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Reservoir Fluid Properties

PTE232
By
Dr Adel M.
Dr. M Salem
Asst. Prof. Of PE
Faculty of Pet. & Min. Eng.
Suez Canal university
SS_2009‐2010

Outlines: Course Contents


Expectation: ?!!!
Chapter about : Fundamentals of Petroleum Chemistry
Chapter about : Problems Related to Crude Oil Composition: ( H2S Problems, Scale Problems, CO2
Problems, Organic Deposition and Control)
Chapter about : Phase Behaviour : Single Components, Two-Components, Three Component
Systems and Multi
Systems, Multi-component
component Systems,…
Systems
Chapter about : Classification of Reservoirs and Reservoir Fluids, and Gas/water Zone Detections
Chapter about : Equation of State – EOS
Ch t about
Chapter b t : Other
Oth Equations
E ti off State
St t forf RealR l Gases
G – Other
Oth EOS
Chapter about : Properties of Dry Gases
Chapter about : Properties of Wet Gases
Ch t about
Chapter b t : Properties
P Oil [ il viscosity,
ti off Oil:[oil i it oilil compressibility,
ibilit oilil formation
f ti volume
l factor,
f t total
t t l volume
l
factor]
Chapter about : Properties of Water:[water viscosity, water compressibility, water formation volume factor, electrical
resistivity of water]
Chapter about : PVT Laboratory Analysis of Oil.
Chapter about : Problems of some types of reservoir fluids.
Chapter about : Case Studies
Chapter about : Numerical analysis and Computer Modeling , Computer Simulation related to the
course, PVTsim, PVT pro,…

The order of these chapters will be modified based on the suitable consequence
May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 2
L t
Lectures 16 & 17

Properties of Wet Gases

May 2010

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 3

Lectures 16 & 17 Agenda


PROPERTIES OF WET GASES

Introduction
Recombination of Surface Fluids­Compositions Known
1.Surface Composition
p – Known
2. Separator Compositions Known:
3 Recombination of Surface Fluids­Compositions
3.
Unknown
1 If Properties & Quantities Are Known
1.
2. Using Charts
Formation Volume Factor of Wet Gas
Bwg Determination Methods

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 4
Properties of Wet Gases: Introduction
The key to the analysis of the properties of a wet gas is that the
properties of the surface gas are not the same as the properties of the
reservoir gas.

Liquid condenses from the reservoir gas as it moves from reservoir


conditions to surface conditions. Thus the composition of the surface
gas is
i quite
i different
diff from
f the
h composition
i i off the
h reservoir
i gas, having
h i
considerably fewer of the intermediate and heavy components.

Wet gases are usually separated in two­stage separation systems such as


next slide Figure.
g At the surface,, the well stream is separated
p into stock
tank liquid (condensate
condensate), separator gas,gas and stock
stock­­tank gas.
gas All three of
these fluids must be included in the recombination calculation.

If a three­stage separator system is used, all three gases must be


included in the recombination calculation.
calculation
May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 5

1 2

1 2
3

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 6
Recombination of Surface Fluids: Compositions Known

The surface liquid and gases must be recombined in order to determine


the p p
properties of the g
gas in the reservoir.

This recombination is done by calculation if the compositions of the


surface
f fluids
fl id are known.
k

1 Surface Composition ­ Known


1.Surface
1.
The composition of the reservoir gas can be calculated given the
compositions
p of the stock­tank liquid,
q separator
p gas,
g and stock­tank vent
gas.

The producing
Th d i gas­oil il ratios
ti mustt be
b known
k also.
l TheTh calculation
l l ti
simulates laboratory recombination of the liquid and gases in quantities
indicated by the gas
gas­­oil ratios.
ratios

Once the composition of the reservoir gas has been calculated, its physical
properties can be calculated as for a dry gas.
gas
May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 7

Recombination of Surface Fluids-Compositions Known


1. Surface Composition
p - Known
The first step is conversion of gas­oil ratios in scf/STB to Ib mole gas/lb
mole stock tank liquid. To accomplish this, the density and apparent
stock­tank
molecular weight of the stock­tank liquid must be calculated.

These gas­oil ratios in terms of Ib moles are used to combine the


compositions of the separator gas, stock­tank gas, and stock­tank oil in
the
h proper ratios.
i AnA example l will
ill best
b illustrate
ill the
h procedure.
d

EXAMPLE X
X-1:
1

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 8
Solution

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 9

Solution
Solution:
First, calculate the apparent molecular weight and density of the stock
tank liquid.
liquid
MSTO = 100.9 Ib/lb mole, [Equation ]
ρSTO = 47.11 lb/cu ft, from 55.9°API, [Equations API = 141γ .5 − 131.5 and ]
Second, convert g
gas­oil ratios to lb mole g
gas/Ib
/ mole stock­tank liquid.
q

47.11

Third, calculate mole fraction of the recombined reservoir gas. See next
Table.

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 10
Solution

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 11

Recombination of Surface Fluids-Compositions Known


2. Separator
p Compositions
p Known:
2. Separator Compositions Known:
Known

Often samples of gas and liquid are taken from the primary separator.

The compositions of these two fluids can be recombined in the manner


of the previous Example.

Sometimes the separator


p gas­oil
g ratio is g
given in scf/STB.
/ If so,, it must
be converted to scf/SP bbl by dividing by the ratio of volume of
separator liquid to volume of stock­tank liquid which is given normally
as a partt off th
the compositional
iti l analysis.
l i

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 12
EXAMPLE X-2:

EXAMPLE X-2:

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 13

EXAMPLE X-2, …

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 14
Solution

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 15

Solution

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 16
Recombination of Surface Fluids
3. Recombination of Surface Fluids-Compositions
p Unknown
3. Recombination of Surface Fluids
Fluids­­Compositions Unknown

If compositional analysis is unavailable


unavailable, the engineer must rely on
production data to estimate the specific gravity of the reservoir gas.
Other properties of the reservoir gas are estimated using specific
gravity.

Next we will look at two methods of estimating the specific gravity of the
reservoir
i gas from
f production
d ti d data.
t

In the first case,


case the properties and quantities of all surface gas streams
are known.

In the second case, only the properties of the gas from the primary
separator are known.

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 17

If Properties & Quantities Are Known


1.Separator Gas and Stock
1.Separator Stock­­Tank Vent Gas Properties Known :
The surface gas is represented by a weighted average of the specific
gravities of the separator gas and stock­tank gas.

The producing gas­oil ratio is;

For a three­stage separator system the equations are:

and;

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 18
Then, on the basis of one stock­tank barrel, the mass of the reservoir gas
in pounds is:

Again,
g on the basis of one stock­tank barrel, the mass of reservoir g
gas in
pound moles is;

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 19

The molecular weight of the reservoir gas is mR/nR, and the specific
gravity of the reservoir gas is molecular weight divided by 29.

The term 133,300 γoMo in the denominator represents the volume in


standard cubic feet of gas that the stock­tank liquid would occupy if it
were vaporized. This is sometimes called the gaseous equivalent of the
stock­tank liquid.

If the molecular weight of the stock­tank liquid is not known, it can be


estimated as:

Where γSTO is the specific


p g
gravity
y of the stock­tank liquid.
q

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 20
EXAMPLE X-3:

Solution:
First, calculate the specific gravity of the surface gas;

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 21

Solution
Second, calculate the molecular weight of the stock­tank liquid.

Third, calculate reservoir gas specific gravity.

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 22
Using Charts
A quicker but less accurate method of obtaining the specific gravity of
the gas in the reservoir is given in the following Figure .

Separator gas and stock tank gas must be added to obtain gas volume
for calculating condensate production rate. Also, the weighted average
of separator and stock­tank specific gravities must be used as surface
gas specific
ifi gravity.
i

The inset
Th i t iin th
the Fi
Figure gives
i a relationship
l ti hi bbetween
t stock­tank
t k t k oil
il
gravity and molecular weight. The graph is not as accurate as Equation:

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 23

Ratios of reservoir
reservoir‐‐gas specific gravity to surface‐
surface‐gas specific gravity
May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 24
Formation Volume Factor of Wet Gas
The equations for the formation volume factor of gas, these two Equations only
pp y to dry
apply yggases.

These equations are not applicable to wet gases


gases.

However,
oweve , itt iss important
po ta t to be able
ab e to calculate
ca cu ate the
t e reservoir
ese vo volume
vo u e o
of wet gas
associated with quantities of surface liquid and gas.

The formation volume factor of a wet gas is defined as the volume of reservoir
gas required to produce one stock­tank barrel of liquid at the surface.

By definition:

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 25

Bwg Determination
Two methods for estimating formation volume factors for wet gases ,
only one will be discussed here.

Surface Compositions Known:

If the compositions
p of the p
produced ggases and liquid
q are known and the
producing gas­oil ratios are available, the composition of the reservoir
gas may be calculated as in stated previously (Example XX).

The results of such a recombination calculation can be used to calculate


the formation volume factor.
factor

The volume of gas in the reservoir and the volume of stock­tank liquid
must be calculated.

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 26
EXAMPLE X-4:

Calculate wet gas formation volume factor at reservoir conditions of 2360


psig and 204 oF.
F
May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 27

Solution
Solution:

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 28
Solution

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 29

Solution

May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 30
May 4, 2010 Reservoir Fluids Properties - PTE232, Dr. Adel Salem Lectures 16 & 17: 31

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