SDS_TUBALL_BATT_NMP_PVDF_EU_ENG_V1-1_(ES extended)

TUBALL BATT NMP
TUBALL: 0.1-1% Dispersant: PVDF

Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Issue date: 21/09/2023 Revision date: 20/10/2023 Version: 1.1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product form : Mixture
Generic name : TUBALL BATT NMP
UFI : QH80-N0AK-300Y-AKGK
Type of product : Nanoform embedded in a matrix
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : Industrial use as additive in metal and/or ceramic composites
1.2.2. Uses advised against

Restrictions on use : Industrial users
1.3. Details of the supplier of the safety data sheet
Supplier
Europe:
OCSiAl Europe S.a.r.l.
L-3364, Leudelange,
1, rue de la Poudrerie,
Grand Duchy of
Luxembourg
T +352 27 99 03 73
09.00-17.00 GMT+2
europe@ocsial.com
1.4. Emergency telephone number

EMEA : +44 1865 407333 (English) (Carechem 24)
East/South East Asia : +65 3158 1074 (English, Hindi, Japanese, Korean, Malay, Mandarin) (Carechem 24)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, Category 2 H315
Serious eye damage/eye irritation, Category 2 H319
Reproductive toxicity, Category 1B H360D
Specific target organ toxicity – Single exposure, Category 3, H335
Respiratory tract irritation
Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May damage the unborn child..
2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :
GHS07 GHS08
20/10/2023 (Revision date) EU - eng 1/34

TUBALL BATT NMP
Safety Data Sheet
Signal word (CLP) : Danger

Hazard statements (CLP) : H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
H360D - May damage the unborn child.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P261 - Avoid breathing dust, fume, gas, mist, spray, vapours.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves, protective clothing, eye protection, respiratory protection.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
Extra phrases : Industrial users
2.3. Other hazards

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Component
Single wall carbon nanotubes This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
N-methyl-2-pyrrolidone This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Component
N-methyl-2-pyrrolidone The substance is not included in the list established in accordance with Article 59(1) of
REACH for having endocrine disrupting properties, or is not identified as having endocrine
disrupting properties in accordance with the criteria set out in Commission Delegated
Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures ►
Name Product identifier % Classification according to

Regulation (EC) No. 1272/2008
[CLP]
N-methyl-2-pyrrolidone* (CAS-No.) 872-50-4 < 96.612 Skin Irrit. 2, H315
substance listed as REACH Candidate (1- (EC-No.) 212-828-1 Eye Irrit. 2, H319
Methyl-2-pyrrolidone (NMP)) (EC Index-No.) 606-021-00-7 Repr. 1B, H360D
(REACH-No.) 01-2119472430-46 STOT SE 3, H335
Poly(vinylidene fluoride) Trade Secret 2 Not classified
Single wall carbon nanotubes** (CAS-No.) Not assigned for EU-REACH 0.1 – 1 Eye Irrit. 2, H319
(EC-No.) 943-098-9
(REACH-No.) 01-2120130006-75-0000
Pyrrolidinone, dimethyl- CAS-No.: 60544-40-3 < 0.388 Skin Irrit. 2, H315

Eye Dam. 1, H318

TUBALL BATT NMP
Safety Data Sheet
Specific concentration limits:

Name Product identifier Specific concentration limits (%)
N-methyl-2-pyrrolidone* (CAS-No.) 872-50-4 (10 ≤ C ≤ 100) STOT SE 3, H335

(EC-No.) 212-828-1
(EC Index-No.) 606-021-00-7
(REACH-No.) 01-2119472430-46
Comments : ** Single wall carbon nanotubes TUBALL™

* Alternative name according to CLP article 24. The chemical identity of this component is non-disclosed to avoid risking the confidential business
nature
Full text of H- and EUH-statements: see section 16
Components – Nanoform
**Single wall carbon nanotubes
Name of (set of) nanoform(s) Tuball™ - all grades are part of one set of nanoform
Number based particle size distribution d10

1.2-1.45 nm
d50
1.6-1.8 nm
d90
1.9-2.2 nm
Particle shape Elongated tubes
Particle aspect ratio length to diameter ratio 2000 – 10000:1
Crystallinity Amorphous
Surface functionalisation/treatment - Process No. Process - Chemical vapor deposition (CVD)
Specific surface area 300 – 1500 m²/g
Additional information G/D range : ≥40 (RAMAN at 532 nm)
SECTION 4: First aid measures
4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Get medical attention.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Get medical attention.
First-aid measures after ingestion : Rinse mouth out with water. Give 200 - 300 ml water to drink. Do not induce vomiting. Get
medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause irritation to the respiratory tract.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Chronic symptoms : May damage the unborn child.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

TUBALL BATT NMP
Safety Data Sheet
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media : Powder, Alcohol-resistant foam, Water spray, Carbon dioxide (CO2).
5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products in case of fire : Carbon dioxide. Carbon monoxide. Nitrous gasses.
5.3. Advice for firefighters

Firefighting instructions : Prevent fire fighting water from entering the environment.
Protection during firefighting : Use chemically protective clothing. Full face mask. Positive pressure self-contained
breathing apparatus (SCBA).
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Protective equipment : Wear suitable protective clothing.
Emergency procedures : Ensure adequate ventilation. Evacuate area. Avoid inhalation of vapours.
6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. Wear suitable
protective clothing, gloves and eye/face protection. In case of fire: Positive pressure self-
contained breathing apparatus (SCBA). For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Provide adequate ventilation. Evacuate area. Avoid inhalation of vapours.
6.2. Environmental precautions

Do not allow to enter into surface water or drains. Collect contaminated extinguishing water separately and must not enter the sewage system.
6.3. Methods and material for containment and cleaning up

For containment : Clean spills promptly. Ventilate affected area. Stop leak if safe to do so.
Methods for cleaning up : Small amounts: Take up liquid spill into absorbent material, e.g.: sand, saw dust. Large
amounts: Recover large spills by pumping.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections

For disposal of contaminated materials refer to section 13 : "Disposal considerations". For further information refer to section 8: "Exposure
controls/personal protection".
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Precautions for safe handling : AVOID EXPOSURE OF PREGNANT WOMEN!. Avoid contact with skin, eyes and clothing.
Carry out operations in the open/under local exhaust/ventilation or with respiratory
protection. Avoid inhalation of vapours. Prevent the build-up of electrostatic charge.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash contaminated clothing before
reuse. Separate working clothes from town clothes. Launder separately. Always wash
hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in dry, well-ventilated area. Keep container tightly closed.
Incompatible products : Bases. Acids.
Storage temperature : > -20 °C

TUBALL BATT NMP
Safety Data Sheet
Heat and ignition sources : Keep away from open flames, hot surfaces and sources of ignition. No smoking.
Information on mixed storage : Store away from water (including sewage plant).
Storage area : Store in a well-ventilated place.
Special rules on packaging : Keep container tightly closed.
7.3. Specific end use(s)

No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters

8.1.1 National occupational exposure and biological limit values
N-methyl-2-pyrrolidone
EU - Indicative Occupational Exposure Limit (IOEL)
IOEL TWA 40 mg/m³
IOEL STEL 80 mg/m³
IOEL STEL [ppm] 20 ppm
Remark Skin
Regulatory reference COMMISSION DIRECTIVE 2009/161/EU
EU - Biological Limit Value (BLV)
BLV 20 mg/g creatinine Parameter: 2-hydroxy-N-methylsuccinimide - Medium: urine - Sampling

time: morning-after-shift ; 18 hours
70 mg/g creatinine Parameter: 5-hydroxy-N-methyl-2-pyrrolidone - Medium: urine -
Sampling time: 2-4 hours after the end of exposure/shift
Regulatory reference SCOEL List of recommended health-based BLVs and BGVs
Belgium - Occupational Exposure Limits
OEL TWA 40 mg/m³
OEL TWA [ppm] 10 ppm
OEL STEL 80 mg/m³
OEL STEL [ppm] 20 ppm
Remark D: la mention “D” signifie que la résorption de l’agent, via la peau, les muqueuses ou les
yeux, constitue une partie importante de l’exposition totale. Cette résorption peut se faire
tant par contact direct que par présence de l’agent dans l’air. # D: de vermelding “D”
betekent dat de opname van het agens via de huid, de slijmvliezen of de ogen een
belangrijk deel van de totale blootstelling vormt. Deze opname kan het gevolg zijn van
zowel direct contact als zijn aanwezigheid in de lucht.
Regulatory reference Koninklijk besluit/Arrêté royal 11/05/2021
Bulgaria - Occupational Exposure Limits
OEL TWA 40 mg/m³
OEL STEL 80 mg/m³
Remark Кожа (възможна е значителна резорбция чрез кожата); • (Химични агенти, за които
са определени гранични стойности във въздуха на работната среда за Европейската
общност)

TUBALL BATT NMP
Safety Data Sheet
Regulatory reference Наредба № 13 от 30.12.2003 г. за защита на работещите от рискове, свързани с
експозиция на химични агенти при работа (изм. и доп. ДВ. бр. 47 от 2021 г., в сила от
04.06.2021 г.)
Croatia - Occupational Exposure Limits
GVI (OEL TWA) [1] 40 mg/m³
GVI (OEL TWA) [2] 10 ppm
KGVI (OEL STEL) 80 mg/m³
KGVI (OEL STEL) [ppm] 20 ppm
Remark Direktiva: 2009/161/EU. Napomena: Koža (razvrstana kao tvar koja nadražuje kožu
(H315)), Repr 1B
Regulatory reference Pravilnik o zaštiti radnika od izloženosti opasnim kemikalijama na radu, graničnim
vrijednostima izloženosti i biološkim graničnim vrijednostima (NN 1/2021)
Croatia - Biological limit values
BLV 20 mg/g creatinine Karakteristični pokazatelj: 2-hidroksi-N-metilsukcinimid - Biološki

uzorak: mokraća - Vrijeme uzorkovanja: Oko 16 sati nakon završetka radne smjene
70 mg/g creatinine Karakteristični pokazatelj: 5-hidroksi-N-metil-2-pirolidon - Biološki
uzorak: mokraća - Vrijeme uzorkovanja: (2-4 nakon radne smjene/prekida
Regulatory reference Pravilnik o zaštiti radnika od izloženosti opasnim kemikalijama na radu, graničnim
vrijednostima izloženosti i biološkim graničnim vrijednostima (NN 91/2018)
Cyprus - Occupational Exposure Limits
OEL TWA 40 mg/m³
OEL STEL 80 mg/m³
Remark δέρμα
Regulatory reference Κανονισμοί του 2012 (Κ.Δ.Π. 70/2012)
Czech Republic - Occupational Exposure Limits
PEL (OEL TWA) 40 mg/m³
PEL (OEL TWA) [ppm] 9.7 ppm
NPK-P (OEL C) 80 mg/m³
NPK-P (OEL C) [ppm] 19.4 ppm
Remark D - při expozici se významně uplatňuje pronikání faktoru kůží, I - dráždí sliznice (oči,
dýchací cesty), respektive kůži, T - toxický pro reprodukci kategorie 1A a 1B (s větou
H360 včetně příslušných kódů).
Regulatory reference Nařízení vlády č. 361/2007 Sb. (Předpis 195/2021 Sb.)
Denmark - Occupational Exposure Limits
OEL TWA [1] 20 mg/m³
OEL TWA [2] 5 ppm
OEL STEL 80 mg/m³
Remark E (betyder, at stoffet har en EF-grænseværdi); H (betyder, at stoffet kan optages gennem
huden)

TUBALL BATT NMP
Safety Data Sheet
Regulatory reference BEK nr 202 af 21/02/2023
Finland - Occupational Exposure Limits
HTP (OEL TWA) [1] 14 mg/m³
HTP (OEL TWA) [2] 3.5 ppm
HTP (OEL STEL) 80 mg/m³
HTP (OEL STEL) [ppm] 20 ppm
Remark Iho
Regulatory reference HTP-ARVOT 2020 (Sosiaali- ja terveysministeriö)
France - Occupational Exposure Limits
VME (OEL TWA) 40 mg/m³
VME (OEL TWA) [ppm] 10 ppm
VLE (OEL C/STEL) 80 mg/m³
VLE (OEL C/STEL) [ppm] 20 ppm
Remark Valeurs règlementaires indicatives; risque de pénétration percutanée; substance classée

toxique pour la reproduction de catégorie 1B
Regulatory reference Arrêté du 30 juin 2004 modifié (réf.: INRS ED 984, 2016)
Germany - Occupational Exposure Limits (TRGS 900)
AGW (OEL TWA) [1] 82 mg/m³
AGW (OEL TWA) [2] 20 ppm
Peak exposure limitation factor 2(I)
Remark EU - Europäische Union (Von der EU wurde ein Luftgrenzwert festgelegt: Abweichungen
bei Wert und Spitzenbegrenzung sind möglich); DFG - Senatskommission zur Prüfung
gesundheitsschädlicher Arbeitsstoffe der DFG (MAK-Kommission); AGS - Ausschuss für
Gefahrstoffe; H - hautresorptiv; Y - Ein Risiko der Fruchtschädigung braucht bei
Einhaltung des Arbeitsplatzgrenzwertes und des biologischen Grenzwertes (BGW) nicht
befürchtet zu werden; 11 - Summe aus Dampf und Aerosolen; 19 - Die Senatskommission
zur Prüfung gesundheitsschädlicher Arbeitsstoffe der DFG hat in der MAK- und BAT-
Werte-Liste zum gleichlautenden MAK-Wert auch einen BAT-Wert festgelegt; 32 - Gemäß
Änderung von Anhang XVII der Verordnung (EG) Nr. 1907/2006 (https://eur-
lex.europa.eu/legal-content/DE/TXT/PDF/?uri=CELEX:32018R0588&from=DE) gilt ab 10.
Mai 2020 eine Verwendungsbeschränkung für NMP, wenn der dort genannte
Luftgrenzwert nicht eingehalten wird
Regulatory reference TRGS900
Germany - Biological limit values (TRGS 903)
Biological limit value 150 mg/l Parameter: 5-Hydroxy- N-methyl-2-pyrrolidon - Untersuchungsmaterial: U = Urin
- Probenahmezeitpunkt: b) Expositionsende, bzw. Schichtende - Festlegung/Begründung:
05/2013 DFG
Regulatory reference TRGS 903
Greece - Occupational Exposure Limits
OEL TWA 40 mg/m³
OEL STEL 80 mg/m³

TUBALL BATT NMP
Safety Data Sheet
Remark Η ένδειξη «δέρμα» στις οριακές τιμές επαγγελματικής έκθεσης επισημαίνει το ενδεχόμενο
σημαντικής διείσδυσης μέσω του δέρματος.
Regulatory reference Π.Δ. 12/2012 - Προστασία της υγείας των εργαζομένων που εκτίθενται σε ορισμένους
χημικούς παράγοντες κατά τη διάρκεια της εργασίας τους
Hungary - Occupational Exposure Limits
AK (OEL TWA) 40 mg/m³
CK (OEL STEL) 80 mg/m³
Remark b (Bőrön át is felszívódik); EU3 (2009/161 /EK irányelvben közölt érték); T (Azok az
anyagok, amelyek egészségkárosító hatása TARTÓS expozíciót követően jelentkezik)
Regulatory reference 5/2020. (II. 6.) ITM rendelet - A kémiai kóroki tényezők hatásának kitett munkavállalók
egészségének és biztonságának védelméről
Italy - Occupational Exposure Limits
OEL TWA 40 mg/m³
OEL STEL 80 mg/m³
Remark Cute
Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.
Netherlands - Occupational Exposure Limits
TGG-8u (OEL TWA) 40 mg/m³
TGG-15min (OEL STEL) 80 mg/m³
Remark H (Huidopname) Stoffen die relatief gemakkelijk door de huid kunnen worden opgenomen,
hetgeen een substantiële bijdrage kan betekenen aan de totale inwendige blootstelling,
hebben in de lijst een H-aanduiding. Bij deze stoffen moeten naast maatregelen tegen
inademing ook adequate maatregelen ter voorkoming van huidcontact worden genomen.
Regulatory reference Arbeidsomstandighedenregeling 2023
Portugal - Biological Exposure Indices
BEI 100 mg/l Parâmetro: 5-Hidroxi-N-metil-2-pirrolidona - Meio: urina - Momento da

amostragem: Fim do turno
Regulatory reference Norma Portuguesa NP 1796:2014
Romania - Occupational Exposure Limits
OEL TWA 40 mg/m³
OEL STEL 80 mg/m³
Remark P - posibilitatea unei penetrări cutanate importante; R1B - poate dăuna fătului; poate
dăuna fertilității
Regulatory reference Hotărârea Guvernului nr. 1.218/2006 (Hotărârea nr. 53/2021)
Serbia - Occupational Exposure Limits
OEL TWA 40 mg/m³

TUBALL BATT NMP
Safety Data Sheet
OEL STEL 80 mg/m³
Remark ЕУ*** – напомена да се ради о хемијским материјама за које су утврђене

индикативне граничне вредности изложености према Директиви 2009/161/ЕУ (трећа
листа); К – напомена да хемијска материја може штетно деловати на кожу
Regulatory reference ПРАВИЛНИК о превентивним мерама за безбедан и здрав рад при излагању
хемијским материјама (,,Службени гласник РС”, бр. 106/09, 117/17 и 107/21)
Slovakia - Occupational Exposure Limits
NPHV (OEL TWA) [1] 40 mg/m³
NPHV (OEL TWA) [2] 10 ppm
NPHV (OEL STEL) 80 mg/m³
NPHV (OEL STEL) [ppm] 20 ppm
Remark K - znamená, že faktor môže byť ľahko absorbovaný kožou
Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (236/2020 Z. z.)
Slovenia - Occupational Exposure Limits
OEL TWA 40 mg/m³
OEL STEL 80 mg/m³
Remark K (Lastnost lažjega prehajanja snovi v organizem skozi kožo), Y (Snovi, pri katerih ni
nevarnosti za zarodek ob upoštevanju mejnih vrednosti in bat vrednosti), BAT (Biološka
mejna vrednost), EU
Regulatory reference Uradni list RS, št. 72/2021 z dne 11.5.2021
Slovenia - Biological limit values
BLV 150 mg/l Parameter: 5‐hidroksi‐N‐metil‐2‐pirolidin - Biološki vzorec: urin - Čas vzorčenja:
ob koncu delovne izmene
Regulatory reference Uradni list RS, št. 72/2021 z dne 11.5.2021
Spain - Occupational Exposure Limits
VLA-ED (OEL TWA) [1] 40 mg/m³
VLA-ED (OEL TWA) [2] 10 ppm
VLA-EC (OEL STEL) 80 mg/m³
VLA-EC (OEL STEL) [ppm] 20 ppm

TUBALL BATT NMP
Safety Data Sheet
Remark Vía dérmica (Indica que, en las exposiciones a esta sustancia, la aportación por la vía
cutánea puede resultar significativa para el contenido corporal total si no se adoptan
medidas para prevenir la absorción. En estas situaciones, es aconsejable la utilización del
control biológico para poder cuantificar la cantidad global absorbida del contaminante),
VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo),
VLB® (Agente químico que tiene Valor Límite Biológico), TR1B (Cuando las pruebas
utilizadas para la clasificación procedan principalmente de datos en animales), r (Esta
sustancia tiene establecidas restricciones a la fabricación, la comercialización o el uso en
los términos especificados en el “Reglamento (CE) nº 1907/2006 sobre Registro,
Evaluación, Autorización y Restricción de sustancias y preparados químicos” (REACH) de
18 de diciembre de 2006 (DOUE L 369 de 30 de diciembre de 2006). Las restricciones de
una sustancia pueden aplicarse a todos los usos o sólo a usos concretos. El anexo XVII
del Reglamento REACH contiene la lista de todas las sustancias restringidas y especifica
los usos que se han restringido).
Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2023. INSHT
Spain - Biological limit values
BLV 20 mg/g creatinine Parámetro: 2-Hidroxi-N-metilsuccinimida - Medio: Orina - Momento de

muestreo: Antes de la jornada laboral
70 mg/g creatinine Parámetro: 5-Hidroxi-N-metil-2-pirrolidona - Medio: Orina - Momento
de muestreo: Entre 2 y 4 horas después del final la exposición
Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2023. INSHT
Sweden - Occupational Exposure Limits
NGV (OEL TWA) 14.4 mg/m³
NGV (OEL TWA) [ppm] 3.6 ppm
KTV (OEL STEL) 80 mg/m³
KTV (OEL STEL) [ppm] 20 ppm
Remark H (Ämnet kan lätt upptas genom huden. Det föreskrivna gränsvärdet bedöms ge tillräckligt
skydd endast under förutsättning att huden är skyddad mot exponering för ämnet ifråga);
R (Ämnet är reproduktionsstörande. Med reproduktionsstörande ämnen avses ämnen
som kan medföra skadliga effekter på fortplantningsförmågan eller avkommans
utveckling)
Regulatory reference Hygieniska gränsvärden (AFS 2020:6)
Norway - Occupational Exposure Limits
Grenseverdi (OEL TWA) [1] 20 mg/m³
Grenseverdi (OEL TWA) [2] 5 ppm
Korttidsverdi (OEL STEL) 80 mg/m³
Korttidsverdi (OEL STEL) [ppm] 20 ppm
Remark H: Kjemikalier som kan tas opp gjennom huden; R: Kjemikalier som skal betraktes som
reproduksjonstoksiske; E: EU har en veiledende grenseverdi og/eller anmerkning for
stoffet.
Regulatory reference FOR-2021-06-28-2248
North Macedonia - Occupational Exposure Limits
OEL TWA 80 mg/m³
KTV 4
Short time value [mg/m³] 320 mg/m³

TUBALL BATT NMP
Safety Data Sheet
Short time value [ppm] 76 ppm
Remark (KTV) краткотрајна вредност (КТВ) значи концентрација на опасни хемиски

супстанци во воздухот на работното место внатре во зона на дишење, на која
работникот без опасност по здравјето може да е изложен на покусо време.
Изложеноста на краткотрајни вредности може да трае највеќе 15 минути и не смее
да се повтори повеќе од четирипати во работната смена, при што меѓу две
изложености на оваа концентрација мора да измине најмалку 60 минути.
Краткотрајната вредност е изразена во mg/m3 или во ml/m3(ppm) а е дадена како
многукратни дозволени пречекорувања на граничната вредност; (К) својство на
полесно пренесување на супстанците во организмот преку кожата; (Y)
Regulatory reference Правилник за минималните барања за безбедност и здравје при работа на

вработени од ризици поврзани со изложување на хемиски супстанци („Службен
весник на Република Македонија” бр.46/10)
Switzerland - Occupational Exposure Limits
MAK (OEL TWA) [1] 80 mg/m³
MAK (OEL TWA) [2] 20 ppm
KZGW (OEL STEL) 160 mg/m³
KZGW (OEL STEL) [ppm] 40 ppm
Notation R, SSC / H, SSC
Remark INRS
Regulatory reference www.suva.ch, 01.01.2023
8.1.2. Recommended monitoring procedures

8.1.3. Air contaminants formed

8.1.4. DNEL and PNEC
Single wall carbon nanotubes

DNEL/DMEL (Workers)
Acute - systemic effects, dermal No hazard identified
Acute - systemic effects, inhalation Low hazard (no threshold identified)
Acute - local effects, dermal No hazard identified
Acute - local effects, inhalation Low hazard (no threshold identified)
Long-term - systemic effects, dermal No hazard identified
Long-term - local effects, dermal No hazard identified
Long-term - local effects, inhalation Low hazard (no threshold identified)
DNEL/DMEL (General population)
Acute - systemic effects, dermal No hazard identified
Acute - systemic effects, inhalation Low hazard (no threshold identified)
Acute - systemic effects, oral No hazard identified
Acute - local effects, dermal No hazard identified
Acute - local effects, inhalation No hazard identified

TUBALL BATT NMP
Safety Data Sheet

Long-term - systemic effects, dermal No hazard identified
Long-term - local effects, dermal No hazard identified
Long-term - local effects, inhalation No hazard identified
PNEC (Water)
PNEC aqua (freshwater) No hazard identified
PNEC aqua (marine water) No hazard identified
PNEC (Sediment)
PNEC sediment (freshwater) No hazard identified
PNEC sediment (marine water) No hazard identified
PNEC (Soil)
PNEC soil No hazard identified
PNEC (Oral)
PNEC oral (secondary poisoning) No potential to cause toxic effects if accumulated (in higher organisms) via the food chain
PNEC (STP)
PNEC sewage treatment plant No data available: testing technically not feasible
DNEL/DMEL (Workers)
Long-term - systemic effects, dermal 4.8 mg/kg bodyweight/day
Long-term - systemic effects, inhalation 14.4 mg/m³
Long-term - local effects, inhalation 40 mg/m³
DNEL/DMEL (General population)
Long-term - systemic effects,oral 0.85 mg/kg bodyweight/day
Long-term - systemic effects, inhalation 3.6 mg/m³
Long-term - systemic effects, dermal 2.4 mg/kg bodyweight/day
Long-term - local effects, inhalation 4.5 mg/m³
PNEC (Water)
PNEC aqua (freshwater) 0.25 mg/l
PNEC aqua (marine water) 0.025 mg/l
PNEC aqua (intermittent, freshwater) 5 mg/l
PNEC (Sediment)
PNEC sediment (freshwater) 1.09 mg/kg dwt
PNEC sediment (marine water) 0.109 mg/kg dwt
PNEC (Soil)
PNEC soil 0.0701 mg/kg dwt
PNEC (STP)
PNEC sewage treatment plant 10 mg/l
8.1.5. Control banding


TUBALL BATT NMP
Safety Data Sheet
8.2. Exposure controls

8.2.1. Appropriate engineering controls
8.2.2. Personal protection equipment

Personal protective equipment:
Gloves. Protective clothing. Gas mask. Protective goggles.
Personal protective equipment symbol(s):
8.2.2.1. Eye and face protection

Eye protection:
Use eye protection according to EN 166. Chemical goggles or safety glasses
8.2.2.2. Skin protection

Skin and body protection:
Protective clothing (with elasticated cuffs and closed neck). EN 14605
Hand protection:
Chemically resistant protective gloves
Hand protection
Type Material Permeation Thickness (mm) Penetration Standard
Reusable gloves Butyl rubber 6 (> 480 minutes) 0.7 EN 374
Disposable gloves Nitrile rubber (NBR) 2 (> 30 minutes) 0.4 EN 374
Disposable gloves Chloroprene rubber (CR) 2 (> 30 minutes) 0.5 EN 374
8.2.2.3. Respiratory protection
Respiratory protection:
Wear respiratory protection
Respiratory protection
Device Filter type Condition Standard
Gas filters Type A - High-boiling (>65 °C) If conc. in air > exposure limit EN 14387
organic compounds
Gas filters Type A-P2, (APF >= 10) Mist formation, Protection for EN 14387
Liquid particles
8.2.2.4. Thermal hazards

8.2.3. Environmental exposure controls

SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Physical state : Liquid
Colour : Black.

TUBALL BATT NMP
Safety Data Sheet
Molecular mass : 99.13 g/mol (N-methyl-2-pyrrolidone)

Odour : Characteristic.
Odour threshold : Not available
Melting point : -24 °C (N-methyl-2-pyrrolidone)
Freezing point : Not available
Boiling point : 202 °C (N-methyl-2-pyrrolidone)
Flammability : Not available
Explosive properties : Not explosive.
Oxidising properties : Non oxidizing.
Lower explosion limit : 0.99 vol % (N-methyl-2-pyrrolidone)
Upper explosion limit : 3.9 vol % (N-methyl-2-pyrrolidone)
Flash point : 86.1 °C (closed cup) (N-methyl-2-pyrrolidone)
Auto-ignition temperature : 270 °C (N-methyl-2-pyrrolidone)
Decomposition temperature : > 300 °C (N-methyl-2-pyrrolidone)
pH : 6 – 10 (N-methyl-2-pyrrolidone)
Viscosity, kinematic : Not available
Solubility : Miscible with water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Partition coefficient n-octanol/water (Log Pow) : -0.54 (N-methyl-2-pyrrolidone)
Vapour pressure : 66 Pa 25 °C(N-methyl-2-pyrrolidone)
Vapour pressure at 50°C : Not available
Density : 1.3 25 °C(N-methyl-2-pyrrolidone)
Relative density : 3.4 (N-methyl-2-pyrrolidone)
Relative vapour density at 20°C : Not available

Particle size See section 3.2
Particle size distribution See section 3.2
Particle shape See section 3.2
Particle aspect ratio See section 3.2
Particle aggregation state Bundles of nanotubes
Particle agglomeration state Single wall carbon nanotubes are embedded in a matrix
Particle specific surface area See section 3.2
Particle dustiness 1660 mg/kg (DIRM - Single wall carbon nanotubes)
See section 3 for more information about nano properties.
9.2. Other information

9.2.1. Information with regard to physical hazard classes
9.2.2. Other safety characteristics

SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions.
10.2. Chemical stability

Stable under normal conditions.
10.3. Possibility of hazardous reactions

Exothermic reaction on contact with: Strong acids, Alkalis.
10.4. Conditions to avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

TUBALL BATT NMP
Safety Data Sheet
10.5. Incompatible materials

Acids. Bases.
10.6. Hazardous decomposition products

Toxic gases.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity (oral) : Not classified.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Not classified.
LD50 oral rat < 4150 mg/kg - OECD 401
LD50 dermal rat > 5000 mg/kg bodyweight - OECD 402
LC50 Inhalation - Rat > 5.1 mg/l air - OECD 403

Skin corrosion/irritation : Causes skin irritation.
pH: 6 – 10 (N-methyl-2-pyrrolidone)
Serious eye damage/irritation : Causes serious eye irritation.
pH: 6 – 10 (N-methyl-2-pyrrolidone)
Respiratory or skin sensitisation : Not available
Germ cell mutagenicity : Not available
Carcinogenicity : Not available
Reproductive toxicity : May damage the unborn child.

NOAEL (animal/female, F0/P) no adverse effects seen at highest dose tested> 1000 mg/kg bw/day - OECD 422
NOAEL (animal, F1) > 1000 mg/kg bw/day - for adverse effects on prenatal development (conceptus to birth) -
OECD 422
NOAEL (animal, F1) > 1000 mg/kg bw/day - for adverse effects on postnatal development (pup) - OECD 422
NOAEL (animal/male, F0/P) 160 mg/kg bodyweight
NOAEL (animal, F1) 160 mg/kg bw/day
NOAEL (animal, F1) 160 mg/kg bw/day

STOT-single exposure : May cause respiratory irritation.
STOT-single exposure May cause respiratory irritation.
STOT-repeated exposure : Not available

NOAEL (oral, rat, 90 days) no adverse effects seen at highest dose tested> 1000 mg/kg bodyweight/day - OECD 422
Aspiration hazard : Not applicable.
11.2. Information on other hazards

11.2.1. Endocrine disrupting properties
Adverse health effects caused by endocrine : No specific data
disrupting properties

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Safety Data Sheet
11.2.2. Other information

SECTION 12: Ecological information
12.1. Toxicity
Hazardous to the aquatic environment, short–term : Not classified.
(acute)
Hazardous to the aquatic environment, long–term : Not classified.
(chronic)
Not rapidly degradable
EC50 crustacea - 48h > 1000 mg/l Daphnia magna (Water flea)
EC50 algae - 96h 600.5 mg/l Desmodesmus subspicatus
NOEC chronic crustacea - 21 days 12.5 mg/l Daphnia magna (Water flea)
12.2. Persistence and degradability
Persistence and degradability Readily biodegradable.
12.3. Bioaccumulative potential
Partition coefficient n-octanol/water (Log Pow) ≥ -0.54
12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment
Component
Single wall carbon nanotubes This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
N-methyl-2-pyrrolidone This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
12.6. Endocrine disrupting properties

Adverse effects on the environment caused by : The mixture does not contain substance(s) included in the list established in accordance
endocrine disrupting properties with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified
as having endocrine disrupting properties in accordance with the criteria set out in
Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU)
2018/605 at a concentration equal to or greater than 0,1 %.
12.7. Other adverse effects

Additional information : No additional data
SECTION 13: Disposal considerations
13.1. Waste treatment methods

Regional legislation (waste) : Dispose of this material and its container at hazardous or special waste collection point.

TUBALL BATT NMP
Safety Data Sheet
Waste treatment methods : Disposal through controlled incineration or authorised waste dump.
Sewage disposal recommendations : Prevent entry to sewers and public waters.
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance
with local, regional, national and/or international regulation.
Additional information : Clean up even minor leaks or spills if possible without unnecessary risk.
European List of Waste (LoW) code : 06 13 99 - wastes not otherwise specified
SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / ADN / RID
ADR IMDG IATA ADN RID
14.1. UN number or ID number

Not regulated for transport
Not regulated Not regulated Not regulated Not regulated Not regulated
14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

No supplementary information available
14.6. Special precautions for user

Overland transport
Not regulated
Transport by sea
Not regulated
Air transport
Not regulated
Inland waterway transport

Not regulated
Rail transport
Not regulated
14.7. Maritime transport in bulk according to IMO instruments

IBC code : Applicable.
IBC product name : N-Methyl-2-pyrrolidone
Ship type : Type 3
Pollution category : Y

TUBALL BATT NMP
Safety Data Sheet
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)

Reference code Applicable on Entry title or description
3(b) Pyrrolidinone, dimethyl- Substances or mixtures fulfilling the criteria for any of the following hazard classes or
categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6,
3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other
than narcotic effects, 3.9 and 3.10
30. N-methyl-2-pyrrolidone Substances which are classified as reproductive toxicant category 1A or 1B in Part 3 of
Annex VI to Regulation (EC) No 1272/2008 and are listed in Appendix 5 or Appendix 6,
respectively.
71. N-methyl-2-pyrrolidone 1-methyl-2-pyrrolidone (NMP)
72. N-methyl-2-pyrrolidone The substances listed in column 1 of the Table in Appendix 12
REACH Annex XIV (Authorisation List)

Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)

Contains substance(s) listed on the REACH Candidate List in concentrations ≥ 0.1 % or SCL: N-methyl-2-pyrrolidone
PIC Regulation (Prior Informed Consent)

Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)

Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)

Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148)

Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)

Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain
substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
15.1.2. National regulations
France
Occupational diseases
Code Description
RG 84 Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid
hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons;
alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters;
dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and
dimethylsulfoxide
Germany
Employment restrictions : Observe restrictions according Act on the Protection of Working Mothers (MuSchG).
Observe restrictions according Act on the Protection of Young People in Employment
(JArbSchG).
Water hazard class (WGK) : WGK 1, Slightly hazardous to water (Classification according to AwSV, Annex 1).

TUBALL BATT NMP
Safety Data Sheet
Chemicals Prohibition Ordinance (ChemVerbotsV) : This product is subject to ChemVerbotsV Annex 2 Entry 1. The following requirements must
be observed: authorization requirement (according to § 6 paragraph 1 sentence 1), basic
requirements for carrying out the delivery (according to § 8 paragraph 1, 3 and 4),
identification and documentation (according to § 9 paragraph 1 to 3) and exclusion of the
shipping route (according to § 10).
Hazardous Incident Ordinance (12. BImSchV) : Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – : None of the components are listed
Vruchtbaarheid
SZW-lijst van reprotoxische stoffen – Ontwikkeling : N-methyl-2-pyrrolidone new is listed
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines
for the storage of flammable liquids must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with
the product
15.2. Chemical safety assessment
For the following substances of this mixture a chemical safety assessment has been carried out:
SECTION 16: Other information
Abbreviations and acronyms:

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
BLV Biological limit value
CAS-No. Chemical Abstract Service number
CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
DMEL Derived Minimal Effect level
DNEL Derived-No Effect Level
EC50 Median effective concentration
EC-No. European Community number
EN European Standard
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Median lethal concentration
LD50 Median lethal dose
NOAEL No-Observed Adverse Effect Level
NOEC No-Observed Effect Concentration
OEL Occupational Exposure Limit

TUBALL BATT NMP
Safety Data Sheet
Abbreviations and acronyms:

PBT Persistent Bioaccumulative Toxic
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS Safety Data Sheet
vPvB Very Persistent and Very Bioaccumulative
WGK Water Hazard Class
Full text of H- and EUH-statements:

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H360D May damage the unborn child.
Repr. 1B Reproductive toxicity, Category 1B
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation
The classification complies with : ATP 12

Revision : All recent revision(s) are noted by a bold triangle pointed to right ‘►’.
Disclaimer : This information is based on our current knowledge and is intended to describe the product for the purposes
of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing
any specific property of the product. It is the user's responsibility to take mentioned precaution measures
and ensure that this information is complete and sufficient for the use of this product.
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

TUBALL BATT NMP
Safety Data Sheet
Annex to the safety data sheet
Lead substance Identified Uses Es N° Short title Page

N-methyl-2-pyrrolidone Formulation 1 Formulation 21
SU3; ERC2; PROC3, PROC4, PROC5
N-methyl-2-pyrrolidone Formulation 2 Formulation 26

SU3; ERC2; PROC8a, PROC8b, PROC9, PROC15
N-methyl-2-pyrrolidone Use as a process chemical 3 Use as a process chemical 31

SU3; ERC4; PROC1, PROC2, PROC3
1. Industrial; Formulation
1.1. Title section
Formulation
ES Type: Worker Issue date: 01/09/2020
Version: 3.0 Revision date: 14/11/2022
Environment Use descriptors

Contributing scenario controlling ERC2
environmental exposure
Worker Use descriptors

Process temperature: 40 °C Contributing scenario controlling worker PROC3
exposure

exposure

exposure
1.2. Conditions of use affecting exposure

1.2.1. Control of environmental exposure: Contributing scenario controlling environmental exposure (ERC2)
ERC2 Formulation into mixture
Amount used, frequency and duration of use (or from service life)
Daily amount per site ≤ 0.333 t/d
Annual amount per site ≤ 100 t/yr
Conditions and measures related to sewage treatment plant
Municipal Sewage treatment plant
Assumed domestic sewage treatment plant flow ≥ 2000 m³/d
Other conditions affecting environmental exposure
Receiving surface water flow > 18000 m³/d

TUBALL BATT NMP
Safety Data Sheet
1.2.2. Control of worker exposure: Contributing scenario controlling worker exposure (PROC3)
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
Product (article) characteristics

Physical form of product Liquid
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently)
Vapour pressure @ 25 °C
66 Pa
Amount used (or contained in articles), frequency and duration of use/exposure
Covers daily exposures up to 8 hours
Conditions and measures related to personal protection, hygiene and health evaluation
In case of potential exposure: Wear suitable gloves tested to EN374
In case of potential exposure: Use suitable eye protection
Wear a respirator which reduces the air impurities by at least a factor of 10 (APF >= 10)
For further specification, refer to section 8 of the SDS.
Other conditions affecting workers exposure

Indoor or outdoor use Indoor
Maximum process temperature 40 °C
PROC4 Chemical production where opportunity for exposure arises

66 Pa
Wear suitable gloves tested to EN374
In case of potential exposure: Use suitable eye protection

TUBALL BATT NMP
Safety Data Sheet

PROC5 Mixing or blending in batch processes

66 Pa
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee
training
Use suitable eye protection

1.3. Exposure estimation and reference to its source

1.3.1. Environmental release and exposure Contributing scenario controlling environmental exposure (ERC2)
Protection target Exposure RCR Assessment method

estimation
Sewage treatment plant 0.421 mg/l 0.042 EUSES 2.1.2
Man via environment - Inhalation (systemic effects) 0.00191 mg/m³ < 0.01 EUSES 2.1.2
Man via environment - Inhalation (local effects) 0.00191 mg/m³ < 0.01 EUSES 2.1.2
Man via environment - Oral 0.161 mg/kg bw/day 0.189 EUSES 2.1.2
Man via environment - combined routes 0.19

TUBALL BATT NMP
Safety Data Sheet
Release estimation Release route Release rate Release estimation

method
Release estimation Water 6.66 kg/day ERC
Release estimation Air 8.325 kg/day ERC
Release estimation soil 0.033 kg/day ERC
1.3.2. Worker exposure Contributing scenario controlling worker exposure (PROC3)
Information for contributing exposure scenario

Route of exposure and Exposure estimate RCR Method
type of effects
Dermal - Long-term - 1.239 mg/kg bw/day 0.086 ECETOC TRA v3.0,Worker
systemic effects
Inhalation - Long-term - 0.138 mg/m³ 0.029 ECETOC TRA v3.0,Worker

systemic effects
Sum RCR - Long-term - 0.115

systemic effects
Long term - Local - 1.239 mg/m³ 0.031 ECETOC TRA v3.0,Worker

Inhalation

type of effects
systemic effects

systemic effects

systemic effects

Inhalation

type of effects
systemic effects

systemic effects

systemic effects

Inhalation
1.4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the ES
1.4.1. Environment
Guidance - Environment As no environmental hazard was identified no environmental-related exposure

assessment and risk characterization was performed

TUBALL BATT NMP
Safety Data Sheet
1.4.2. Health
Guidance - Health For scaling see: http://www.ecetoc.org/tra

Please note that a modified version has been used (see exposure estimates)

TUBALL BATT NMP
Safety Data Sheet
2. Industrial; Formulation
2.1. Title section
Formulation


Process temperature: 40 °C Contributing scenario controlling worker PROC8a
exposure
Process temperature: 40 °C Contributing scenario controlling worker PROC8b

exposure

exposure

exposure

ERC2 Formulation into mixture
Receiving surface water flow ≥ 18000 m³/d
2.2.2. Control of worker exposure: Contributing scenario controlling worker exposure (PROC8a)
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated facilities

66 Pa

TUBALL BATT NMP
Safety Data Sheet

2.2.3. Control of worker exposure: Contributing scenario controlling worker exposure (PROC8b)
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

66 Pa

PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including
weighing)


TUBALL BATT NMP
Safety Data Sheet

66 Pa

PROC15 Use as laboratory reagent

66 Pa


TUBALL BATT NMP
Safety Data Sheet


estimation
Man via environment - Oral 0.161 mg/kg bw/day 0.189 EUSES 2.1.2
Man via environment - combined routes 0.19

method
Release estimation Water 6.66 kg/day ERC
Release estimation Air 8.325 kg/day ERC
Release estimation soil 0.033 kg/day ERC
2.3.2. Worker exposure Contributing scenario controlling worker exposure (PROC8a)

type of effects
systemic effects

systemic effects

systemic effects

Inhalation
2.3.3. Worker exposure Contributing scenario controlling worker exposure (PROC8b)

type of effects
systemic effects

systemic effects

systemic effects

Inhalation

TUBALL BATT NMP
Safety Data Sheet

type of effects
systemic effects

systemic effects

systemic effects

Inhalation

type of effects
systemic effects

systemic effects

systemic effects

Inhalation
2.4.1. Environment

2.4.2. Health


TUBALL BATT NMP
Safety Data Sheet
3. Industrial; Use as a process chemical
3.1. Title section
Use as a process chemical



exposure

exposure

exposure

ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
Receiving surface water flow ≥ 18000 m³/d
PROC1 Chemical production or refinery in closed process without likelihood of exposure or

processes with equivalent containment conditions

66 hPa

TUBALL BATT NMP
Safety Data Sheet

PROC2 Chemical production or refinery in closed continuous process with occasional controlled
exposure or processes with equivalent containment conditions

66 Pa

PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition


TUBALL BATT NMP
Safety Data Sheet

66 Pa



estimation
Man via environment - Oral 0.00793 mg/kg bw/day < 0.01 EUSES 2.1.2
Man via environment - combined routes < 0.01

method
Release estimation Water 6.66 kg/day
Release estimation Air 0.333 kg/day
Release estimation soil 16.65 kg/day

type of effects
Dermal - Long-term - 6.8 mg/kg bw/day < 0.01 ECETOC TRA v3.0,Worker
systemic effects

TUBALL BATT NMP
Safety Data Sheet

Inhalation - Long-term - 4.13 mg/m³ < 0.01 ECETOC TRA v3.0,Worker
systemic effects
Sum RCR - Long-term - < 0.01

systemic effects
Long term - Local - 4.13 mg/m³ < 0.01 ECETOC TRA v3.0,Worker
Inhalation

type of effects
systemic effects

systemic effects

systemic effects

Inhalation

type of effects
systemic effects

systemic effects

systemic effects

Inhalation
3.4.1. Environment

3.4.2. Health


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TUBALL BATT NMP

TUBALL: 0.1-1% Dispersant: PVDF

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.2.2. Uses advised against

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

2.2. Label elements

20/10/2023 (Revision date) EU - eng 1/34

Signal word (CLP) : Danger

2.3. Other hazards

SECTION 3: Composition/information on ingredients

Name Product identifier % Classification according to

Poly(vinylidene fluoride) Trade Secret 2 Not classified

Pyrrolidinone, dimethyl- CAS-No.: 60544-40-3 < 0.388 Skin Irrit. 2, H315

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Specific concentration limits:

N-methyl-2-pyrrolidone* (CAS-No.) 872-50-4 (10 ≤ C ≤ 100) STOT SE 3, H335

Comments : ** Single wall carbon nanotubes TUBALL™

**Single wall carbon nanotubes

Number based particle size distribution d10

Particle shape Elongated tubes

Particle aspect ratio length to diameter ratio 2000 – 10000:1

Surface functionalisation/treatment - Process No. Process - Chemical vapor deposition (CVD)

Specific surface area 300 – 1500 m²/g

Additional information G/D range : ≥40 (RAMAN at 532 nm)

SECTION 4: First aid measures

4.1. Description of first aid measures

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SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.2. For emergency responders

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

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7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

IOEL TWA 40 mg/m³

IOEL STEL 80 mg/m³

IOEL STEL [ppm] 20 ppm

Regulatory reference COMMISSION DIRECTIVE 2009/161/EU

EU - Biological Limit Value (BLV)

BLV 20 mg/g creatinine Parameter: 2-hydroxy-N-methylsuccinimide - Medium: urine - Sampling

Regulatory reference SCOEL List of recommended health-based BLVs and BGVs

Belgium - Occupational Exposure Limits

OEL TWA 40 mg/m³

OEL TWA [ppm] 10 ppm