II. Assertion-Reason TVpe Questions
Azeotropic mixures are formed onty
In the questions given below. fwostatements are
given one labelled Assertion (A) and the other
Inbelled Reason (R). Sclet the correct answer
to these questions from the cndes (a). (h), (c) and
(d) given belew :
(a) Both A and R are correct and R is the correct
explanation of A.
(5) Both A andR are correct but R is not the correct
explanation of A.
(c) A is correct but R is wrong.
(d) A is wrong but R is correct.
60. Assertion. Henry's law constant is the ratio of
pressure of the gas to the mole fraction of the gas
in the solution.
Reason. Henry's law constant for a particular gas
in aparticular solvent is constant and does not
depend upon temperature.
61. Assertion. A mixture of chloroform and acetone
forms a non-ideal solution with positive deviation.
Reason. Acetone is more volatile than chloroform.
62. Assertion. In reverse osmosis, pressure higher than
osmotic pressure has to be applied.
Reason. Higher pressure pushes the solution from
one side of the semipermeable membrane to the
other side.
63. Assertion. 0- 1 M HCI solution has higher oSmotic
pressure than 0-1 M NaCl solution
Reason. CI ions being common, the small size
H* ions have greater ionic mobility than large size
Na ions.
64. Assertion. Out of various colligative properties,
osmotic pressure is used for determination of
molecular masses of polymers.
Reason. Polymer solutions do not possess
constant boiling point or freezing point.
65. Assertion. Ebullioscopic constant is constant for
a particular solvent at a particular temperature and
does not depend upon the solute.
Reason. Elevation in boiling point depends upon
the mass of the solute dissolved in definite mss
of a particular solvent and is independent of the
nature of the solute and solvent.
66. Assertion. Cooking time is reduced in pressure
cooker.
Reason. Boiling point inside the pressure cooker
is raised.
67. Assertion.
hy non ideal soutions and they may have hoiling
points either greater than or less than heth the
components
Reason. The compnsition of the vapoIr phase is
same as that of liquid phase of the azeotropic
mixture
68. Assertion. Increasing pressure on pure water
decreases its freezing point.
Reason. Density of water is maximum at 273 K.
69. Assertion. For NaClsolution in water. for the same
molality. the elevation in boiling point is equal to
the depression in freezing point.
Reason. van't Hoff factor i is fixed for NaCl viz. 2.
70. Assertion. van't Hoff factor for benzoic acid in
benzene is less than one.
Reason. Benzoic acid behaves as a weak
electrolyte in benzene.
71. Assertion. Relative lowering in vapour pressure
is a colligative property.
Reason. Relative lowering in vapour pressure
depends upon mole fraction of pure solvent.
(CBSE 2021)
72. Assertion. Araw mango placed in a saline solution
loses water and shrivels into pickle.
Reason. Through the process of reverse osmosis,
raw mangoes shrivel into pickle. (CBSE 2021)
73. Assertion. Molarity of a solution changes with
temperature.
Reason. Molarity is a colligative property.
74. Assertion. Cryoscopic constant depends upon the
nature of the solvent.
Reason. Cryoscopic constant is a universal
constant.
75. Assertion. One molar barium chloride solution
gives double the elevation in boiling point than
one molar sodium chloride solution.
Reason. Ba ions carry double the charge than
Nat ions.
76. Assertion. Osmotic pressure is a colligative
property.
Reason. Osmotic pressure is porportional to the
molality. (CBSE 2023)