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CHEMICAL BONDING – SHEET: 11
B.M.O., A.B.M.O., Bond order, Bond Length
LEVEL - 1

1. Which of the following has fractional bond order?

2+ 2– 2– –
(a) O2 (b) O2 (c) F2 (d) H2
+ – 2–
2. The bond length in O2 , O2, O2 and O2 follows the order:
2– – + + – 2–
(a) O2  O2  O2  O2 (b) O2  O2  O2  O2
– 2– + – 2– +
(c) O2  O2  O2  O2 (d) O2  O2  O2  O2
+
3. The bond order in O2 is the same as in
+ – +
(a) N2 (b) CN (c) CO (d) NO
2–
4. The correct order of increasing C—O bond lengths in CO, CO3 and CO2 is
2– 2–
(a) CO3  CO2  CO (b) CO2  CO3  CO
2– 2–
(c) CO  CO3  CO2 (d) CO  CO2  CO3
+
5. The bond order in NO is 2.5, while that in NO is 3. Which statement is true?
(a) Bond length is unpredictable (b) Bond length in NO is greater than is NO+
+ +
(c) Bond length in NO is equal to that in NO (d) Bond length in NO is greater than in NO

6. Which of the following pairs of species have the same bond order?
– + – + – – +
(a) CN and NO (b) CN and CN (c) O2 and CN (d) NO and CN

7. Using MO theory predicts which of the following species has the shortest bond length?
2+ + – 2–
(a) O2 (b) O2 (c) O2 (d) O2

8. Find the bond order of B2

9. Find the bond order of Be2

10. Find the bond order of N2

LEVEL - 2

11. Find the bond order of CO

12. Select the correct statements

+ – + –
(a) Bond order for N2 and N2 are same (b) Stability order N2  N2
+ –
(c) Bond length of N2  N2 (d) None of these

13. The pair of species with the same bond order in

2– + +
(a) O2 , B2 (b) O2 , NO (c) NO, CO (d) N2, O2
– +
14. The common feature among the special CN , CO, and NO are
(a) Bond order three and isoelectronic (b) Bond order three and weak field ligands
(c) Bond order two and  acceptors (d) Isoelectronic and weak field ligands

15. The species having bond order different from that in CO is

– + –
(a) NO (b) NO (c) CN (d) N2

16. Four dia atomic species listed below. Identify the correct order in which the bond order is increasing in them
– 2– + – 2– +
(a) NO  O2  C2  He2 (b) O2  NO  C2  He2
2– + – + – 2–
(c) C2  He2  O2  NO (d) He2  O2  NO  C2

17. Which of the following species have equal bond order?

(a) He2+ (b) H2– (c) N2 (d) O2+

18. Match the following:

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Column – I Column – II
(a) O2 (p) Bond order = 2
(b) N2 (q) Diamagnetic
(c) H2 (r) Bond order = 3
2–
(d) O2 (s) Paramagneetic

19. Match the following:

Column – I Column – II
(a) Li2 (p) 3
(b) N2 (q) 1.5
(c) Be2 (r) 1
(d) O2 (s) 0
(t) 2

20. Match the following:

Column – I Column – II
(A) N(SiH3 ) 3 (P) p - d back bonding
3
(B) N(CH3 )3 (Q) sp -hybridisation for underlined atom
(C) B2H6 (R) p - p back bonding
(D) BF3 (S) Neither p-p nor p - d back bonding
(T) Underlined atom combines with Lewis base

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ANSWERS
CHEMICAL BONDING – SHEET – 11

1. D 2. A 3. A 4. D 5. B 6. A 7. A

8. 1 9. 0 10. 3 11. 3 12. A 13. A 14. A

15. A 16. D 17. A, B

18. A – p, s, B – r, q, C – q, D – q

19. A – r, B – p, C – s, D – t

20. (A – p), (B – q, s), (C – q, s, t), (D – r, t)

——

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