SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.

-1 to 13 Topic: Mole Concept

Single correct :
1. Select the correct option for decreasing order of number of atoms.
(I) 2 gm of hydrogen (II) 16 gm of sulphur
(III) 4 gm of oxygen (IV) 31 gm of phosphorus
(A) II > III > IV > I (B) IV > II > III > I (C) I > IV > II > III (D) I = IV > II > III

2. Find the correct option for 36 gm C6H12O6.

(A) 4.8 NA molecules of C6H12O6 (B) 19.2 NA electrons
(C) 0.8 moles (D) 0.6 gm-molecules of oxygen

18 −2
3. Number of electrons in 36mg of 8 O ions are (Take NA = 6 × 1023)
(A) 1.2 × 1021 (B) 9.6 × 1021 (C) 1.2 × 1022 (D) 1.9 × 1022

4. Molar mass of electron is nearly (NA = 6 × 1023, mass of electron = 9.1 × 10 31

kg)
(A) 9.1 × 10 31 kg mol 1 (B) 9.1 × 10 31 gm mol 1
(C) 54.6 × 10 gm mol
8 1
(D) 54.6 × 10 8 kg mol 1

5. What is the specific gravity of a liquid if 260 mL of the liquid has the same mass as 390 mL
of water ?
(A) 0.66 (B) 0.5 (C) 1.5 (D) 1.8

6. The number of electron in 3.1 mg NO3− is -

(A) 32 (B) 1.6 × 10 3
(C) 9.6 × 1020 (D) 9.6 × 1023

7. One gm of each 1H1 , 8O16 , 6C14, 92U238 have -

(A) same atoms (B) same protons (C) same nucleons (D) Same electrons

8. The number of oxygen atoms present in 20.4 g of Al2O3 are equal to the number of :
(A) Oxygen atoms in 3.6 g of water (B) Oxygen atoms in 5.4 g of water
(C) Hydrogen atoms in 5.4 g of water (D) Hydrogen atoms in 10.8 g of water

9. 1.61 gm of Na2SO4.10H2O contains same number of oxygen atoms as present in

(A) 0.98 gm H2SO4 (B) 0.08 gm SO3 (C) 1.78 gm H2S2O7 (D) 0.05 gm CaCO3

Multiple Choice :
10. 1 mol of 717 N−3 ions contains :
(A) 7 NA electrons (B) 7NA protons (C) 7 NA neutrons (D) 14 NA protons

Answer Key
1. (C) 2. (B) 3. (C) 4. (D) 5. (D) 6. (C) 7. (C)
8. (C) 9. (C) 10. (BC)

KT01_7098 1
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-2 Topic: Mole Concept

Single correct :
1. A pure sample of CaCO3 contain 100 moles of total atoms. What is the mass of sample -
(A) 1 kg (B) 2.5 kg (C) 2.0 kg (D) 1.66 kg

16
2. If the weight of one atom is gm and it form X2 type gas. How many grams of X2 is required to
NA
fill up the gas vessel with volume 350 mL at 0°C and to obtain the pressure 2 atm -
(A) 1 gm (B) 16 gm (C) 8 gm (D) 32 gm

3. One atom of an element X weighs 6 × 10 23

gm. Number of moles of atoms in 3.6 kg of sample of X
will be : (NA = 6 × 1023)
(A) 40 (B) 0.04 (C) 100 (D) 1000

4. 0.36 gm of a triatomic gas, X3, occupies 168 ml at 1 atm & 273 K. The atomic weight of X is
(A) 48 (B) 16 (C) 24 (D) 12

5. Which of the following will occupy greater volume under the similar conditions of pressure and
temperature?
(A) 6 gm oxygen (B) 0.98 gm hydrogen
(C) 5.25 gm nitrogen (D) 1.32 gm helium

6. A sample of oxygen gas (only O2 molecules) contains O16 and O17 oxygen atoms only in 9 : 1 atomic
ratio. The average molecular mass of O2, this sample, is :
(A) 32.00 (B) 16.30 (C) 32.20 (D) 33.80

Multiple Choice :
7. The number of oxygen atoms present in 24.5 gm of H3PO4 is equal to (P = 31)
(A) Number of electrons present in 1.6 gm methane (CH4)
(B) Number of molecule of CO2 present in 22 gm CO2.
(C) Number of moles of proton present in NA gm-atom of Hydrogen.
4
(D) Number of total atoms present in mol of CO2.
3

KT01_7099 2
8. An elements has three isotopes X20, X21 and X22. Percentage abundance (mole %) of X20 is 90 and
average atomic mass of X is 20.18. Select correct option(s) -
(A) Percent abudance of X21 = 8% (B) Percent abudance of X21 = 2%
(C) Percent abudance of X22 = 8% (D) Percent abudance of X22 = 2%

Subjective :
9. Find the volume (in ml) of monoatomic gas that contain 0.005 NA atoms at 0°C & 760 torr.

10. Calculate the number of Na+ ion present in 142 amu of Na2SO4 in aqueous solution.

Answer Key
1. (C) 2. (A) 3. (C) 4. (B) 5. (B) 6. (C) 7. (AC)
8. (BC) 9. 112 10. 2

3
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-3 Topic: Mole Concept

Single correct :
1. Which of the following has the smallest no. of molecules:
(A) 22.4 mL of CO2 gas at 0°C, 1 atm (B) 22 g of CO2 gas
(C) 11.2 L of CO2 gas at 0°C, 1 atm (D) 0.1 moles of CO2 gas

2. How many moles are there in 1m3 of any gas at 0°C and 1 atm:
(A) 44.6 moles (B) 44.6 × 10 3
moles
(C) 4.46 moles (D) 44.6 × 10 mole
3

3. Calculate the total number of atoms in 5.6L of SO2 gas at 0°C and 1 atm:
NA 3 3
(A) (B) N (C) NA (D)
4 4 A 4

4. Number of neutrons present in 1.7 grams of ammonia is

(A) NA (B) 0.4 NA (C) 0.7 NA (D) 70 NA

5. The volume of a gas in discharge tube is 1.12 × 10 7

ml. at 0°C and 1 atm. The number of molecule
of gas in the tube is
(A) 3.01 × 104 (B) 3.01 × 1015 (C) 3.01 × 1012 (D) 3.01 × 1016

6. Number of electrons present in 3.6 mg of NH4+ are : (NA = 6 × 1023)

(A) 1.2 × 1021 (B) 1.2 × 1020 (C) 1.2 × 1022 (D) 2 × 10 3

7. Which one of the following contains largest number of atoms :

(A) 50 g of N2O
(B) 17 g of NH3
(C) 150 cm3 of pyridine (C5H5N), density of pyridine = 0.983 g cm 3

(D) 1 mol of N2

8. A sample of MgSO4 contains 8 × 1020 'O' atoms what is the mass of 'S' in the sample ?
(A) 32 g (B) 1.06 × 10 2
g (C) 3.33 × 10 2
g (D) 50 × 10 2
g

KT01_7101 4
9. 6 × 1024 atoms of an element weight 200g. If this element forms homodiatomic gas (X 2) then
calculate gram molecular mass of X2(NA = 6 × 1023)
(A) 10 (B) 20 (C) 30 (D) 40

10. 4.4 g of CO2 and 2.24L of H2 at 0oC & 1atm are mixed in a container. Find total number of molecules
present in the container ?
(A) 6.022 × 1023 (B) 1.2044 × 1023 (C) 2 mol (D) 6.022 × 1024

Answer Key
1. (A) 2. (A) 3. (B) 4. (C) 5. (C) 6. (A) 7. (C)
8. (B) 9. (D) 10. (B)

5
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-4 Topic: Mole Concept
Single correct :
1. Which is heaviest ?
(A) 25 g of Hg (B) 2 moles of H2O (C) 2 moles of CO2 (D) 4 g atoms of oxygen

2. How many atoms are present in 1/4 mole of H2SO4 ?

(A) 3 × 6.02 × 1023 (B) 5 × 6.02 × 1023 (C) 6 × 6.02 × 1023 (D) 7/4 × 6.02 × 1023

3. A certain gaseous mixture contains methane and sulphur dioxide in ratio of 1 : 8 by mass. The ratio
of the number of molecules is :-
(A) 1 : 8 (B) 1 : 2 (C) 1 : 1 (D) 2 : 1

4. What is not correct regarding 22 g of CO2 ?

1
(A) it occupies always 11.2 L of volume (B) it corresponds to mol of carbon dioxide
2
(C) it contains one g-atom of oxygen (D) it contains 6.0 g of carbon

5. The ratio of the mass of C-12 atom to that of an atom of element X (whose atomicity is four) is
1 : 9. The molecular mass of element X is :-
(A) 480 g mol 1
(B) 432 g mol 1
(C) 36 g mol 1
(D) 84 g mol 1

6. If 1kg of common salt costs Rs. 7 and 1 kg of sugar costs Rs. 14. What would be the cost of 1 mole
of salt and sugar
(A) Both will have the same cost
(B) The cost of sugar will be half the cost of salt
(C) The cost of sugar will be more than that of the salt
(D) The cost of sugar will be twice the cost of salt

7. A person adds 1.71 gram of sugar (C12H22O11) in order to sweeten his tea. The number of carbon atoms
added are
(A) 3.6 × 1022 (B) 7.2 × 1021 (C) 0.05 (D) 6.6 × 1022

8. Average molecular weight of a gaseous mixture which contains 80% by mole N2 & rest O2 gas is
(A) 28 (B) 30.6 (C) 28.8 (D) 29.2

KT01_7102 6
9. Find vapour density of mixture having 64% by mass of CH 4, 32% by mass of O2 and remaining H2
mol.wt.
(Vapour density = )
2
(A)10.28 (B) 20.56 (C) 14.28 (D) 7.14

10. The number of F ions in 4.2 gm AlF3 is (Al = 27, F = 19)

(A) 0.05 (B) 9.03 × 1022 (C) 3.01 × 1022 (D) 0.15

Answer Key

1. (C) 2. (D) 3. (B) 4. (A) 5. (B) 6. (C) 7. (A)

8. (C) 9. (B) 10. (D)

7
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-5 Topic: Mole Concept

Single correct :
12
1. A plant virus contains spherical particles of diameter 4Å. If the density of virus is gm/ cm3, the

molar mass of virus is
(A) 76.8 gm/mol (B) 9.6 gm/mol (C) 614.4 gm/mol (D) 128 gm/ mol

2. Certain mass of starch, (C6H10O5)n, is burnt completely. If 26.4 kg CO2 is produced, the mass of water
produced simultaneously is
(A) 9.0 gm (B) 18.0 kg (C) 9.0 kg (D) 27.0 kg

3. Each molecules of a compound contains 5 carbon atoms, 8 hydrogen atoms and 4 × 10 23

gm of
other elements. The molecular mass of compounds is (NA = 6 × 1023)
(A) 92 (B) 68 (C) 308 (D) 108

4. Calculate the mass of HCl (in gm) produced if 2gm H 2 is mixed with 71 gm Cl2.
H2 + Cl2 ⎯⎯→ 2HCl
(A) 35.5 (B) 72 (C) 36.5 (D) 73

5. For the reaction: 7A + 13B + 15C ⎯⎯→ 17P

If 15 moles of A, 26 moles of B & 30.5 moles of C are taken initially then liniting reactant is
(A) A (B) B (C) C (D) None of these

6. In 2.6 kg of FeSO4. 6H2O (At. wt. of Fe = 56)

(A) Number of atoms of O are 100 × NA (B) Moles of H-atoms are 120 × NA
2−
(C) Molecules of water are 60 × NA (D) Moles of e present in SO4 are 500

7. 5 moles of VO & 6 mole of Fe2O3 are allowed to react completely according to reaction
VO + Fe2O3 → FeO + V2O5 The number of moles of V2O5 formed is
(A) 6 (B) 2 (C) 3 (D) 5

Match the list:

8. List-I List-II
(Amount of substance) (No. of moles of particular atoms in
the given substance)
(P) 6.022 × 1024 formula units of (1) 15 mole O-atoms
Al2(SO4)3.3H2O
(Q) 90 gm C6H12O6 (2) 3 mole O-atoms
(R) 112 litre SO3(g) at 1 atm and 0°C. (3) 2.5 mole O-atoms
(S) 54 gram N2O5 (g) (4) 150 mole O-atoms

KT01_7103 8
 Code:
(P) (Q) (R) (S)
(A) 4 2 1 3
(B) 4 2 3 1
(C) 4 1 2 3
(D) 2 1 4 3

9. Based on following reaction, give minimum possible value of 'x' for 1 mol AF 6.
AF6 + H2O → AOx + HF
AF6 + 3H2O → AO3 + 6HF

10. A sample of NaHCO3(s) on heating undergoes 1.845 gm loss of mass. Approximate mass of NaHCO3
(in nearest integer) in gm is

Answer Key
1. (A) 2. (C) 3. (A) 4. (D) 5. (B) 6. (ACD) 7. (B)
8. (A) 9. (3) 10. (5)

9
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-6 Topic: Mole Concept

Single correct :
1. Balanced chemical equation is given as following:
C2H5OH (l) + 3O2(g) ⎯→ 2CO2(g) + 3H2O(l)
What value of the volume in litre of CO2 (g) measured at 200 K and 1 atm, produced from the
combustion of 0.25 mole of C2H5OH (l)? [Use R = 0.08 L atm mol 1K 1]
(A) 5 (B) 8 (C) 10 (D) 15

1
2. 12 moles of each A & B are allowed to react as given: 3A + 2B → C + D. If 60 g of D is produced
2
then calculate the atomic mass of D.
(A) 30 (B) 45 (C) 60 (D) 15

3. A cylinder of compressed gas contains nitrogen and oxygen gas in the mol ratio 3: 1, if the cylinder
is known to contain 2.40 gm of oxygen. What is the total mass of gas mixture
(A) 8.7 g (B) 7.2 g (C) 6.8 g (D) 6.3 g

4. If 0.5 mol of BaCl2 is mixed with 0.1 mole of Na3PO4, the maximum number of mole of Ba3(PO4)2 that
can be formed is:
(A) 0.7 (B) 0.05 (C) 0.30 (D) 0.10

Multiple correct:
5. Select the correct statement(s) about chemical reaction in a closed container -
(A) total mass remains conserved
(B) total moles of molecules remains conserved
(C) total moles of atoms remains conserved
(D) total moles of molecules may change

Matrix type:
6. Match the column:
Column-I (Reaction) Column-II (At the end)
50%yield
(A) 2A + 2B ⎯⎯⎯⎯⎯→ 3C (P) 3 moles C formed
4 mol 6 mol

1 80%yield
(B) A + 2B ⎯⎯⎯⎯⎯ →C (Q) 3.2 moles C formed
2 8 mol
4 mol
60%yield
(C) 3A + 2B ⎯⎯⎯⎯⎯ →C (R) A is limiting reagent
15 mol 20 mol
20%yield
(D) A + 3B ⎯⎯⎯⎯⎯ → 2C (S) B is limiting reagent
5 mol 12 mol

(T) 1.6 moles C formed

KT01_7104 10
Subjective:
7. A person produce 2.5 L gastric juice per day, which contains 3.65 gm HCl per litre. The minimum
integer number of antacid tablets, each containing 870 mg Mg(OH)2, which should be taken by that
person to neutralise all HCl produce in one day, is : [Mg = 24]

8. P & Q are two elements which form P 2Q3 and PQ2 molecules. If 0.15 mole each of P 2Q3 and PQ2
weighs 15.9 gm and 9.3 gm respectively. Calculate the atomic weights of P and Q.

9. An element X is found to combine with oxygen to form X4O6. If 8.4 gm of this element combines
with 6.4 gm of oxygen, then calculate the atomic weight of X.

10. Moles of glucose, which produce a total of 744 gm CO2 and water on complete combustion, is:

Answer Key

1. (B) 2. (A) 3. (A) 4. (B) 5. (ACD)

6. (A) → (P, R); (B) → (Q, S); (C) → (P, R); (D) → (S, T)
7. (9) 8. (26, 18) 9. (31.5) 10. (2)

11
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-7 Topic: Mole Concept

Single Correct :
1. 2 moles of KClO3 is completely decomposed to produce O2. How many moles of butane can be
completely burnt by the O2 gas produced
(A) 0.5 mole (B) 1 mole (C) 2 mole (D) 3 mole

2. 20 gm pyrolusite ore exactly requires 29.2 gm HCl for complete reaction:

MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O
The mass percent of pure MnO2 in the pyrolusite ore is (Mn = 55)
(A) 17.4 % (B) 87 % (C) 43.5 % (D) 14.6 %

3. How many gram glucose should be burnt completely to produce sufficient CO 2 which may convert
12 gm NaOH into Na2CO3?
(A) 4.5 gm (B) 9.0 gm (C) 2.25 gm (D) 13.5 gm

4. 10 gm NaOH and 9.8 gm H2SO4 are allowed to react by which 8.52 gm Na 2SO4 is formed. The
percentage yield of products is
(A) 60 % (B) 48 % (C) 100 % (D) 75 %

5. 20 gm of a chalk sample is dissolved completely in excess of dilute HCl solution. If 3.36 L CO 2 gas
is produced at 273K and 1atm, the percentage of pure CaCO3 in chalk is (assume that the impurities
are inert to HCl and CO2 is completely insoluble in water)
(A) 25 % (B) 50 % (C) 75 % (D) 80 %

Multiple correct:
6. For reaction:
2Fe2S3 + 6H2O + 3O2 ⎯⎯→ 4 Fe(OH)3 + 6S
If 4 moles of Fe2S3 react completely with 2 mole of H2O and 3 moles of O2, then which of the
following statement (s) is/are correct
(A) H2O is limiting reagent (B) Moles of Fe(OH)3 formed is 4/3
(C) Moles of Fe2S3 remaining is 10/3 (D) Mass of O2 remaining is 32 gm

7. For reaction
MnO2 + 4HCl ⎯⎯→MnCl2 + 2H2O + Cl2(g)
261 gm MnO2 mixed with 448 litre of HCl gas at 273°C & 1 atm pressure to produce product.
[NA = 6 × 1023; Atomic mass of Mn = 55, Cl = 35.5]
Select correct statement(s).
(A) MnO2 is limiting reagent
(B) Chlorine gas produced contains 15 × 1023 molecules.
(C) Moles of excess reactant left is 0.5 moles
(D) If % yield of reaction is 50%, then mass of MnCl2 obtained will be 315.

KT01_7105 12
Subjective:
8. 42 gm of a mixture of propyne (C3H4) and oxygen gas is collected in a vessel and fired. The maximum
possible mass (in gm) of water formed is

9. 27 gm of Al react with excess of oxygen to give 4.59 gm of Al 2O3. Calculate percentage yield of
reaction.

10. If 5g H2 is mixed with 14g of nitrogen gas for the following reaction
N2 + 3H2 → 2NH3
At the end, mass (in gm) of H2 left unreacted is

Answer Key
1. (A) 2. (B) 3. (A) 4. (A) 5. (C) 6. (ABC) 7. (BC)
8. (9) 9. (9) 10. (2)

13
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-8 Topic: Mole Concept

Single correct :
1. Mass ratio of NH3 and CO2 for maximum product formation as per reaction:
2NH3 + CO2 → NH2COONH4
17 17 22 44
(A) (B) (C) (D)
22 44 17 17

2. To obtain maximum mass of NO2 from a given mass of a mixture of NH3 and O2, the ratio of mass
2
of NH3 to O2 should be 2NH3 + O2 ⎯⎯→2NO2 + 3H2O
7
17 4 17
(A) (B) (C) (D) None of these
40 7 56

3. A mixture containing 3 moles each of C4H8 and C6H6 undergoes complete combustion with O2 to
form CO2 and H2O. Calculate total mass of CO2 produced
(A) 1320 gm (B) 610 gm (C) 528 gm (D) 792 gm

4. Calculate % yield of the reaction if 1 Kg KHCO3 produces 110 g of CO2 upon strong heating.
(A) 25 (B) 75 (C) 50 (D) 80

5. When a solid mixture of NaHCO3 and Na2CO3 is strongly heated to 500K in an open vessel, the mass
of sample decreases. The decrease is
(A) Only due to CO2(g) formed by decomposition of Na2CO3
(B) Only due to CO2(g) formed by decomposition of NaHCO3
(C) Only due to CO2(g) formed by decomposition of both, Na2CO3 and NaHCO3
(D) Due to CO2(g) and water vapour formed by decomposition of NaHCO3

6. 1.5 gm mixture of SiO2 and Fe2O3 on very strong heating leave a residue weighing 1.46 gm. The
reaction responsible for loss of weight is
Fe2O3 (s) ⎯→ Fe3O4 (s) + O2(g)
What is the percentage by mass of Fe2O3 in original sample.
(A) 80% (B) 20% (C) 40% (D) 60%

7. An organic compound contains 40% carbon atom 6.67% hydrogen atoms and remaining oxygen
atoms by mass. The empirical formula will be
(A) CH2 (B) CH2O (C) C2H4O2 (D) CH3O

KT01_7106 14
Matrix type:
8. Match the column:
Column-I (compound) Column-II (Relative amounts of products
on complete combustion)
(A) CH4 (P) Moles of CO2 < Moles of H2O
(B) C2H4 (Q) Moles of CO2 = Moles of H2O
(C) C2H2 (R) Moles of CO2 > Moles of H2O
(D) C3H8 (S) Mass of CO2 > Mass of H2O

Subjective:
9. 62.5 gm of a mixture of CaCO3 and SiO2 are treated with excess of HCl and 1.1 gm of CO2 is produced.
What is mass % CaCO3 in the mixture.

Answer Key

1. (A) 2. (C) 3. (A) 4. (C) 5. (D) 6. (A) 7. (B)

8. (A) → (P, S); (B) → (Q, S); (C) → (R, S); (D) → (P, S) 9. (4)

15
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-9 Topic: Mole Concept

Single correct :
1. Find % (w/v) of 20% (w/w) H2SO4 solution, if density of solution is 1.2 gram / ml.
(A) 24% (B) 12% (C) 20% (D) 16.6%

2. Molality of pure liquid benzene (C6H6) if its density d = 2 gram/ml is

(A) 2 m (B) 0.78 m (C) 12.8 m (D) 50 m

3. 30 ml , 50% (v/v) HCl added into 70 ml, 20% (v/v) HCl solution. Find % (v/v) of resultant solution
(A) 14 (B) 29 (C) 15 (D) 70

4. A deci-molar solution of urea is diluted 100 times. It's final molarity is

(A) 10 2
(B) 10 3
(C) 10 (D) 100

5. Mole fraction of aqueous solution of CH3COOH is 0.1. Select incorrect statement

(A) % (w/w) = 27 (B) Molality = 6.17 m(C)
nH O WH O
(C) 2
=9 (D) 2
= 27
nCH COOH WCH COOH
3 3

6. A hydrocarbon (containing only carbon, hydrogen) on complete combustion gave 4.4 gm CO2 and 1.8
gm H2O. What is it's empirical formula
(A) CH2 (B) CH (C) CH3 (D) C2H5

7. An oxide of iron contains 70% iron by mass, simplest formula of oxide is: [Fe = 56]
(A) FeO (B) Fe2O3 (C) Fe2O (D) Fe3O4

Subjective:
8. Calculate the amount of ZnO produce (in gram) when 390 gram of ZnS reacts with 179.2 litre O 2 at
1 atm and 273 K [Zn = 65.5]
ZnS + O2 → ZnO + SO2

9. 90 g of a silver coin was dissolved in strong nitric acid, and excess of sodium chloride solution was
added. The silver chloride precipitate was dried and weighed 71.75 g. Calculate the percentage of
silver in the coin (Atomic mass of Ag = 108)
Ag + 2HNO= ⎯→ AgNO3 + NO2 + H2O
AgNO= + NaCl ⎯→ AgCl + NaNO3

KT01_7107 16
10. Preparation of Na2SnO2 involves the following set of reaction.
(i) Sn + 2HCl ⎯→ SnCl2 + H2
(ii) SnCl2 + 2NaOH ⎯→ Sn(OH)2 + 2NaCl
(iii) Sn(OH)2 + 2NaOH ⎯→ Na2SnO2 + 2H2O
(a) Mass of Sn (in kg) required to produce 19.7kg Na2SnO2, assuming 100% yield of each reaction.
(b) If % yield of reaction (i), (ii), (iii) 25%, 50%, 40% respectively. Calculate the mass of Sn (in kg)
required to produce 19.7kg of Na2SnO2. [Sn = 119]

Answer Key

1. (A) 2. (C) 3. (B) 4. (B) 5. (D) 6. (A)

7. (B) 8. (326 gram) 9. (60) 10. (a) 11.9 kg ; (b) 238 kg

17
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-10 Topic: Mole Concept

Single correct :
1. A monobasic acid contains: N = 22.22%, H = 1.59% and rest oxygen atoms. The number of oxygen
atoms in the molecular formula of acid is
(A) 1 (B) 3 (C) 4 (D) 2

2. A metal sulphate is isomorphous with CaSO4. 2H2O and contains 10%S. What is atomic weight of
metal (Given : Ca = 40, S = 32)
(A) 108 (B) 94 (C) 188 (D) 208

3. What is % H2O in CuSO4.5H2O (Cu = 64, S = 32)

(A) 36% (B) 7.2% (C) 20% (D) 25%

4. 2.8 gram of an organic compound treated according Kjeldahl's method and evolved NH 3 was
absorbed in aqueous sulphuric acid solution having 0.01 mole of sulphuric acid. Find % of N in
organic compound
(A) 14% (B) 5% (C) 20% (D) 10%

5. Which compound, contain equal percentage of all elements in its compound

(A) CO2 (B) HCOOH (C) SO2 (D) CH3COOH

6. If ratio of mole fraction of solute to solvent is unity, what would be % by wt. (concentration of
solute) (M solute = molecular mass of solute, M solvent = M molecular mass of solvent)
M solute
(A)  100 (B) 50%
(M solute + M solvent )
M solute
(C) 66.67 % (D)  100
M solvent

7. Decreasing order (first having highest & then others following it) of mass of pure NaOH in each of
the aqueous solution
(i) 50 gm of 40% (w/w) NaOH (ii) 50 gm of 50% (w/v) NaOH [dsoln. = 1.2 gm/ml]
(iii) 50 gm of 20 M NaOH [dsoln. = 1 gm/ml]
(A) (i), (ii), (iii) (B) (iii), (ii), (i)
(C) (ii), (iii), (i) (D) All contain same wt. of NaOH

5
8. 100 ml. aqueous solution (density = gm/ml) contain 40 % by weight NaOH. The number of
3
molecules of NaOH dissolved in the above solution is:
(Use NA = 6 × 10+)
(A) 2 × 1022 (B) 3.33 × 1022 (C) 1024 (D) 3.33 × 1023

KT01_7108 18
Multiple correct:
89
9. 90 gm glucose is dissolved in 800 gm water to get a solution of density gm/ ml. The correct
80
concentration of solution is /are
90 90
(A) % (w/w) (B) % (w/v) (C) 0.625 m (D) 0.625 M
8 8

Integer Type :
10. Calculate molarity of NaOH in a solution made by mixing 2 lit. of 1.5 M NaOH, 3 lit. of 2M NaOH and
1 lit. water.

Answer Key
1. (B) 2. (C) 3. (A) 4. (D) 5. (C) 6. (A) 7. (B)
8. (C) 9. (BCD) 10. 1.5 M

19
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-11 Topic: Mole Concept

Single correct
1. 200 ml of an aqueous solution of glucose (C6H12O6) has molarity of 0.01M. Which of the following
operations can be done to this solution so as to increase molarity to 0.015 M?
(A) Evaporate 50 ml water from this solution
(B) Add 0.18 g glucose to solution without changing its volume
(C) Add 50 ml water to this solution
(D) None of these

2. A gaseous mixture of C3H8 and CH4 exerts a pressure of 320 mm Hg at temperature TK in a V litre
flask. On complete combustion of mixture, flask containing only CO 2 exerts a pressure of 448 mm
Hg under identical condition. The mole fraction of C3H8 in the given mixture is
(A) 0.35 (B) 0.5 (C) 0.2 (D) 0.4

3. 50 ml Toluene [C6H5CH3(g)] undergoes combustion with excess of oxygen. Calculate the volume
contraction.
(A) 50 ml (B) 150 ml (C) 75 ml (D) 100 ml

4. The questions below to consist of an Assertion and the Reason. Mark appropriate option using the
given directions.
Assertion: Molarity & molality for very dilute aqueous solution is approximately same
Reason: For all aqueous solution total mass of solvent is approximately equal to total volume of
solution.
(A) If both Assertion and Reason are CORRECT, and Reason is the CORRECT explanation of the
Assertion.
(B) If both Assertion and Reason are CORRECT, but Reason is not the CORRECT explanation of the
Assertion.
(C) If Assertion if CORRECT but Reason is INCORRECT.
(D) If Assertion is INCORRECT Reason is CORRECT.

KT01_7109 20
5. An alkane on complete combustion with O2 shows 50% of volume contraction. Molecular formula
of alkane is
(A) C4H10(g) (B) CH4(g) (C) C2H6(g) (D) C3H8(g)

Multiple Correct :
6. Aqueous solution containing 30gm CH3COOH are
(A) 250 ml of 2M CH3COOH solution
(B) 600 gm of 5% (by wt.) CH3COOH solution
(C) 111gm of solution in which mole fraction of CH3COOH is 0.1
(D) 500 gm of 7m CH3COOH solution

7. Molarity of solute A (mol.wt. = 60) and B (mol.wt. = 40) in an aqueous solution are 2M each.
(Density of aqueous solution is 1.2 gm/ml.)
(A) Molality of A in the solution is 2m (B) Molality of B in the solution is 2m
(C) wt% of B in the solution is 10% (D) wt % of A in the solution is 10 %

Subjective:
8. 1000 ml solution of CaBr2 contain 200 gm CaBr2. If density of solution is 1200 kg/m3, calculate
molarity of solution

9. What volume (in litres) of 0.4 M HCl completely reacts with 0.5 M, 4 litre of NaOH solution

10. What is Cl concentration (in M) in 2.5 M BaCl2 solution which is 80% dissociated?

Answer Key

1. (B) 2. (C) 3. (B) 4. (C) 5. (D) 6. (ABC) 7. (ABD)

8. (1) 9. (5) 10. (4)

21
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-12 Topic: Mole Concept

Single correct:
1. What volume of 95% H2SO4 by weight (dsolution = 1.85 g/ml) must be taken to prepare 100 ml of 15%
w
  solution of H2SO4 (dsolution = 1.1 g/ml)
w
(A) 9.4 ml (B) 18.8 ml (C) 28.2 ml (D) 56.4 ml

2. How many gram of KCl is required to make it's 500 ml solution of molarity 0.1M. (K = 39, Cl = 35.5)
(A) 3.725 (B) 1.8625 (C) 0.745 (D) 7.45

w
3. 500mL, 0.2M Na2SO4 solution is mixed with 100 mL, 17.1%   Al2(SO4)3 solution and resulting
V
solution is diluted to 5 times. Find the molarity of SO4 2
ions in the final solution
[Mw of Al= 27, s = 32, Na = 23]
1 5 7 12
(A) M (B) M (C) M (D) M
12 12 5 5

Multiple correct:
4. Select the correct statement(s):
(A) Ratio of gm/litre & % w/v of a solution is independent of solute substance.
(B) Ratio of % w/v and molarity of a solution depends on solute substance.
(C) Ratio of % w/v and molarity of a solution depends on solvent substance
(D) Ratio of % w/v & ppm for any solution is same

5. 400 ml 0.1 M BaCl2 is mixed with 600 ml 0.1 M H2SO4 to form product according to following reaction
BaCl2 + H2SO4 ⎯⎯→ BaSO4 + 2HCl
Select the correct option(s), after reaction is completed
(A) Molarity of Ba+2 ions in final solution is 0.04 M
(B) Molarity of SO42 ions in solution is 0.02 M
(C) Molarity of H+ ions do not change on mixing
(D) Final molarity of H+ ion in solution is 0.12 M

6. A sample of H2SO4 solution having density 1.96g/ml. If 50 ml of this solution is completely neutralize
by 2M, 100ml NaOH solution. Wt % of H2SO4 in the solution is.
(A) 6 % (B) 12.5 % (C) 10 % (D) 2 %

KT01_7110 22
7. Which of the following is incorrect for 17g/L of H2O2 solution?
(A) Volume strength is 5.675
(B) Molarity of solution is 0.5M
(C) 1 ml of this solution gives 2.8 ml O2 at 273K and 2 atm
(D) The molarity of solution is 2M

Match the column

8. Match the column:
Column-I Column-II
(P) 20% (w/w) solution of KOH (A) 8.64 M
(density of solution = 1.02 gm/mL)
(Q) Solution containing 864 gm (B) 3.64 M
of CaCO3 in a 1 L.
(R) Volume of 1.204 × 1024 (C) 5 mL
molecules of water at 4°C
(S) Volume of 0.2 M NaOH solution (D) 36 mL
containing 40 mg of NaOH
Code:
P Q R S
(A) 4 1 2 3
(B) 2 1 3 4
(C) 4 1 3 2
(D) 2 1 4 3

9. 5 ml of 1.2 M- NaOH solution is diluted till the concentration becomes 2% (w/v). Assuming volume
to be additive, the volume of water added for dilution is
(A) 12 ml (B) 7 ml (C) 19 ml (D) 5ml

10. An aqueous glucose solution of density 1.71 gm /ml has mole-fraction of solute equal to 0.10. The
molarity of solution is
(A) 0.5 M (B) 5.0 M (C) 2.5 M (D) 1.5 M

Answer Key

1. (A) 2. (A) 3. (A) 4. (AB) 5. (BD) 6. (C) 7. (D)

8. (D) 9. (B) 10. (B)

23
SUBJECT: IIT-PC COURSE: GROWTH (XI) ELP NO.-13 Topic: Mole Concept

Single correct:
1. The air contains 78% N2 & 22% O2 by volume. The volume occupied by 40 gm air at 20°C & 745 mm
Hg pressure approximately.
(A) 34 lit. (B) 34 ml (C) 3.4 K. lit. (D) 3.4 lit.

2. Human lungs can absorb 8 gm O2 per hour by respiration. If all oxygen atoms are converted to
carbohydrates (C6H12O6) how long will it take to produce 180 gm C6H12O6
(A) 8 hour (B) 12 hour (C) 10 hour (D) 6 hour

Paragraph type:
Paragraph for Q.3 to Q.5
Labelled as '% oleum', it means maximum amount of H 2SO4 that can be obtained from 100 gm of
such oleum (mixture of H2SO4 and SO3) by adding sufficient water. For ex. 109 % oleum sample
means, with the addition of sufficient water to 100 gm oleum sample 109 gm H2SO4 is obtained.
% labelling of oleum sample = (100 + x)%
x = mass of H2O required for the complete conversion of SO3 in H2SO4

3. 50 gm of 109 % oleum is mixed with 50gm of another 118% oleum. Calculate the maximum weight
of H2SO4 which can be obtained from the resulting mixture.
(A) 100 gm (B) 113.5 gm (C) 127 gm (D) 118 gm

4. What is the maximum mass of H2SO4 that can be obtained from a 100 gm oleum sample labelled
as 110%
(A) 110 gm (B) 120 gm (C) 90 gm (D) 115 gm

5. 25 gm of an oleum sample contains 15 gm H2SO4. What is % labelling of this oleum sample

(A) 104.5 (B) 109 (C) 118 (D) 115

KT01_7111 24
Subjective:
6. An alkene upon combustion produces CO2(g) and H2O(g). In this combustion process, if there is no
volume change then the no. of C atoms per molecule of alkene, is.

7. The % by volume of C4H10 in a mixture of C4H10, CH4 and CO is 41, then calculate volume of CO2
(in ml) produced when 100 ml of mixture is burnt in excess of O2.

8. What volume (in ml) of 0.8 M - Ca(NO3)2 solution should be mixed with 40 ml of 0.6M- Al(NO3)3
solution to get a solution having NO3 ion concentration equal to 1.70 M?

9. 80 ml of 0.5 M - Na2SO4 solution is mixed with 100 ml of 0.4 M - BaCl2 solution. The molarity of Na+
ion in the resulting solution is.

10. H2O2 decomposes as:

2H2O2(aq.) → 2H2O(l) + O2(g)
If 50% of H2O2 present in 400 ml of 0.4M - H2O2 solution decomposed as above, the volume (in L)
of O2(g) produced at 27°C and 608 torr is (R = 0.08 L-atm/K-mol)

Answer Key

1. (A) 2. (B) 3. (B) 4. (A) 5. (B) 6. (2) 7. (223)

4
8. (40) 9. M 10. (1200)
9

25