Colour of salt is Blue Presence of Cu²+ noted Dark brown Presence of Fe²+ White May be absence of Co²+ , Cu²+, Fe²+
2.Smell : the Pungent ammoniacal May be presence
pinch of salt is smell of NH4+ rubbed with a drop a water Vinegar smell may be presence of CH3COO- No characteristics smell May be absence of NH4+ CH3COO-
3.Appearance Crystalline May be presence
the appearance of of the salt is Powdery SO4²-,Cl-,NO3-,Br noted -, CH3COO-,
May be presence of CO3²-
4.Action of 1. Colourless , 1. May be
heat the pinch odourless gas presence of of salt is evolved which CO3 heated gently turns lime water 2. May be in a dry test milky. presence of tube. 2. Reddish brown gas NO3- evolved turns 3. May be ferrous sulphate presence of solution black. NH4+ 3. Salt sublimes with 4. May be evolution of presence of pungent smelling Cl- gas giving dense 5. May be white fumes with a presence of glass rod dipped in Br- Conc.HCl. 6. May be 4. Pungent smell , presence of white fumes with Zn²+ ammonia 7. May be 5. Reddish brown gas presence of evolved turns CH3COO- starch paper 8. may be orange yellow. presence of 6. The salt turned PbNO3 yellow when hot 9. May be and white when presence of cold. Ba²+,Ca²+,M 7. Evolved vapour g²+, Al³+. given vinegar like 10. May be smell and salt absence of turned black. Cl-,NO3-,Br-, 8. Salt decrepitated. CH3COO-. 9. White residue glows on heating No characteristics changes 5.Flame test: a 1. Brick red flame 1. Presence of small amount 2. Dull bluish white Ca²+ of the salt is flame 2. Presence of made into a 3. Grassy green Pb²+ paste with colour flame. 3. Presence of conc.HCl in a 4. Green flashes Ba²+ watch glass 5. No characteristics 4. Presence of and introduced changes Zn²+ into the 5. May be non-luminous absence of part of the bunsen flames Ca²+,Pb²+,Ba²+,Z n²+ Identification of acid radical 6.Action of 1.Brisk effervescence Presence of Dil.HCl of colourless gas, carbonate To a small odourless gas amount of the turning lime water salt dil.hcl is milky Absence of added carbonate 2. No characteristics gas is evolved 7.Action of 1. Colourless gas with 1. Presence of conc.H2SO4 pungent smell , Cl- To a pinch of white fumes with 2. Presence of salt in the test aqueous NH4OH Br- tube 2 ml of and white ppt. Is 3. Presence of conc.H2SO4 is obtained on adding NO3- added. 2 ml of AgNO3. 4. Presence of 2. Reddish brown CH3COO- vapours with 5. Absence of pungent smell turns Cl-, Br-, starch paper CH3COO-, yellow. NO3- 3. Reddish brown gas with pungent smell turns FeSO4 soln black 4. Colourless vapours with smell of vinegar turns blue litmus red 5. No characteristics changes 8.BaCl2 test 1. A white precipitate 1. Presence of A small amount insoluble in SO4²- of salt is boiled conc.Hcl 2. Absence of with dil.Hcl in a 2. No white ppt sulphate test tube and filtered. To a filtrate add few drops of BaCl2 Confirmatory test for Acid radical
Confirmatory ● Colourless ● Carbonate is
test for CO3²- odourless gas with confirmed ● Dil.Hcl brisk effervescence ● Carbonate is test to a turning lime water confirmed small milky evolved. amount of ● A white ppt in the salt cold confirmed the solution, presence of soluble dil.Hcl is carbonate added. ● To a salt solution 2 ml of magnesiu m sulphate is added. Confirmation ● A curdy white ppt ● Chloride is of Cl- completely soluble confirmed 1. Silver in excess of nitrate test NH4OH is obtained to few drops of the original soln 2 ml of AgNO3 2. Red, orange 2. Chloride is solution is vapours evolved confirmed added. and white ppt is 2. Chromyl obtained when chloride passed through test dil.acetic acid and To an lead acetate original solution solution add a pinch of K2Cr2O7 and heated with a drops of conc.H2S O4