CO-ORDINATION COMPOUNDS

TUTORIAL–3
1. In which of the following octahedral complexes of Co (At. no. = 27), will the magnitude of
o be the highest ?
(a) [Co(C2O4)3]3– (b) [Co(H2O)6]3+ (c) [Co(NH3)6]3+ (d) [Co(CN)6]3–
2. [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4 are a pair of ............ isomers.
(a) Ionization (b) Ligand (c) Coordination (d) Hydrate
3. Type of isomerism shown by [Cr(NH3)5NO2] Cl2 is
(a) optical (b) hydration (c) geometrical (d) linkage
4. The organometallic compound is
(a) Ti(OCOCH3)4 (b) Ti(C2H4)4 (c) Ti(OC6H5)4 (d) Ti(OC2H5)4
5. The type of isomerism in coordination compounds [Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [CuCl4]
is
(a) coordination isomerism (b) geometrical isomerism
(c) ionization isomerism (d) linkage isomerism
6. In Fe(CO)5, the Fe—C bond possesses
(a) both  and  characters (b) ionic character
(c) -character only (d) -character only
7. [Fe(NO2)3Cl3] and [Fe(ONO)3Cl3] shows
(a) linkage isomerism (b) geometrical isomerism
(c) optical isomerism (d) None of these
8. The coordination compounds
[Co(NH3)6]3+ [Cr(CN)6]3– and [Cr(NH3)6]3+ [Co(CN)6]3– are the examples of
(a) linkage isomerism (b) coordination isomerism
(c) ionization isomerism (d) geometrical isomerism
9. The example of coordination isomerism is
(a) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6]
(b) [Co(NH3)5 Br] SO4 and [Co(NH3)5SO4] Br
(c) [Co(NH3)5NO3]SO4 and [Co(NH3)5SO4]NO3
(d) [Pt(NH3)4Cl2]Br2 and [Pt(NH3)4Br2]Cl2
10. Which of the following compound would exhibit coordination isomerism ?
(a) [Cr(en)2]NO2 (b) [Cr(H2O)6]Cl3
(c) [Cr(NH3)6] [Co(CN)6] (d) None of these
11. Nitropentaamminechromium (III) chloride shows isomerism
(a) geometrical (b) optical (c) linkage (d) All of these
12. CH3MgBr is organometallic compound due to
(a) C—Mg bond (b) CH3—Br bond (c) C—H bond (d) All of these

13. Optical isomerism is not shown by the complex :

(a) [Cr(ox)3]3– (b) [Co(en)2Cl2]+ (cis-form)
(c) [Co(en)2Cl2]+ (trans-form) (d) [Cr(en)3]3+
ox oxalate; en ethylenediamine

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14. Which of the following is not considered as an organometallic compound ?
(a) Ferrocene (b) Cis-platin
(c) Zeise’s salt (d) Grignard reagent
15. Which of the following is considered to be an anticancer species ?
CH2
Cl
CH2 Cl Cl
Pt
Pt
(a) Cl (b)
Cl Cl
Cl

H3N Cl H3N Cl
Pt Pt
(c) (d)
H3N Cl Cl NH3
16. The ligand called -acid is :
(a) CO (b) NH3
(c) C 2 O 42  (d) ethylene diamine
17. Octahedral complex,

a a b

M
is :
a b
b
(a) cis (b) trans (c) mer (d) fac
18. [Cr(NH3)5Br]Cl and [Cr(NH3)5Cl]Br can be distinguished by/and isomerism shown is :
(a) BaCl2, ionisation (b) AgNO3, ionisation
(c) AgNO3, coordinate (d) BaCl2, linkage
19. Lead poisoning in the body can be removed by :
(a) EDTA in the form of calcium dihydrogen salt
(b) cis-platin
(c) Zeisse’s salt
(d) DMG

ANSWER KEY

1. (d) 2. (a) 3. (d) 4. (b) 5. (a) 6. (a)

7. (a) 8. (b) 9. (a) 10. (c) 11. (c) 12. (a)
13. (c) 14. (b) 15. (c) 16. (a) 17. (d) 18. (b)
19. (a)

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