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Introductory Chemistry, 4e (Tro)
Chapter 10 Chemical Bonding
True/False Questions
1) Bonding theories are used to predict how atoms bond together to form molecules.
Answer: TRUE
Diff: 1 Page Ref: 10.1
2) Drugs to fight HIV have been developed using bonding theory models.
Answer: TRUE
Diff: 1 Page Ref: 10.1
6) Lewis structures only use the valence electrons in determining the bonding.
Answer: TRUE
Diff: 1 Page Ref: 10.2
8) A correct Lewis structure for an atom of carbon would have eight dots surrounding the symbol of the element.
Answer: FALSE
Diff: 1 Page Ref: 10.2
10) Chlorine has 8 valence electrons in the Lewis structure for KCl.
Answer: TRUE
Diff: 1 Page Ref: 10.3
11) The Lewis theory predicts that the formula for a compound of magnesium and sulfur is MgS 2.
Answer: FALSE
Diff: 1 Page Ref: 10.3
1
Copyright © 2012 Pearson Education, Inc.
12) The Lewis theory predicts that the formula for a compound made of sodium and fluorine is NaF.
Answer: TRUE
Diff: 1 Page Ref: 10.3
13) Lewis theory predicts that the formula for a compound made of aluminum and phosphorus is AlP.
Answer: TRUE
Diff: 1 Page Ref: 10.3
14) The Lewis structure of water has two sets of lone pair electrons.
Answer: TRUE
Diff: 1 Page Ref: 10.4
17) The double bond is shorter and stronger than a single bond.
Answer: TRUE
Diff: 1 Page Ref: 10.4
18) The triple bond present in diatomic nitrogen, N2, is what makes this molecule so reactive.
Answer: FALSE
Diff: 1 Page Ref: 10.4
19) When calculating the number of electrons for the Lewis structure of a polyatomic ion, subtract one electron for
each negative charge.
Answer: FALSE
Diff: 1 Page Ref: 10.5
20) The correct Lewis structure for CO2 shows that the molecule contains two double bonds.
Answer: TRUE
Diff: 1 Page Ref: 10.5
21) The correct Lewis structure for CO2 shows that the carbon atom has two sets of lone pair electrons.
Answer: FALSE
Diff: 1 Page Ref: 10.5
2
Copyright © 2012 Pearson Education, Inc.
24) Boron forms compounds that violate the octet rule.
Answer: TRUE
Diff: 1 Page Ref: 10.5
25) Resonance structures are the best representation we can draw but do not accurately reflect the true structure.
Answer: TRUE
Diff: 1 Page Ref: 10.6
27) The VSEPR theory predicts that the angle between the central carbon atom and the two oxygen atoms in CO 2
measures 180°.
Answer: TRUE
Diff: 1 Page Ref: 10.7
28) The VSEPR theory predicts that the H-C-H angle in CH4 measures 120°.
Answer: FALSE
Diff: 1 Page Ref: 10.7
29) It is important to identify lone pairs around a central atom because they do not repel other electron groups.
Answer: FALSE
Diff: 1 Page Ref: 10.7
30) The electron geometry of a molecule is never the same as its molecular geometry.
Answer: FALSE
Diff: 1 Page Ref: 10.7
31) When you have 2 electron groups and none are lone pairs, the molecular geometry is linear.
Answer: TRUE
Diff: 1 Page Ref: 10.7
32) When you have 4 electron groups and 1 of them is a lone pair, the molecular geometry is bent.
Answer: FALSE
Diff: 1 Page Ref: 10.7
33) When you have 4 electron groups and none of them are lone pairs, the molecular geometry is trigonal
pyramidal.
Answer: FALSE
Diff: 1 Page Ref: 10.7
34) When you have 4 electron groups, the electron geometry is tetrahedral.
Answer: TRUE
Diff: 1 Page Ref: 10.7
35) The compound H2S contains polar bonds but the molecule is nonpolar.
Answer: FALSE
Diff: 1 Page Ref: 10.8
3
Copyright © 2012 Pearson Education, Inc.
36) Water and oil do not mix because water molecules are nonpolar and molecules that compose oil are generally
polar.
Answer: FALSE
Diff: 1 Page Ref: 10.8
A) K⁺ [ ]⁻
B) K⁺ [: :]⁻
C) K : :
D) : :: :
3) Which Lewis structure below correctly represents the compound formed between magnesium and sulfur?
A) Mg⁺ [: :]⁻
D) Mg⁺2 [: :]⁻2
4
Copyright © 2012 Pearson Education, Inc.
4) Lewis theory predicts that the formula of a compound formed between bromine and aluminum is:
A) AlBr
B) Al2Br
C) AlBr3
D) AlBr2
E) none of the above
Answer: C
Diff: 1 Page Ref: 10.3
5) Lewis theory predicts that the formula for a compound between fluorine and calcium is:
A) CaF
B) Ca2F
C) CaF2
D) CaF3
E) none of the above
Answer: C
Diff: 2 Page Ref: 10.3
6) Lewis theory predicts that the formula for a compound between barium and sulfur is:
A) BaS
B) Ba2S
C) BaS2
D) BaS3
E) none of the above
Answer: A
Diff: 2 Page Ref: 10.3
7) Lewis theory predicts that the formula for a compound between potassium and sulfur is:
A) KS
B) K2S
C) KS2
D) K3S
E) none of the above
Answer: B
Diff: 2 Page Ref: 10.3
5
Copyright © 2012 Pearson Education, Inc.
9) What is the correct Lewis structure for water?
A) H-: :-H
B) : - - :
C) H= =H
D) H- -H
B) : - :
C) =
D) : Br≡ Br :
B) : - :
C) =
D) : O ≡ O :
6
Copyright © 2012 Pearson Education, Inc.
12) What is the correct Lewis structure for N2?
A) N-N
B) : - :
C) =
D) : N ≡ N :
13) The Lewis structure for carbon monoxide is This structures shows
A) 4 lone pairs and 1 bonding pair.
B) 4 lone pairs and 3 bonding pairs.
C) 2 lone pairs and 3 bonding pairs.
D) 2 lone pairs and 1 bonding pair.
E) none of the above
Answer: C
Diff: 1 Page Ref: 10.4
14) Which sequence below represents the proper order of increasing bond strength?
A) single < double < triple
B) double < single < triple
C) single < triple < double
D) triple < double < single
E) none of the above
Answer: A
Diff: 1 Page Ref: 10.4
16) The total number of electrons to be counted for the Lewis structure of the PO 43- polyatomic ion is
A) 8.
B) 26.
C) 29.
D) 32.
E) none of the above
Answer: D
Diff: 1 Page Ref: 10.5
7
Copyright © 2012 Pearson Education, Inc.
17) The central atom in the chlorate anion, ClO3- is surrounded by
A) two bonding and two unshared pairs of electrons.
B) one bonding and three unshared pairs of electrons.
C) three bonding and one unshared pair of electrons.
D) two double bonds and no unshared pairs of electrons.
E) none of the above.
Answer: C
Diff: 2 Page Ref: 10.5
A) : - - :
B) : = = :
C) : = C= :
D) : = C= :
A) NO2+
B) NO2-
C) NO2
D) both NO2+ and NO2-
E) none of the above
Answer: B
Diff: 2 Page Ref: 10.5
8
Copyright © 2012 Pearson Education, Inc.
21) What is the correct Lewis structure for CN⁻?
A) [C-N]⁻
B) [: - :]⁻
C) [ = :]⁻
D) [: C≡ N :]⁻
22) The correct Lewis structure for BF3 would have exactly:
A) 1 double bond.
B) 2 double bonds.
C) 1 triple bond.
D) no double bonds.
E) none of the above
Answer: D
Diff: 2 Page Ref: 10.5
23) Which symbol should be used between two structures that represent resonance structures?
A) →
B) ←
C) ↔
D) ≡
E) none of the above
Answer: C
Diff: 1 Page Ref: 10.6
24) Which set shows the correct resonance structures for SeO2?
A) : - - :↔ = =
B) : = - :↔: - = :
D) = - :↔: - =
9
Copyright © 2012 Pearson Education, Inc.
25) Which of the following compounds have resonance structures?
A) CH4
B) H2O
C) NH3
D) O3
E) None of the compounds have resonance structures.
Answer: D
Diff: 2 Page Ref: 10.6
26) Consider the Lewis structures for the compound SO3 and the polyatomic ions SO32- and SO42-. Which of
these would exist as a set of resonance structures?
A) SO3 only
B) SO32- only
C) SO42- only
D) all of these show resonance
E) none of these show resonance
Answer: A
Diff: 3 Page Ref: 10.6
27) What is the angle between electron groups in the linear electron geometry?
A) 90°
B) 109.5°
C) 120°
D) 180°
E) not enough information
Answer: D
Diff: 2 Page Ref: 10.7
28) What is the angle between electron groups in the trigonal planar electron geometry?
A) 90°
B) 109.5°
C) 120°
D) 180°
E) not enough information
Answer: C
Diff: 2 Page Ref: 10.7
29) What is the angle between electron groups in the tetrahedral geometry?
A) 90°
B) 109.5°
C) 120°
D) 180°
E) not enough information
Answer: B
Diff: 2 Page Ref: 10.7
10
Copyright © 2012 Pearson Education, Inc.
30) Which of the following is considered a single electron group?
A) a lone pair of electrons
B) a single bond
C) a double bond
D) a triple bond
E) all of the above
Answer: E
Diff: 2 Page Ref: 10.7
31) What is the electron geometry if you have 4 electron groups around the center atom?
A) linear
B) trigonal planar
C) tetrahedral
D) trigonal bipyramidal
E) not enough information
Answer: C
Diff: 2 Page Ref: 10.7
32) What is the electron geometry if you have 2 electron groups around the center atom?
A) linear
B) trigonal planar
C) tetrahedral
D) trigonal bipyramidal
E) not enough information
Answer: A
Diff: 2 Page Ref: 10.7
33) What is the electron geometry if you have 3 electron groups around the center atom?
A) linear
B) trigonal planar
C) tetrahedral
D) trigonal bipyramidal
E) not enough information
Answer: B
Diff: 2 Page Ref: 10.7
34) What is the molecular geometry if you have 3 single bonds and 1 lone pair around the central atom?
A) bent
B) linear
C) tetrahedral
D) trigonal pyramidal
E) not enough information
Answer: D
Diff: 2 Page Ref: 10.7
11
Copyright © 2012 Pearson Education, Inc.
35) What is the molecular geometry if you have 4 single bonds around the central atom?
A) bent
B) linear
C) tetrahedral
D) trigonal pyramidal
E) not enough information
Answer: C
Diff: 2 Page Ref: 10.7
36) What is the molecular geometry if you have a double bond, a single bond and 1 lone pair around the central
atom?
A) bent
B) linear
C) tetrahedral
D) trigonal pyramidal
E) not enough information
Answer: A
Diff: 2 Page Ref: 10.7
38) Which of the following compounds would have a linear molecular geometry?
1. N2
2. H2S
3. CO2
A) 1 and 2 only
B) 1 and 3 only
C) 2 and 3 only
D) 1,2 and 3
E) neither 1, 2,or 3
Answer: B
Diff: 2 Page Ref: 10.7
12
Copyright © 2012 Pearson Education, Inc.
40) What is the molecular geometry of PH3?
A) bent
B) linear
C) tetrahedral
D) trigonal pyramidal
E) not enough information
Answer: D
Diff: 2 Page Ref: 10.7
13
Copyright © 2012 Pearson Education, Inc.
45) The electron geometry and the molecular geometry of ammonia (NH 3) are, respectively,
A) trigonal planar, bent.
B) tetrahedral, tetrahedral.
C) tetrahedral, trigonal pyramidal.
D) tetrahedral, bent.
E) none of the above
Answer: C
Diff: 2 Page Ref: 10.7
46) The electron geometry and the molecular geometry of water are, respectively,
A) trigonal planar, bent.
B) tetrahedral, tetrahedral.
C) tetrahedral, trigonal pyramidal.
D) tetrahedral, bent.
E) none of the above
Answer: D
Diff: 2 Page Ref: 10.7
47) Which of the following has a tetrahedral electron geometry and a trigonal pyramidal molecular geometry?
A) Br2O
B) GeH4
C) SO2
D) PF3
E) none of the above
Answer: D
Diff: 3 Page Ref: 10.7
48) Which term matches the definition: A separation of charge within a bond.
A) coulombic attraction
B) dipole moment
C) polar covalent
D) nonpolar covalent
E) electronegativity
Answer: B
Diff: 2 Page Ref: 10.8
49) The elements with the highest electronegativity values tend to be found in the:
A) upper right-side of the periodic table.
B) lower right-side of the periodic table.
C) upper left-side of the periodic table.
D) lower left-side of the periodic table.
E) center of the periodic table.
Answer: A
Diff: 1 Page Ref: 10.8
14
Copyright © 2012 Pearson Education, Inc.
50) Which term matches the definition: The ability of an element to attract electrons within a covalent bond?
A) coulombic attraction
B) dipole moment
C) polar covalent
D) nonpolar covalent
E) electronegativity
Answer: E
Diff: 2 Page Ref: 10.8
15
Copyright © 2012 Pearson Education, Inc.
55) Which molecule listed below is a nonpolar molecule?
A) CCl4
B) CO2
C) BH3
D) all of the compounds
E) none of the compounds
Answer: D
Diff: 2 Page Ref: 10.8
58) Which compound listed below will dissolve in carbon tetrachloride, CCl 4?
A) NaCl
B) CS2
C) NH3
D) all of the compounds
E) none of the compounds
Answer: B
Diff: 2 Page Ref: 10.8
59) Which of the following statements is TRUE for the covalent molecule HCl?
A) Chlorine is more electronegative and the shared electron pair is likely to be found on the hydrogen atom.
B) Chlorine is more electronegative and the shared electron pair is likely to be found on the chlorine atom.
C) Hydrogen is more electronegative and the shared electron pair is likely to be found on the hydrogen atom.
D) Hydrogen is more electronegative and the shared electron pair is likely to be found on the chlorine atom.
E) none of the above
Answer: B
Diff: 2 Page Ref: 10.8
16
Copyright © 2012 Pearson Education, Inc.
60) Which of the following statements about the water molecule is TRUE?
A) A water molecule has two dipole moments and they cancel each other.
B) A water molecule is symmetrical and therefore is nonpolar.
C) A water molecule is asymmetric and therefore is polar.
D) The electronegativities of hydrogen and oxygen are equal and therefore a water molecule is nonpolar.
E) none of the above
Answer: C
Diff: 2 Page Ref: 10.8
61) Which of the following statements are TRUE about the BF 3 molecule?
A) BF3 has a trigonal planar molecular geometry.
B) BF3 violates the octet rule for the central atom.
C) BF3 is nonpolar.
D) All of the above statements are true.
E) None of the above are true.
Answer: D
Diff: 2 Page Ref: 10.8
62) The electronegativity value for N is 3.0 and that for O is 3.5. Based on these values, which of the following
statements is TRUE about the compound NO?
A) NO is an ionic compound.
B) NO is a pure covalent compound.
C) NO is a polar covalent compound.
D) There is not enough enough information to determine the nature of NO.
E) None of the above statements is true.
Answer: C
Diff: 2 Page Ref: 10.8
63) The electronegativity value for Mg is 1.2 and the value for O is 3.5. Based on these values, what type of bond
is expected for a compound formed between Mg and O?
A) Ionic
B) Pure covalent
C) Polar covalent
D) not enough information
E) none of the above
Answer: A
Diff: 2 Page Ref: 10.8
17
Copyright © 2012 Pearson Education, Inc.
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CROQUETTES OF RICE. (ENTREMETS.)
Swell the rice in thin cream, or in new milk strongly flavoured with
vanilla or cocoa-nut; add the same ingredients as in the foregoing
receipt, and when the rice is cold, form it into balls, and with the
thumb of the right hand hollow them sufficiently to admit in the centre
a small portion of peach jam, or of apricot marmalade; close the rice
well over it; egg, crumb, and fry the croquettes as usual. As, from the
difference of quality, the same proportions of rice and milk will not
always produce the same effect, the cook must use her discretion in
adding, should it be needed, sufficient liquid to soften the rice
perfectly: but she must bear in mind that if not boiled extremely thick
and dry, it will be difficult to make it into croquettes.[136]
136. We must repeat here what we have elsewhere stated as the result of many
trials of it, that good rice will absorb and become tender with three times its
own bulk or measure of liquid. Thus, an exact half pint (or half pound) will
require a pint and a half, with an extremely gentle degree of heat, to convert
it into a thoroughly soft but firm mass; which would, perhaps, be rather too
dry for croquettes. A pint of milk to four ounces of rice, if well managed,
would answer better.
SAVOURY CROQUETTES OF RICE. (ENTRÉE.)
This is the French name for small fried pastry of various forms,
filled with meat or fish previously cooked; they may be made with
brioche, or with light puff-paste, either of which must be rolled
extremely thin. Cut it with a small round cutter fluted or plain; put a
little rich mince, or good pounded meat, in the centre, and moisten
the edges, and press them securely together that they may not burst
open in the frying. The rissoles may be formed like small patties, by
laying a second round of paste over the meat, or like cannelons; they
may, likewise, be brushed with egg, and sprinkled with vermicelli,
broken small, or with fine crumbs. They are sometimes made in the
form of croquettes, the paste being gathered round the meat, which
must form a ball.[137]
137. If our space will permit, more minute directions for these, and other small
dishes of the kind, shall be given in the chapter of Foreign Cookery.
In frying them, adopt the same plan as for the croquettes, raising
the pan as soon as the paste is lightly coloured. Serve all these fried
dishes well drained, and on a napkin.
From 5 to 7 minutes, or less.
VERY SAVOURY ENGLISH RISSOLES. (ENTRÉE.)
(Very delicate.)
Pare the crust neatly from one or two French rolls, slice off the
ends, and divide the remainder into as many patties as the size of
the rolls will allow; hollow them in the centre, dip them into milk or
thin cream, and lay them on a drainer over a dish; pour a spoonful or
two more of milk over them at intervals, but not sufficient to cause
them to break; brush them with egg, rasp the crust of the rolls over
them, fry and drain them well, fill them with a good mince, or with
stewed mushrooms or oysters, and serve them very hot upon a
napkin; they may be filled for the second course with warm apricot
marmalade, cherry-jam, or other good preserve. This receipt came to
us direct from Dresden, and on testing it we found it answer
excellently, and inserted it in an earlier edition of the present work.
We name this simply because it has been appropriated, with many
other of our receipts, by a contemporary writer without a word of
acknowledgment.
TO PREPARE BEEF MARROW FOR FRYING CROUSTADES,
SAVOURY TOASTS, &C.
(Author’s Receipt.)
Cut very evenly, from a firm stale loaf, slices nearly an inch and a
half thick, and with a plain or fluted paste-cutter of between two and
three inches wide press out the number of patties required,
loosening them gently from the tin, to prevent their breaking; then,
with a plain cutter, scarcely more than half the size, mark out the
space which is afterwards to be hollowed from it. Melt some clarified
beef-marrow in a small saucepan or frying-pan, and, when it begins
to boil, put in the patties, and fry them gently until they are equally
coloured of a pale golden brown. In lifting them from the pan, let the
marrow (or butter) drain well from them; take out the rounds which
have been marked on the tops, and scoop out part of the inside
crumb, but leave them thick enough to contain securely the gravy of
the preparation put into them. Fill them with any good patty-meat,
and serve them very hot on a napkin.
Obs.—These croustades are equally good if dipped into clarified
butter or marrow, and baked in a tolerably quick oven. It is well, in
either case, to place them on a warm sheet of double white blotting-
paper while they are being filled, as it will absorb the superfluous fat.
A rich mince, with a thick, well-adhering sauce, either of mutton and
mushrooms, or oysters, or with fine herbs and an eschalot or two; or
of venison, or hare, or partridges, may be appropriately used for
them.
SMALL CROUSTADES À LA BONNE MAMAN.
Fry lightly, in good butter, clarified marrow, or very pure olive oil,
some slices of bread, free from crust, of about half an inch thick, and
two inches and a half square; lift them on to a dish, and spread a not
very thick layer of Captain White’s currie-paste on the top; place
them in a gentle oven for three or four minutes, then lay two or three
fillets of anchovies on each, replace them in the oven for a couple of
minutes, and send them immediately to table. Their pungency may
be heightened by the addition of cayenne pepper, when a very hot
preparation is liked.
Obs.—We have spoken but slightly in our chapter of curries of
Captain White’s currie-paste, though for many years we have had it
used in preference to any other, and always found it excellent.
Latterly, however, it has been obtained with rather less facility than
when attention was first attracted to it. The last which we procured
directed, on the label of the jar, that orders for it should be sent per
post to 83, Copenhagen Street, Islington. It may, however, be
procured without doubt from any good purveyor of sauces and other
condiments. It is sold in jars of all sizes, the price of the smallest
being one-and-sixpence. We certainly think it much superior to any
of the others which we have tested, its flavour being peculiarly
agreeable.
TO FILLET ANCHOVIES.
Drain them well from the pickle, take off the heads and fins, lay
them separately on a plate, and scrape off the skin entirely; then
place them on a clean dish and with a sharp-edged knife raise the
flesh on either side of the back-bone, passing it from the tail to the
shoulders, and keeping it nearly flat as it is worked along. Divide
each side (or fillet) in two, and use them as directed for the
preceding toasts or other purposes. They make excellent simple
sandwiches with slices of bread and butter only; but very superior
ones when they are potted or made into anchovy butter.
SAVOURY TOASTS.
Cut some slices of bread free from crust, about half an inch thick
and two inches and a half square; butter the tops thickly, spread a
little mustard on them, and then cover them with a deep layer of
grated cheese and of ham seasoned rather highly with cayenne; fry
them in good butter, but do not turn them in the pan; lift them out,
and place them in a Dutch oven for three or [TN: missing word.]
minutes to dissolve the cheese: serve them very hot.
To 4 tablespoonsful of grated English cheese, an equal portion of
very finely minced, or grated ham; but of Parmesan, or Gruyère, 6
tablespoonsful. Seasoning of mustard and cayenne.
Obs.—These toasts, for which we give the original receipt
unaltered, may be served in the cheese-course of a dinner. Such
mere “relishes” as they are called, do not seem to us to demand
much of our space, or many of them which are very easy of
preparation might be inserted here: a good cook, however, will easily
supply them at slight expense. Truffles minced, seasoned, and
stewed tender in butter with an eschalot or two, may be served on
fried toasts or croûtons and will generally be liked.
TO CHOOSE MACCARONI AND OTHER ITALIAN PASTES.