PINNAACLE CLASSES

26. (a)(I) 1 molecule of oxygen 6 .023×1023

molecule has mass =32 gm ∴ 1 ml at NTP has =22400
23
∵ 6×10

32 23 19
= =0 . 0002688×10 =2 . 69×10 .
O
∴ 1 molecule of 2 has mass 6×10
23

=5.3×10−23 gm 32. (c)Sp. heat × atomic wt.= 6.4

0.16 × atomic wt.= 6.4
(II) 1 atom of nitrogen
6.4
∵ 2×6×10 atoms of
23 N2 = =40
has mass = 28gm Atomic wt. 0 . 16 .
28
=
N
∴ 1 atom of 2 has mass 2×6×1023 C 2 H 4 +2O 2 →2CO 2 +2 H 2 O
33. (b)
−23
=2.3×10 gm ∵ 28gm C 2 H 4 requires 64gm oxygen
−10
(III) 1×10 g molecular weight of oxygen 64
×2 . 8×103 gm
∴ 2 .8×10 gm C 2 H 4 requires =28
3
−10
g atomic weight =2×1×10 =2×10−10 g
=6 . 4×10 3 gm = 6.4kg.
−10
(IV) 1×10 g atomic weight of copper
So, order of increasing masses II< I <III< IV . 34. (b)∵ 1mole (COOH )2 . 2 H 2 O has 96gm oxygen
∴ 0.3 mole (COOH )2
. 2 H 2 O has 96×0 . 3=28 . 8 gm
−
wt . of metal hydroxide EM + EOH 1 .520 x+17 28 . 8
= − = = = =1. 8
wt . of metal oxide EM + EO 0 . 995 x +8 ∴ No. of gram atoms of oxygen 16
27. (d) .
=1 . 520 x +1 .520×8 =0. 995 x +0 . 995×17
1 .520 x +12. 160=0. 995 x +16 . 915 35. (c)Equimolecular proportion means both gases occupied
2 .24
= =1. 12 L
or 0 . 525 x=4 . 755 equal volume 2
x=
4 . 755
=9 For CH 4 :
0 . 525 .
22.4L CH 4 has mass =16 gm
16
−19 CH = ×1 .12=0 .8 gm
28. (b)One ion carries 3×1.6×10 coulomb 1.12L 4 has mass 22 . 4 .
3−
Then 1 gm ion N (1 mole) carries For C 2 H 6

=3×1 .6×10−19×6. 02×1023 22.4L C 2 H 6 has mass = 30gm

30 3.0
=2.89×10 5 coulomb C H = ×1 .12 = gm=1. 5 gm
1.12L 2 6 has mass 22 . 4 2
Total mass =1 . 5 gm+0 . 8 gm=2 .3 gm .
CP
=1 . 4
CV
29. (a) so, given gas is diatomic 36. (c)Let wt. of metal oxide = 100gm
23 wt. of metal = 53gm
11.2L =3 . 01×10 molecules
wt. of oxygen = 47gm
23 23
∴ No. of atoms =3 . 01×10 ×2 =6 . 023×10 atoms wt . of metal
= ×8
Equivalent weight of oxygen wt . of oxygen
30. (b)The acid is dibasic. 53
=
×8=9 .02
47
H 3 PO 3 =3+ 31+ 48=82
Molecular weight of 2×V . D 2×66 132
= = = =2 . 96≈3
Molecular weight 82 Valency E+35 . 5 9+35 .5 44 . 5
= =
∴ Equivalent weight Basicity 2 = 41. ∴ Atomic weight =Equivalent weight×Valency
=9. 02×3=27 . 06
23
31. (b)∵ 22400 ml at NTP has 6 . 023×10 molecule 23
37. (b)∵ 22400cc of gas at STP has 6×10 molecules

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∴ 1.12 ¿ 10
−7
of gas at STP has 32
= ×8=64
23 −7 0.4
6×10 ×1. 12×10
22400 =. 03×1014=3×1012 . mol . wt
=
Vapour density 2

38. (a)∵ 2.24L of gas has mass = 4.4gm Mol. wt =2×V . D=2×32=64
4.4 mol . wt 64
= ×22. 4=44 n= = =1
∴ 22.4L of gas has mass 2 .24 eq . wt 64
As we know that
CO 2 CO 2 M 2 On
So given gas is because has molecular mass=44. Suppose, the formula of metal oxide be . Hence
=M 2 O
the formula of metal oxide .
O
39. (d)1L of air =210cc 2
22400cc = 1 mole
45. (c)wt. of metallic chloride¿ 74.5
1
210 cc = ×210=0 . 0093 wt. of chlorine = 35.5
22400 .
∴ wt. of metal ¿ 74.5−35.5=39
Equivalent weight of metal
40. (d)∵ 22.4L of a gas at STP has no. of molecules
=6 . 023×1023
weight of metal
¿ ×35.5
∴ 8.96L of a gas at STP has no. of molecules
weight of chlorine
6 . 02×1023 ×8 .96 39
= ¿ ×35.5=39
22 . 4 =2 . 408×1023 =24 .08×1022 . 35.5

41. (a) Given equivalent weight of metal = 9 2× V . D 2× 59.25

46. (b)Valency of the element ¿ =
Vapour density of metal chloride = 59.25 E+35.5 4 +35.5
∴ molecular weight of metal chloride 118.50
¿ =3.
=2×V . D=2×59 .25=118 . 5 39.5
∴ valency of metal

molecular weight of metal chloride W ( gm)×1000

= =
equivalnet weight of metal +35. 5 47. (d)Molarity V (ml )×molecular weight
118 .5 118 . 5 1 . 25×1000
= = =2. 66 0 . 25=
Valency of metal 9+35 . 5 44 .5 25×molecular weight
Therefore atomic weight of the metal 1 .25×1000
= =200
=equivalent weight ¿ valency ∴ Molecular weight 0 .25×25 .
=9×2 . 66=23 . 9
48. (c)Let weight of metal oxide = 100gm
molecular wt . of metal Weight of oxygen = 32gm
=
42. (d)The density of gas volume ∴ weight of metal =100−32=68 gm
45 wt . of metal
= =2 gm litre−1 = ×8
22 . 4
Equivalent weight of oxide wt . of oxygen
68
43. (c)Equivalent weight of bivalent metal = 37.2 = ×8=17
32 .
∴ Atomic weight of metal =37 . 2×2=74 . 4

∴ Formula of chloride =MCl 2

CuSO 4 . 5 H 2 O
Hence, molecular weight of chloride 49. (c)[∵ Molecular weight of
( MCl 2 )=74 . 4+2×35 .5=145 . 4 =63 . 5+32+64 +90 =249 . 5 ]
6×1023 molecules has weight =249 . 5 gm
44. (c)As we know that 249 . 5×1×1022
weight of metal =
= ×8 1×10 22 molecules has weight 6×1023
Equivalent weight weight of oxygen
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=41. 58×10−1 =4 . 158

Na2 SO 4 . 10 H 2 O =2×23+32+ 4×16 +10×18

50. (b)
=46+32+64 +180=322 gm
Na2 SO 4 . 10 H 2 O
322gm contains = 224 gm oxygen
Na SO . 10 H O
32.2gm 2 4 2 contains
32 .2×224
=22. 4 gm
= 322

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