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Design Fabrication and Characterization of High-Performance PMUT Arrays Based On Potassium Sodium Niobate
Design Fabrication and Characterization of High-Performance PMUT Arrays Based On Potassium Sodium Niobate
Abstract— The demand for high-performance lead-free comparable piezoelectric properties but without drawbacks of
piezoelectric ultrasound transducers has grown significantly, the lead content. Ferroelectric materials with perovskite struc-
driven by their applications in implantable, biocompatible ture (ABO3 ), such as barium titanate (BT), potassium niobate
medical devices and environmentally friendly consumer (KN), barium strontium zirconate titanate (BSZT) and potas-
electronics. In this study, we present the design, fabrication, and
characterization of arrays of lead-free (K, Na)NbO3 (KNN)-based sium sodium niobate (KNN) are promising lead-free piezo-
piezoelectric micromechanical ultrasonic transducers (PMUTs) electric materials and have been used for traditional ultrasound
with a center frequency of 4.7 MHz in liquid and 5.85 MHz in air. transducers as demonstrated by numerous studies [6], [7], [8].
High-quality KNN thin film (FWHM of 0.32◦ , e31, f = −12 C/m2 , However, traditional ultrasonic transducers operating in
ϵ r = 1200) was deposited via physical vapor deposition (PVD) and thickness mode present several technical challenges, including
patterned using an optimized wet etching process with an oxide complexities in array formation, limitations in electrical rout-
layer as a mask. Additionally, we obtained a −6 dB fractional
ing, and inherently low bandwidth, which degrade their perfor-
bandwidth of 95.7% through optimizing layer stacks and
transducers mutual acoustic impedance based on finite element mance in handheld medical imaging, implant ultrasound, and
model (FEM) and lumped element model (LEM) methods. consumer electronics. Alternative prototypes for traditional
We achieved high transmitting performance of 3.8 kPa/V at 3 cm ultrasonic transducers have emerged as promising technolo-
away from a PMUT super-pixel (with an area of 0.278 mm2 , gies. Specifically, piezoelectric micromechanical ultrasonic
consisting of 3 × 12 PMUTs). The measured transducer transducers (PMUTs) operating in flexural mode fabricated
performance is comparable to previous PMUTs based on PZT through a lithography-based micro-electromechanical system
(lead-included) thin films and demonstrates the potential of
(MEMS) process have emerged as a promising technology.
KNN-based PMUTs in future advanced applications.[2024-0005]
PMUTs offer several significant advantages compared to
Index Terms— Ultrasonic transducer, PMUT, KNN, band- conventional transducers, which enable miniaturization, cost-
width, wet etch, lead-free. effectiveness, and ease of integration with complementary
metal-oxide-semiconductor (CMOS) technology, making them
I. I NTRODUCTION a desirable option for various applications, such as medical
imaging [9], [10], [11], gesture recognition [12], range-finding
U LTRASONIC technology has played a pivotal role in
diverse applications, particularly in fields of medical
applications, consumer electronics, etc. One of the key compo-
[13], [14], and fingerprint sensing [15].
Regarding piezoelectric thin films for PMUTs, researchers
nents in ultrasonic systems is the transducer, which converts have explored various options. Aluminum nitride (AlN)
electrical energy into mechanical vibrations and vice versa. thin film is lead-free but suffers from a low piezoelectric
Traditionally, transducers are mostly made of lead-containing coefficient (e31, f = −1.05 C/m2 ) and scandium-doped alu-
piezoelectric ceramics like lead zirconate titanate (PZT) minum nitride (ScAlN) can improve piezoelectric coefficient
[1], [2], lead magnesium niobate–lead titanate (PMN-PT) (e31, f = −2.3 C/m2 ) with Sc concentration 36% [16], [17].
[3], [4] and lead magnesium niobate–lead indium niobate–lead Thin film lithium niobate (LiNbO3 ) is a biocompatible mate-
titanate (PIN–PMN–PT) [5], known for excellent piezoelectric rial and needs a lateral-field for efficient flexural mode
properties such as high piezoelectric coefficients and energy excitation with a piezoelectric coefficient (e11 = 4.6 C/m2 ),
conversion efficiency. However, their lead content has raised however suffering from a small intrinsic capacitance and easily
environmental and health concerns, particularly in biocom- affected by parasitic capacitance [18]. PZT thin film can
patible and sustainable applications like medical implantable have |e31, f | up to 10 to 18 C/m2 range but it is toxic and
ultrasound devices, which has led to a lead-free thin film. not environment-friendly due to its lead content, limiting its
Researchers have been exploring alternative materials with suitability for specific applications. Alternatively, potassium
sodium niobate (KNN) emerges as a promising lead-free
Manuscript received 11 January 2024; revised 19 April 2024; accepted piezoelectric ceramic material with a high piezoelectric
19 April 2024. This work was supported by the National Key Research
and Development Program under Grant 2023YFEO209600. Subject Editor
coefficient (e31, f = −12 C/m2 ) [19], [20]. Its environment-
E. S. Kim. (Corresponding author: Yipeng Lu.) friendly characteristics and superior piezoelectric properties
The authors are with the School of Integrated Circuits, Peking University, make it an appealing choice for PMUT development [19],
Beijing 100091, China (e-mail: yplu@pku.edu.cn). [20], [21], [22]. Nevertheless, utilizing KNN in PMUTs
Color versions of one or more figures in this article are available at
https://doi.org/10.1109/JMEMS.2024.3395294. presents unique challenges, particularly in thin film fabrication
Digital Object Identifier 10.1109/JMEMS.2024.3395294 processing.
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Fig. 6. XRD pattern of KNN-Pt thin film with (001) crystal orientation.
A small FWHM of 0.32◦ and no apparent peak splitting in the (001)
orientation exhibit good crystallinity and pure perovskite structure.
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Fig. 10. Measured acoustic pressure map of scanned various planes for a KNN-based PMUT chip (a) and measured acoustic pressure map of the XZ plane
at y = 0 mm (b) and y = 1 mm (e), YZ plane at x = 0 mm (c) and x = 1 mm (f) and YX plane at z = 3 mm (d) and z = 5 mm (g).
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TABLE II
C OMPARISON B ETWEEN THE PMUT A RRAY IN T HIS PAPER AND P REVIOUSLY R EPORTED PMUT A RRAYS IN L ITERATURE
more efficient ultrasonic wave generation and transmission, super-pixel operating at a central frequency of 4.7 MHz
and therefore results in an improved sensitivity of the PMUTs. underwater was demonstrated utilizing PMUT array design
Furthermore, higher poling voltages contribute to a more stable optimization with FEM and LEM methods. These features
and uniform poling state in the piezoelectric material, ensuring demonstrate the array of promising for diverse ultrasound
consistent and improved transmitting performance over time. imaging and sensing applications. The array’s small beam
An acoustic pressure map covering the planes of different width in the XZ plane was verified through measured acoustic
directions was measured, as depicted in Fig. 10. With a pressure mapping across various planes. Additionally, a pos-
high-precision position stage, a commercial hydrophone, and itive correlation between the applied poling voltage and the
a function generator interfaced with a PC control, the acoustic transmitting pressure of the KNN-PMUT was established.
pressure map of a PMUT super-pixel in FC-3283 fluid was Furthermore, this study presents high-quality thin PVD KNN
obtained. Fig. 10 (a) shows various pressure maps measured in films and an efficient, cost-effective KNN wet etching process
different planes for a KNN-based PMUT chip, setting horizon- to pattern the PVD KNN thin film, which behaves differently
tal intervals (X/Y direction) at 0.2 mm and vertical intervals from sol-gel KNN thin film. This study contributes to the
(Z direction) at 0.4 mm. Fig. 10 (b)(e) and Fig. 10 (c)(f) advancement of ultrasonic technology and its application in
display acoustic pressure maps measured in XZ and YZ medical devices and consumer electronics while addressing
planes with different cross-sections, respectively. These results environmental concerns associated with lead-based materials.
reveal different focusing patterns within a horizontal range of
(−2 mm to 2 mm) and a vertical range of (1 mm to 5 mm).
ACKNOWLEDGMENT
The findings demonstrate a peak acoustic pressure of 160 kPa
at the focal point. The measured acoustic pressure map of The authors thank Prof. Isaku Kanno from the Department
the same plane exhibits an approximate pressure distribution. of Mechanical Engineering, Kobe University, for the
As the cross-sectional acoustic pressure distribution deviates discussion of KNN thin film etching process.
from the focal center, it tends to diverge.
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vol. 68, no. 11, pp. 3371–3377, Nov. 2021. Ph.D. degree from the University of California
at Davis, CA, USA, in 2015. He is currently an
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ultrasonic transducers,” in Proc. IEEE Int. Ultrason. Symp., Sep. 2009, Circuits, Peking University. Prior to joining Peking
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for flexural disks in a rigid plane,” J. Acoust. Soc. Amer., vol. 36, no. 6, MEMS, microfabricated sensors and actuators,
pp. 1154–1161, Jun. 1964. ultrasonics, biometrics, and fingerprint sensors.
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