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Chapter 10 Gases
Page 167
Chapter 10 Gases
7. Hydrogen gas exerts a pressure of 466 torr in a container. What is this pressure in
atmospheres (1 atm = 101,325 Pa = 760 torr)?
A) 0.217 atm B) 0.466 atm C) 0.613 atm D) 1.63 atm E) 4.60 atm
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
8. The pressure of hydrogen sulfide gas in a container is 35,650 Pa. What is this pressure
in torr (1 atm = 101,325 Pa = 760 torr)?
A) 46.91 torr B) 267.4 torr C) 351.8 torr D) 3612 torr E) 27,090 torr
Ans: B Bloom's Taxonomy: 3 Difficulty: easy
9. The pressure of sulfur dioxide in a container is 159 kPa. What is this pressure in
atmospheres (1 atm = 101,325 Pa = 760 torr)?
A) 0.209 atm B) 0.637 atm C) 1.57 atm D) 21.2 atm E) 15,900 atm
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
10. The air pressure in a volleyball is 75 psi. What is this pressure in torr (1 psi = 14.7 atm,
1 atm = 101,325 Pa = 760 torr)?
A) 520 torr B) 562 torr C) 3900 torr D) 7600 torr E) 75,000 torr
Ans: C Bloom's Taxonomy: 3 Difficulty: difficult
11. If the atmospheric pressure in Denver is 0.88 atm then what is this in mmHg (1 atm =
101,325 Pa = 760 torr, 1 torr = 1 mmHg)?
A) 151.5 mmHg D) 8.92 × 104 mmHg
–3
B) 1.16 × 10 mmHg E) 668.8 mmHg
C) 863.6 mmHg
Ans: E Bloom's Taxonomy: 3 Difficulty: moderate
12. A flask containing neon gas is connected to an open–ended mercury manometer. The
open end is exposed to the atmosphere, where the prevailing pressure is 745 torr. The
mercury level in the open arm is 50 mm below that in the arm connected to the flask of
neon. What is the neon pressure, in torr?
A) –50 torr B) 50 torr C) 695 torr D) 795 torr E) none of the above
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
13. A flask containing argon gas is connected to a closed–ended mercury manometer. The
closed end is under vacuum. If the mercury level in the closed arm is 230 mm above that
in the arm connected to the flask, what is the argon pressure, in torr?
A) –230 B) 230 C) 530 D) 790 E) none of the above
Ans: B Bloom's Taxonomy: 3 Difficulty: moderate
Page 168
Chapter 10 Gases
14. What is the pressure in atmospheres exerted by a column of water that is 12.5 m high
(density of water = 0.987 g/cm3, gravitational constant = 9.80665 m/s2,1 atm = 101,325
Pa = 760 torr = 760 mmHg)?
A) 0.012 atm D) 1.19 atm
B) 1.3 × 105 atm E) 1.01 × 10–6 atm
C) 815.8 atm
Ans: D Bloom's Taxonomy: 3 Difficulty: difficult
15. What is the pressure in atmospheres exerted by a column of mercury that is 100 m high
(density of mercury = 13.5951 g/cm3, gravitational constant = 9.80665 m/s2, 1 atm =
101,325 Pa = 760 torr = 760 mmHg)?
A) 1.4 × 1010 atm
B) 0.013 atm
C) 0.73 atm
D) 1.37 atm
E) 131.6 atm
Ans: E Bloom's Taxonomy: 3 Difficulty: difficult
16. “The pressure of an ideal gas is inversely proportional to its volume at constant
temperature and number of moles” is a statement of __________________ Law.
A) Charles's
B) Boyle's
C) Amontons's
D) Avogadro's
E) Gay–Lussac's
Ans: B Bloom's Taxonomy: 1 Difficulty: easy
17. “The volume of an ideal gas is directly proportional to its absolute temperature at
constant pressure and number of moles” is a statement of ________________ Law.
A) Charles's B) Boyle's C) Amontons's D) Avogadro's E) Henry's
Ans: A Bloom's Taxonomy: 1 Difficulty: easy
18. “The volume of an ideal gas is directly proportional to the number of moles of the gas at
constant temperature and pressure” is a statement of _____________ Law.
A) Charles's
B) Boyle's
C) Amontons's
D) Avogadro's
E) Gay–Lussac's
Ans: D Bloom's Taxonomy: 1 Difficulty: easy
19. A sample of an ideal gas has its volume doubled while its temperature remains constant.
If the original pressure was 100 torr, what is the new pressure?
A) 10 torr B) 50 torr C) 100 torr D) 200 torr E) 1000 torr
Ans: B Bloom's Taxonomy: 3 Difficulty: easy
Page 169
Chapter 10 Gases
20. What is the formula which describes the relationship between the pressure and volume
at constant temperature and constant moles?
A) PV = k1 B) V/P = k1 C) P/V = k1 D) k1P = V E) none of the above
Ans: A Bloom's Taxonomy: 1 Difficulty: easy
21. A sample of a gas has an initial pressure of 0.987 atm and a volume of 12.8 L. What is
the final pressure if the volume is increased to 25.6 L?
A) 2.03 atm B) 1.97 atm C) 0.494 atm D) 0.003 atm E) 323.4 atm
Ans: C Bloom's Taxonomy: 3 Difficulty: easy
22. A sample of nitrogen gas at 298 K and 745 torr has a volume of 37.42 L. What volume
will it occupy if the pressure is increased to 894 torr at constant temperature?
A) 22.3 L B) 31.2 L C) 44.9 L D) 112 L E) 380 L
Ans: B Bloom's Taxonomy: 3 Difficulty: easy
23. A sample of carbon dioxide gas at 125°C and 248 torr occupies a volume of 275 L.
What will the gas pressure be if the volume is increased to 321 L at 125°C?
A) 212 torr B) 289 torr C) 356 torr D) 441 torr E) 359 torr
Ans: A Bloom's Taxonomy: 3 Difficulty: easy
24. A sample of gas occupies 24.5 L at a pressure of 1.57 atm, what is the pressure if the
volume is increased to 48.3 L?
A) 0.796 atm B) 1.26 atm C) 3.1 atm D) 5.3 × 10–4 atm E) 1858 atm
Ans: A Bloom's Taxonomy: 3 Difficulty: easy
26. What is the formula which describes the relationship between the volume and
temperature at constant pressure and constant moles?
A) VT = k2
B) V2/T = k2
C) V = k2T
D) k2VT = 0
E) none of the above
Ans: C Bloom's Taxonomy: 1 Difficulty: easy
27. What is the temperature in Celsius at 77 K which is the temperature of liquid nitrogen?
A) –350°C B) –196°C C) 350°C D) 196°C E) 3.55°C
Ans: B Bloom's Taxonomy: 3 Difficulty: easy
28. What is the temperature in Celsius at 4 K which is the temperature of liquid helium?
A) –269°C B) 269°C C) 277°C D) 68.3°C E) –277°C
Ans: A Bloom's Taxonomy: 3 Difficulty: easy
Page 170
Chapter 10 Gases
29. A sample of a gas occupies 1.40 × 103 mL at 25°C and 760 mmHg. What volume will
it occupy at the same temperature and 380 mmHg?
A) 2800 mL B) 2100 mL C) 1400 mL D) 1050 mL E) 700 mL
Ans: E Bloom's Taxonomy: 3 Difficulty: easy
30. A sample of nitrogen gas has a volume of 32.4 L at 20°C. The gas is heated to 220ºC
at constant pressure. What is the final volume of nitrogen?
A) 2.94 L B) 19.3 L C) 31.4 L D) 54.5 L E) 356 L
Ans: D Bloom's Taxonomy: 3 Difficulty: moderate
31. If 25.5 L of oxygen are cooled from 150oC to 50oC at constant pressure, what is the new
volume of oxygen?
A) 0.0514 L B) 19.5 L C) 33.4 L D) 0.03 L E) 3.5 L
Ans: B Bloom's Taxonomy: 3 Difficulty: moderate
32. A sample of N2 gas occupies 2.40 L at 20°C. If the gas is in a container that can
contract or expand at constant pressure, at what temperature will the N2 occupy 4.80 L?
A) 10°C B) 40°C C) 146°C D) 313°C E) 685°C
Ans: D Bloom's Taxonomy: 3 Difficulty: moderate
33. A sample of nitrogen gas has the temperature drop from 250oC to 150oC at constant
pressure. What is the final volume if the initial volume is 310 mL?
A) 383.3 L B) 383 mL C) 0.251 L D) 0.4 L E) 6,85 L
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
34. A gas sample occupies 8.76 L at a temperature of 37°C, what is the volume if the
temperature is lowered to 0°C at constant pressure?
A) 9.95 L B) 0 L C) 4.22 L D) 74.1 L E) 7.71 L
Ans: E Bloom's Taxonomy: 3 Difficulty: moderate
35. What is the final temperature of a gas that expands from a volume of 22.4 L at 278 K to
a volume of 38.3 L?
A) 162.6 K B) 293.9 K C) 3.09 K D) 217.3 K E) 475.3 K
Ans: E Bloom's Taxonomy: 3 Difficulty: easy
36. What is the formula which describes the relationship between the volume and number of
moles in the sample at constant pressure and constant temperature?
A) Vn = k3
B) V2/n = k3
C) n/V2 = k3
D) V/n = k3
E) none of the above
Ans: D Bloom's Taxonomy: 1 Difficulty: easy
Page 171
Chapter 10 Gases
37. If 2.3 mol of a gas occupies 50.5 ml how many moles of the gas will occupy 85.5 mL at
the same temperature and pressure?
A) 1.4 moles B) 0.7 moles C) 3.9 moles D) 0.3 moles E) 2.3 moles
Ans: C Bloom's Taxonomy: 3 Difficulty: easy
38. If 2.38 moles of a gas has a volume of 120.0 mL what is the volume of 1.97 mole of the
gas at the same temperature and pressure?
A) 57.5 mL B) 285.6 mL C) 11.8 mL D) 99.3 mL E) 145.0 mL
Ans: D Bloom's Taxonomy: 3 Difficulty: easy
39. What is the volume of NH3 produced in the following reaction when 3.0 L of N2 reacts
with 4.0 L of H2?
N2(g) + 3H2(g) → 2NH3(g)
A) 1.5 L B) 2.66 L C) 0.66 L D) 2.0 L E) 0.5 L
Ans: B Bloom's Taxonomy: 3 Difficulty: easy
40. What is the formula which describes the relationship between the pressure, volume,
temperature, and moles?
A) PV
1 2 PV D) PT PT
= 2 1 1 1
= 2 2
n2T1 n1T2 n2V1 n1V2
B) PV
1 1 PV E) PT PT
= 2 2 1 2
= 2 1
n1T1 n2T2 n1V1 n2V2
C) PT
1 2 PT
= 2 1
n2V1 n1V2
Ans: B Bloom's Taxonomy: 1 Difficulty: easy
41. If a constant number of moles of a gas is at a pressure of 1.35 atm and has a volume of
23.8 L at a temperature of 205.1 K then what is the final volume of the gas if the
pressure changes to 2.84 atm and the temperature rises to 233.4 K?
A) 9.9 L B) 44.0 L C) 12.9 L D) 57.0 L E) 0.18 L
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
42. If a constant number of moles of a gas is at a pressure of 2.71 atm and has a volume of
85.3 L at a temperature of 173.4 K then what is the final temperature of the gas if the
pressure changes to 1.04 atm in a 105.3 L container?
A) 53.9 K B) 4.6 K C) 366.0 K D) 82.1 K E) 557.8 K
Ans: D Bloom's Taxonomy: 3 Difficulty: moderate
43. What is the initial pressure of a gas having an initial temperature of 90.5 K, an initial
volume of 40.3 L, a final pressure of 0.83 atm, a final temperature of 0.54 K ,and a final
volume of 2.7 L?
A) 0.074 atm B) 4.0 atm C) 1.9 atm D) 1.3 atm E) 9.3 atm
Ans: E Bloom's Taxonomy: 3 Difficulty: moderate
Page 172
Chapter 10 Gases
44. A gas evolved during the fermentation of sugar was collected at 22.5°C and 702 mmHg.
After purification its volume was found to be 25.0 L. How many moles of gas were
collected (R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760 mmHg)?
A) 0.95 mol B) 1.05 mol C) 12.5 mol D) 22.4 mol E) 724 mol
Ans: A Bloom's Taxonomy: 3 Difficulty: moderate
45. How many molecules of N2 gas can be present in a 2.5 L flask at 50°C and 650 mmHg
(R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760 mmHg, 1 mole = 6.022 × 1023 molecules)?
A) 2.1 × 10 –23 molecules D) 3.6 × 1025 molecules
B) 4.9 × 1022 molecules E) 0.081 molecules
23
C) 3.1 × 10 molecules
Ans: B Bloom's Taxonomy: 3 Difficulty: difficult
47. Calculate the volume occupied by 35.2 g of methane gas (CH4) at 25°C and 1.0 atm (R
= 0.0821 L·atm·K-1·mol-1).
A) 0.0186 L B) 4.5 L C) 11.2 L D) 49.2 L E) 53.7 L
Ans: E Bloom's Taxonomy: 3 Difficulty: moderate
48. Calculate the volume occupied by 25.2 g of CO2 at 0.84 atm and 25°C (R = 0.08206
L·atm·K-1·mol-1).
A) 0.060 L B) 1.34 L C) 16.9 L D) 24.2 L E) 734 L
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
49. Calculate the mass, in grams, of 2.74 L of CO gas measured at 33°C and 945 mmHg (R
= 0.08206 L·atm·K-1·mol-1, 1 atm = 760 mmHg).
A) 0.263 g B) 2.46 g C) 3.80 g D) 35.2 g E) 206 g
Ans: C Bloom's Taxonomy: 3 Difficulty: difficult
50. A sample of propane, a component of LP gas, has a volume of 35.3 L at 315 K and 922
torr. What is its volume at STP (R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760 torr)?
A) 25.2 L B) 30.6 L C) 33.6 L D) 37.1 L E) 49.2 L
Ans: D Bloom's Taxonomy: 3 Difficulty: moderate
51. A sample of nitrogen gas is confined to a 14.0 L container at 375 torr and 37.0°C. How
many moles of nitrogen are in the container (R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760
torr)?
A) 0.271 mol B) 2.27 mol C) 3.69 mol D) 206 mol E) 227 mol
Ans: A Bloom's Taxonomy: 3 Difficulty: difficult
Page 173
Chapter 10 Gases
52. A gas cylinder containing 1.50 mol compressed methane has a volume of 3.30 L. What
pressure does the methane exert on the walls of the cylinder if its temperature is 25°C (R
= 0.08206 L·atm·K-1·mol-1)?
A) 9.00 × 10–2 atm
B) 0.933 atm
C) 1.11 atm
D) 1.70 atm
E) 11.1 atm
Ans: E Bloom's Taxonomy: 3 Difficulty: moderate
53. Gases are sold in large cylinders for laboratory use. What pressure, in atmospheres,
will be exerted by 2500 g of oxygen gas (O2) when stored at 22°C in a 40.0 L cylinder
(R = 0.08206 L·atm·K-1·mol-1)?
A) 3.55 atm
B) 1510 atm
C) 47.3 atm
D) 7.56 × 104 atm
E) 10.2 atm
Ans: C Bloom's Taxonomy: 3 Difficulty: difficult
54. Calculate the density of carbon dioxide, CO2(g), at 100°C and 10.0 atm pressure (R =
0.08206 L·atm·K-1·mol-1).
A) 1.44 g/L B) 134 g/L C) 44.0 g/L D) 53.6 g/L E) 14.4 g/L
Ans: E Bloom's Taxonomy: 3 Difficulty: moderate
55. Calculate the density, in g/L, of SF6 gas at 27°C and 0.500 atm pressure (R = 0.08206
L·atm·K-1·mol-1).
A) 3.38 × 10–3 g/L
B) 2.96 g/L
C) 22.4 g/L
D) 32.9 g/L
E) 3.38 kg/L
Ans: B Bloom's Taxonomy: 3 Difficulty: moderate
56. Calculate the density of Ar(g) at –11°C and 675 mmHg (R = 0.08206 L·atm·K-1·mol-1, 1
atm = 760 mmHg).
A) 1.52 g/L B) 1.65 g/L C) –39.3 g/L D) 39.95 g/L E) 1254 g/L
Ans: B Bloom's Taxonomy: 3 Difficulty: difficult
57. Assuming ideal behavior, what is the density of argon gas at STP, in g/L (R = 0.08206
L·atm·K-1·mol-1)?
A) 0.0176 g/L B) 0.0250 g/L C) 0.0561 g/L D) 1.78 g/L E) 181 g/L
Ans: D Bloom's Taxonomy: 3 Difficulty: moderate
Page 174
Chapter 10 Gases
58. What is the density of carbon dioxide gas at –25.2°C and 98.0 kPa (R = 0.08206
L·atm·K-1·mol-1, 1 atm = 101,325 Pa)?
A) 0.232 g/L B) 0.279 g/L C) 0.994 g/L D) 1.74 g/L E) 2.09 g/L
Ans: E Bloom's Taxonomy: 3 Difficulty: difficult
59. Determine the molar mass of chloroform gas if a sample weighing 0.389 g is collected
in a flask with a volume of 102 cm3 at 97°C. The pressure of the chloroform is 728
mmHg (R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760 mmHg).
A) 187 g/mol D) 31.6 g/mol
B) 121 g/mol E) 8.28 × 10–3 g/mol
C) 112 g/mol
Ans: B Bloom's Taxonomy: 3 Difficulty: difficult
60. Determine the molar mass of Freon–11 gas if a sample weighing 0.597 g occupies 100
cm3 at 95°C, and 1000 mmHg (R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760 mmHg).
A) 0.19 g/mol
B) 35.3 g/mol
C) 70.9 g/mol
D) 137 g/mol
E) 384 g/mol
Ans: D Bloom's Taxonomy: 3 Difficulty: difficult
61. A flask with a volume of 3.16 L contains 9.33 grams of an unknown gas at 32.0°C and
1.00 atm. What is the molar mass of the gas (R = 0.08206 L·atm·K-1·mol-1)?
A) 7.76 g/mol
B) 66.1 g/mol
C) 74.0 g/mol
D) 81.4 g/mol
E) 144 g/mol
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
62. A 0.271 g sample of an unknown vapor occupies 294 mL at 140°C and 847 mmHg. The
empirical formula of the compound is CH2. What is the molecular formula of the
compound (R = 0.08206 L·atm·K-1·mol-1)?
A) CH2 B) C2H4 C) C3H6 D) C4H8 E) C6H12
Ans: B Bloom's Taxonomy: 3 Difficulty: difficult
63. A gaseous compound is 30.4% nitrogen and 69.6% oxygen by mass. A 5.25 g sample
of the gas occupies a volume of 1.00 L and exerts a pressure of 1.26 atm at –4.0°C.
Which of the following is its molecular formula (R = 0.08206 L·atm·K-1·mol-1)?
A) NO B) NO2 C) N3O6 D) N2O4 E) N2O5
Ans: D Bloom's Taxonomy: 3 Difficulty: difficult
Page 175
Chapter 10 Gases
64. A 250.0 mL sample of ammonia, NH3(g), exerts a pressure of 833 torr at 42.4°C. What
mass of ammonia is in the container (R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760 torr)?
A) 0.0787 g B) 0.180 g C) 8.04 g D) 17.0 g E) 59.8 g
Ans: B Bloom's Taxonomy: 3 Difficulty: difficult
65. What volume of CO2 gas at 645 torr and 800 K could be produced by the reaction of 45
g of CaCO3 according to the equation CaCO3(s) → CaO(s) + CO2(g) (R = 0.08206
L·atm·K-1·mol-1)?
A) 0.449 L B) 22.4 L C) 25.0 L D) 34.8 L E) 45.7 mL
Ans: D Bloom's Taxonomy: 3 Difficulty: difficult
66. How many liters of chlorine gas at 25°C and 0.950 atm can be produced by the reaction
of 12.0 g of MnO2? MnO2(s) + 4HCl(aq) → MnCl2(aq) + 2H2O(l) + Cl2(g) (R =
0.08206 L·atm·K-1·mol-1)
A) 5.36 × 10–3 L B) 0.138 L C) 0.282 L D) 3.09 L E) 3.55 L
Ans: E Bloom's Taxonomy: 3 Difficulty: moderate
67. Magnesium metal (0.100 mol) and a volume of aqueous hydrochloric acid that contains
0.500 mol of HCl are combined and react to completion. How many liters of hydrogen
gas, measured at STP, are produced? Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g) (R =
0.08206 L·atm·K-1·mol-1)
A) 2.24 L of H2 D) 11.2 L of H2
B) 4.48 L of H2 E) 22.4 L of H2
C) 5.60 L of H2
Ans: A Bloom's Taxonomy: 3 Difficulty: moderate
68. When active metals such as magnesium are immersed in acid solution, hydrogen gas is
evolved. Calculate the volume of H2(g) at 30.1°C and 0.85 atm that can be formed when
275 mL of 0.725 M HCl solution reacts with excess Mg to give hydrogen gas and
aqueous magnesium chloride (R = 0.08206 L·atm·K-1·mol-1).
A) 3.4 × 10–3 L B) 2.2 L C) 2.9 L D) 5.8 L E) 11.7 L
Ans: C Bloom's Taxonomy: 3 Difficulty: difficult
69. Calculate the volume of H2(g) at 273 K and 2.00 atm that will be formed when 275 mL
of 0.725 M HCl solution reacts with excess Mg to give hydrogen gas and aqueous
magnesium chloride (R = 0.08206 L·atm·K-1·mol-1).
A) 0.56 L B) 1.12 L C) 2.23 L D) 4.47 L E) 3.54 L
Ans: B Bloom's Taxonomy: 3 Difficulty: difficult
70. What mass of KClO3 must be decomposed to produce 126 L of oxygen gas at 133°C
and 0.880 atm? (The other reaction product is solid KCl.) (R = 0.08206
L·atm·K-1·mol-1)
A) 24.6 g B) 70.8 g C) 272 g D) 408 g E) 612 g
Ans: C Bloom's Taxonomy: 3 Difficulty: difficult
Page 176
Chapter 10 Gases
71. Hydrogen peroxide was catalytically decomposed and 75.3 mL of oxygen gas was
collected over water at 25°C and 742 torr. What mass of oxygen was collected? (Pwater =
24 torr at 25°C, R = 0.08206 L·atm·K-1·mol-1)
A) 0.00291 g B) 0.0931 g C) 0.0962 g D) 0.0993 g E) 0.962 g
Ans: B Bloom's Taxonomy: 3 Difficulty: moderate
72. A block of dry ice (solid CO2, density = 1.56 g/mL) of dimensions 25.0 cm × 25.0 cm ×
25.0 cm is left to sublime (i.e., to pass from the solid phase to the gas phase) in a closed
chamber of dimensions 4.00 m × 5.00 m × 3.00 m. The partial pressure of carbon
dioxide in this chamber at 25°C will be (R = 0.08206 L·atm·K-1·mol-1, 1 atm = 760
mmHg)
A) 171 mmHg. D) 0.171 mmHg.
B) 107 mmHg. E) 14.4 mmHg.
C) 0.225 mmHg.
Ans: A Bloom's Taxonomy: 3 Difficulty: difficult
73. The mole fraction of oxygen molecules in dry air is 0.2095. What volume of dry air at
1.00 atm and 25°C is required for burning 1.00 L of octane (C8H18, density = 0.7025
g/mL) completely, yielding carbon dioxide and water (R = 0.08206 L·atm·K-1·mol-1)?
A) 718 L B) 367 L C) 8990 L D) 1880 L E) 150 L
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
74. A 2.50 L flask contains a mixture of methane (CH4) and propane (C3H8) at a pressure of
1.45 atm and 20°C. When this gas mixture is then burned in excess oxygen, 8.60 g of
carbon dioxide is formed. (The other product is water.) What is the mole fraction of
methane in the original gas mixture?
A) 0.34 B) 1.00 C) 0.66 D) 0.85 E) 0.15
Ans: D Bloom's Taxonomy: 3 Difficulty: difficult
75. Hydrogen and oxygen gas are mixed in a 7.75 L flask at 65oC and contains 0.482 g of
hydrogen and 4.98 g of oxygen. What is the partial pressure of oxygen in the flask?
A) 0.557 atm B) 0.043 atm C) 1.11 atm D) 33.5 atm E) 67 atm
Ans: A Bloom's Taxonomy: 3 Difficulty: moderate
76. A spacecraft is filled with 0.500 atm of N2 and 0.500 atm of O2. Suppose an object
strikes this spacecraft and puts a very small hole in its side. Under these circumstances,
A) O2 is lost from the craft 6.9% faster than N2 is lost.
B) O2 is lost from the craft 14% faster than N2 is lost.
C) N2 is lost from the craft 6.9% faster than O2 is lost.
D) N2 is lost from the craft 14% faster than O2 is lost.
E) N2 and O2 are lost from the craft at the same rate.
Ans: C Bloom's Taxonomy: 2 Difficulty: difficult
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Chapter 10 Gases
77. 1.000 atm of oxygen gas, placed in a container having a pinhole opening in its side,
leaks from the container 2.14 times faster than does 1.000 atm of an unknown gas
placed in this same apparatus. Which of the following species could be the unknown
gas?
A) Cl2 B) SF6 C) Kr D) UF6 E) Xe
Ans: B Bloom's Taxonomy: 2 Difficulty: difficult
78. At what temperature in Kelvin is the root–mean–square speed of helium atoms (atomic
weight = 4.00) equal to that of oxygen molecules (molecular weight = 32.00) at 300. K?
A) 37.5 K B) 75 K C) 106 K D) 292 K E) 2400 K
Ans: A Bloom's Taxonomy: 3 Difficulty: difficult
79. Select the gas with the highest average kinetic energy per mole at 298 K.
A) O2
B) CO2
C) H2O
D) H2
E) All have the same average kinetic energy.
Ans: E Bloom's Taxonomy: 2 Difficulty: moderate
80. Select the gas with the largest root–mean–square molecular speed at 25°C.
A) NH3
B) CO
C) H2
D) SF6
E) All the gases have the same root–mean–square molecular speed at 25°C.
Ans: C Bloom's Taxonomy: 2 Difficulty: moderate
82. Freon–12, CF2Cl2, which has been widely used in air conditioning systems, is
considered a threat to the ozone layer in the stratosphere. Calculate the
root–mean–square velocity of Freon–12 molecules in the lower stratosphere where the
temperature is –65°C.
A) 20 m/s B) 120 m/s C) 210 m/s D) 260 m/s E) 4.4 × 104 m/s
Ans: C Bloom's Taxonomy: 3 Difficulty: moderate
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Chapter 10 Gases
85. A 3.0 L sample of helium was placed in container fitted with a porous membrane. Half
of the helium effused through the membrane in 24 h. A 3.0 L sample of oxygen was
placed in an identical container. How many hours will it take for half of the oxygen to
effuse through the membrane?
A) 8.5 h B) 12 h C) 48 h D) 60 h E) 68 h
Ans: E Bloom's Taxonomy: 3 Difficulty: difficult
86. A compound composed of carbon, hydrogen, and chlorine effuses through a pinhole
0.411 times as fast as neon. Select the correct molecular formula for the compound.
A) CHCl3 B) CH2Cl2 C) C2H2Cl2 D) C2H3Cl E) CCl4
Ans: A Bloom's Taxonomy: 3 Difficulty: difficult
87. The temperature of the carbon dioxide atmosphere near the surface of Venus is 475°C.
Calculate the average kinetic energy per mole of carbon dioxide molecules on Venus.
A) 2520 J/mol D) 9330 J/mol
B) 4150 J/mol E) 5920 kJ/mol
C) 5920 J/mol
Ans: D Bloom's Taxonomy: 3 Difficulty: moderate
89. Complete this sentence: The molecules of different samples of an ideal gas have the
same average kinetic energies, at the same ________.
A) pressure B) temperature C) volume D) density
Ans: B Bloom's Taxonomy: 1 Difficulty: easy
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Chapter 10 Gases
90. If equal masses of O2(g) and HBr(g) are in separate containers of equal volume and
temperature, which one of the following statements is true?
A) The pressure in the O2 container is greater than that in the HBr container.
B) There are more HBr molecules than O2 molecules.
C) The average velocity of the O2 molecules is less than that of the HBr molecules.
D) The average kinetic energy of HBr molecules is greater than that of O2 molecules.
E) The pressures of both gases are the same.
Ans: A Bloom's Taxonomy: 2 Difficulty: moderate
91. Which gas has molecules with the greatest average molecular speed at 25°C?
A) CH4 B) Kr C) N2 D) CO2 E) Ar
Ans: A Bloom's Taxonomy: 2 Difficulty: moderate
92. Which of the following gas molecules have the highest average kinetic energy at 25°C?
A) H2
B) O2
C) N2
D) Cl2
E) All the gases have the same average kinetic energy.
Ans: E Bloom's Taxonomy: 2 Difficulty: moderate
94. For a substance that remains a gas under the conditions listed, deviation from the ideal
gas law would be most pronounced at
A) 100°C and 2.0 atm D) –100°C and 4.0 atm
B) 0°C and 2.0 atm E) 100°C and 4.0 atm
C) –100°C and 2.0 atm
Ans: D Bloom's Taxonomy: 2 Difficulty: easy
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Chapter 10 Gases
96. At very high pressures (~ 1000 atm), the measured pressure exerted by real gases is
greater than that predicted by the ideal gas equation. This is mainly because
A) such high pressures cannot be accurately measured.
B) real gases will condense to form liquids at 1000 atm pressure.
C) gas phase collisions prevent molecules from colliding with the walls of the
container.
D) of attractive intermolecular forces between gas molecules.
E) the volume occupied by the gas molecules themselves becomes significant.
Ans: E Bloom's Taxonomy: 2 Difficulty: easy
97. True or False: Gases form heterogeneous mixtures or solutions with one another.
Ans: False Bloom's Taxonomy: 1 Difficulty: easy
98. True or False: Gases are compressible and have a density that is much higher than
liquids and solids.
Ans: False Bloom's Taxonomy: 1 Difficulty: easy
99. True or False: When a closed–ended manometer is used for pressure measurements,
and the closed end is under vacuum, the level of manometer liquid in the closed arm can
never be lower than that in the other arm.
Ans: True Bloom's Taxonomy: 2 Difficulty: moderate
100. True or False: For a gas obeying Boyle's Law, a plot of V versus 1/P will give a
straight line passing through the origin.
Ans: False Bloom's Taxonomy: 1 Difficulty: moderate
101. True or False: At a temperature of absolute zero, the volume of an ideal gas is zero.
Ans: True Bloom's Taxonomy: 1 Difficulty: easy
103. True or False: The rate of diffusion of a gas is inversely proportional to its molar mass.
Ans: False Bloom's Taxonomy: 1 Difficulty: easy
104. True or False: According to the postulates of kinetic–molecular theory, the molecules
of all gases at a given temperature have the same average speed.
Ans: False Bloom's Taxonomy: 1 Difficulty: easy
105. Give five examples of elements that occur as gases at room temperature and pressure?
Ans: (Answers will vary.) Oxygen, nitrogen, helium, hydrogen, argon, chlorine
Bloom's Taxonomy: 1 Difficulty: easy
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Chapter 10 Gases
106. Give five examples of compounds that exist as gases at room temperature and pressure.
Ans: (Answers will vary.) Ammonia, carbon dioxide, sulfur dioxide, nitrogen dioxide,
methane
Bloom's Taxonomy: 1 Difficulty: easy
110. An aerosol can with a volume of 0.50 L has a bursting point of 2.6 atm. If the can
contains 1.0 g CO2 and is heated to 400°C, will it burst?
Ans: no
Bloom's Taxonomy: 3 Difficulty: difficult
111. What is the mole fraction of NO in a 55.0 L gas cylinder at 30oC which comes from a
mixture of N2 and NO if you have 3.238 mol of N2 and the gas cylinder has a total
pressure of 2.14 atm?
Ans: 0.336
Bloom's Taxonomy: 3 Difficulty: moderate
114. ___________ is a device used to measure the pressure of gases other than the
atmosphere.
Ans: Manometer
Bloom's Taxonomy: 1 Difficulty: easy
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Chapter 10 Gases
116. ___________ states that the volume of a fixed amount of gas maintained at constant
pressure is directly proportional to the absolute temperature of a gas.
Ans: Charles's Law
Bloom's Taxonomy: 1 Difficulty: moderate
118. ___________ is the formula to determine the amount of a reactant or product in units of
moles using the ideal gas law.
Ans: n = PV/RT
Bloom's Taxonomy: 2 Difficulty: moderate
120. ___________ is the formula to determine the molar mass of a compound using the ideal
gas law.
Ans: M =dRT/P
Bloom's Taxonomy: 1 Difficulty: easy
121. ___________ is the formula to determine the density of a substance using the ideal gas
law.
Ans: d = pM/RT
Bloom's Taxonomy: 1 Difficulty: easy
123. Explain why you do not feel atmospheric pressure pushing on your body?
Ans: A pressure exists inside your body that is equal to the atmospheric pressure
pushing on the outside of your body.
Bloom's Taxonomy: 2 Difficulty: difficult
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Chapter 10 Gases
125. Packaged cake mixes usually contain baking powder, a mixture of sodium hydrogen
carbonate and calcium hydrogen phosphate, that react to produce carbon dioxide gas
when they come into contact with water. Many such mixes have special instructions
for use at high altitudes. Why?
Ans: The baking powder acts as a leavening agent. Due to the reduced atmospheric
pressure, a greater volume of carbon dioxide is created.
Bloom's Taxonomy: 2 Difficulty: difficult
126. Starting from the Ideal Gas Equation, derive an equation corresponding to Charles's
Law, stating all important assumptions or conditions.
Ans: Ideal Gas Equation is PV = nRT. Charles's Law refers to a fixed amount of gas (n
is a constant) and constant pressure P. R is always constant. Rearrange the
equation to V = (nR/P)T. The quantities in parentheses are all constant, so V =
constant × T, which is Charles's Law.
Bloom's Taxonomy: 4 Difficulty: difficult
127. What is the significance of the magnitude of the van der Waals “a” constant?
Ans: The magnitude of the van der Waals “a” constant reflects the strength of the
attractions between molecules of a given type of gas.
Bloom's Taxonomy: 1 Difficulty: moderate
Page 184
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but very prettily made. And they went through their exercises with
great grace and beauty. One incident only marred the day’s
proceedings. A little girl had written to Vienna complaining that her
teacher ate all her food. She was brought before Baroness Einam.
The teacher, a red-faced girl of over-fed appearance, feeling herself
wronged, rushed at the pale child as if to strangle her. The girl was
stubborn and refused to make amends. What was done to the little
Bolshevik I don’t know. But it was gratifying to the organizers of the
scheme, and very interesting to us to discover that the kindly Swiss
peasants grew so attached to the little Austrians that when the time
came for them to go home they offered to keep them all until the next
Austrian harvest.
We drove home through the lovely Swiss scenery in the cool
evening air. But what obtrudes on the mind to spoil the memory of
that drive? The six luckless idiots, with vacant faces and staring
eyes, the disfiguring goitre thickening their poor throats, we counted
on the roadside before we were out of sight of the little mountain
town.
CHAPTER V
THE CONFERENCE OF WOMEN AT ZURICH
(JUNE, 1919)
I left the Conference that day in the company of one of the most
brilliant of living Germans. He had never been optimistic about the
Peace. He was more than half in sympathy with the militarist point of
view although a sincere internationalist. It was not any fighting
proclivity which had shaped his opinion. He hated violence for the
vulgar, futile thing it is. But an inherited capacity for facing realities,
and a cultivated habit of looking squarely at facts, led him to severe
criticism of those he contemptuously spoke of as idealists. He was
an idealist himself after a fashion; but his ideal was not of the
complexion of that exemplified in the conference of women. He had
no use for democracy. He spoke openly of the stupid, ignorant thing
which, he alleged, most people really believe it to be if they were
honest with themselves and the rest of the world. He differed from
those who acknowledge frankly the weaknesses of democracy, but
who, recognizing its inevitability, hope that with education and
organization it need not to all eternity be the victim of the cunning
and the corrupt. He believed democracy to be the predestined victim
of power till the end of time. His ideal was the domination of mankind
by a few great empires, commonwealths, call them what you will,
British, German, Russian and American. The small nationalities he
regarded as a nuisance. He was bitterly hostile to those British
delegates who contemplated complacently the break-up of the
British Empire. He would have applauded the dissertations of Dean
Inge on “the squalid anarchy of democracy,” laughed to scorn the
idea of an entirely independent India, Egypt, Ireland, and through all
his pain at the destruction of the German Empire, pleaded for the
preservation of that of Great Britain.
For the “strong men” of England he had the warmest admiration.
To my astonishment, before I knew him properly, he expressed an
equal regard for M. Clemenceau. “What!” I exclaimed, “the man who
is doing his best to ruin Germany? Or, at least, to benefit France in
such a way that only the ruin of Germany can result? You astonish
me!”
“But why not?” he replied. “In Clemenceau there is a man who
knows what he wants and means to get it; who looks for the
attainable and means to attain it. When did you read from
Clemenceau a speech full of delightful and impossible pledges and
promises? Has Clemenceau disguised the real objects of this war
under a cover of fine and deceptive phrases? All he cares about is
France. He would stop at nothing to advance the interests of France.
One can understand a point of view like that. It is cruel. It hurts
Germany. Very well. That is sad for Germany; but, at least, with such
a man we know where we are and what to expect. If that is nothing,
it is better to expect nothing and get it than to expect much and be
disappointed. Clemenceau knows that in strangling Germany he will
satisfy the immediate demands of France. That is all he cares about.
This is the present. The future is far away, indefinite. New events will
shape and govern that. For the present it is France, only France, all
the time France; and for the rest? N’importe! It is an intelligible point
of view.”
There was a long pause during which I marvelled for the
hundredth time at the amazing facility for languages of the cultivated
European.
“It is not the Clemenceaus and the Ludendorffs of the world, but
your Wilsons, your Lloyd Georges, your idiotic idealists who are
bringing it to ruin.” He glanced at me to see if I were offended.
“Please go on,” I murmured. “You interest me deeply.”
“Your idealists have promised the people impossible things,
Wilson’s Fourteen Points, for instance, Lloyd George’s wonderful
phrases, Asquith’s war-time speeches, the Russian manifestoes,
numberless ministers of religion with no more knowledge of
international politics than the Bibles they thump. They have told the
stupid masses that this is a holy war; that the peace will be based
upon justice: that nothing but good is intended the German people, if
they will only get rid of their blood-stained Kaiser. The same sort of
amiable idiots in Germany believe this sort of thing. All Germans,
with the exception of a few so-called pan-Germans, are intoxicating
themselves with the thought that liberty is born anew; that militarism
is dead for ever; that with the new German democracy the Allied
democracies will make a fair and democratic peace. Pathetically
relying on the Fourteen Points, they are pre-figuring a glorious future
for free Germany, its place in the sun assured according to plan, a
member of the great Society of Nations which shall maintain the
peace of the world. Poor deluded wretches! What an awakening
there will be!”
All this was in Berne during the International.
We left the Zurich conference hall together and discovered a little
café famous for its good tea and delicious pastries. Not a word did
we speak for many minutes. I was filled with awe at the spectacle of
his misery. The ordinarily smiling brown eyes were black with pain,
the pain of a suffering dumb animal. He lit a cigarette. The silence
continued. I felt like an intruder gazing in at the windows of a man’s
stricken soul; but to retire would have been unsympathetic. So I
stayed and poured out the tea and waited in silence for the speech
that I hoped might come.
“How can you sit there looking so fresh and beautiful? How can
the sun go on shining and the birds continue to sing when the world
is really dark and black and sunk in rottenness?” was the beginning.
“You feel it more than you expected?” I asked, reminding him of
the Berne conversation.
“It is so much worse than I expected. I did not expect much, God
knows. But this thing—it means famine, anarchy, war in Europe for
twenty, thirty, forty years!” I waited patiently.
“Germany is to pay the uttermost farthing for the damage she did
to civilians, which is not unreasonable; an enormous amount of the
war damage, of which I do not complain; but also incalculable sums
for the mischief for which she is not responsible, or only in part,
which is wrong. At the same time practically all the means by which
she is to make the money are to be taken from her—ships, minerals,
colonies. She is to be disarmed and her deadly enemy is to remain
fully armed. Any fool can see where that will lead. And the worst is
not told. The slow starvation of Germany, the lynch-pin of European
civilization, will mean incredible moral decline and spiritual
degradation. Millions of people will think food, talk food, dream food,
steal food, lie for food, bribe, corrupt and even murder for food. What
man would see his wife and children die of hunger whilst food was to
be had? Masses of disbanded soldiers, for whom there will be no
work, will enlist for adventures, will quarrel, fight and kill, either for
subsistence or in the service of the enemies of their country, having
no choice, if they are to live. The new states will be insolent,
ambitious, tyrannical, unscrupulous. Instead of one big war there will
be twenty little ones—war never ceasing, war for crude material
things. Art, music, literature, the drama—these will decay. First class
artists will go to America where they can be paid. Grass will grow in
decayed cities and ignorant peasants will instal themselves in the
seats of power. We shall have restored the age of bigotry and
superstition. Central Europe will not merely be Balkanized; it will be
atomized. Our horizon will decline to the level of each man’s
immediate family, if he has a conscience. He will have no horizon but
himself if he has none. And as for your ideals”—here he paused
—“the failure of Wilson has made faith in them impossible to revive
for decades, if ever again. Faith in the pledged word of public men,
faith in idealism, faith in religion—this is dying or dead. And our
idealists have killed it, not the men who never professed more than
the crudest material objectives in this war. Wilson and Lloyd George
between them have damaged the world’s moral currency infinitely
more than the Treaty of Peace has damaged the financial currency
of Germany; and the world is poorer by the loss of the one than of
the other, grave though that is.”
As the passionate words fell from his lips I felt humiliated to the
very dust for the failure that I felt myself to embody. Weeping in a
public place is not a habit of mine or I might have wept. But if my
friend saw no tears, he must have felt the sympathy, for as we rose
to go to the University he said:
“But justice and sanity owe much to you. I am grateful for your
speech of this morning. It will have no effect. It will accomplish
nothing. But it is good to know there are some with the courage to
speak what they believe even when it is on behalf of a beaten foe.
And the German women will be grateful for your protest against the
blockade.”
It was not the full International, but the special Council appointed
by it which met at Lucerne in July of 1919. This time my position was
that of a representative of the Press, and not a delegate. I had an
honorary commission from a London daily newspaper to report the
proceedings of the Conference. I am afraid my report was not too
sympathetic. Everybody felt the same thing in some degree. Far too
much time was wasted on petty national squabbles. The old fight on
responsibility for the war was taken up with renewed lustiness.
French and Germans yelled at one another, like children in a street
squabble, with the old vituperativeness. Meantime the crime of Paris
had been committed, and the world was shrieking from its gaping
and undoctored wounds. A problem presented itself to me: How to
make a genuine International out of men so filled with national hates
and envies that they were at one another’s throats for the slightest
word! Of course, I am sure they said a great deal more than they
meant. They always do at Socialist conferences. Nobody could stay
for five minutes in any Socialist Party I know, if he believed that all
the abuse and violence of language used by members against one
another were intended to be taken at their face value. But it seemed
pitiful that the old vice of talking and saying nothing should have
possessed the International at such a tragic time in the world’s
history. Apart from the awfulness of the Peace, the persecution of
the Jews and the Hungarian counter-revolution should have
absorbed the attention of any body of enlightened Socialists sitting in
conference.
Lucerne is not a good place for a congress. It is too beautiful. The
delegates wanted to be out amongst the mountains or to be dipping
their hands into the lake as they rowed lazily on its still surface. The
most inveterate lover of eloquence could not get up any enthusiasm