biological pro REACTION KINETICS Apart from playing an important role in industries and study of kinetics also plays a tole in environmental and atmospheric chemistry as part of an eftort to understand a variety ‘of issues ranging from the fate of prescription pharmaceutical in ‘waste Waterto cascade of reactions involved in theazoneeydle Rate of Reaction (Change in concentration of reactams er products as function of ime (Unit emalL-! loro) Differential Rate Equation aAtbR—> eC =dD “Vaal __ tds) vale]_ 119) Mie bi ei a InstantaneousRate Average Rate AR ae “de ar” AL Rate Lav/Rate Equation 2 The expression of rate in terme of molar concentration of reactants. Forreaclion, aA +hB —> et!+dD Rate=KlA/ 1B)" Where, h = rate wonstant or specifi: reaction rate Depondsonly upen temperature. Emo ™ © Unitofe= NT vier, onder ofreution Order of Reaction Sum of powers of concentratien terms in the rate lawexprossien, Rate=KLAILB)* Order=142=3 © ForntMorder, © Experimental concept and cin be 2610 or fractional. © Depends upon pressurcand \emperatuce, Molecularity of Reaction ‘the number of molecules of reactants taking partin elementary step ofs reaction, ¢ ‘Theoretical concept and can never he vero or fractional. © Independent of pressureand temperate. Integrated Rate Equation Zero Order Reaction © Rute horkt— [Rhy [8] # Unitof k= mal Toler! ‘Rly © typ halraite)= o ae nition 23, © Uniutk: ‘ + hy. 0074 ® Tn termsof pressure, 22h ag lolR, Rate—> In[Ri—> =-slope = Ta Useful elationsfor Fist Order Reaction fig 2 star. sni Hija toa.rs— Ata fygces— Staton om — Oho Second Order Reaction © Rate=K[R]’ or V/[R]p=kt+1/L Ry, cra nt” Order Reaction we Rate=k(R" orin—Lik= 1-4 © Uniturk=(moll Y's! Pla 1a RIS + Dependency of Rate on) Temperature Arrhenius Equation Ag PART Here, A = pre-exponential fretor R =Cas constant &,= Activationenergy < tog’? = _ Fa a, 2.3038 Activation Energy (Ea) Lovrgy reyuired by the reactant molecules for effective collisions to form products, ‘The slope of ln k we VT has the value ~By/R and is used to calculate valve oF Effect of Catalyst on Activation Energy ‘A catalyst incceases the rate of reaction by providing a path of lower activation enemgy. Reaetionpath ssi clas pan iS ‘tals Reaviaits tiers Produces Reaction oveinate —> Temperature Coefficient Th ig the ratin of Kaus to ky For every 10° rise in temperature the rate becomes double Collision Theory Rate P-L gerbe! sins EE