KANHA MAKHAN PUBLIC SCHOOL

CLASS-12 SUBJECT-CHEMISTRY
WORKSHEET-SOLUTIONS
1. Isotonic solutions have
(a) same osmotic pressure (b) same boiling point
(c) same melting point (d) same vapour pressure
2. Value of Henry's constant KH
(a) increases with decrease in temperature (b) decreases with increase in temperature
(c) increases with increase in temperature (d) remains constant.
3. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid
solvent Does not depend upon
(a) Temperature (b) Nature of solute
(c) Pressure (d) Nature of solvent
4. The value of Henry's constant KH is
(a) greater for gases with higher solubility. (b) greater for gases with lower solubility
(c) constant for all gases. (d) not related to the solubility of gases.
5. The vapour pressure curve of the mixture of ethanol and acetone is higher than its constituents,
because of
(a) Weaking of interactions between molecules takes place
(b) Strengthening of interactions between molecules takes place
(c) New hydrogen bonds are formed
(d) Molecules are not able to escape from the solution
6. An azeotropic mixture of two liquids has a boiling point higher than either of the two liquids when it
(a) Shows large negative deviation from Raoult's law
(b) Shows no deviation from Raoult's law
(c) Shows large positive deviation from Raoult's law.
(d) Obeys Raoult's law.
7. Which one of the following pairs will not form an ideal solution?
(a) Benzene and Toluene (b) Nitric acid and Water
(c) Hexane and Heptane (d) Ethyl chloride and Ethyl bromide
8. Adding a salt to water leads to increase in the boiling point of solution with respect to water because
(a) Vapour pressure of solution is increased (b) Solubility of salt in water is increased
(c) Solubility of salt in water is decreased (d) Vapour pressure of solution is decreased
9. Salt is used to clear snow on the roads covered with snow to:
(a) Decrease the freezing point (b) Increase the boiling point
(c) Increase the osmotic pressure (d) Increase the solubility of salt
10. Which of the following is a colligative property?
(a) Vapour pressure (b) Osmotic pressure
(c) Freezing point (d) Boiling point
11. Blood cells collapse, when placed in water containing less than 0.9% mass by volume salt solution.
This is due to
(a) Reverse osmosis (b) Gain of water by osmosis
(c) Loss of water by osmosis (d) Diffusion
12. In isotonic solutions
(a) solute and solvent both are same
(b) osmotic pressure is same
(c) solute and solvent may or may not be same.
(d) solute is always same solvent may be different.
13. Coligative properties are observed when
(a) a non volatile solid is dissolved in a volatile liquid
(b) no solution is formed
(c) a gas is dissolved in non volatile liquid.
(d) a volatile liquid is dissolved in another volatile liquid
 14. A compound undergoes complete dimerization in a given organic solvent. The van't Hoff factor 'i' is
(a) 2.0 (b) 0.5 (c) 0.25 (d) 1.0

For Question No. 15 & 16

Given below are two statements labeled as Assertion (A) and Reason (R).
Select the most appropriate answer from the options given below :
(a) Both (A) and (R) are true and (R) is the correct explanation of (A) .
(b) Both (A) and (R) are true, but (R) is not the correct explanation of
(c) (A) is true, but (R) is false.
(d) (A) is false, but (R) is true.
15. Assertion (A): Elevation in boiling point is a colligative property.
Reason (R): The lowering of vapour pressure of solution causes elevation in boiling point.
16. Assertion (A): Osmotic pressure is a colligative property.
Reason (R): Osmotic pressure is proportional to the molality
17. On mixing liquid X and liquid Y, volume of the resulting solution decreases
(A). What type of deviation from Raoult's law is shown by the resulting solution?
(B)What change in temperature would you observe after mixing liquids X and Y?
18. Give reasons:
(A) Cooking is faster in pressure cooker than in cooking pan
(B) Red Blood Cells (RBC) shrink when placed in saline water but swell in distilled water.
19. Out of 0.1 molal aqueous solution of glucose and 0.1 molal aqueous solution of KCl, which one will
have higher boiling point and why?
20. Predict whether van't Hoff factor, (i) is less than one or greater than one in the following:
(A) CH3COOH dissolved in water (B) CH3COOH dissolved in benzene
21. Define the following terms
(A) molality (B) mole fraction (C) vant hoff factor (D) Colligative properties
22. State Henry's law. Why is air diluted with helium in the tanks used by scuba divers?
23. Define Azcotrope. What type of azeotrope is formed by negative deviation from Raoult's Law?
Give an example
24. An antifreeze solution is prepared by dissolving 31 g of ethylene glycol (Molar mass - 62 g /mol) in
600 g of water. Calculate the freezing point of the solution. (Kf for water 1.86 K kg/ mol)
25. Elevation of boiling point of 1 M KCI solution is nearly double than that of 1 M sugar solution A
10% solution (by mass) of sucrose in water has freezing point of 269.15 K. Calculate the freezing
point of 10% glucose in water, if freezing point of pure water is 273.15 K. Given: (Molar mass of
sucrose 342 g mol) (Molar mass of glucose = 180 g/ mol)
26. Write 2 characteristics of non-ideal solution.
27. 2g of benzoic acid dissolved in 25 g of benzeneshows a depression in freezing point equal to 1.62K.
What is the percentage association of acid if it forms dimer in solution? (molal depression constant
for benzene is 4.9 K Kg/mol)