FIITJEE

ALL INDIA TEST SERIES

JEE (Advanced)-2023
FULL TEST – XI
PAPER –1
TEST DATE: 28-05-2023

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

Section – A
1. B, C
1 1 1 1
Sol.    min = 1.5
mi x  1 7 5
1 1
5 3
1 4  1 2
Mmix   3 g/mol = 3  103 kg/mole
1 1
25
1.5   375
minRT 3
vmi x    1250 m/s
Mimn 3  103
v 1 T 1 7.5
 100   100    100  1 %
v 2 T 2 375
2. B, C
 400
Sol. Speed of light in the medium v    2  108 m/s
k 2  106
c 3  108
Refractive index of the medium n    1.5
V 2  108
n  r r
Since for non magnetic medium r = 1, r = 9/4
E   
Since, B0  0 and v || E  B
v

ˆ ˆ
B  (1.5i  2 j)  1010 sin(2  106 z  4  1014 t)T
Peak value of magnetic field = (1.5)2  (2)2  1010  2.5  10 10 T
1 2 1
Average energy density in electric field = 0 r Erms  0 r E02
2 4
1 9 225 3
 0   25  10 4  0  10 4 J/m
4 4 16

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 2

3. B, C, D
Sol. Let n2 be the quantum number of excited state after absorption of photon.
n2 (n2  1)
 10  n2 = 5
2
The quantum number of energy level before excitation may be either n1 = 3 or n1 = 2
Let n1 = 2
256E0  1 1 
  E0 z 2  2  2 
225  2 5 
Here z has no integral value after calculation. So, n1 = 2 is not possible
Then, n1 = 3
256E0  1 1 
 E0 z 2  2  2 
225 3 5 
256E0 16
  E0 z 2
225 225
z=4
The minimum energy of the emitted photons corresponds to n = 5 to n = 4
 1 1  9E0
E  E0  42  2  2  
4 5  25

4. A, B, D
A
k 0
q1 C1 4d  k
Sol.  
q2 C2 A 3
0
4d
since, q1 = q2 (given)  k = 3
q2
force between the plates of a parallel plate capacitor is F 
2A0
2
 F1 
 q/ / 2 

q20
A 2A0
2 
4 0
(q0 / 2)2 q2
F2   0
 3A  6A0
2  0
 4 
F1 1/ 2
 3
F2 1/ 6
Induced charge on dielectric
q  1 C V  1 C V
q  0  1    0  1    0
2  k 2  3 3
q02
F0 
2A0
2q20
F  F1  F2 
3A0
F 2 / 3 4
 
F0 1/ 2 3

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 3 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

5. B, C
Sol. V = ar2  br3
2
E = 2ar + 3br
2 q 3 4 q
E(4r ) =  8ar + 12br =
0 0
dq 4r 2 dr
 (24ar 2  48 br 3 )  
0 dr 0 dr

6a  12br 
0
  = 0(12br  6a) = 60(2br a)
=0
a
 r
2b

6. B, C
Sol. x  x1  x2
n3 = 1.6 P
 n1S 2B  n2S 2P  n2 (S1P  t)  n3 t
S1
h t = 1 m
B
= n1d  n2 (S 2P  S1P)  (n3  n2 )t
D 0 C O
h dy h A
 n1d  n2  (n3  n2 )t n2 = 1.4
D D n1 = 1.2
S2
(i) h = 0 S
0
 x  n2  (n3  n2 )t  (0.2)t  2  10 7 m D D
d
2 2
 7
 2  107  
6  10 3
 I
I  I0 cos2  0
2 4
(ii) For constructive interference at P, x = n
y
= n2  (n3  n2 )t  n
D
dy
n2  n  (n3  n2 )t  n  6  10 7  0.2  10 6
D
1 n  6  107  2  10 7   2  104  1 mm
y  3
10  1.4   1.4 7
h
(iii) At y = 0, x  x1d  (n3  n2 )t
D
1.2  10 3  103  0.2  10 6  1.4  106
2  1.4  10 6 14
 7

6  10 3
I = I0/4
d2 dy
(iv) n1  n2  0.2  106  n
D D
dy 1.2  106
 n2  n  6  107   2  107  n  6  10 7  14  107
D 1

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 4

4
1  2  6  10 7  14  107   2  10  1 mm
y (for ymin, n = 2)
10 3
 1.4   1.4 7

7. D
Sol. (I) frequency of sound receive by the reflector
v  vr
fr  f
v
The frequency of reflected sound
v v  vr 330  33
f  fr  f  660
v  vr v  vr 330  33
(II) frequency of sound reaching the hill
v
fh  f
v  vb
The frequency of reflected sound
v  vb v  vb 330  16.5
f  fh  f  627  693 Hz
v v  vb 330  16.5
v v v2 vP
(III) f   f f f
v  vP cos   vP  v 2  vP2 
 v  vP v 
  v
v2 4
2
f   450  600 Hz
v 3
v2   
2
Observer

c
c
cv 2  500 3  500 GHz
(IV) f   f
cv c
c
2

8. A
1  1 1 
Sol. (I)  (  1)   
f  R1 R2 
1 1 1  1
  (1.5  1)   
20  R R  R
 R = 20 cm
For refraction at first surface (air-lens interface)
1.5 1 1.5  1
  …(i)
v1 60 20
For refraction at second surface (lens-water interface)
4
 1.5
4 / 3 1.5 3
  …(ii)
v2 v1 20
Adding equations (i) and (ii)
4 1 0.5 0.5
  
3v 2 60 20 60
 v 2 = 80 cm
(II) Let F be the focal length of the silvered lens

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 5 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

1 2 1 1
  
f fe fm 60  60 
 
 2 
 f = 15 cm
For slivered lens
1 1 1
 
v u f
1 1 1
  
v 20 15
 v =  60 cm

(III) The system is equivalent to three thin lens in contact. Let f 2 be the focal length of the
concave lens filled with water.
1 4  1 1 
  1  
f2  3  15 15 

45
 f2 =  cm
2
The focal length of the equivalent lens from by the three thin lenses in contact
1 1 1 1 1 1 1
Then,      
f f1 f2 f3 30 45 / 2 30
 f = 45 cm
For the equivalent lens
1 1 1
 
v 60 45
 v = 180 cm
(IV) For concave lens
1 1 1
   v1 = 12 cm
v1 30 20
For refraction at air convex lens interface
1.5 1 1.5  1
   v 2 = 120 cm
v 2 40 40
For refraction at convex lens-liquid interface
4
 1.5
4 1.5 3
 
3v 3 120 40
 v 3 = 160 cm

9. C
0I  I I
Sol. (I) BP   0  0
4a 4a 2a
I  I  I
BQ  0 (sin90  sin 45)  0 (sin90  sin 45)  0
4a 4a 2a
BP
1
BQ

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 6

0 I 0I 0I y
(II) BP   
2r 2r r
0  I 0Ir 2 0I  1 
BQZ  cos 45kd   1  
2 2r 2(r 2  r 2 )3/2 4r  2
0I  I x
BQx  sin 45  0
2 2r 4r

2 2 0I (5  2 2)
BQ  BQx  BQz 
4r 2
BP 4 2

BQ 52 2
0I  I 1 
(III) BP  2  (sin90  sin 45)  0  1  
4r 2r  2
 I I 1 
BQ  2  0 (sin90  sin 45)  0  1  
4r 2r  2
Here r is perpendicular distance of pints P and Q from any one straight current carrying
wire
BP 2 1
 32 2
BQ 2 1
0I 2 20I
(IV) BP  2  (sin 45  sin 45) 
4 
 
0I 
20I  / 2 /2  1 2 0I
BQ  4  (sin   sin  )sin 45     
   3  3  2 3 
4  
2  2 2 
BP
 6
BQ

10. C
2R

2R
Sol. (I) EP  3 
30 90
3
4 R
 
1 3  3  R
EQ  2

40  2R  360
 3 
 
EP
8
EQ
R 4 R
   R3 
2 1 3 2  R
(II) EP   3
20 40 R 120
4
  R3  R
R 1 3 R
EQ   3

20 40 R 60

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 7 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

EP 1

EQ 2
R
0iR2 
(III) BP  2  0 jR
2R3 4
2
R
0 j  
R
BQ   0 j   4   70 jR
2 R 16
2  
2
 
BP 4

BQ 7
R

(IV) EP  2  R
20 40
2
R
  
R  4   7R
EQ  
20  R  160
20  
2
EP 4

EQ 7

Section – B

11. 2.24
Sol. Induced emf in loop BENM E
1m N 0.5 m
F
dB
1  A1  1 2  2 V I2
dt q 1V
Induced emf in loop CFNM 2V 1m
+q
dB I2
2  A 2  0.5  2  1 V B
dt M C
I1I2
Induced emf in loop ABCD
dB I1 I1
3  A 3  1.5  2  3 V 1m
dt
Applying loop rule in ADFE A D
3V
3  7I1  7I2 + 3 = 0
6
 I1  I2  …(i)
7
Applying loop rule in ADCB
3  7I1  3(i1  i2 )  0
 10I1  3I2 = 3 …(ii)
After solving equations (i) and (ii)
3
I1  I2 
7
Applying loop rule in MNEF
q
2  4I2 + (I1  I2)  2   0
C

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 8

q 3 2
  2  4 
C 7 7
2
 q   7.84  2.24 C
7
12. 0.11
Sol. P0  | Pm coskx |
3 
 Pm  Pm coskx  kx 
2 6
   4L / 3 3
 x    (since L = )
6k 2 12 12 4
6

L 0.99
=   0.11 m
9 9
13. 1.91
Sol. Q-value of reaction = (7.01601  3me + 1.00783  me )  (7.01693  4me + 1.00867)  931.5 MeV
  1.64 MeV
From conservation of momentum
pP  pBe
From conservation of energy
p2p 2
pBe
  1.64
2mp 2mBe
pp2  mp 
  1    1.64
2mp  mBe 
pp2 7
Kinetic energy of proton =   1.64  1.91 MeV
2mp 6
14. 4.20
Sol. For minimum de-Broglie wavelength of electron, the momentum and hence kinetic energy of
electron must be maximum
 1 1  h2
13.6  2  2    
1 2  2m 12
1 1  h2
13.6z2  2  2  
1 2   2 
2m  1 
 6.1 
 
3
13.6  
4 1
 …(i)
3 6.1
13.6z2   
4
For the unknown gas
Energy of first lyman line-energy of Balmer series limit = 2  13.6 eV
3  1
 13.6z2    13.6z 2    2  13.6
4
  4
z=2
So from equation (i)
 = 4.20 eV

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 9 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

15. 3.46
Sol. Considering the motion of detached bit of mud w.r.t. centre of the wheel v
v 2 sin120
2Rcos30 = 60
g
30
 v  2gR  2  10  0.6  2 3  3.46 m/s R/2
R
v

16. 1.25
Sol. For block m
m
(N mg) t = 0 (mv1) = mv1
For block M
N = Mg + N
and N = (M + m)v3 Mv2 mg N
 mv1  N
   Mg   mg  t  (M  m)v 2  Mv 2
 t 
Mgt and mgt are negligible M
 mv1  6v 3  5x 2
 0.25  1 10  6v 3  10
Mg N
 v 3 = 1.25 m/s

17. 5.50
Sol. Applying junction Rule at P
4
4(I1  I2 )  I1  0  I1   I2
5
Applying loop rule in loop MTS
  3(I1 + I2)  
4(I1 + I2) N 2(I1 + I2) (I1 + I2)
xV
I1 I2 (x+3)V I2 (x+2)V I2 (x+) V I2 I1
I1 I1 I1
R R R R R

M
4V 3V 2V V 0V
I1R + I2R   = 0

I2  I1 =
R
4  5
 I2  I2   I2 
5 R 9R
4
 I1  
9R
4
0  x = I1R  x = I1R =
9
4 22
VN  VM  x  2  0   2 
9 9
22
  2.25  5.50V
9

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 10

18. 3.60
Sol. The work done by gas is the sum of work done against the force of atmospheric pressure and the
work done against the gravity. The mercury gas interface is shifted upon the complete
2 8
displacement of mercury =  
3 3
8
Work done against atmospheric pressure, W1   P0 S
3
Work done against the gravity is equal to change in potential energy of mercury as a result of its
displacement. The initial height of centre of mass of liquid
2m  2m 
  m 0  
h1  3 3 3 3  4
7m 21
3
The final height of centre of mass of mercury = 
Work done against gravity W 2 = U2  U1
 4m   4   4  17 17
 m   g      s  s  g  s 2 g
 3   21   3  21 9
8 17
Total work done = W 1 + W 2 = P0S  S2 g = 3.60 J
3 9

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 11 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

Chemistry PART – II

Section – A

19. A, B, D
Sol. (1) Lactose on hydrolysis produces D-Glucose and D-Galactose.
(2) Sucrose does not undergo mutarotation.
(3) D-Glucose and D-Mannose are C-2 epimers

20. B, C
Sol. CONH2 NH2 N2Cl

A= B= C=

CN NC

D= E=

21. A, D
Sol. 1. When Chromyl Chloride vapour is passed into NaOH solution, yellow solution is formed.
2. Colour of Chromyl Chloride vapour is orange red.

22. A, B, C
Sol. Pine oil or Eucalyptus oil is added as frother.

23. A, D
Sol. 1. PH3 when passed through CuSO4 solution black ppt. (Cu3P2) is formed.
2. PCl3 on hydrolysis produces H3PO3.

24. D
Sol. 1. Flocculation power is PO3-
4 > Cl .


2. Higher is the gold number, lower is the protecting power.

25. B
3
Sol. FeF6  - sp3 d2 , Paramagnetic
2
NiCl4  - sp3 , Paramagnetic
2
Ni  CN 
 4
- dsp2 , Diamagnetic
3
COF6  - sp3 d2 , Paramagnetic

26. D
Sol. P4 O10  4HNO3  4HPO3  2N2 O5

Pb  NO3 2   4NO2  2PbO  O2
2NaNO2  2FeSO4  3H2 SO4  Fe2  SO 4 3  2NaHSO4  2H2 O  2NO

NH4 NO3   N2 O  2H2 O

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 12

27. D
Sol. 2Cu  NO3 2  K 4 Fe  CN6   Cu2 Fe  CN6    4KNO3
Chocolate
brown ppt.
Pb  NO3 2  K 2 CrO4  PbCrO 4  2KNO3
Yellow ppt.
BiCl3  H2 O  BiOCl  2HCl
White ppt.
Pb  CH3 COO 2  H2 S  PbS  2CH3 COOH
Black ppt.

28. B
Sol. O O
CF3 CO3H
H3C C CH3  H3C C O CH3
O CH2
 
H3C C CH3 
Ph3 P C H2
 H C C CH 3 3
O
 i NH2 NH2
H3C C CH3  H3C CH2 CH3
ii KOH
O OH
LiAlH4
H3C C CH3 
H O
 H3C CH CH3
3

Section – B

29. 37.50
P0  PS WB / MB
Sol. S

P WA / MA
WB  37.50

30. 83.50
7
Sol. C2H6  g  O2  g  2CO 2  g   3H2 O   
2
Ho  2Hof CO2  3Hof H2 O    Hof C2H6 
Hof C2 H6  83.50 kJ .

31. 43.75
Sol. N2 O 4  g  2NO2  g 
Dd 46  32
 
d  n  1 32  2  1
  0.4375
 % degree of dissociation = 43.75%.

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 13 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

32. 5.36
Sol. CH3 COOH  NaOH  CH3 COONa  H2 O
40  0.1 32  0.1 0 0
0.8 0 3.2
CH3 COO  
 
pH  pK a  log
CH3 COOH
3.2
pH  4.76  log
0.8
pH = 5.36
33. 15.05
Sol. COOH CONH2 NH2

3NH ,  Br , KOH
 2



P 
Formula of P = C6H7N
Molecular mass of P = 93
14
Weight % of N   100  15.05
93
34. 52.80
Sol. OH Cl
2SOCl
  O
O
P  Q
1 mole   0.5 mole 

3AlCl
 Zn Hg, HCl
 

O S
R 
 0, 4 mole 
 0, 4 mole 
Molecular weight of S = 132
 Wt. of compound S formed = 132  0.4  52.8 g

35. 2.61
Sol. MnO2  4HCl  MnCl2  2H2 O  Cl2
2KI  Cl2  2KCl  I2
2Na2 S2 O3  I2  Na2 S 4 O6  2NaI
Meq. of MnO2 = Meq. of Na2 S2 O3  30  0.1  3
3  87
Wt. of MnO2   0.1305 g
2  1000
0.1305
Wt. % of MnO2   100  2.61
5

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 14

36. 4.32
Sol. Ba  N3 2 
  Ba  3N2
 0.02 mole   0.06 mole 
3Mg  N2  Mg3 N2
 0.18 mole   0.06 mole 
Mass of Mg = 0.18 × 24 = 4.32 g

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 15 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

Mathematics PART – III

Section – A

37. A, B, C, D
Sol. f(x) = –(e–x + ex)  0
f(0) = 0 and f(x)  0  x  [0, )
 f(x) = 0
=0

38. B
Sol. Tangent at B is perpendicular to line segment AC

39. A, B, C
2
Sol. z + z +  = 0
z2  z    0
r 4 r 2
     0 (As |z| = r)
z2 z
 z 2  r 2 z  r 4  0
1   2
 2  4  || = r
 r r

40. A, B
1 1
7 7 6
Sol. Let I   207 C7 x 200 1  x  dx  207
C7  x 201 1  x  dx
0 201 0
1
 I  k = 13
208

41. A, C, D
Sol. kn  2n 1  2

42. A, B
1 52
Sol. r ,d=2 S
4 25

43. C
Sol. Number of singular matrices with no zero entry = 209
Number of singular matrices with atleast one zero entry = 171
2
 D  A   10  1  2  3  .....  9 
A S
 20250

 T  A   100 1  2  3  .....  9   900  0  1  .....  9  = 1900  45 = 85500

A S

 T  A   900 1  2  3  .....  9   900 1  2  .....  9  = 1800  45 = 81000

A S

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 16

44. A
Sol. (I) y  e 4x  2e  x
dy d2 y
  4e4 x  2e x , 2  16e4 x  2e x
dx dx
3
dy
 64e4 x  2e  x  k = 12
dx3
(II) Since the degree of the equation is 2, so two lines are possible
dy dt
(III) y = tm   mt m1 
dx dx
6 4m
dt 4x  t 3
   m
dx 2mx 4 t 2m1 2
dy
(IV) y  Axm  Bx n   Amx m 1  Bnx  n 1
dx
 m = 3 or –4 and n = 4 or –3

45. C
Sol. Let Ei denote the event that the bag contains i black and (12 – i) white balls (i = 0, 1, 2, ....., 12)
and A denote the event that the four balls drawn are all black. B denote the probability of drawing
2 black and 2 white balls
1 A
P  Ei   i  0, 1, 2, ....., 12  , P    0 for i = 0, 1, 2, 3
13  Ei 
i
A C
P    12 4 for i  4
E
 i C4
12
A 1
(I) P  A    P  Ei .P   
i 0  Ei  5
10
 A  C4 14
(II) P  12

 E10  C4 33
1 14

E  13 33 70
(III) P  10   
 A  1 429
5
1
(IV) P B  
5

46. D
 15 5 3 
Sol. (I) p2 + 9q2 + 25r2 = pqr      p = 3q = 5r
 p q r
2 1 1
(II) (r – p)2 + (q + r)(p – 2q + r)   
q p r
2
(III) f(x) = px + qx + r  f(x) = 2px + q
f(1) = f(–1)  q = 0
Also, 2p2 + 2pr = 0  p, q, r are in A.P.
(IV) p = 5, q = 8, r = 12

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 17 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

Section – B

47. 2.00
2
Sol. Let P and Q be  at12 , 2at1  and  at 22 , 2at 2  respectively t 2   t1 
t1
 t1(t1 + t2) = –2
tan  = –t1, tan  = –t2
 |tan (tan  + tan )| = 2

48. 1.00
cos  sin  cos  sin 
Sol. 1 and 0 are the roots of the equation  1   1
cos  2 sin 2 cos  2 sin 2
cos2  sin2  sin  1  sin2  sin 0 sin 1
 2
 1 2
2  2
 2
  sin2 2
cos 2 sin 2 sin 2 cos  2 sin 2
cos 0 cos 1 sin 0 sin 1 cos 0 cos 1
Similarly,   cos2 2   1
2
cos 2 sin2 2 cos2 2

49. 9.00
9999 9999
1
  n  1 
1/ 4
Sol. S    n1/ 4
n 1
n 1/ 2
  n  1
1/2
 n1/ 4
  n  1
1/ 4
 n 1

 S = (10000)1/4 – 11/4 = 9

50. 3.00
Sol. Let (x + 3) = –t  3 2t  1  t  k
 18t = t2 + 2(k + 1)t + (k + 1)2
7
As t > 0  k   [k]  3
2
51. 4.00

Sol. Let I  
1 sin1  x  dx  I
1 sin1  1 x  dx  1 cos 1  x  dx
0
2
x  x 1 0
2
x  x 1 
0
2
x  x 1
1 2 2
 dx  
 2I    I n=4
2 0 x 2  x  1 3 3 6 3

52. 3.00
Sol. cos–1(2x) + cos–1(3x) =  – cos–1(x)  6x 2  1  4x 2 1  9x 2   x
3 2
 12x + 14x – 1 = 0  a= 12, b = 14, c = 0, d = –1
53. 9.00
n n  n  1
Sol. By using 1  x   1  nx  x 2  .....
2
3
L
4
54. 49.00
49  2r  48r  1
2
49 
r 1 r 
Sol.   50  r 
r 1
50
Cr
   50
r 1  Cr 1
 50 
Cr 

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