[ PERBUTYL P ] page 1 of 3

Ｓ Ａ Ｆ Ｅ Ｔ Ｙ Ｄ Ａ Ｔ Ａ Ｓ Ｈ Ｅ Ｅ Ｔ
SDS No.F02111 Effective Date : 14, Oct. 1995 / The 8th Amended Date : 6, Jul. 2017

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : PERBUTYL P
MANUFACTURER : NOF CORPORATION
Yebisu Garden Place Tower
20-3, Ebisu 4-Chome, Shibuya-ku, Tokyo 150-6019 JAPAN
FACSIMILE (G3) : +81 (0)3-5424-6814
INFORMATIONAL TELEPHONE : +81 (0)3-5424-6838

2. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL COMPONENTS
Component: CAS Registry No. Exposure Guideline % by wt.
Di-(tert-butylperoxyisopropyl)benzene(s) 25155-25-3 No information ≧98

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW :
White powder with particular odor.
Can burn vigorously in fire.
Contact with phosphine, strong acids, reducing agent or heating may cause fire or hazardous decomposition with
producing flammable vapors, gases and fumes.
POTENTIAL HEALTH EFFECTS :
Irritating to skin and eyes.
May cause irritating to mucosa

4. FIRST AID MEASURES

ROUTE OF EXPOSURE.......: Skin contact / absorption, eye contact, inhalation, swallow.
EYES....................... : Remove any contact lenses at once.
Flush eyes well with copious quantities of water or normal saline for at least 20-30 minutes.
Seek medical attention.
SKIN....................... : Flood all areas of body that have contacted the substance with water.
Don’t wait to remove contaminated clothing; do it under the water stream.
Use soap to help assure removal.
INGESTION............ : Contact a physician, hospital or poison center at once.
If conscious and not convulsing, give a glass of water or milk to dilute the substance.
Vomiting should not be induced without a physician’s advice.
If the victim is unconscious or convulsing, DO NOT INDUCE VOMITING or give
anything by mouth.
Assure that his airway is open and lay him on his side with his head lower than his body and
transport immediately to a medical facility.
INHALATION......... : Leave contaminated area immediately; breathe fresh air.
Proper respiratory protection must be supplied to any rescuers.
If coughing, difficult breathing or any other symptoms develop, seek medical attention at
once, even if symptoms develop many hours after exposure.
Effective Date : 14, Oct. 1995 / The 8th Amended Date : 6, Jul. 2017 [ PERBUTYL P ] page 2 of 3

5. FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES
Flash point................................................... :
115°C (Cleveland Open Cup)
Flammable limits.........................................
LEL = Not available. : UEL = Not available.
Autoignition point........................................
479°C (ASTM E659) :
EXTINGUISHING MEDIA............................ :
Use water, foam, CO2 or dry chemical extinguisher.
When fire extinguished, continue cooling with water for prevention
of reignition.
FIRE & EXPLOSION HAZARDS................... : Rapid burning and high heat liberation, due to decomposition.
Contact with accelerators, acids, alkalis or amines may cause
vigorous decomposition.
The decomposition may release gases, rapture closed container,
spreading fire.
FIRE-FIGHTING INSTRUCTIONS................ : Full emergency equipment with self-contained breathing apparatus
and full protective clothing should be worn by firefighters.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
This chemical may explode when exposed to heat.
Caution should be observed due to possible unexpected increases in
fire intensity.

6. ACCIDENTAL RELEASE MEASURES

Remove all sources of ignition.
Wear suitable protective equipment.
Collect waste in closed drum or container for disposal and wet it with water.
The waste must be removed completely with absorbent, and so it must be burned in a chemical incinerator.
Disposal method refers to section 13 [ DISPOSAL CONSIDERATIONS ].

7. HANDLING AND STORAGE

Precaution to be Taken in Handling and Storing :
Keep away from heat, sparks and flame.
Never return any peroxide to its container, once it has been poured out.
Take precautionary measures against static discharges.
Avoid contact with skin, eyes and clothing.
Avoid breathing vapor.
Use with adequate ventilation.
Keep container tightly closed.
Wash thoroughly after handling.
Store at temperature not exceeding 30°C.
Keep container out of sun and away from heat.
Keep out of reach of children.
Other Precautions :
General ventilation is recommended.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

ENGINEERING CONTROLS......................... : Use with adequate ventilation.
PERSONAL PROTECTION :
Respiratory protection.................................. : Self-contained breathing apparatus or organic canister are desirable,
particularly if heated.
Hand protection........................................... : Protective gloves.
Eye protection.............................................. : Protective goggles.
Other Protective Clothing or Equipment...... : Mask.
Work / Hygienic Practices............................ : Use good personal hygiene practice.
Wash thoroughly after handling.
Effective Date : 14, Oct. 1995 / The 8th Amended Date : 6, Jul. 2017 [ PERBUTYL P ] page 3 of 3

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance..................................................... : White powder.
Odor................................................................ : Particular odor.
Boiling point................................................... : Not applicable.
Melting point.................................................. : Above 50°C
Bulk Specific Gravity...................................... : 0.35 (20°C)
Specific Gravity............................................... : 0.915 (60°C)
Solubility in water........................................... : Insoluble.
Vapor pressure................................................ : 1.3KPa(158°C)

10. STABILITY AND REACTIVITY

Chemical stability(condition to avoid)............. : Unstable to heat, sunlight and sparks.
High temperature exceeding room temperature and direct sunshine.
(SADT=85°C)
Incompatibility (Materials to Avoid)................ : Organometallic compounds, strong acids metals, phosphines.
Hazardous decomposition products.................. : Acetone, t-butanol and etc.
Hazardous Polymerization............................... : Will not occur.

11. TOXICOLOGICAL INFORMATION

Acute toxicity.................................................. : [Orl] LD50 > 23,000mg/kg (rat)
LD50 >4,500mg/kg (mus)
Skin irritation.................................................. : Mild irritation. (rbt)
Skin sensitization............................................ : Not a sensitizer. (gpg)
Eye irritation................................................... : Minimal irritation. (rbt)
Mutagenicity................................................... : Negative in the Ames test.
Carcinogenicity............................................... : Not listed on NTP, IARC, OSHA.
Signs and Symptoms....................................... : May irritate skin, eyes, nose, and mucous membranes.
Medical Conditions Generally Aggravated by Exposure... : Unknown.

12. ECOLOGICAL INFORMATION

No information is available.

13. DISPOSAL CONSIDERATIONS

Steps to be Taken in Case Material is Released or Spilled :
Remove all sources of ignition.
Wear suitable protective equipment.
Collect waste in closed drum or container for disposal and wet it with water.
The waste must be removed completely with absorbent, and so it must be burned in a chemical incinerator.
Waste Disposal Method :
This material may be burn in a chemical incinerator equipped with an afterburner and a scrubber.
Dilution of peroxide to no more than 1% of the active oxygen or no more than 10wt% of the concentration
(whichever is lower) in an inert organic solvent(which are readily soluble with the peroxide) is recommended.

14. TRANSPORT INFORMATION

Proper shipping name...................................... : ORGANIC PEROXIDE TYPE D, SOLID.
Identification number...................................... : IMO CLASS 5.2, UN No.3106, P.G.－
IATA CLASS 5.2, UN No.3106, P.G.－

15. REGULATORY INFORMATION

Component: CAS Registry No. ENCS(JAPAN) TSCA EINECS No
Di-(tert-butylperoxyisopropyl)benzene(s) 25155-25-3 (3)-1067 Registered. 2466783

16. OTHER INFORMATION

This information is taken from sources or based upon data believed to be reliable.
However, NOF CORPORATION makes no warranty as to the absolute correctness or sufficiency of any of the
foregoing or that additional or other measures may not be required under particular conditions.