LP ee scl ra = Q Subject —- Physical Chemistry ede emel iL d Bertil iad 7" Lecture No.- 4 \ i BY: Amit Mahajantonic eee geet 44 Rules to attend class “Always Sim ee mem TeH CM eter Li med ready with your copy and pen. < Never ever attend a class from in between or don't join a live class in the middle of the chapter. 3° Make sure to revise the last class before ELT ond OPIS e eA MEN CMCC RACi a eT m Lee) Same Te Can Oy eae TC Merete eT PCR VINER On CMR Tae e meee Cem ed Oe eM AMR Meo LeC can be cancelled.4 Rules to attend class Palas to make maximum notes during the class if something is left then u can use the notes pdf after the class to complete the remaining class. y. NEN) ACU MMC Meee Ome MeO faculty. Before asking any doubt please check whether same doubt has been asked by someone or not. VA aOR B NR oom ACR CHORE Ce Telit teteraBienes >? DEWAR c- ise tana s eRe Salto aa Racer cee Lanter lcd et py NailRevision of best Close Pee ea a (iJ bia ee Ne yeas ao ee ee as ree cue eer Ss Rea or Cea) are)#Q. Which one of the following equations does not correctly represent the first law of thermodynamics for the given process involving an ideal gas? CC ORE aCe Zou} (JEE Main 2019, 8 April Shift-I) v ea) Cyclic process : q = - W, ER =- o SI Ce aaah ee }) Adiabatic process : AU = 4 er ay ) Isochoric process : AU = q OViee +O) Isothermal process : q = - W Bree Cy#Q. Which of the following statements in false? (IT 2001) MOSSE Recetas (ony Bee Re Cate Sa (EW oe Reece cree nye ciae ine MMe eel EMR de Cceee Scrat (cre Aye ey ee eM OCC IM Ame Cy= we sy # Aa aes] (RPA ST eco = adiobotic Y=O TAO toe) .or lag K ‘OC elute RAteng IN NS, ‘G Iw) olla ale ia IC ere a (enol s N (EE Main 2017) @PAPA OCR ese Coe el at 25°C. Work done in an open vessel is Ae ca ae Ce eee pe ce A Pann eo) iad ary Are so aa an (rae A PO eee Vein aN) We At eae ==) ne .an fing pram ci f ep ed a aa é rau dl es Beet aetna pmet = BEREAN OS hav) Pree aneae #Q. During compression of a spring the work done is 10 kJ and 2 kJ escaped to PC eee ene B Cmca we COs eo (JEE Main 2019, 9 April Shift-I1) @) as} (CU ae van acs AC: ey w= res es ules AAV aad raea #Q. An ideal gas undergoes a cyclic process as shown in figure: es ee hort hee esr ee aS ned Heat absorbed by the system during process CA is: (JEE Main (Online) 2018) yen toe A b3] Soe spite as id ef a J) 5 kj mol "4 v esc6 ret a i= av+ 9) ae H=>U + OY Ce eee nue = p+ PMp-®@ aj S rm ea Ay 10} iy - ry) rs eas D/O baleed = Up* P¥p — COR *P%RD ne waz, a ng z Pana eae ene za yea ie aCe , wrk Auta @rta igNaw Enthalpy (Energy) Change Av An : 3) v4 Ly eae Ean Ye Dame Dy J Argan Mpls Oe ea Ua er ere) SUEY ee eT 4 ® writ Pera an, Yan K Yost Gl > erttenne eee OO ea ears OE ee een eee Cae re aa (Aiea eee eed ee li#Q. For a reaction, Aj) —+> Aq; AH = -3RT. The correct statement for the Prune eH 4 (EE Main 2017 (Online)) Le NeG)- Mnly ‘Conny od eae a Viet ake C) AH =AU20 us |av! ‘C} FANS Ea as, a pe Ir) AH = AU =0\ CMM ioe ae RC RU meee mole of heptane (Q) is carried out at a temperature T, is equal to: ro) aay Ca eres Cea c" a 4 vas Tae em eee GCE aed i aie a ‘eae ea 7X i a © hay ang ey ~ ee ae peas ae Ce 3RT |Cite mo oe kJ mol at 373 K and 1 bar pressure. Assuming that EM CED Cee ed Cee MEO Me Ce mas OT CUE m Cm emeCU eo Demo Lm Ce ——_lJ mol“. [Use: R= 8.3 J mol K-"]_ (JEE Main Fine 26" Aug Shift-II) (a coe Kl ma! Es in CYC? 0 od ead ro AY Pace) a led ae i ng P28 pom Verh utal Ang a 7 ee al 63) ane e exe cE nen a a ik fs LUN eer ST adCrs az, Z Se A a i 7 oon er eee ers & eatsa a Pa OR Rue A Vite a ae cea Vand aa G uh fhHeat Capacity is Extensive Property > Heat Capacity is path function: Rao a any td Ee (A) Heat capacity of constant volume (C,) (B) Heat capacity of constant pressure (Cp) ~ na ty Si SO 66 Heat Capacity at Constant Volume (C,) A O TIL (haan lara aa macy ar, ae au i, Gay 7 tad carpe us a 40 fre TS er Wee eee a calwe & Ran CO Oo em lene ry OV Oren nen an ‘oye = NCym ATHeat Capacity at Constant @22=mp (C,) Hugh +P. v- rer TL iad — roe RT Comet vate Eee RC aa -@ oe ea ba ai ce 6A : #Q. Why C, is greater than Cy?be CTY eo aS Av=o SEPA) VN ee Oe Oe eae Oc ate eo ea temb nc Vary fou cane CLS arena 4 ROE eae ee ene) Gone thank Uxed te lac it asunak orgy VS Fee Cont by ed Carat Sodas ae evPears) Cos a a ln oe See a oom Ge a © -e4ev (crema z oa go BHR © -\wWeev 0 iy Daa sete ae reece oe ea tie errataOe ee ea ald na Pe eee ee @ Pee a aa (ORS Tacs On ens ome oes @ reutaonfer ES ie @® QE split of opelrel Lins (ov presence of mapa ae Ci) Cees oad Ne ae (ene Nesta cae Non af Hoseee alee ro ae y EOra x OM TL dean as Sa dee nae Tae nae eee es F a St aed NGM iar > Rodiowme 7 a eae ad (sas Kj Tngroed < Pers ed Cae een Se pa nue ByeQe abs af auchems Ve 5 aaa Cay aoe ©w @ \o i —_How to increase Your Focus ? PaO acme CRU a Tey Com Reed >» 2Use Ear Plugs while Studying - discussed in chapter 1 Lecture 3 How to increase Your Efficiency ? » Use Pomodoro technique - discussed in chapter 1 Lecture 5 A Stop Mobile Addiction- _ discussed in chapter 1 Lecture 10How to reduce your revision time & increase efficiency ? > Gold dust method - discussed in Chapter 2 Lecture 5