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Properties of Viscose
Properties of Viscose
Viscose Rayon
It is a regenerated cellulosic fibre and cellulose is the raw material for producing this man made fibre.
The raw material is obtained from a special variety of wood called spruce.
Manufacturing Process
a. Purification of Cellulose:
The manufacture of viscose rayon starts with the purification of cellulose. Spruce trees are cut into timber. Their barks are removed and cut into
pieces measuring 7/8" x 1/2" x 1/4". These pieces are treated with a solution of calcium bisulphite and cooked with steam under pressure for
about 14 hours.
The cellulosic component of the wood is unaffected by this treatment, but the cementing material called lignin, which is present in the wood, is
converted into its sulphonated compound which is soluble in water. This can be washed off, thereby purifying the remaining cellulose. This
cellulose is treated with excess of water. After this it is treated with a bleaching agent (sod hypochlorite) and finally converted into paper boards
or sheets. This is called wood pulp, which is normally purchased by the manufacturers of viscose rayon.
c. Steeping Process:
The conditioned wood pulp sheets are treated with caustic soda solution ( about 17.5%). It is called mercerising or steeping. The high DP
cellulose (1000) is converted into soda cellulose. The sheets are allowed to soak (steep0 until they become dark brown in colour. This takes about
1-14 hours. The caustic soda solution is drained off and sheets are pressed to squeeze out excess caustic soda solution. 100 kg of sulphite pulp
gives about 310 kg of soda cellulose.
5. Ageing Process:
To obtain almost ideal solution of cellulose, the soda cellulose is stored in small galvanised drums for about 48 hours at 28 deg C. This process is
called ageing process.The ageing process is essential. During This process, the DP od soda cellulose is decreased from 1000 to about 300 by
oxygen present in the air, contained in the drum.
8. Ripening Process:
This viscose solution requires to be ripened to give a solution having best spinning qualities. Ripening is carried by storing the viscose solution
for 4-5 days at 10 to 18 deg. The viscosity of the solution first decreases and then rises to its original value. The ripened solutoin is filtered
carefully and is now ready for spinning to produce viscose rayon filaments.
9. Spinning Process:
The viscose solution is forced through a spinnerette, having many fine holes ( 0.05-0.1mm) diameter. The spinnerette is submerged into a
solution containing the following chemicals.
10% --> sulphuric acid, 18%- Sod sulphate, 1% - Zinc sulphate, 2% glucose, 69% water.
Sodium sulphate precipitates the dissoved sod. cell.xanthate. Sulphuric Acid converts xanthate into cellulose, carbon disulphide and sod.
sulphate. the glucose is supposed to give softness and pliability to the filaments whereas zinc sulphate gives added strength.
As a number of filaments emerge from the spinnerette, they are taken together to an eye at the surface of the spinning bath and then guided to two
rollers from where they are wound on to a spindle.
Moisture Absorption
It absorbs more moisture than cotton. Moisture Content of Coton is 6% at 70 deg F and 65% RH, and for Viscose Rayon it is 13% under the same
conditions.
Tensile Strength
The Tensile Strength of the fibre is less when the fibre is wet than when dry. It is 1.5-2.4 gpd in the dry state and 0.7-1.2 gpd in the wet state. For
high tenacity variety the values are 3-4.6 gpd and 1.9 to 3.0 gpd.
Elasticity
The elasticity of Viscose Rayon is less than 2-3%. This is very important in handling viscose yarns during weaving, stentering etc when sudden
tensions are applied.
Elongation at Break
Ordinary Viscose rayon has 15-30% elongation at break, whule high tenacity rayon has only 9-17% elongation at break.
Density
The density of Viscose rayon is 1.53 g/cc. Rayon filaments are available in three densities: 1.5, 3.0 and 4.5
At 300 deg F or more, VR loses its strength and begins to decompose at 350-400 deg F. Prolonged exposure to sunlight also weakens the fibre
due to moisture and ultraviolet light of the sunlight.
Chemical Properties
Viscose rayon consists of cellulose of lower DP than cotton cellulose. Also amorphous region of Viscose rayon is present to a greater extent,
therefore, Viscose rayon reacts faster than cotton with chemicals. Acids like H2SO4 HCL breaks the cellulose to hydrocellulose. Oxidising agents
like Na(OCl)2, Bleaching powder, K2Cr2O7, KMnO4- form oxycellulose. Cold acid solutions for a short time do not attack viscose rayon.
Action of Solvents
Textile solvents can be used on Viscose rayon without any deteriorating effect. Viscose rayon dissolves in cuprammonium hydroxide solution.
Effect of Iron
Contact with iron in the form of ferrous hydroxide weakens viscose rayon yarns. Therefore staining, marking or touching of rayon to iron or iron
surface should be avoided.
Action of Microorganisms
Microorganisms ( moulds, mildew, fungus, bacteria) affect the colour, strength, dyeing properties and lustre of rayon. Clean and dry viscose
rayon is rarely attacked by moulds and mildew.
Longitudinal View
The longitudinal view of these fibres show many striations running parallel to the long axis of the fibre. The cross section of viscose has striated
periphery, having many sharp indentations, and cross sectional contours vary from circular and oval to ribbon-like forms.