CHEMISTRY FORM 5 KSSM

9.0 REDOX EQUILIBRIUM

9.1 OXIDATION AND REDUCTION

9.2 STANDARD ELECTRODE POTENTIAL

9.3 VOLTAIC CELL

9.4 ELECTROLYTIC CELL

9.5 EXTRACTION METAL FROM ITS ORE

9.6 RUSTING
9.4 ELECTROLYTIC CELL
PREPARED BY: NURULKAMILAH BINTI KHAIRIR
ELECTROLYTIC CELL
SELF CHECKLIST
Learning Standard
Pupils are able to:
1.4.1 Describe electrolysis
1.4.2 Describe electrolysis of molten compound
through activities

1.4.3 Explain factors that affect electrolysis of a

queous solution through experiment
1.4.4 Compare voltaic cell and electrolytic cell

1.4.5 Describe electroplating and purification of

metal by electrolysis through activities
ELECTROLYSIS
 Electrolyte

Lead(II) bromide, PbBr2

Electrolyte Sodium chloride, NaCl
Acetamide, CH3CONH2 Non-Electrolyte

Non-Electrolyte Glucose, C6H12O6

Identify electrolyte substance and non-electrolyte substance
Why electrolyte can conduct electricity?
Comparison between Conductors and Electrolytes
ACTIVITY 1H
Page 33 Chemistry Form 5 KSSM Text Book
 How to answer?

Apparatus set up Observation Inference Conclusion

Choose figure Bulb light up Presence of free The substance,
(Draw) moving ions ___________
-Figure 1.22 or is electrolyte
or or
-Figure 1.23 Bulb does not or
light up No free moving
ions non electrolyte
LABORATORY ACTIVITY 1E
Page 34 Chemistry Form 5 KSSM Text Book
Discussion
b)
Electrolysis of Lead(II) Bromide
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Electrolysis of Lead(II) Bromide
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ACTIVITY 1I
Page 37 Chemistry Form 5 KSSM Text Book
 Observation
Anode
Explain how the product is
Name/formula of formed
substance
Observation
Cathode
Explain how the product is
formed
Answer
Answer
ELECTROLYSIS OF AN
AQUEOUS SOLUTION
Factors that Affect the Electrolysis of
an Aqueous Solution
Using carbon or titanium electrodes
Using carbon or titanium electrodes
Using active metal electrodes
Example
Electrolysis of CuSO4 solution
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Electrolysis Factor:
Standard Electrode
Potential Value or
E0 Value
Ion that has more negative E0 value Ion that has more positive E0 value
will be selected to be discharged will be selected to be discharged
*The three factors (E0 values, Concentration of ions in the electrolyte
& type of electrodes used) affect the products of electrolysis at the
ANODE. While the ion that is selectively discharged at the CATHODE is
ONLY affected by the E0 VALUE.

• The halide ions with a higher concentration in the electrolyte will be

selectively discharged at the anode even if it positioned higher
(more negative E0 Value) in the standard electrode potential series.
• Oxidation process occurs at the anode or positive electrode due to
the releasing of electron.
• Reduction process occurs at the cathode or negative electrode due
to the receiving of electrons.
ACTIVITY 1J
Page 43 Chemistry Form 5 KSSM Text Book
Answer
Factor of electrolysis:
Concentration of ins in the
Electrolyte.
Answer
Factor of electrolysis:
E0 Values
Comparison Between Voltaic Cell
and Electrolytic Cell
LABORATORY ACTIVITY 1F
Page 38 Chemistry Form 5 KSSM Text Book
Discussion
Answer
Answer
EXPERIMENT 1B
Page 41 Chemistry Form 5 KSSM Text Book
Discussion
EXPERIMENT 1C
Page 42 Chemistry Form 5 KSSM Text Book
Answer
Discussion
ELECTROPLATING AND PURIFICATION OF METALS
SELF CHECKLIST
Learning Standard
Pupils are able to:
1.4.1 Describe electrolysis
1.4.2 Describe electrolysis of molten compound
through activities

1.4.3 Explain factors that affect electrolysis of aq

ueous solution through experiment
1.4.4 Compare voltaic cell and electrolytic cell

1.4.5 Describe electroplating and purification of metal

by electrolysis through activities
ELECTROPLATING AND PURIFICATION OF METALS

Metal plating is done to make metals look

more attractive and resistant to corrosion.
 ELECTROPLATING OF METALS
Object being electroplated as the cathode
The electroplating metal as the anode
Anode
An aqueous solution containing the ions of the el
Copper Iron ring
strip
ectroplating metal as the electrolyte
Cathode

1M of copper(II) sul
phate solution

The blue CuSO4 solution does not change because the concentration of Cu 2+ ion
remains the same. The rate of ionization of Cu at the anode is the same as the
rate of discharged Cu2+ ion at the cathode
 PURIFICATION OF METAL
Anode:
Pure metal as the cathode
Impure copper
The impure metal as the anode
Cathode:
Pure copper An aqueous solution containing the ions of the
Copper strip metal as the electrolyte

Example
1M of copper(II) sulphate
solution
LABORATORY ACTIVITY 1G
Page 45 Chemistry Form 5 KSSM Text Book
Click here
Discussion
 Purification of Metal
Impure Pure metal as the cathode
copper The impure metal as the anode
An aqueous solution containing the ions of the
Pure copper
electrolyte
electrode

1M of copper(II)
sulphate solution
LABORATORY ACTIVITY 1H
Page 46 Chemistry Form 5 KSSM Text Book
Discussion
SELF ASSESS 1.4
Page 47 Chemistry Form 5 KSSM Text Book
 Thank you
Prepared by: Puan Nurulkamilah binti Khairir , Edited by: LYD