CHEMICAL EQUILIBRIUM

91. One mole of was placed in a litre reaction vessel at a certain temperature. The following
equilibrium was established ⇌
At equilibrium 0.6 moles of were formed. The equilibrium constant of the reaction will
be
(a) 0.36 (b) 0.45 (c) 0.54 (d) 0.675
92. For the reaction,

N2 + 3H2 2NH3, H = -25 kJ

If we insert 20 moles of Argon, at constant pressure
(a) more back ward reaction (b) more forward reaction
(c) no effect (d) all of these
93. For the reaction ⇌ ; is equivalent to
(a) 1 (b) (c) (d)
94. Which equilibrium in gaseous phase would be unaffected by an increase in pressure?
(a) N2O4 2NO2 (b) N2 + O2 2NO
(c) N2 + 3H2 2NH3 (d) CO + 1⁄2 O2 CO2
95. The degree of dissociation of PCl5 (α) obeying the equilibrium,
PCl5 (g) PCl3 (g) + Cl2 (g).
Is approximately related to the pressure at equilibrium by:
(a) a μ P (b) a μ (c) a μ (d) a μ
96. Pure ammonia is placed ina vessel at a temperature where its degree of dissociation ( �)
is
appreciable. At equilibrium:
(a) Kp does not change with pressure (b) � does not change with pressure
(c) [NH3] does not change with pressure (d) [H2] < [N2]
97. The reaction quotient (Q) for the reaction
⇌

is given by . The reaction will proceed from right to left is

(a) Q = 0 (b) Q = (c) Q < (d) Q >
Where is the equilibrium constant
98. The following equilibrium exists in aqueous solution ⇌ . If dilute

is added without a change in temperature, then the

(a) Concentration of will increase (b) Concentration of will
decrease
(c) Equilibrium constant will increase (d) Equilibrium constant will decrease
99. For the gaseous phase reaction, nA(g) B(g) the unit of Kp would be
(a) (atm)n (b) (atm)n+1 (c) (atm)1-n (d) (atm)n-1
101. The volume of the reaction vessel containing an equilibrium mixture of the reaction
SO2Cl2(g) SO2(g) + Cl2(g) is increased. When equilibrium is re-established, which of
the following will occur?
(a) The amount of SO2Cl2(g) increases. (b) The amount of SO2(g) decreases.
(c) The amount of Cl2(g) remains unchanged. (d) The amount of Cl2(g) increases.
102. When NaNO3(s) is heated in a closed vessel, oxygen is liberated and NaNO2(s) is left
behind.
At equilibrium,
(a) addition of NaNO2 favours reverse reaction.
(b) addition of NaNO3 favours forward reaction.
(c) increasing temperature favours forward reaction.
(d) decreasing pressure favours reverse reaction
103. of urea are present in solution, the active mass of urea is
(a) 0.2 (b) 0.06 (c) 0.4 (d) 0.08
104. For the system ⇌ , the expression for equilibrium constant K is
(a) (b) (c) (d)
105. If concentration of reactants is increased by , then becomes
(a) ln ( ) (b) (c) (d)
106. Densities of diamond and graphite are 3.5 and 2.3 g/ml, respectively. Increase of
pressure on
the equilibrium C(diamond) C(graphite)
(a) Favours backward reaction (b) Favours forward reaction
(c) Have no effect (d) Increase the reaction rate
107. A cylinder fitted with a movable piston contains liquid water in equilibrium with water
vapour
at 25°C. Which operation result in a decrease in the equilibrium vapour pressure?
(a) Moving the piston downward a short distance
(b) Removing a small amount of vapour
(c) Removing a small amount of the liquid water
(d) Dissolving salt in the water
108. Le Chatelier’s principle is not applicable to
(a) Homogeneous reactions
(b) Heterogeneous reactions
(c) Homogeneous or heterogeneous system in equilibrium
(d) Systems not in equilibrium
109. The active mass of 64 gm of HI in a two litre flask would be
(a) 2 (b) 1 (c) 5 (d) 0.25
111. For the system ⇌ , the equilibrium concentrations are (a) 0.06 mole/litre (b)
0.12 mole/litre (c) 0.216 mole/litre. The for the reaction is
(a) 250 (b) 416 (c) (d) 125
112. Partial pressures of A, B, C and D on the basis of gaseous system ⇌ are A =
0.20; B = 0.10; C = 0.30 and D = 0.50 atm. The numerical value of equilibrium constant is
(a) 11.25 (b) 18.75 (c) 5 (d) 3.75
113. For the reaction, PCl5(g) PCl3(g) + Cl2(g), the forward reaction at constant temperature
is favoured by
(a) Introducing an inert gas at constant volume.
(b) Introducing chlorine gas at constant volume.
(c) Introducing an inert gas at constant pressure.
(d) None of these.
114. The equilibrium constant, Kc for the reaction,
SO2(g) + NO2(g) SO3(g) + NO(g)
is 1.6. If 1 mol of each of all the four gases is taken in 1 dm3 vessel, the equilibrium
concentration of NO would be
(a) 0.4 M (b) 0.115 M (c) 1.4 M (d) 1.6 M
115. Consider the reaction, PCl5(g) PCl3(g) + Cl2(g) in a closed container at equilibrium. At
a
fixed temperature, addition of more PCl5 at equilibrium will show.... in equilibrium
concentration of Cl2(g).
(a) Decrease (b) Increase (c) No change (d) None of them
116. ⇌ In the above reaction, one mole of each of
acetic acid and alcohol are heated in the presence of little conc. . On equilibrium being
attained
(a) 1 mole of ethyl acetate is formed (b) 2 mole of ethyl acetate are formed
(c) 1/2 moles of ethyl acetate is formed (d) 2/3 moles of ethyl acetate is formed
117. In the reaction ⇌ , the value of the equilibrium constant depends on
(a) Volume of the reaction vessel
(b) Total pressure of the system
(c) The initial concentration of nitrogen and hydrogen
(d) The temperature
118. 3.2 moles of hydrogen iodide were heated in a scaled bulb at 444°C till the equilibrium
was
reached. The degree of dissociation of HI at this temperature was found to be 22%. The
number
of moles of hydrogen iodide present at equilibrium are
(a) 1.87 (b) 2.496 (c) 4.00 (d) 2.00
119. The vapour density of completely dissociated would be
(a) Slight less than half that of
(b) Half that of
(c) Double that of
(d) Determined by the amount of solid in the experiment
120. In the equilibrium ⇌ ; if the equilibrium concentration of A is doubled, the equilibrium
concentration of B would become:
(a) Twice (b) Half (c) 1/4th (d) 1/8th