800 800 242
GAS OXYGEN TOXICOLOGICAL: +56-2- 2 635 3800
CONTACT: ccc.cl@ccclinde.com
Linde Gas Chile SA
Use Restrictions Paseo Pdte. Errázuriz E. 2631 – P3. Providence
MAKER:
Do not use with incompatible materials ccc.cl@ccclinde.com

2 .- IDENTIFICATION OF HAZARDS
GHS label: Marking according to Safety Sign NCH1411/4:
NCH2190:

Classification According to Brand on label Specific Classification and Distinctive:

NCH382: Not applicable
NON-FLAMMABLE
A.
Class 2, Division 2.2
HAZARDS TO PEOPLE'S HEALTH GAS
Inhalation of high concentrations (> 75%) can produce excess oxygen in the blood causing cramps, nausea, dizziness,
respiratory distress and seizures. It can cause dryness of the respiratory tract.
B. HAZARDS TO THE ENVIRONMENT: Does not cause environmental damage
SPECIAL HAZARDS OF THE PRODUCT: Highly oxidizing, reaction to fats, oils and petroleum derivatives. c. Warning: H270: May
cause or aggravate fire, oxidizer.
H280: Contains gas under pressure, may explode if heated.

3.- COMPOSITION/INFORMATION OF THE COMPONENTS

PURE SUBSTANCE
Name of the substance: GAS OXYGEN
Chemical name: Oxygen
Chemical formula: Or 2

Common or Generic Name: Oxygen

Synonymous: Compressed Oxygen / GOX
WILDEBEEST: 1072
CAS: 7782 – 44 – 7
Concentration Range: 99.5 (Minimum)%
MIX: Not applicable

4 .- FIRST AID
Inhalation : If exposure of 3 to 7 atm. has occurred, even the most severe cases will recover rapidly after a prompt reduction in
oxygen pressure. Supportive treatment should include immediate sedation, rest, and anti-seizure therapy if needed.
Skin Contact : Contact with rapidly expanding gas may cause frostbite. If this occurs, immerse affected parts in water no higher than
37°C. Do not heat abruptly. Do not rub frozen parts. Get medical help and transfer to the Assistance Center.
Eye contact : No adverse effects are expected from this product, beyond the projection of particles. Ingestion : Not applicable. It is
not considered a potential route of exposure.
Effects of acute overexposure: Continuous inhalation of concentrations greater than 75% may cause nausea, dizziness, breathing
difficulties and convulsions.
Expected delayed effects: No history
Most important symptoms/effects: Nausea and vertigo.
Protection of First Aid personnel: No special protection required.
5 .- FIRE FIGHTING MEASURES
Extinguishing agent : Not applicable to gas. For surrounding fires, check burning material.

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 GAS OXYGEN No. 002
Unsuitable extinguishing agent: Oxygen accelerates combustion. A large amount of extinguishing agent should be used with burning
materials. If possible, cut off the oxygen supply. Cool the cylinders with plenty of water from a protected place, as there is a risk of
overpressure. Contact the supplier.
Combustion/thermal degradation products: None for this product.
Specific associated hazards: Oxidant
Specific extinguishing methods : Preferably, use water in the form of fog or spray to cool the containers involved in the fire. If
possible and has occurred, stop the oxygen leak. Materials that burn in oxygen-rich environments increase their combustion
temperature.
Personal protective equipment for fire fighting : Standard mechanical protective equipment. The use of a self-contained respirator is
recommended for closed spaces.

6 .- MEASURES TO TAKE IN CASE OF ACCIDENTAL SPILL OR LEAK

Personal precautions: Keep away from gas cloud. Evacuate area and eliminate ignition sources. Do not touch/drink the liquid that
drains.
Emergency procedures if there is a spill : Evacuate personnel from the area, if possible turn off the main supply. Eliminate all
sources of ignition and flammable materials in the vicinity. Contact the supplier.
Emergency personal protective equipment : Cotton or special clothing. Face protection. Gloves. Self-contained breathing apparatus.
Environmental precautions : Not applicable
Methods and materials for containment, confinement and/or abatement : Not applicable to gas
Containment methods : Not applicable
Recovery: Not applicable
Neutralization: Not applicable
Disposal method : Not applicable

7 .- MANIPULATION AND STORAGE

Precautions for safe handling : Use product in well-ventilated areas. Use materials compatible with oxygen and elements free of
petroleum derivatives.
Operational and technical measures: Use only equipment specifically appropriate for this product and its supply pressure and
temperature. Keep equipment free of oil and grease. Open the valve slowly to avoid water hammer. Use only oxygen compatible
lubricants and adjustments. Use only equipment clean for use with oxygen and suitable for the pressure of the container. Keep all
valves clean and free of oil, petroleum or water. Consult the supplier for instructions for use and handling.
Recommendations on handling : Cylinders must be operated according to the supplier's instructions by trained persons. Use only
equipment compatible with the product and free of oil, grease and petroleum derivatives. Do not remove fixed caps. Return with
residual pressure of 25 psi. Do not transfer to other containers.
Contact prevention: Avoid leaks in equipment. Locate in ventilated areas.
Storage condition : Store full and empty cylinders separately. Protect against physical damage. Keep the cylinders tied up. Do not
store next to combustible materials and flammable gases.
Technical Measures: Close the container valve after use, even when empty. You should never attempt to repair or modify container
valves. Replace all valve guards as soon as the vessel has been disconnected from your equipment. Avoid storing in places with
pedestrian traffic. Protect containers from corrosion. Avoid paved areas.
Incompatible substances and mixtures: Petroleum derivatives, flammable substances.
Recommended and unsuitable packaging : Only cylinders authorized by the supplier. Do not transfer.

8 .- EXPOSURE CONTROL/PERSONAL PROTECTION

Control parameter : Percentage of oxygen present (< 23%)
Weighted and absolute permissible limits : Not applicable
Respiratory protection : In normal use, protection is not required.
Hand protection : Leather or cryogenic gloves.
Eye protection : Due to the pressure of the cylinders, a face shield or glasses with side protection are recommended.
Skin and body protection : Clothing without synthetic fiber / safety shoes with steel toe caps.
Engineering measures : Avoid leaks in equipment. Risk assessment must be carried out and documented in each work area to
evaluate the risks related to the use of the product and to select personal protective equipment corresponding to the risk. It is
recommended to have self-contained breathing apparatus for use in an emergency. Personal protective equipment must be selected
based on the tasks to be performed and the risks involved. Adequate ventilation in work and storage areas.

9 .- PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Gas
How it is presented : Compressed gas
Color : Colorless

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 GAS OXYGEN No. 002
Smell Lavatory
pH Not applicable
Decomposition temperature A stranger
Flashpoint Not applicable. Non-flammable.
Autoignition temperature Not applicable
Melting point/freezing point -218°C
Boiling point -183°C
Explosive limits Not applicable
Vapor pressure at 20°C 4,053 kPa (-124.1 °C)
Density 1.1 (Air = 1)
Gas density 21°C/1 atm. 1.36 kg/m 3
n-octanol/water partition coefficient 0.65 (as log Pow)
Water solubility 39 mg/l

10 .- STABILITY AND REACTIVITY

Chemical stability : Chemically stable as a product. There are no dangers of
reaction other than those described in other sections
Conditions to avoid : Violently oxidizes organic materials. can react
violently with combustible materials and reducing agents.
Incompatibility, materials to avoid Combustible materials. Reducing agents. Keep equipment free of oil and
grease. For material compatibility, consult the latest version of the ISO-
11114 standard. In case of combustion, take into account the potential
danger of toxicity due to the presence of chlorinated or fluorinated
polymers in high pressure oxygen lines (>30 bar).
Under normal conditions of use and storage, decomposition into
Hazardous decomposition products hazardous products should not occur.
Reacts with combustible materials and reducing agents.
Dangerous reactions

11 .- TOXICOLOGICAL INFORMACION
They do not meet the classification criteria according to available data.
Acute toxicity
They do not meet the classification criteria according to available data.
They do not meet the classification criteria according to available data.
Skin irritation/corrosion
They do not meet the classification criteria according to available data.
They do not meet the classification criteria according to available data.
Serious eye damage/eye irritation
They do not meet the classification criteria according to available data.
They do not meet the classification criteria according to available data.
Respiratory or skin sensitization

They do not meet the classification criteria.

Mutagenicity of reproductive cells
They do not meet the classification criteria.
They do not meet the classification criteria according to available data.
Carcinogenicity
They do not meet the classification criteria according to available data.
reproductive toxicity
Specific toxicity to particular organs 12.- ECOLOGICAL INFORMATION
- Unique exhibitions
Stable
- Repeated exposures
Biodegradable product. Gas.
Inhalation hazard
Ecotoxicity Biodegradable product.
Persistence/degradability Bio-accumulative potential High volatility gaseous product.
Related symptoms
Mobility in soil Other adverse effects Is not expected.
13 .- INFORMATION ON FINAL PROVISION
Waste : Product does not generate waste, but the remainder of the cylinders
can be discharged into the atmosphere in a controlled manner.
Disposal of contaminated containers/packaging : Return the clearly identified container. Only the supplier is authorized to dispose of
packaging.
Contaminated material : It does not pollute.

14 .- TRANSPORTATION INFORMATION

Transport Mode
Land Maritime Air
Regulations DS 298 IMDG IATA

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 GAS OXYGEN No. 002

Number one 1072 1072 1072

Official shipping designation gaseous oxygen gaseous oxygen gaseous oxygen
2.2 Non-flammable 2.2 Non-flammable 2.2.Non-flammable
UN Primary Hazard Classification gas gas gas
UN Secondary Hazard Classification 5.1 Oxidizer 5.1 Oxidizer 5.1 Oxidizer
Packing group Not applicable Not applicable Not applicable
Environmental hazards Not applicable Not applicable Not applicable
Special precautions High pressure High pressure High pressure

Transport in bulk in accordance with MARPOL 73/78 Annex II, and with IBC Code:
ANNEX II of MARPOL 73/78 does not apply, as it is a packaged product. Product not included in chapters 17 or 18 of the IBC Code.
Additional information: Avoid transportation in vehicles where the cargo space is not separated from the driver's compartment.
Ensure that the driver is aware of the potential risks of the load and knows what to do in the event of an accident or emergency.
Secure the gas container before transport. Make sure the bottle valves are closed and do not leak. Valve guards must be in place.
Ensure proper air ventilation.

15 .- REGULATORY INFORMATION
NCh 1025.Of90 – NCh 1411/4. Of78 – NCh 2190.Of2003 –
NCh 2120/2. Of2004 – NCh 2245.Of2015 – NCh 2168.Of91 - DS- 43:
Regulations on the Storage of Dangerous Substances;
Applicable national regulations :D.S. 148/03 Hazardous Waste Management (MINSAL); Beef. 408/16
MINSAL Approves List of Substances Hazardous to Health; DS-298:
Regulates Transportation of Dangerous Cargoes on Streets and Roads.
Brand on label : Non-flammable gas
The recipient must verify the possible existence of local regulations applicable to the product.

16 .- OTHER INFORMATION
NFPA Hazard Code: Health: 1, Flammability: 0, Reactivity: 0, Special Hazards: Oxidizer
References: International Chemical Safety Sheets from the National Institute of Safety and Hygiene at Work (INSHT) of Spain.
Globally Harmonized System of Classification and Labeling of Chemicals (GHS), Fourth Edition; 2011.
The data contained in this Fact Sheet was obtained from reliable sources. However, they are provided without express or implied
warranty regarding their accuracy or correctness. The opinions expressed in this form are those of trained professionals. The
information provided in it is what is currently known on the subject.

Explanation of Abbreviations:
GHS = Globally Harmonized System
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods Code
Log Pow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution from Ships, 1973 with the 1978 Protocol. ("Marpol" = marine
pollution)
UN = United Nations Organization

Change control:
- Rev 10: National Regulations are updated and Explanation of Abbreviations is included

Considering that the use of this information and the products is beyond the control of the supplier, the company does not assume any
responsibility for this concept. Determining the conditions of safe use of the product is the user's obligation.

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