SEC:SR_*CO-SC(MODEL-A) Date: 16-07-23

Time: 3 Hrs Max. Marks: 180

CHEMISTRY: PRESENTWEEK (80%): CO-Ordination Compounds: Introduction,

Definition of important terms related to co-ordination compound, types
of ligands, IUPAC rules, Nomenclature, Werner theroy and Sidgwick
theory, VBT -hybridization and geometries (linear, tetrahedral, square
planar and octahedral)
PREVIOUS WEEK (20%): Colour, Magnetic properties,Catalytic
properties, alloy and interstitial compounds formation, oxides and
oxoanions of metals,Preparation & Properties of Potassium dichromate
&Potassium permanganate
f-block Elements: Lanthanoid and actinoid contractions; oxidation
states; general characteristics.
Narayana IIT Academy 16-07-23_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-47_Q’P
CHEMISTRY Max. Marks: 60
SECTION - I
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
19. EAN of central atom in some of the complexes is given as

(atomic number of Fe  26, Co  27, Ni  28, Cr  24 )

3 3
 FeF6  Co  NH3 6   Ni  CO 4   c; Cr  CN 6 
3
 a;  b; d

abcd 
The value of   is
 4 

20. (i) Secondary valency of Pt in  Pt  en 2 Cl2  is ‘X’

(ii) Oxidation state of cobalt in K Co  CO 4  is ‘Y’

(iii) Effective atomic number of Mo (Z=42) is 54 in the complex  Mo  CO  Z  .

The value of (X + Y + Z ) is

21. Sum of the oxidation states of the central metal ion in the following complexes is _____
2 
Co  H2O CN  en 2  ;  PtCl4  ; Cr  NH3 3 Cl3  ; CoBr2  en 2  ;K3 Fe  CN 6 
2
 

22. The weight of precipitate formed by 200ml 0.1M solution of CrCl  H 2O 5  Cl2 .H 2O with
excess AgNO3 in gram is _____
(Gram Atomic weight of Ag = 108, Cr = 52, Cl – 35.5 ,O = 16, H = 1)

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Narayana IIT Academy 16-07-23_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-47_Q’P
23. Among the following ligands

 gly1 ,C2O42 ,(DMG) ,  EDTA 4 ,CN ,SCN , F , PPh3 , en,dien,OCN ,OH , Py
Number of chelating ligands = x
Number of ambident ligands = y
Number of symmetrical bidentate ligands = z
Value of x + y + z =
24. In the given structure ‘x’ and ‘y’ are bond lengths in pm. The value of x+y is _____

25. Among the given ion pairs, the number of pairs with same outermost electronic
configuration from
Set I are X and from Set II are Y. The value of X  Y is

Set I:  Ac3 , Th 4  ,  Th 3 , Pa 4  ,  Pa 3 , U 4  ,  U 3 , Np 4  ,  Np3 , Pu 4  ,  Pu 3 , Am 4  ,

 Am 3
, Cm 4  ,  Cm3 , Bk 4  ,  Bk 3 , Cf 4  ,  Cf 3 , Es 4  ,  Es3 , Fm 4  ,  Fm3 , Md 4 

 Md 3
, No 4  ,  No3 , Lr 4  

Set II:  La 2 , Ce3  ,  Ce 2 , Pr 3  ,  Pr 2 , Nd3  ,  Nd 2 , Pm3  ,  Pm 2 ,Sm3  ,  Sm 2 , Eu 3  ,

 Eu 2
, Gd 3  ,  Gd 2 , Tb3  ,  Tb 2 , Dy3  ,  Dy 2  , Ho 3  ,  Ho 2  , Er 3  ,  Er 2 , Tm3  ,  Tm 2 , Yb3  ,

 Yb 2
, Lu 3 

26. 7.5 mole H2C2O4 .2H2O is completely oxidized by X mole KMnO4 / H  and also by Y
mole K2Cr2O7 / H . The value of X + Y is…..

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Narayana IIT Academy 16-07-23_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-47_Q’P
SECTION – II
(Maximum Marks : 24)
This section contains SIX(06) multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE THAN ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
27. Which one of the following is/are INCORRECT combination:

Coordination Compound IUPAC Name

A) Cr  NH3 3  H 2O 3  Cl3 Triamminetriaquachromate(III) chloride

Tris(ethane – 1,2 – diamine)cobalt(II)

B) Co  H2 NCH2CH2 NH2 3  SO4  3
2
sulphate

C)  Ag  NH3 2   Ag  CN 2  Diamminesilver(I) dicyanidoargentate(I)

D) K 3 Cr  C2O 4 3  Potassium trioxalatochromium(III)

28. Choose the CORRECT IUPAC names to the given complexes

Coordination Compound IUPAC Name

Tetrapyridineplatinum(II)
A)  Pt  py 4   PtCl4 
tetrachloridoplatinate(II)

Tris(ethylenediammine)nickel(II) trioxalato
B)  Ni  en 3  Fe  C2O4 3 
3 2
iron(III)

C)  
CuCl2 O  C  NH2  
2 2  Dichloridobis(urea) copper(II)

D) K2 OsCl5 N Potassium pentachloridonitridoosmate(IV)

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Narayana IIT Academy 16-07-23_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-47_Q’P
29. Which of the following is/are CORRECT regarding valence bond theory?
A) It does not give quantitative interpretation of magnetic data
B) It does not explain the colour exhibited by coordination compounds
C) It does not give a quantitative interpretation of the thermodynamic or kinetic
stabilities of
coordination compounds
D) It effectively distinguish weak and strong ligands
30. Identify the CORRECT IUPAC names among the following given complexes
A) Co  NH3 4 Cl  NO2   Cl - Tetraamminenitrito – N – chloridocobalt(III) chloride

B) K Cr  H 2O 2  C2O 4 2  .3H 2O - Potassium diaquadioxalatochromate(III)trihydrate

C)  CH3 4 N Cr  C2O4 3  - Tetramethylammonium trioxalatochromate(III)

D)  Pt  NH3 2 Cl  CH3 NH 2   Cl - Diamminechloridomethanammineplatinum(II) chloride

31. Which of the following statement/s is / are CORRECT

3 3 3
A) [Co( NH 3 )6 ] , [Co(CN )6 ] , [Co( NO2 )6 ] are diamagnetic and so involve d 2 sp3
hybridization
B) [ Zn( NH 3 )4 ]2 & [ Ni(CO) 4 ] are diamagnetic and so involve sp3 hybridization
C) [Cu ( NH 3 )4 ]2 & [ Ni(CN ) 4 ]2 are diamagnetic and so involve dsp 2 hybridization
D) The spin only magnetic moment of K4 [MnF6 ] & K3[ FeF6 ] are same
32. In which of the complexes the central metal atom/ion follows the Sidgwick EAN rule
(Atomic numbers of Pd = 46, Ni=28, Fe=26, Cr=24)
A) [ Pd ( PPh3 )2 Cl2 ] B) [ NiBrCl (en)] C) Na4[Fe(CN )5  NOS ] D) [Cr (CO)6 ]0

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Narayana IIT Academy 16-07-23_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-47_Q’P
SECTION - III
(Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has TWO (02) matching lists: LIST-I and LIST-II.
FOUR options are given representing matching of elements from LIST-I and LIST-II. ONLY ONE of these four
options corresponds to a correct matching.
For each question, choose the option corresponding to the correct matching.
For each question, choose the option corresponding to the correct matching.
Full Marks : +3 If ONLY the option corresponding to the correct matching is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
33. Match the properties of given complexes in their solution of equal strength

Column I Column II
K 4  Fe  CN 6 
White precipitate is formed with
(A) (p)
aq.sol.AgNO3
(B)  Pt  NH3  Br  Cl  Py   (q) Highest osmatic pressure in solution
(C) Co  NH3 6  Cl3 (r) Least boiling point of solution
(D)  Pt  NH3 4 Br2  Cl2 (s) Maximum molar conductance
A) A  r,s; B  p,s;C  s, t; D  p,s B) A  p; B  q,s;C  r,; D  q
C) A  p, q, r,; B  p, q,;C  q,s; D  r D) A  q,s; B  r;C  p; D  p
34. Match the column – I with column – II and mark the correct option from the codes
given below:
Column I Column II
(A) Sodium argentothiosulphate (p) Neutral complex
(B)  Pt  NH3 5 Cl  Cl3 (q) Cationic complex
(C) Na 2  ZnCl4  (r) Anionic complex
(D)  Pt  NH3 2 Br2Cl2  (s) Heteroleptic complex
(t) Homoleptic complex
A) A  p; B  p,s;C  q; D  r,s B) A  q; B  r,s;C  p, r,s; D  q
C) A  r, t; B  q,s;C  r, t; D  p,s D) A  p; B  q,s;C  r, t; D  q

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Narayana IIT Academy 16-07-23_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-47_Q’P
35. According to balanced equation match the following stoichiometric coefficients for the
given reaction.

Column I Column II
(A) xMnO4  yS2O32  H2O  aMnO2  bSO42  OH (p) x = 2

(B) xMnO4  yC2O24  H   aMn 2  bCO2  H 2O (q) y = 3

(C) xCr2O72  yH2S  H  aCr3  bS  H2O (r) a=2

(D) xMn 2  yS2O82  H2O  aMnO4  bSO42  H (s) b = 10

A) A  p; B  p,s;C  q; D  r,s B) A  q; B  p, r,s;C  q, r; D  p, r,s

C) A  r,s; B  q,s;C  r,s; D  p,s D) A  p; B  q,s;C  r, t; D  q

36. Match the following

Column I Column II
Complex Property
(A)  Pt  NH3 2 Cl2  (p) Number of ions per molecule = 0

(B) K 3 CoCl2  ox 2  (q) Secondary valency = 6

(C) Cr  en 3  Cl3 (r) Oxidation state = 2

(D)  Ni  NH3 2  C2O4   (s) Number of ions per molecule = 4

A) A  p, r; B  q,s;C  q,s; D  p, r B) A  s; B  p, r,s;C  q, r; D  p, r,s

C) A  p, q, r; B  q,s;C  q, r; D  r,s D) A  p; B  q,s;C  r,s; D  q

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19 35 20 11 21 14 22 5.74 23 11

24 342 25 2 26 5.5 27 ABD 28 AC

29 ABC 30 BD 31 ABD 32 CD 33 D

34 C 35 B 36 A
 Narayana IIT Academy 16-07-23_SR.IIT_*COSC(MODEL-A)_WAT-47_Key&Sol’s
CHEMISTRY
19. EAN   z  x  n  2   ,

z : atomic number; x : oxidation state; n: no. of ligands

20. x  6, y  1, z  6
21. 3  2  3  3  3  14
22. 2Cl  2AgNO3  2AgCl 
23. x=6,y=3,z=2
24. x = 179 pm y = 163 pm

25.   
Except La 2 , Ce3 and Gd 2 , Tb3 
26. 2KMnO 4  5H 2Cr2O 4  3H 2SO 4  K 2SO 4  2MnSO 4  10CO2  8H 2O

K 2Cr2O7  3H 2C2O 4  4H 2SO 4  K 2SO 4  Cr2  SO 4 3  6CO 2  7H 2O

32. EAN for A = 52, B = 34, C = 36, D = 36

35. 8MnO 4  3S2O32  H 2O  8MnO 2  6SO 42  2OH 

2MnO 4  5C2O 42  16H   2Mn 2  10CO 2  8H 2O

Cr2O72  6H 2S  14H   2Cr 3  6S  7H 2O

2Mn 2  5S2O82  8H 2O  2MnO 4  10SO42  16H 

MATHS
37.
37.

SR(MODEL-A)_WAT-47_16.07.23_FINAL KEY
S.NO
38. xSUBy Q.NO GIVEN KEY FINAL KEY REMARKS
  1 and a  b  2020
aPHYb NILL
x y
1 
CHEM 23  1 formi11 the
forming 11eliminating
he D.E. by or 12 ‘b’ we get KEY CHANGE
2020  b b
There is space in between complex
2  dy
CHEM 
28dy  AC dy y A or AC
x  y   1  2020  0  k  2020 name
 dx  dx  dx
x In option-D 'methammine' is given but
3 CHEM
y 2  8x, x  230 BD B
it should be 'methanamine'

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Narayana IIT Academy 07-08-22_INSR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-57_Q’P
CHEMISTRY Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct.
21. A complex whose IUPAC name is correctly written is
Complex Name
3
A)  Fe  C2O4 3  Trioxalatoiron (III) ion

B) Cr  CO 6  Hexacarbonmonoxidechromium (O)

C) CoCl2  H 2O 4  2 H 2O Tetraaquadichlorido cobalt (II)-2-water

2
D)  Zn  NCS 4  Tetrathioscynanato – N – Zincate (II)

22. Which of the following is an outer orbital complex?

4 4 3 2
A)  Fe  CN 6  B)  Mn  CN 6  C) Cr  NH 3 6  D)  Ni  NH 3 6 

23. Which among the following are correct?

A) K 3  Mn  C2O4 3    2.82BM B)  Ni  CO 4    0.00BM

2
C)  Ni  CN 4    5.90BM D)  FeCl4    1.73BM
2

24. The true statements among the following

A) Hexacyanoferrate (II) ion has four unpaired electrons in 3d orbital

B) Tetra cyanonickelate (II) ion has squre planar geometry

2
C) IUPAC name of  Zn  OH 4  ion is tetrahydroxy zinc ion

3
D) The coordination number of Cr in Cr  NH 3 2  en 2  is 6

25. Which are correct about  Fe  H 2O 5 NO  SO4 (not by considering mass bar)

A) It is diamagnetic as it has no unpaired electron

B) It is paramagnetic as it has unpaired electrons
C) Oxidation number of Fe is +2
D) Oxidation number of Fe is +1

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Narayana IIT Academy 07-08-22_INSR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-57_Q’P
26. Which of the following are coloured?

A) Ti  NO3 4 B) Cu  NC.CH 3 4  BF4

C) Cr  NH 3 6   Cl3  D) K3VF6

27. Which of the following do not explain the reason why CN  is a strong field ligand?

A) It carries –ve charge and have high electronegativity

B) It is a conjugate base of weak acid

C) It can accept electrons from metal ion

D) It forms high spin complexes with metal ions

28. Which are the correct statements?


A)  Ag  NH 3 2  is linear with sp hybridized Ag  ion

B)  NiCl4  , VO43 and MnO4 have tetrahedral geometry

2

2 2
C) Cu  NH 3 4  and  Ni  CN 4  have dsp 2 hybridization of metal ions

D) Fe  CO 5 have bipyramidal structure with dsp 3 hybridized Fe

29. Which of the following complex ions exhibit a spin only-moment of 4.8B.M ?
2
A) CoF6  B)  Fe  H 2O 6  C) Fe  CO 5 D)  MeCl4 
3 2

30. To fom coordination bond, one needs a ligand. Which of the following species can not
be a ligand?

A) NH 4 B) PH 4 C) H 3O  D) NO 

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Narayana IIT Academy 07-08-22_INSR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-57_Q’P
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
31. Disaccharide (A) is hydrolyzed by dilute acid to give a mixture of D-glucose and D-
glactose. Compound (A) is reducing sugar and is oxidized by bromine water to an
acid. Compound (B) is methylated by sodium hydroxide and dimethylsulphate to yield
an octa-O-methylated compound. Hydrolysis of the latter gives a tetra-O-
methylgluconic acid (C), and a tetra-O-methylgalactose (D). Compound (C) is
oxidized by nitric acid to tetra –O-methylglucaric acid. Compound (C) is also obtained
by the acidic hydrolysis of methyl 2,3,4,6-tetra-O-methylgalactopyranoside.
Compound (A) is hydrolyzed by an   galctosidase.

When compound ‘A’ is reacted with CH 3OH / dry.HCl gives a derivative (E). The
number of methoxy groups in compound ‘E’ is

32. How many compounds are expected to yield a white precipitate with AgNO3 Solution?

PtCl4 .4 NH 3 ; CoCl3 .3NH 3 ; Vinyl chloride; Allyl chloride, Carnalite; Tertiary butyl

chloride

33. How many statements are correct regarding  Ni  DMG 2  ?

i) The complex is diamagnetic.

ii) The complex forming 5 membered chelate with ligand and metal ion

iii) The complex forming hydrogen bonding and 6 membered chelation is possible.

iv) The complex forming 6 membered chelate with ligand and metal ion

v) It is rosy red colour

vi) It is tetrahedral complex

vii) It is square planar complex

viii) O,O is the donor atom for ligand.

ix) N,N is the donor atom for ligand

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Narayana IIT Academy 07-08-22_INSR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-57_Q’P
34. Find out the number of bidentate ligands where both oxygen atoms act as donor atom

a) Acetylacetonato b) Biuret

c) Dimethylglyoximato d) Glycinato

e) Biguanido f) Oxalato

g) Dimethylglycol
1
35. In Co  EDTA   number of N  Co  O linkage present?

36. Identify total number of carbohydrates which give ve tollen test

CH 2OH

H O H

 
H Br2
37. OH Compound (A); Number of chiral centre in compound A is
H H 2O
HO OH
H OH

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Narayana IIT Academy 07-08-22_INSR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-57_Q’P
38. Identify compounds which faster than benzene in ArSE reaction?

39. Identify the total number of compounds that give diastereomeric product on reaction
with MeMgCl

3
40. The number of unpaired electrons in “3d” orbitals of cobalt in Co  H 2O 6  is

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Sec: INSR.IIT_*CO SC(MODEL-A) WAT-57 Date: 07.08.22
Time: 3 HRS 2014_P1 Max. Marks: 180
KEY SHEET

CHEMISTRY
21 ACD 22 ABC 23 ACD 24 BD 25 BD
26 CD 27 ACD 28 ABCD 29 AB 30 ABC
31 1 32 4 33 6 34 4 35 8
36 3 37 4 38 6 39 2 40 0

CHEMISTRY
21. Since the disaccharide (A) on hhydrolysis gives a mixture of D-glucose andd D D-galactose on cleavage
of   linkage, it is 6  O   D  galactose pyranosyl-D- glucopyranosenose.. O
On treatment with
bromine water, the hemiacetaal pa
part of the rign is oxidized to form acid (B)

The further reactions of (B) caan be depicted as follows

INSR.IIT_*CO SC Page No: 10

Narayana IIT Academy 07-08-22_INSR.IIT_*COSC(MODEL-A) _WAT-57_Key&Sol’s
22. CoCl3 .3NH 3 , vinyl chloride failed
23.

24. a , b, f , g
25.
OOCCH 2 CH 2COO 

CH 2CH 2 N
OOCCH 2 CH 2COO 
Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-50_Q’P
CHEMISTRY Max. Marks: 61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
19. The correct IUPAC name of Co  en 3   SO 4 3 is 2

A) [Tris(ethane – 1, 2 – diaminecobalt(III)] trisulphate

B) Tris(ethane -1,2-diamine)cobalt(III) trisulphate

C) Tris(ethane -1,2-diamine)cobalt(II) sulphate

D) Tris(ethane -1,2-diamine)cobalt(III) sulphate

20. Increasing order of EAN of the metals in

2 3 3
(i)  Ni  CN 4  (ii)  Fe  CN 6  (iii) Cu  CN 4  is

A) ii  i  iii B) iii  i  ii C) iii  ii  i D) i  ii  iii

21. I) Fe3 and Mn2 have the same paramagnetic character(consider hydrated ions)

II) Cu2Cl2 is a red coloured compound

III) MnO4 has purple colour and hence has 3d unpaired electrons

IV) The calculated spin only magnetic moment of both Fe 2 and Co3 is 2 6 B.M .

(consider hydrated ions)

Identify the correct statements?

A) only I,II and III B) II and IV only C) I and IV only D) only IV

2
22. Maximum number of atoms in one plane in  Ni  CN 4  (diamagnetic complex) is

A) 8 B) 9 C) 5 D) 4

Sr.IIT_*CO SC Page 9
Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-50_Q’P
23. Which of the following is a correct statement?

A)  MnBr4  is a tetrahedral complex

2

(Given that the calculated spin only magnetic moment of the complex is 5.9 BM)

B) In  Ni  dmg 2   diamagnetic  , the central metal atom and the donor atom of the ligand

are in the same hybridized state

2
C)  Ni  NH 3 6  is a diamagnetic complex

3
D) Cu  CN 4  is a square planar complex

24. The oxidation states of iron atoms in compounds (A), (B) and (C), respectively, are x,
y and z. The sum of x, y and z is _______

Na 4  Fe  CN 5  NOS  , Na 2  FeO 4  ,  Fe 2  CO 9 
A  B C

A) 7 B) 8 C) 9 D) 6

25. The EAN value of central metal in the complex Co  CO 4  is

A) 35 B) 34 C) 36 D) 54

SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
3
26. Which of the following is/are correct about Co  NH 3 6  ?

A) Inner orbital complex B) diamagnetic

C) d 2 sp 3 hybridized central atom D) high spin complex

Sr.IIT_*CO SC Page 10
Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-50_Q’P
27. Which of the following pairs of name and formula of complexes, is / are correct?

A) Tetraamminecopper(II) sulphate…….. Cu  NH3 4  SO 4

B) Diamminesilver(I) chloride…………  Ag  NH3 2  Cl

C) Potassium hexacyanidoiron(III)……… K 4  Fe  CN 6 

D) Potassium amminepentachloridoplatinate(IV)………. K  Pt  NH3  Cl5 

28. Which are correct about [Fe(H2O)5NO]SO4?

(Given that: Calculated spin only magnetic moment of the complex is 15 BM )

A) The secondary valency of the central metal ion is 6

B) Its IUPAC name is pentaaquanitrosyliumiron(I) sulphate

C) Oxidation number of Fe is +2

D) Oxidation number of Fe is +1

29. Which of the following are chelating neutral ligands

A) gly B) en C) dien D) ox

30. Which of the following is/are correct?

(Given that: most of the metal carbonyls exhibit a strong tendency to achieve
Sidgwick EAN values)

(EAN – effective atomic number)(Atomic numbers of Tc = 43, Nb =41, Pt =78)

A)  Mn(CO)6  can act as a reducing agent

B) V (CO )6  can act as an oxidising agent

 
C) Tc  CO 6  act as reducing agent and  Nb  CO 6  act as oxidizing agent

D)  Pt ( NH 3 ) 4 
2
obeys EAN rule

Sr.IIT_*CO SC Page 11
Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-50_Q’P
31. Which of the following is/are incorrect statement(s)?
3
A) Co  C2O 4 3  is a diamagnetic complex (Given that: oxalate is a chelated ligand)


B) In the complex CoCl3 .5 NH 3 , one Cl ion satisfy both primary and secondary

valencies simultaneously.

C) If AgNO3 solution is added to the aqueous solution of the compound CoCl3 .3 NH 3

, a white precipitate is formed.

D)  Pt  NH3 2 Cl2  is a neutral complex in which the oxidation number of Pt is also

zero.

32. Which of the following is/are correct about Valence bond theory?

A) It does not give quantitative interpretation of magnetic data

B) It does not explain colour properties of the complexes

C) It clearly distinguish strong field and weak fields ligands

D) It does not make exact predictions regarding the tetrahedral and square planar
structures of four coordinate complexes

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 33 and 34:
In general ions of the same charge in a given transition series show progressive
decrease in radius with increasing atomic number. This is because the new electron
enters a d orbital each time the nuclear charge increases by unity. It may be recalled
that the shielding effect of a d electron is not that effective , hence the net electrostatic
attraction between the nuclear charge and the outermost electron increases and the
ionic radius decreases

Sr.IIT_*CO SC Page 12
Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-50_Q’P
33. Which of the following is correct statement?

1) The order of IE2 value = Cr > Mn > V

2) Metallic radius of Cu > Zn

3) The atomic size of Hf is much larger than Zr

4) In a group of transition elements, lower oxidation states are stable for heavier
members

34. Which of the following statements is incorrect?(IE – ionization enthalpy)

A) Number of 5s – electrons in Pd are Zero
B) IE3 of Mn is more than that of Fe
C) IE1 of Cu is more than that of Zn but IE2 of Cu is less than that of Zn
D) Low oxidation states are found when a complex compound has ligands capable of
  acceptor character in addition to the   bonding

Paragraph For Questions 35 and 36:

Transition metals vary widely in their chemical reactivity. Many of them are
sufficiently electropositive to dissolve in mineral acids, although a few are noble – that
is, they are unaffected by single acids. The metals of the first d block series with the
exception of copper are relatively more reactive and are oxidized by 1M H  , though
the actual rate at which these metals react with oxidizing agents like hydrogen ion
 H   is sometimes slow.
35. Which of the following will liberate hydrogen from a dilute acid?

A) Cr 2 B) Mn3 C) Co3 D) Cu

36. Which of the following is incorrect statement?

A) E 0 value for the Mn3 / Mn 2 couple much more positive than that for Cr 3 / Cr 2

B) The E 0  M 2 / M  value for copper is negative

C) Many copper(I) compounds are unstable in aqueous solution and undergo

disproportionation
D) VO2  Cr2O72  MnO4 : increasing order of oxidizing power

Sr.IIT_*CO SC Page 13
 Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL

CHEMISTRY
2
22.  Ni  CN 4  : square planar complex
2
23.  Ni  NH 3 6  : paramagnetic complex
3
Cu  CN 4  : tetrahedral complex
24. Na 4  Fe  CN 5  NOS   : Fe  2 
Na 2  FeO 4  : Fe  6 
Fe 2  CO 9 : Fe(0)
3
26. Co  NH 3 6  - low spin complex
27. potassiumhexacyanidoferrate(II)
29. glycinate and oxalate ions: chelating anionic ligands
en – ethane - 1,2 – diamine and dien – diethylenetriamine – chelating neutral complexs
e  
30. A)

 Mn  CO  
6   Mn  CO  
6
EAN  37 EAN  36
0 e  1
B) V  CO   EAN  35  V  CO 6   EAN  36 
31. CoCl3 3 NH 3 : CoCl3  NH 3 3  : non - electrolyte
 Pt  NH  Cl  is a neutral complex in which the oxidation number of Pt is +2
 3 2 2
32. It does not distinguish between strong field and weak fields ligands
33. Metallic radius of Cu < Zn
The atomic size of Hf  Zr(due to lanthanide contraction)
In a group of transition elements, higher oxidation states are stable for heavier members
34. IE1 of Cu is less than that of Zn but IE2 of Cu is more than that of Zn
` Cu :  Ar  4s1 3d10 ; Zn :  Ar  4s 2 3d10

35. Mn 3 and Co3 ions are the strong oxidizing agents in aq solutions. The ions Ti 2 , V 2 and Cr 2 are
strong reducing agents and will liberate hydrogen from a dilute acid
2Cr 2  aq   2H   aq   2Cr 3  aq   H 2  g 

36. The E 0  M 2 / M  value for copper is positive

CHEMISTRY
19 D 20 C 21 C 22 B 23 A

24 B 25 C 26 ABC 27 ABD 28 ABD

29 BC 30 AB 31 CD 32 ABD 33 A

34 C 35 A 36 B
Narayana IIT Academy 14-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-48_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. The correct order of EM0 3 / M 2 is

A) Mn  Fe  Co B) Mn  Co  Fe C) Co  Mn  Fe D) Co  Fe  Mn

20. Among the following bidentate ligands, which one forms more membered chelating
ring with metal ion in mononuclear complex?
A) dipy B) phen C) acac D) dmg
21. Among the following complexes which one gives maximum number of ions per one
formula unit when the complex is dissolved in the water (assume that all complex
compounds are water soluble)

A)Potassium hexacyanoferrate(II) B)Iron(III) hexacyanoferrate(II)

C) Iron(II) hexacyanoferrate(III)

D)Tetraaquadichloridocobalt(III) hexacyanochromate(III)

22. On treatment of100ml of 0.1M solution of CoCl3.6H2O with excess of AgNO3

,1.2X1022 ions are precipitated. The complex is

A) Co  H 2O 4 Cl2  Cl.2 H 2O B) Co  H 2O 5 Cl  Cl2 .H 2O

C) Co  H 2O 3 Cl3  3H 2O D) Co  H 2O 6  Cl3

23. The magnetic moment of a certain complex (A) of Co was found to be 4.89 B.M and the
EAN as 36.Co also forms complex (B) with magnetic moment 3.87 B.M and EAN 37,
and complex (C) with EAN as 36 but diamagnetic. Which of the following statements is
true regarding the above observation?

A)The oxidation states of Co in (A),(B)and (C) are +3.+2 and +3 respectively.

B)Complexes (A) and (B) have sp 3 d 2 hybridization state while (C) has dsp 3
hybridization state.
C)The spin multiples of Co in (A),(B)and (C) are 4,3 and 1 respectively
D)The oxidation states of Co in (A),(B) and (C) are +6,+8, and +1 respectively.
Narayana IIT Academy 14-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-48_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
24. In which of following unipositive ions one 4s electron present

A)Ti+ B)V+ C)Mn+ D)Zn+


25. Which of the following statement is correct for Co  edta   complex?

A) Number of N  Co  O linkages are ‘8’

B) Coordination number of central metal is ‘6’

C) EAN of central metal is 36

D) Five membered chelations rings 5 present

26. Some complexes and EAN of their central metal ions given below. The correct match
is/are

A) Ti   C5 H 5   C5 H 5    34 B)Ferrocene  Fe  5  C5 H 5 2  -36

C)  Fe  H 2O 5  NO   SO4  37 D)  Fe  CO 2  NO 2   36

27. Which of the following is/are  acceptor ligand?

A) CO B) CN  C) NO D) NH 3

28. In sp3d 3 hybridization which d atomic orbitals are involved?

A) d xy B) d x  y
2 2 C) d xz D) d z 2

29. Number of isomers possible for Co  NH 3 4 Cl2  Cl are

A) Three if it exist in planar hexagon structure

B) Three if itexist intrigonal prism structure

C) Two if it exist inoctahedral structure

D) Three if it exist in octahedral structure

Narayana IIT Academy 14-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-48_Q’P
30. In which of the following chelating ligands, different types of atoms acting as donor
atoms

A) edta 4 B) Dimethyl glyoximato

C) Glycinato D) Nitrilotriacetato

31. Correct statement but K 4  Fe  CN 6  is/ are

A) Primary valence of iron is two

B) Secondary valence of iron is six

C) Two cyanide ions satisfy both primary and secondary valence

D) It is anionic and homolyptic complex

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. Among the following how many do not exist

TiF2 ,VF2 , CrF2 , FeI 3 , CuI 2 , CuBr2 , FeCl3 , CuF , PbI 4 , BiCl5 , PH 5

33. How many of the following show increase in weight in applied magnetic field?

NO, NO2 , O2 , MnSO4 , NiSO4 , CuSO4 , ZnSO4 , K 2Cr2O7 , Cl2

If  PtCl6  follows Sidgwick rule of stability , x value is

x
34.

35. Find the number of Co-N linkages in

Pentaaminecobalt(III)-  -amidodiamminetriaquacobalt(III)chloride.

36. One mole of each PdCl2.4NH3 and PtCl4.2HCl gives two moles and zero moles of

silver chloride precipitate with excess of silvernitrate solution, the difference in

secondary valence of platinum and palladium is

Narayana IIT Academy 14-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-48_Key & Sol’s
CHEMISTRY
20. C) Six member ring
21. B) 7 ions
24. For V  and Ti  when electron jump from 4s to 3d, there is gain in exchange energy.
26.   C5 H 5 is 2 electrons donor.
  C5 H 5 is 6 electrons donor.
27. CO, CN  , NO  have empty  *  orbital. Thus they are   acceptor ligands.
29. When coordination number is 6, structure is Octahedral. Werner finalized this by
comparing the experimentally possible isomers and number of possible isomers with
different structures like Planar hexagon, Trigonal prism and Octahedral. (J.D.Lee,
PgNo.197)
30. edta 4 - Four N and two O
dmg - Two N
gly - One N, One O
nta3 - One N, three O
32. Except CrF2 , CuBr2 , FeCl3
33. Para magnetic substances
NO, NO2 , O2 , MnSO4 , NiSO4 , CuSO4 .
36. PdCl2  4 NH 3   Pd  NH 3 4  Cl2 , S.V. of Pd is 4
PtCl4  2 HCl  H 2  PtCl6  , S.V. of Pt is 6.

19 C 20 C 21 B 22 A 23 A

24 CD 25 ABCD 26 BCD 27 ABC 28 ABD

29 ABC 30 ACD 31 ABCD 32 8 33 6

34 2 35 9 36 2