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Chemistry Review00
Chemistry Review00
Chemistry Review00
Mole City
All atoms of every single element are not necessarily stable, but they are electrically neutral.
Oxygen
one atom – 16 AMUs
one mole – 16 grams
Steps to Calculate Molarity: Pg. 205 #42:
1. convert units to moles if 5.23 g Fe(NO 3 ) 2 in 100.0 cm3 of solution 1(Fe) - 55.845
needed 5.23 g moles: 2 (N) - 28.000
2. put in the form of moles per 1 mol 6 (O) - 96.000
____________________
liter 5.23 g × ----------- = .029080 mol
3. done 179.845g 179.845
Empirical Formula
Steps pg. 210 #56:
1. convert grams to moles empirical formula of a compound that contains 1.67 g Ce, and 4.54 g I.
2. write formula using moles 1.67 x 1 mol/ 140.12 g = .011918 %Ce = 26.90%
3. divide by smaller number and
round to nearest whole 4.54 x 1 mol/ 126.90 g = .035776 %I = 73.1%
Ce .011918 I .035776 = CeI 3
Hydrates
Steps BaI 2 · ? H 2 O; mass of 10.407 g; dry BaI2 has a mass of 9.520 g.
1. convert grams to moles 9.520 BaI 2 · .887 H 2 O
2. divide by smaller number and
round to nearest whole 9.520 BaI 2 x 1 mol/ 391 g = .0243mol / .0243 1
3. write equation .887 H 2 O x 1 mol/ 18 g = .0493mol / .0243 2
*substance is ALWAYS ONE. BaI 2 · 2H 2 O
Reaction Description
Synthesis Substance + Substance Compound
Decomposition Compound Substance + Substance
Single Displacement Element + Compound Different Element + Different Compound
Double Displacement Compound + Compound Compound + Compound
Combustion Hydrocarbon + Oxygen Carbon Dioxide + Water
1. Carbon 2. Hydrogen 3. Fix Oxygen (Half Molecules May Be Needed)
Diatomic Molecules: H, N, O, F, Cl, Br, I (make a 7 on Periodic Table)
Nitric Acid – H(NO 3 )
Carbonic Acid – H 2 (CO 3 )
Sulfuric Acid – H 2 (SO 4 )
Multiple Oxidation States: Copper, Lead, Iron, Nitrogen
(l) – liquid (g) – gas (c) (cr) – solid (aq) – aqueous (in water)
anode/cation – positive (anode – ain’t negative)
cathode/anion – negative
Q = m(ΔT)C p
Pg. 72 #35:
BP: 2600°C & FP: 1400°C, C p =0.1733 J/g°C Joules to heat 10.0g from FP to BP?
Q = 10.0g (1200°C).1733 J/g°C
Q = 2079.6 J OR 2.0796 kJ
Ex: 10g Ag ring @ 50°C put into 100 ml of H 2 O @ 1°C; find final temperature of the system
Q LOST BY SILVER = Q GAINED BY WATER
m(ΔT)C p = m(ΔT)C p hot final cold
10(ΔT).2350 = 100(ΔT)4.18 [50°C - (X] - 1°C)
10(50 – x).2350 = 100(x – 1)4.18
2.350(50 - x) = 418(x - 1)
(50 – x) = 177.87(x – 1)
50 – x = 177.87x – 177.87
227.87 = 178.87x
x = 1.27°C
Millikan and the “Oil Drop Experiment” – proved that electron charge is negative by using an atomizer.
Neils Bohr – planetary model of the atom (definite energy levels, but not on the same plane)
Electromagnetic Spectrum – Wavelength (λ); Frequency – cycles/second – Hz; Amplitude - height
Max Planck – quantum theory (energy is given off in little “packets” called “quanta” or photons.)
Newtonian Mechanics vs. Quantum Mechanics
ordinary objects at ordinary velocities vs. infinitesimally small objects at light speeds
De Broglie (de BROY) – Wave-Particle Duality of Nature
Refraction – bends due to change in medium; the more bends, the easier something is to see
Index of Refraction – degree to which a substance bends light
Momentum = mass x velocity
Werner Heisenberg – Heisenberg Uncertainty Principle – We can NEVER know both the exact position and
momentum of an electron. The more certain we are of one, the less certain we are of the
other.
– WHY: To determine the position of an electron, you have to see it. If you see an
electron, it has had a collision with a photon of light. The collision alters the
electron’s velocity, thus changing its momentum.
Schrödinger – developed wave equation (describes electron behavior)
Quantum Numbers
1. Principal Quantum Number – N – cloud size and energy level
To determine the maximum number of electrons in an energy level = 2n2 (n - # of energy levels)
2. Azimuthal Quantum Number – L – cloud shape and sublevels
To determine the number of sublevels that make up an energy level: l = n (n - # of energy levels)
3. Magnetic Quantum Number – M – orbitals and direction in space of orbitals
Orbitals make up sublevels and can house up to two electrons.
Sublevel Number of Orbitals Max e-
S 1 2
P 3 6
D 5 10
F 7 14
odd numbers x 2
4. Spin Quantum Number – S – spin of electron (one spins clockwise, one spins counter-clockwise)
s p d f
1
2
3
4
Electron Configuration – Diagonal Rule Chart: (Go through one, one, then two, two, three, three, four, four)
1s2
2s2 2p6
3s2 3p6 3d 10
4s2 4p6 4d 10 4f 14 (energy level) (sublevel) # of electrons
2 6 10 14
5s 5p 5d 5f
6s2 6p6 6d 10
7s2 7p6
(8s2)
Ex: Bromine (35 e-) - 1s2 2s2 2p6 3s2 3p6 3d 10 4s2 4p5
Lewis Electron Dot Diagram – show the valence electrons as dots around the chemical symbol of the element.
6 3
2
4
7 Ga
5 8
1 Z = 31: Ga
Pauli Exclusion Principle – no two electrons in the same atom can have all the same quantum numbers.
56 mm 7.5 mm CONSTANT
----------- = ----------
7.5 kPa 1 kPa
7.5 kPa
+ 102.2 kPa (atmospheric pressure)
109.7 kPa
The gas moved the mercury towards the open end, so the
gas pressure is greater than atmospheric pressure. Hence,
you add the atmospheric pressure in the end. In a closed
manometer, the number you get in the proportion is your
answer because atmospheric pressure is not involved.
Boltzman Distribution Law – Most particles in a given system have a kinetic energy at or about the average,
but some are above and some are below.
Saturated – When a substance is in equilibrium with its vapor, the gas phase is saturated.
Dynamic Equilibrium – Rates of change from liquid to gas and vice versa are equal.
Vapor – Prefers to be a liquid at room temperature
Gas – Prefers to be a gas at room temperature
Le Chatelier’s (SHOT-LEE-AY) Principle – If you take a system at equilibrium and place a stress on that
system, it will respond so as to relieve the stress. (Stress can be a change in temperature, pressure, or
concentration)
Vapor Pressure – the tendency of a substance to move towards the gaseous state.
Volatile Non-Volatile
High Vapor Pressure Low Vapor Pressure
Weak Intermolecular Forces Strong Intermolecular Forces
Rapid Evaporation Slow Evaporation
Low Critical Temperature High Critical Temperature
Low Boiling Point High Boiling Point
Ex: Alcohol, Dry Ice, Gasoline Ex: Glycerol (Lotion), Ethylene Glycol
Hydrogen Bonding – Hydrogen atoms are not affected by Van der Waals forces, but still have strong bonds.
Melting Point – (same as freezing point), temperature at which a solid changes to the liquid state and the V.P.
of the solid is equal to the V.P. of the liquid.
Sublimation – when a solid changes directly to the gaseous state without passing through the liquid state. (very
high vapor pressure) Ex: solid CO 2 (dry ice), iodine, mothballs, snow
Deposition – the process of changing directly from a gas to a solid without passing through the liquid state.
Boiling vs. Evaporation – Evaporation occurs only at the surface and will happen at temperatures lower than
the boiling point.
Boiling Point – the temperature at which the vapor pressure on the surface of the liquid equals the vapor
pressure within the liquid.
Normal Boiling Point – the temperature at which a substance boils when the pressure on the surface in 1atm
(101.325 kPa)
Pressure will change the boiling point and the melting/freezing point.
Liquefaction – the condensation of a substance that is typically a gas. To liquefy a gas, lower the temperature
and raise the pressure.
T c (Critical Temperature) – the temperature above which no amount of pressure can cause liquefaction. (T c is
usually very high.)
P c (Critical Pressure) – the quantity of pressure required to liquefy a gas that is at its critical temperature.
Phase Diagram – shows the relationship between temperature, pressure, and the physical state of a substance.
**Any point on any one of the three lines represents an equilibrium between two states of
matter.**
H f (Enthalpy of Fusion) – the quantity of heat that is required to melt one gram of a substance that is at its
melting point.
H v (Enthalpy of Vaporization) – the quantity of heat that is required to vaporize one gram of a substance.
Ex: How much heat is needed to change the temperature of 10g of ice from -10°C to 110°C?
C p ice = 2.06 J/g°C H f ice = 334 J/g
C p H 2 O = 4.18 J/g°C H v H 2 O = 2260 J/h
C p steam = 2.02 J/g°C
• -10°C to 0°C Q = m(ΔT)C p = 10 (10) (2.06) = 206 J
• H melt = m(H f ) Q = 10 (334) = 3340 J
• 0°C to 100°C Q = 10 (100) (4.18) = 4180 J
• H boil = m(H v ) Q = 10 (2260) = 22600 J
• 100°C to 110°C Q = 10 (10) (2.02) = 202 J
Total = 30,528 J
S.T.P. – Standard Temperature and Pressure - 0°C (273K) and 101.325 kPa
An Ideal Gas is composed of Point Masses – infinitely small points with no volume, only mass, and not
subject to Van der Walls forces.
Boyle’s Law – (pressure change) If the temperature remains constant, the pressure will vary inversely as the
volume.
Ex: A gas has a volume of 200 cm3 and has a pressure of 150 kPa. What pressure will this gas have at a volume
of 225 cm3? (Assume temperature is constant.)
P 1 = 150 kPa
P 2 = ___ kPa 200 cm3
T1 = 150 kPa x ----------- = 133.3 kPa
T2 = 225 cm3
V 1 = 200 cm3
V 2 = 225 cm3 V↑ P↓ Pressure is going DOWN, so put the SMALLER one on top.
Charles’ Law – (temperature change) the volume of a gas, held at a fixed pressure, will vary directly as the
KELVIN temperature.
(Kelvin because Celsius scale uses a zero and zero can mess you up in fractions.)
Problems work the same as Boyle’s Law.
°C + 273 = K
Combined Gas Law – You can correct a volume of gas for not only a change in pressure but also a change in
temperature at the same time.
Ex: A gas has a volume of 250 cm3, a pressure of 103 kPa, and a temperature of 75°C. What volume will this
gas have if the pressure is 250 kPa and the temp is 120°C?
P 1 = 103 kPa P↑ V↓
P 2 = 250 kPa 103 kPa 393 K
T 1 = 348 K T↑ V↑ 250 cm x ------------- x --------- = 116.32 cm3
3
When acids/bases combine with H 2 O, they conduct electricity and are called electrolytes.
Arrhenius’ Theory – When these substances go into solution, they break down into charged particles.
Gilbert Newton Lewis’ Theory – Not all acids and bases focus on proton transfer (Hydrogen). The Lewis
Theory focuses on electron transfer and is very commonly associated with organic acids.
Lewis Acid – electron pair ACCEPTOR.
Lewis Base – electron pair DONOR.
Acids – sour; lemons cation is usually Hydrogen anion either IS or CONTAINS a non-metal
any substance which, when dissolved in water, will produce hydrogen ions. (H+ is a bare proton.)
HCl H+ + Cl- (ionization)
Brönsted-Lowry Theory - any substance that will DONATE a proton.
Bases – bitter; soap cation is a metal anion is usually Hydroxide (OH)1-
any substance which, when dissolved in water, will produce hydroxide ions.
Na(OH) Na+ + (OH)-
Brönsted-Lowry Theory - any substance that will ACCEPT a proton.
Salts – salty; table salt
Conjugate Base – particle that remains after the acid has donated a proton.
Conjugate Acid – particle formed after the base gains a proton from the acid.
HCl + H 2 O H 3 O+ + Cl-
NH 3 + H 2 O NH 4 + + OH-
Binary Acids – contain two and only two different elements. (cation is Hydrogen)
Naming: hydro + root element modified “to sound good” + ic
Ex: hydrosulfuric acid – H 2 S
Ex: H 2 Te – hydrotelluric acid
Ternary Acids – usually contain three different elements. (cation is Hydrogen; usually anion is a polyatomic
ion containing a non-metal and usually the last element is oxygen)
Naming: Most Common Form: arises from the “ate” polyatomic ions
no prefix + root nonmetal + ic
One Less Oxygen Form: arises from the “ite” polyatomic ions
no prefix + root nonmetal + ous
Two Less Oxygen Form: arises from nothing
hypo + root nonmetal + ous
One More Oxygen Form: arises from nothing
per + root nonmetal + ic
One More Oxygen Most Common One Less Oxygen Two Less Oxygen
per + root + ic root + ic root + ous hypo + root + ous
H(NO 4 ) – pernitric acid H(NO 3 ) – nitric acid H(NO 2 ) – nitrous acid H(NO) – hyponitrous acid
H 2 (SO 5 ) – persulfuric acid H 2 (SO 4 ) – sulfuric acid H 2 (SO 3 ) – sulfurous acid H 2 (SO 2 ) – hyposulfurous
H 2 (CO 4 ) – percarbonic H 2 (CO 3 ) – carbonic H 2 (CO 2 ) – carbonous H 2 (CO) – hypocarbonous
acid acid acid
H(ClO 4 ) – perchloric acid H(ClO 3 ) – chloric acid H(ClO 2 ) – chlorous acid H(ClO) - hypochlorous
*the number of hydrogen stays the same because the oxidation numbers stay the same when changing oxygen*
Ex: Name: H 2 SeO 2 H 2 (SeO 4 ) – selenic acid hyposelenous acid (two less oxygen)
Ex: Write: tellurous acid H 2 (TeO 4 ) – telluric acid H 2 TeO 3 (one less oxygen)
Ex: Write: periodic acid H(IO 3 ) – iodic acid H(IO 4 ) (one more oxygen)
Ex: Write: HBr hydrobromic acid
Acidic Anhydrides – any nonmetal oxide which when dissolved in water will produce an acid (synthesis
reaction). Ex: CO 2 + H 2 O H 2 (CO 3 ) Ex: SO 2 + H 2 O H 2 (SO 3 ) ***ACID RAIN***
Basic Anhydrides – any metallic oxide which when dissolved in water will produce a base (synthesis reaction).
Ex: Na 2 O + H 2 O 2Na(OH)
Why Acids Act Like Acids and Bases Act Like Bases
Electronegativity – the ability/tendency of an atom to attract a shared pair of electrons to itself (chemical
bonds).
Groups IA & IIA – lowest electronegativity (They are trying to get rid of one or two electrons, not gain more.)
Groups on Right – highest electronegativity (They only need to attract a few electrons before they are full.)
The Shielding Effect – When filled inner energy levels block the attraction of the nucleus from reaching the
outer electrons
F highest electronegativity
LOWEST
HIGHEST
increases
electronegativity increases
lowest electronegativity Fr
1. distance of electrons from nucleus
2. the shielding effect
Most Common Elements in Acids & Bases:
H : O : X ; if element X is very HIGHLY electronegative (nonmetal), then the electron pair it
shared electrons is sharing with Oxygen will be more attracted by X. In water, X will take the
electrons from Oxygen, which will in turn take electrons from Hydrogen. When
+
ionization occurs, H ions are produced. ACTS LIKE AN ACID. ; if element X is very LOWLY
electronegative (metal), then the electron pair will be more attracted by O. In water, O will take the electron
pair. When ionization occurs, X+ ions and (OH)- ions are produced. ACTS LIKE A BASE.
Amphoteric – acts as an acid and a base; ex: water.
Haber Process – extracting atmospheric nitrogen and making ammonia (NH 3 )
Allotrope – two different forms of the same element; ex: graphite and diamonds
Galvanization – coating Iron with Zinc to prevent rusting.
Entropy - disorder
**The element being REDUCED is found in the OXIDING agent and vice versa**
1+ 5+ 2- 1+ 3+ 2- 2+ 2- 1+ 5+ 2- 1+ 2-
Ex: H(NO 3 ) + H 3 (PO 3 ) NO + H 3 (PO 4 ) + H 2 O
N reduced, oxidizing agent: NO 3 ; P oxidized, reducing agent: H 3 PO 3
1+ 5+ 2- 1+ 3+ 2- 2+ 2- 1+ 5+ 2- 1+ 2-
Ex: H(NO 3 ) + H 3 (PO 3 ) NO + H 3 (PO 4 ) + H 2 O
strong acid weak acid oxide weak acid water
Reduction Oxidation
(4H+ + 3e- + NO 3 NO + 2H 2 O) x 2 (H 2 O + H 3 (PO 3 )
H 3 (PO 4 ) + 2e- + 2H+) x 3
4+ 3- 5+ 6- 2+ 2- 4+ 4- 2+ 2- 3+ 3+ 6- 3+ 5+ 8- 2- 2+
82H + 6e + 2NO 3 + 3H 2 O + 3H 3 (PO 3 ) 2NO + 4H2 O + 3H 3 (PO 4 ) + 6e + 6H+
+ - -
2H+ + 2NO 3 + 3H 3 PO 3 2NO + H 2 O + 3H 3 PO 4
pH and pOH
pH – a measure of hydronium ion concentration – [H 3 O+]
pOH – a measure of hydroxide ion concentration – [OH-]
on the pH scale: 0 ≤ acidic < 7 < basic ≤ 14
pH + pOH = 14 [H 3 O+] x [OH-] = 1 x 10-14 pH = -log[H 3 O+] pOH = -log[OH-
]
Ex: If [H 3 O+] is 10-7, what is the pH? 7
Ex: If the pH is 8, what is [H 3 O+]? 10-8
Ex: If [H 3 O+] is 4.37 x 10-4, what is the pH? pH = -log[4.37 x 10-4] = -(log 4.37 + log 10-4) = 3.36
Ex: If the pH is 2.3, what is [H 3 O+]? 2.3 = -log[H 3 O+] -2.3 = log[H 3 O+] 10-2.3 = [H 3 O+] = 5 x 10-3
Radioactive Decay
alpha – nuclei of He atoms
beta – electrons
gamma – electromagnetic radiation (most common
form of penetrating radiation)
alpha + beta = He atom
beyond Z=83, all radioactive
Inverse Square Law - some physical quantity or
strength is inversely proportional to the square of
the distance from the source of that physical
quantity. (twice as far away, ¼ the effect)
Strong Interaction – stronger than the force of
repulsion between two protons
mass (A) 4
protons (Z) 2 He+ one proton = 53Li
As you add protons, the nucleus gets bigger, and
you need more and more neutrons.
Transmutation – when atoms change from one
form to another.
Natural Transmutation –
238
92 U 42He + 23490Th
First Artificial Transmutation –
14
7 N + 42 He 11 H +178 O
Freezing Point Depression/Boiling Point Elevation
Molality – moles of solute per kg (1000g) of H 2 O
Ex: What is the freezing-point depression of water in a solution of 35g of glucose, C 6 H 12 O 6 , and 200.0g of
water? (Molal freezing point depression constant for water is -1.86°C/m.)
35g C 6 H 12 O 6 1 mol C 6 H 12 O 6 1000g H 2 O -1.86°C
------------------- x --------------------- x --------------- x ------------ = -1.8°C
200g H 2 O 180g C 6 H 12 O 6 1 kg H 2 O 1 mol/kg
Ex: What is the expected boiling-point elevation for a solution that contains 100g of calcium nitrate, Ca(NO 3 ) 2 ,
and 700g of water? (Molal boiling point elevation constant for water is 0.51°C/m.)
100g Ca(NO 3 ) 2 1 mol Ca(NO 3 ) 2 1000g H 2 O 0.51°C
--------------------- x ----------------------- x --------------- x ------------- = .44°C
700g H 2 O 164.1g Ca(NO 3 ) 2 1 kg H 2 O 1 mol/kg