MARKING SCHEME FOR CHEMISTRY 2019

Q1. (a) (i) A = Chlorine gas [1]

B = Hydrochloric acid [1]

C = Salt bridge/KNO3 and KCl [1]

D = Platium cathode or Pt/H+ [1]

E = Hydrochloric acid [1] ANY FOUR [4

(ii) Cl2 + 2e- 2Cl- [1] Reduction [1]

Fe2+ Fe3+ + e- [1] Oxidation [1]

(iii) Left to right [1]

(iv) Cl2 + 2e- 2Cl- Eo = +1.36V

Fe2+ Fe3+ + e- EO = + 0.77V

Ecell = E reduction – E oxidation

Ecell = +1.36 – 0.77V [1]

Ecell = + 0.56V [1] any equivalent

(b) (i) E R – E p = E rxn

[(3 x -166.2) + (1 x - 48.5)]-(1 x -399.5) [1]
E rxn= (-498.72 -48.5) + 399.5
E rxn = -148.02KJ/mol [1] correct
answer one mark only.
(ii) 2FeCl3 + 3Cu 3CuCl2 + 2Fe [1]
E rxn = E reduction – E oxidation
-0.04V- -0.34V

0.30V [1] correct

answer one mark only
Q2. (a) State of balance for a forward reaction and the backward reaction [1] any
equivalent with similar wordings

[ CH 3 C O2 C 2 H 5 ][ H 2 O]
(b) Kc =
[ C H 3 C O2 H ] [C 2 H 5 OH ]
[1]

(c) (i) CH3CO2H + C2H5OH CH3CO2C2H5 + H2O

Initial 0.5mol 0.5mol 0.1mol 0.1mol

Aft rxn -x -x +x +x

Eqlm 0.5-x 0.5-x 0.1 + x 0.1+ x [1]

[ 0.1+ x ] [0.1+ x]
Kc = [1]
[ 0.5−x ] [0.5−x ]
[ 0.1+ x ] [0.1+ x]
4.0 =
[ 0.5−x ] [0.5−x ]
4[(0.5-x)(0.5-x)]=(0.1+x)(0.1+x)
3x2 -3.8x +1.01= 0

−b ± √ b 2−4 ac
Using x =
2a
X = 0.38 mol [1] other x value 0.89mol just mathematical correct.
CH3CO2H + C2H5OH CH3CO2C2H5 + H2O

0.5 - 038 0.5 -0.38 0.1 + 0.38 0.1 + 0.38

0.12mol 0.12mol 0.48mol 0.48mol [1] products & [1] reactants

or just one on each side indicated allow full marks
(ii) because the Kc = 4.0 is greater than 0.01.
(d) (i) 2P4O3 + 9 O2 4P2O5 + 6SO2 balancing [1] correct eqn [1]
(ii) P2O3 + H2O 2H2PO4 Correct eqn [2] x 2
SO2 + H2O H2SO3
Q3. (a) (i) Cu + H+ + NO3- Cu2+ + 2NO3- + H2O + NO (in acidic)

Half reactions

Cu + HNO3 Cu(NO3)2 oxidation

HNO3 NO Reduction

Cu + HNO3 Cu(NO3)2 + 2e-

HNO3 + 3e- NO [1]

Cu + HNO3 Cu(NO3)2 + 2e- + 2H+

HNO3 + 3e- + 3H+ NO [1]

(Cu + HNO3 Cu(NO3)2 + 2e- + 2H+ ) x 3

(HNO3 + 3e- + 3H+ NO) x2 [1]

3Cu +3 HNO3 3Cu(NO3)2 + 6e- + 6H+

2HNO3 + 6e- + 6H+ 2NO [1]

3Cu + 5HNO3 3Cu(NO3)2 + 2NO [1]

Be on the look out of another method using water to balance hydrogens.

(a) (ii) MnO4- + SO32- MnO2 + SO42- (in basic)

MnO4- MnO2 Reduction

SO32- SO42- Oxidation

Balance electrons

MnO4- + 3e- MnO2

SO32- SO42- + 2e- [1]

Balance oxygens

MnO4- + 3e- + 4H+ MnO2 + 2H2O

 SO32- + H2O SO42- + 2e- + 2H [1]

Balance the charges and converting to basic by addition of water where H + and OH on the other side

MnO4- + 3e- + 4H2O MnO2 + 2H2O + 4OH-

SO32- + H2O + 2OH- SO42- + 2e- + 2H2O [1]

Balance electrons by multiplying with 2 and 3 respectively for upper and lower eqns

(MnO4- + 3e- + 4H2O MnO2 + 2H2O + 4OH- )x2

(SO32- + H2O + 2OH- SO42- + 2e- + 2H2O ) x 3

2MnO4- + 6e- + 8H2O 2MnO2 + 4H2O + 8OH-

3SO32- + 3H2O + 6OH- 3SO42- + 6e- + 6H2O [1]

2MnO4- + 6e- + 8H2O 2MnO2 + 4H2O + 8OH-

3SO32- + 3H2O + 6OH- 3SO42- + 6e- + 6H2O

2MnO4- + 3SO32- + H20 2MnO2 + 3SO42- + 2OH- [1]

(b)

(i) 3 B (s) + 3/2 O2 (g) B2O3 (s) ΔH -1273 KJ

(ii) B2O3 + 3H2O (g) 3 O2 (g) + B2H6 (g) ΔH +2035 KJ

(iii) 3 H2 (g) + 3/2 O2 (g) 3H2O (l) ΔH -286 KJ x 3 = -858KJ [1]

(iv) 3H2O (l) 3H2O (g) ΔH +44 KJ x 3 = +132KJ [1]

NET 2B(s) + 3H2(g) B2H6 ΔH = 36 KJ [2]

[1] for all correctly cancelled species [1]

Q4. (a) ANY THREE ATMOST

Phenyl,

Pyrimidine ring

Amine

Chloro

Methyl [1x3]

(b) C16H19ClN2 or C16H19N2Cl any correct [3]

(c) C16H19ClN2

2 x 14 = 28

1 x 35.5 = 35.5

19 x 1 = 19

16 x 12 = 192

274.5g/mol [3] no marks without units

(d) (i) 160mg = 0.16g

1ml = 0.001l

Moles n = mass m/Molar mass M

n = 0.16g/274.5g/mol = 0.000583 mols [1]

conc = n/vol

conc = 0.000583/0.001dm3 [1]

= 0.583M [1] no mark without units

(ii) pKa = 9.13

-log Ka = pKa [1]

-log 9.13 = pKa

10-9.13 = Ka [1]

= 7.41 x 10-10 [1]

Q5. (a) (i) R1 = 9.2 Molar Mass (M1) = 32g/mol

R2 = ? M2 = 28g/mol

R1
R2
=
M2
M1 √ [1]

( ) (√ )
2
9.2 2 28
= [1]
R2 32

R2 =
√ 2708.48 = 9.8ml/min
28
[1] no mark without units

(ii)
R 1 P1
=
R 2 P2 √ M2
M1
[1]

9.2 178 28
=
9.8 P2 32 √ [1]

( ) ( ) (√ )
2
9.2 2 178 2
28
= [1]
9.8 P2 32

P2 =
√ 1782
0.881299458
(0.875)

P2 = 177.3 mmHg [1]

(b) Molar mass nitrogen 28g/mol, R2 = 14.65ml/min

Molar mass unknown Mun R1 = 9.2ml/min

R1
R2
=
M2
M1√
9.2
14.65
=
28
√
M un
[1]

) (√ )
2

( 9.2 2
14.65
=
28
32
2
14.65
M un= 2
x 28 [1]
9.2
 M un=71.0 g/mol [1]

Unknown gas could be Cl2 or Chlorine gas [1]

2
n a
(c) 2 = correction on pressure [1]
V
nb=correction of volume [1] Q6. (a) (i) CuCO3 (s) + 2HCl (aq)
CuCl2 (aq) + H2O (l) + CO2 (g) correct balancing [1]

Correct state symbols [1]

Correct equation [1]

(ii) moles of CuCO3 n = m/M = 4.7g/124g/mol

= 0.0379 mol

Moles n = conc x vol = 2 x 0.025 = 0.05mol

CuCO3 : HCl

1 2 [1]

0.0379 x. x = 2 x 0.0379mol = 0.0758moles HCl [1]

But HCl available is 0.05moles meaning HCl is limiting. [1]

OR

CuCO3 : HCl

1 2 [1]

X 0.05mol

X = 0.05/2 = 0.025moles Copper (II) carbonate [1]

But available copper (II) carbonate is 0.379 moles meaning it is excess [1]

(iii) HCl : CO2

2 1

0.05mol x [1]

2x = 0.05mol = 0.05mol/2 = 0.025moles of CO2 [1]

1mol = 24dm3

0.025 x x=0.025 x24 = 0.60dm3. of CO2 [1]

PV = nRT P = nRT/V = 0.025 x 8.314 x 298/0.6 [1]

 P = 1003.2 Pascal = 1.00 atm [1]

(iv) excess mass =(moles excess – moles used)x Molar mass

Excess mass = (0.0379-0.025)x 124g/mol [1]

Excess mass = 1.5996g [1]