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P block Sheet
P block Sheet
P block Sheet
(D) BN
Q3 Melting point is highest for
A B
( ) B Al
( ) Q9 Boron is unable to form BF6 3− because of
(C) Ga (D) In A high electronegativity of boron
( )
(C) ln < Tl < Ga < Al Q10 Which metal is protected by a layer of its
(D) Ga < ln < Al < Tl own oxide?
A Ag
( )
Q5 Which one of the following has the lowest m.p.? (B) Al
( ) A B ( ) B Al (C) Au
( C) Ga ( D) Tl (D) Fe
Q6 The increasing order of atomic radii of Q11 Which of the following is amphoteric?
the following group 13 elements is A Al(OH)3
( )
(A) Al > Ga < In < Tl
B B(OH)3
( )
(B) Ga < Al < In < Tl
(C) Mg(OH)2
(C) Al < In < Ga < Tl
(D) NaOH
(D) Al < Ga < Tl < In
Chemistry
DPP: 2
P- BLOCK Elements
Q1 The most basic oxide of elements in group 14 of Q6 The thermal stability order for group 14 halides
the periodic table is is
(A) SiO2 (A) CX4 > SiX4 > GeX4 > SnX 4
(B) GeO2 (B) SnX 4 > GeX4 > SiX4 > CX4
(C) SnO2 (C) SiX4 > CX4 > GeX4 > SnX 4
Q2 In SiF6 2− and SiCl6 2− , which one is known Q7 Ionisation enthalpy ( Δi H1 kJ mol−1 ) for
and why? the elements of Group 13 follows the order.
(A) SiF 6
2− because of small size of F (A) B > Al > Ga > In > TI
(B) SiF 6
2− because of large size of F (B) B < Al < Ga < In < TI
(C) SiF 6 because of small size of Cl (C) B < Al > Ga < In > TI
2−
(D) SiF 6
2− because of large size of Cl (D) B > Al < Ga > In < TI
Q3 The element that shows greater ability to form Q8 The relationship between first, second and third
pπ - p π multiple bonds, is ionisation enthalpies of each group- 13 element
A Ge
( ) is
(B) Si (A) Δi H1 > Δi H2 > Δi H3
(C) Ge − Ge
Q11 The most stable +2 oxidation state is exhibited
(D) Sn − Sn
by
A Fe
( ) B Sn
( )
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Pt
Q2 Heating of ammonium dichromate produces NH3 + O2 Δ→ A + H2 O
(A) NH3 , Cr2 O3 and H2 O A + O2 B
Android App | iOS App | PW Website (B) N2 , Cr2 O3 and H2 O B + O2 + H2 O C
(C) NO, CrO3 and H2 O
(D) N2 O, CrO3 and H2 O A, B and C are
(A) N2 O, NO2 and HNO3
Q3 A gas which is used as anaesthetic in dental (B) NO, NO2 and HNO3
surgery is (C) NO2 , NO and HNO3
( A) N 2 (D) N2 O, NO and HNO3
(B) CO˙
(D FeSO4 ⋅ HNO3
) Q4 (A) Q12 (A)
Q11 Incorrect statement for white phosphorus (P4 ) Q5 (D) Q13 (D)
has : Q6 (B) Q14 (B)
A Six P P single bonds
( ) -
Q7 (D) Q15 (A)
B Four P P single bonds
( ) -
C Tellurium
( ) ( D Polonium
)
molecule
D All of the above
( )
( B H2 O + SO2
)
( C H2 O + SO3
)
( D H2 SO4 + S
)
(A S2 O8 2−
)
(B S2 O6 2−
)
(C S2 O5 2−
)
(D S2 O3 2−
) .
A H2 O because of H bonding
( ) - .
C H2 S because of H bonding
( ) - .
D
(
)
A
( )3 B
( )4 opposed by the polarity of lone pair
(C) 5 (D) 6
Q8 Thermodynamically, most stable form
Q3 Elements of group-15 form compounds in of phosphorus is
+5 oxidation state. However, bismuth forms (A) Red B Black
( )
The compound is
(A) BiO5
Q9 Which of the following fluorides does not exist?
(B) BiF5
A NF5
( )
(C) BiCl3
B PF5
( )
(C) AsF5
(D) Bi2 S5
(D) SbF5
(C) N2 O5
C) Tellurium
( D) Polonium
(
(C) First decreases upto AsH3 and then Q12 Correct order of melting and boiling point
increases A O > S > Se > Te
( )
(D) First increases upto AsH3 and then B O < S < Se < Te
( )
decreases (C) O < S < Se > Te
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Q2 The most powerful oxidizing agent is Q8 Among the 15th group elements, as we move
Android App | iOS App | PW Website A Fluorine
( ) B Chlorine
( ) from nitrogen to bismuth, the pentavalency
(C) Bromine (D) Iodine becomes less pronounced and trivalency
becomes more pronounced due to
Q3 The most electronegative elements of the (A) Non metallic character
third period. (B) Inert pair e ect
A
( )F
(C) High electronegativity
(B) P
(D) Large ionization energy
(C) Br
(B) Cl
(C) Xe > Kr > Ar > Ne > He
2
(C) I
(D) Ar > Ne > He > Kr > Xe
2
(B) O and Ar
(A) Square planar, trigonal bipyramidal
2
(C) O and CO
(B) T-shaped, octahedral
2 2
(D) CO and Ar
(C) Square pyramidal, octahedral
2
Answer Key
Q1 (A) Q7 (C)
Q2 (A) Q8 (B)
Q3 (D) Q9 (A)
Q4 (B) Q10 (C)
Q5 (B) Q11 (A)
Q6 (B)