Test #3 Fall 2021 Name: _______

CHE303
In putting my name on this quiz and turning it in I am certifying that it is my work alone.

1. Assign (E) or (Z) designations to each of the following alkenes: (2pts each)

2. For the following molecules, indicate if they are chiral or achiral: (2pts each)

3. Assign (R) or (S) designations to each of the following compounds: (3pts each)

4. (a). Place an asterisk next to the chiral carbons. (2pts)

(b) Calculate the maximum number of stereoisomers possible for the following molecule: (1 pt)
5. Circle the term that describes the relationship between the pairs of structures below. (3pts each )
(fisher projections)

same compound same compound

enantiomers enantiomers
diastereomers diastereomers
constitutional isomers constitutional isomers

same compound same compound

enantiomers enantiomers
diastereomers diastereomers
constitutional isomers constitutional isomers

6. Using curved arrows, write a mechanism for the following reaction: (2pts)

7(a) Write the rate equation for the reaction above in question 6: (2pts)

7(b) If you double the amount of solvent for this reaction, what would be the effect on the rate of the reaction?
(2pts)
8. Give structures for the major organic product(s) for each of the following reactions: (5pts each)
9. Using any reagents necessary, outline a synthesis of the following compound via SN2 reaction: (5pts)
In other words, give the two starting materials needed to make this product.