\ '

d. a~d· f-~l~_~k. El~ me~ ts ~--~

·-. ~------- ----------- . • -- •
• r
,.
.. . ........___
-~

I •
1

Which of the following lanthanoids has smallest 7. All the lanthanides are non-radioactive ex
1. cept
atomic radius ? ,, '') ( ,I (1) Pr (2) Sm
(1) Pm (2)_. 9e \ ,
' (3) Lu (4) Pm
(3) Gd (4) Er 8. Most common oxidation state of lanthanides is
,, • I I

2. • Correct order of oxidising strength of the oxoanions (1) +2 (2) +3

will follow the order (3) +4 • (4) +1
(1) era:-> Moo:-> wo:- ' 9. Which of the following salt on heating with solid
K2Cr20 7 and cone. H2S04 evolved orange red va
which turn NaOH solution yellow ? P0ur
(2) era:- < Moo:- > w o:-
. . (2) AgCI
(1) Nal
(3) wo:- >Moo:-> cre:- • (4) NaCl
(3) NaBr
1o. The transitional element having highest melting point
(4) Moo42- > wo42.;; > cr042- )
is :
3. The colour of KMn04 is purple due to (2) Os
(1) Ru
(1) d-d electronic transition (4) W
". \ ' - (3) Rh
\
(2) ligand to metal charge transfer spectra \ -·: 11. The correct order of ionic radii of Ce, La, Pm and
Yb in +3 oxidation state is :
I

(3) metal to ligand charge transfer spectra

(4) transition of 4s electron~ in Mn

I
•·\
I \

'· +•)
(1) Yb3+ > Ce3+ > Pm3+ > La3+

The Deacon's process for Cl 2 preparation the 1 (2) Yb 3+ > Pm3+ > Ce3+ > La3+
4. .,..,.1
4

catalyst used is . (3) Yb3+ < Pm3• < Ce3+ < La3•
(1) CuCl2 (4) La3• < Pm 3• < Yb 3+ < Ce3+

(3) PdCl2 12. KMnO4 is manufactured from

5. Which of the following chloride will not give chromyl (1) Side rite
chloride test ?
(2) Pyrolusite
(1) NaCl (2) KCI
(3) Magnesite
(3) AgCI (4) CaCl2 (4) Atacamite
6. Find incorrect statemen~ among the following 13. Find the correct statement
(1) Na2Cr20 7 is more soluble than K2Cr20 7 in water (1) For M3• of lanthanides, species having same
(2) ~Cr20 7 on heating gives 0 2 gas unpaired electrons have nearly same colour

(3) Cr 0 2- in acidic medium stronger oxidising (2) Mischmetal is an alloy made up of actinides
2 7
- , ,_.,
..
-- ;;.--- .,.,, • .,....,....,.. ' r"'f
1• - , r~_,, r: I 1 1. 1 (3) Higher oxidation states are more probable in
lanthanides than in actinides
are only two different
(4) Lanthanides form large number of oxo cations
 ~ ' ' --··-s
d """ f.erock Ef1tm1tn ft , Mt-~-~-~
The strongest oxidising power of KMn0 _
14• observed In 4 11 23 Serect trom lhe foflowfng that Is correct ebOUt b'-"ie
atrength of hydroxide
(1) Neutral medium
<1) Sc(OHh>Y(OHh>La(OHh
(2) Acidic medium
(2) La(OH)3>Y(OHh>Sc(OHh
( ) Strongly basic medium
3 (3) La(OHh = Y(OHh > Sc(OHh
( ) equal in all medium
4 (4) Y(OHh>La(OH)3>Sc(OHh
eu2+ can act as 24. Select that donot decolo urise KMnO 4 aqueous
15, 63
( ) oxidising agent solution
1
( ) Reducing agent (1) C20/- (2) HSO3-
2
( ) eoth oxidising agent and reducing agent
3
(3) CO/- (4) so/-
( ) Neither oxidising agent nor reducing agent 25. In 3d-series which ion has positive value of standard
4 reduction potential?
Which of the following element is most unlikely to
16, show +2 oxidation state ? (1) Ti2+ (2) Zn2•

(2) Mn (3) Cu 2+ (4) Fe2•

(1) cu
(4) Sc Acidic Medium ®
(3) Cr

'('he yellow colour ~f chromate ( Cro:-) changes to

26. KMnQ4 +Kl
-C Alkaline Mediu m@

7• orange The product (A) and (B) are respectively

colour on acidification due to formation of
(1) 12, 12 (2) KI, 12
(1) cr3• (2) Cr20 3

(3) Cr05 27. Correct match of melting point

Highest stabl~ oxidati on state observ ed in (1) Zr<Mo (2) Re<W

18, .
Lanthanoids 1s (3) Tc<Ru (4) All of these
• (2) +3 1 28. Which of the following pairs are both coloured in
(1) +4
(4) +6 aqueous solutions?
(3) +2
. KMnO, can be prepared by reaction of pyrolusite (1) Sc3•, Co 3• (2) Cu<±>, Ti3+
19
with (3) Ni2+, Ti 3+ (4) Zn2+, cu2+
(1) HCI (2) KOH and 0 2
29. Select the correct :
(3) (4) MnSO4
20. Four members of the· first row transition element are
listed below with atomic numbers. Select the one of
them that is expected to have the highest 2nd IE. (ii) Ag20 t1 >AgO + 0 2
(1) Ti (2) Mn (iii) E0 of Mn 3+/Mn 2+ is more positiv e than Fe 3+/
Fe 2+
(3) Cr (4) Zn
I

21. The ore u~ in preparation of K Cr 0 is (1) (i), (ii) only (2) (iii) only
2 2 7
(1) Ferrate ores (3) (i), (iii) only (4) (i), (ii), and (iii)
(2) Ferri~ ores
(3) Chromite ores 30. As the oxidati on state of metal increas es, ionic
'. (4) Potassium ores
c~aracter gene~ally
2~· Sel~ct from the followi
ng halide ion that has
maximum ability to stabilise the higher Oxidation (1). Decreases
number of d-block metals (2) Increases
(1) F-
(2) c1- (3) First increases then decreases
(3) Br
(4) 1- (4) First decreases then increases
..... .,._,,.;, d ana r-1:SIocK 1:Iemenrs -·'ti~.
'fo,
39, Which Is Incorrect regarding lntersual corn
31. Among Lanthanold which element can exhibit (+4)
oxidation state only In Its oxides (1) They are non stoichiometric In nature l>otJ~"r

(1) Gd, Tb, Tm (2) Lu, Yb, Tm (2) The bonds present In them are
Ionic nor covalent nei1her
(3) Nd, Dy, Ce (4) Pr, Nd, Tb
(3) Their melting points are higher than th
. 32. Select the statement that Is correct .. metals Ole of n...
""'''
(1) K2Cr20 7 Is good oxidising Agent (4) Their density Is same as that of pure meta1
1
(2) K2Cr20 7 Is used as primary standard In 4 Which one Is most acidic In nature ?
volumetric Analysis o. (1) MnO (2) Mn20 3
(3) On heating on K2Cr20 7 forms a green colour (3) Mn02 (4) Mn03
compound
41. Most stable oxidation state for Ti is
(4) All of these (2) +3
(1) +2
33, Ce and Yb exhibit +4 and +2 oxidation state (4) +5
respectively. This Is because (3) +4
value for copper is positive because
42. E (M2•/M)
0

(1) Both ce+4 and Yb+2 acquire t1 configuration

(1) Of high enthalpy of atomisation
(2) Both ce+4 and Yb+2 acquire fO configuration
14 (2) Of high second ionisation
(3) ce+4 and Yb+2 acquire fO and f configuration
respectively (3) Of high first ionization enthalpy
(4) ce+4 and Yb+2 acquire f7 and t1 configuration
4
\
' (4) Both (1) and (2) • •
. I

43. Lanthanide fo~ which (+2) and (+3) oxidation states

34. are common in
In the above reaction. (A), (B) and (C) respectively (2) Nd
(1) La
are • I )
• I''
(4) Eu
• (3) Ce
(1) FeCr20 4, Fe30 4, CO2 ..
44. Which of the following set has all the coloured ions
0
(2) F~Cr2 4 , Fe 0
2 3 ,C0 2 . :,: , due to d-d transition ?
(3) FeCr04, Fe20 3,CO • · 1'·· (1) Co3•, Ni2+
'
(2) c~2·•, •Sc3•, co2•
' <.
' I

35. Which of the following compound are. coloured due (3) Cu2•, Fe2•, Ti4+ I'

to charge transfer spectral? -, -

(4) cr3•, Mn2•, ~i2•
(1) K2Cr20 7 (2) KMn04 2
J f 'I.
45. The lowest S.R.P. value for the M •/M couple is fo
(3) AgBr (4) Both (1). and (2) '
(1) Mn (2) Cu

- (3) Zn (4) Fe
Product of the above reaction is
46. Find the most basic oxide from the following
(2) Cr20 3
(4) FeO
37. The orange colour of KiCr20 7 is due to
47. Which of the following transition metals can ha,
. (1) Incomplete d subshell (2) Charge transfer
highest oxidation state ?
(3) d - d transition (4) None of these •r
(1) (Ar)3d64s2 ••
38. In 3d-series which one of the following has positive
standard reduction potential (2) (Ar)3d 104s1

(1) Chromium . (2) Cobalt (3) (Ar)3d104s2

(3) Copper . . (4) Gold (4) (Ar)3d34s2
 catalyst t"'ctGKage ror NEET
---
4a. Find the incorrec t statement.
4~9~---~
d and f-Block Element s ~~3~

51. Amongs t TiF 6 2-, CoF 63-, Cu 2 Cl 2 and NiCl42- the

(1) in alkaline medium KM no 'd• colourless species are
1
4 OXI 1ses 1- to IO -
3
(2) in acidic medium KMnO oxid' (1) CoF63- and NiCI42-
' 4 Ises 1- to 12
(3) in acidic medium, KM no4 oxidises 1- to IO - (2) TiF62- and CoF63-
3
(4) KMnO 4 in acidic medium stronger oxidising (3) Cu2Cl2 and NiCI42-
agent than K2 Cr o •
2 7 (4) TiF6 2- only
49. Which one pair of ions having similar magneti c 52. Which one has maximu m second ionisat ion
momen t?
enthalpy ?
(1) Ti 3+, \/3+
(2) cr3•, Mn+2 (1) Fe (2) Cr
(3) Fe2•, Mn•2 (4) Mn+2 , Fe+3 (3) . Mn (4) Ti
50. Find the correct statemen t • I

53. Choose the correct order of basic strength

(1) Al(OH)3 is more basic than Ce(OH'3 • (1) Ce(OHh > Lu(OH)3 > Gd(OH) 3
(2) All lanthanides are radioactive I •
(2) Gd(OHh > Ce(OH)3 > Lu(OH)3
r •, "I
' i
(3) Actinide s are radioactive •' (3) Lu(OH)3 > Gd(OH)3 > Ce(OH)3
. l' " ..

(4) Maximum lanthanides are man made / artificial (4) Ce(OH)3 > Gd(OH)3 > Lu(OH)3
• i
 ' , --· I"/ vv. ('-'/
..., .. . ,
ts
1. (4)
Chapter 21 : d- and f-Block Elemen (4 )
2. 7.
(1) 3. (2) 4. (1) • 5. 6. (3)
8. (2)
(3) (1 )
9. 14 .
(4) 10. (4) 11. (3) 12. (2) 13. (1)
15. (2) (3 )
16. (4) 21 .
17. (4) 18. (1) 19. (2) 20 . (4)
Aakash r::..a .. __ .. :-::--- -- -~~ - ,,, -,a ?~ 56
 27. (4)
-
(3) 25. (3) 26. (4) 28. (3)
22. (1) 23. '(2) 24. ..
(4) 33. (3) 34. (2) 35. (4)
29. (2) ,30. (1) 31. (4) 32.
40. (4) 41. (3) 42. (4)
(3) 37. (2) 38. (3) 39. (4)
36.
47. (1) 48. (3) 49. (4)
(4) 44. (4) 45. (1) 46. (4)
43.
51. (4) 52. (2) .53. (4)
50. (3)