ANSWER LATIHAN PSPM II SK025 (SET 3)

1 (a) 4𝐶𝑙2 𝑂 (𝑔) → 2𝐶𝑙𝑂2 (𝑔) + 3𝐶𝑙2 (𝑔)

1
𝑑[𝐶𝑙2 𝑂]
− = 1.35 × 10−2 𝑀 𝑚𝑖𝑛−1
𝑑𝑡
1 𝑑[𝐶𝑙2 ] 1 𝑑[𝐶𝑙2 𝑂]
+ =−
3 𝑑𝑡 4 𝑑𝑡 1
𝑑[𝐶𝑙2 ] 3
+ = (1.35 × 10−2 )
𝑑𝑡 4
= 0.010125 𝑀 𝑚𝑖𝑛−1
rate of formation of Cl2 is 0.010125 M min-1 1
(b) 1
Graph of ln [H2O2] against time give a linear graph.
Thus, the reaction is a first order reaction.

[𝐻2 𝑂2 ]𝑜 1
𝑙𝑛 = 𝑘𝑡
[𝐻2 𝑂2 ]
[𝐻2 𝑂2 ]𝑜 1
𝑙𝑛 = (7.45 × 10−4 )(1600)
[𝐻2 𝑂2 ]
[𝐻2 𝑂2 ]𝑜
= 3.294
[𝐻2 𝑂2 ]
[𝐻2 𝑂2 ]
% = 30.36%
[𝐻2 𝑂2 ]𝑜
1
percentage of H2O2 decomposed: 69.63%

Graph of ln [H2O2] against time

1

0.5
3
LN [H2O2]

0
0 500 1000 1500 2000 2500 3000 3500
-0.5

-1

-1.5
TIME/ S
1

2 (a) ℎ𝑒𝑎𝑡 𝑟𝑒𝑙𝑒𝑎𝑠𝑒𝑑 = ℎ𝑒𝑎𝑡 𝑎𝑏𝑠𝑜𝑟𝑏𝑒𝑑

1 𝑞𝑟𝑥𝑛 = 𝑚𝑠 𝑐𝑠 ∆𝑇
= 104 × 4.18 × 10
= 4347.2 𝐽
1 𝑚𝑜𝑙
𝑛𝑁𝑎𝑂𝐻 = 4.00 𝑔 × = 0.1 𝑚𝑜𝑙 1
40 𝑔

0.1 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 ≡ −4347.2 𝐽

1 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 ≡ −43472 𝐽

ND KHALID 1
 ANSWER LATIHAN PSPM II SK025 (SET 3)

∆Hsoln = -43.47 kJ mol-1 1

(b)
∆Hf = -1123 kJ
Mg (s) + F2 (g) MgF2 (s)

∆H1 = +148 kJ ∆H4 = +159 kJ

4
Mg (g) 2F (g)
∆Hlattice = ?
∆H2 = +738 kJ

Mg+ (g) ∆H5 = -656 kJ

∆H3 = +1450 kJ

Mg2+ (g) + 2F- (g)

∆𝐻𝑓 = ∆𝐻1 + ∆𝐻2 + ∆𝐻3 + ∆𝐻4 + ∆𝐻5 + ∆𝐻𝑙𝑎𝑡𝑡𝑖𝑐𝑒 1
∆𝐻𝑙𝑎𝑡𝑡𝑖𝑐𝑒 = −1123 − (148 + 738 + 1450 + 159 − 656)
= −2962 𝑘𝐽 𝑚𝑜𝑙 −1 1
3 (a) anode (oxidation): Mg (s) → Mg2+ (aq) +2e-
cathode (reduction: Cd2+ (aq) + 2e- → Cd (s)
𝐸 𝑜 𝑐𝑒𝑙𝑙 = 𝐸 𝑜 𝑐𝑎𝑡ℎ𝑜𝑑𝑒 − 𝐸 𝑜 𝑎𝑛𝑜𝑑𝑒
= −0.40 − (−2.37)
= +1.97 𝑉 1

𝑜
0.0592 [𝑀𝑔2+ ]
𝐸𝑐𝑒𝑙𝑙 = 𝐸 𝑐𝑒𝑙𝑙 − 𝑙𝑜𝑔 1
𝑛 [𝐶𝑑 2+ ]
0.0592 [1.00]
1.54 = 1.97 − 𝑙𝑜𝑔
2 [𝐶𝑑 2+ ]
[𝐶𝑑 2+ ] = 2.97 × 10−15 𝑀 1
(b) Cathode (reduction): Ca2+ (l) + 2e- → Ca (l)
𝑄 = 𝐼𝑡
= 0.452 × (1.5 × 60 × 60) 1
= 2440.8 𝐶
2 × 96500 𝐶 ≡ 1 𝑚𝑜𝑙 𝑜𝑓 𝐶𝑎
2440.8 𝐶 ≡ 0.01264 𝑚𝑜𝑙 𝑜𝑓 𝐶𝑎 1
40 𝑔
𝑚𝐶𝑎 𝑑𝑒𝑝𝑜𝑠𝑖𝑡𝑒𝑑 = 0.01264 𝑚𝑜𝑙 × = 0.5059 𝑔 1
1 𝑚𝑜𝑙
4 (a) product formed:
1-bromo-2,2-dimethylpropane 1
1

ND KHALID 2
 ANSWER LATIHAN PSPM II SK025 (SET 3)

(b) (i)
1

(ii)

5 (a) Benzene is an aromatic compound because:

o it is cyclic and planar
o completely conjugated
3
o satisfy Huckel’s rule

(b)

(c)
1

6 (a) C: D:
2

D is 3° alcohol because it reacts immediately with Lucas reagent. Thus, C must

1
be a 3° haloalkane.

(b) SN1 mechanism 1

Step 1: Formation of carbocation
δ-

1
δ+

Step 2: Nucleophile attack the carbocation

7 (a) reagent & condition: conc. H2SO4, heat

1

ND KHALID 3
 ANSWER LATIHAN PSPM II SK025 (SET 3)

(b) Iodoform test 1

no light yellow precipitate formed

1
light yellow precipitate formed

8 (a) i. O3
ii. Zn/ H2O 1

(b) F is an alkene because ozonolysis of this alkene will give butanone

and propanal.
1
1

(c)

(d) butanone has a methyl carbonyl group while propanal doesn’t. 1

9 (a) phenol < propanoic acid < 2-chloropropanoic acid 1

When dissociate in water, phenol, propanoic acid and 2-chloropropanoic acid will
formed the following ions respectively:

A B C

Ions B and C are more stable than A because the negative charge in the ions are
1 delocalized between two O atoms while in A, the negative charge is delocalized
into the benzene ring. Thus, propanoic acid and 2-chloropropanoic acid more
acidic than phenol.

ND KHALID 4
 ANSWER LATIHAN PSPM II SK025 (SET 3)

2-chloropropanoic acid is more acidic than propanoic acid because due to the
inductive effect. The presence of an electron withdrawing group (-Cl) reduce the
1 electron density on O atoms and stabilizes the ion C.

(b) (i)

(ii)

10 primary amine:

1 @ @ @

Secondary amine:

1
@ @

Tertiary amine:

N-methyl-1-propanamine (2° aliphatic amine) is more basic than 1-butanamine

2 (1° aliphatic amine) because it has more electron donating group (alkyl group)
compare to 1-butanamine. Basicity of amines increases as the number of alkyl
group increases.

1 @

ND KHALID 5
 ANSWER LATIHAN PSPM II SK025 (SET 3)

11
and

4 peptide
bond

12
@
1

ND KHALID 6