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Lectures 1- 4_Reservoir Fluid Properties
Lectures 1- 4_Reservoir Fluid Properties
Lectures 3 - 4:
4
PProblems
bl RRelated
l d to Crude
C d Oil CComposition:
ii
H2S Problems,
Scale Problems,
Organic Deposition and Control, and
Summary and Appendix
March 2010
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 36
1. Hydrogen Sulfide Gas Problems
Hydrogen sulfide is a colourless,
colourless flammable,
flammable poisonous gas that
smells like rotten eggs.
Hydrogen
y g sulfide ((or hydrogen
y g sulphide)
p ) is the chemical
compound with the formula H2S. This colorless, toxic,
flammable gas is partially responsible for the foul odor of rotten
eggs and flatulence. It often results from the bacterial break
down of sulfur‐containing organic matter in the absence
of oxygen, such as in swamps and sewers (anaerobic digestion).
It also occurs in volcanic gases,
gases natural gas and some well waters.
waters
The body produces small amounts of H2S and uses it as a
signaling molecule.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 37
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 38
1.2. Toxicity of H2S
¾ Hydrogen sulfide is considered a broad‐spectrum poison
poison, meaning that it can
poison several different systems in the body, although the nervous system is
most affected. The toxicity of H2S is comparable with that of hydrogen cyanide.
It forms a complex bond with iron in the mitochondrial cytochrome enzymes,
thereby blocking oxygen from binding and stopping cellular respiration. Since
hydrogen sulfide occurs naturally in the environment and the gut, enzymes
exist in the body capable of detoxifying it by oxidation to (harmless)
sulfate Hence,
sulfate. Hence low levels of sulfide may be tolerated indefinitely.
indefinitely
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 40
2. Mineral Scale
Mineral scales (subsequently referred to as scales) are inorganic solids
precipitated from water and subsequently deposited. Scales are a common form
of formation damage and blockages or restrictions to perforations
perforations, screens
screens, liners
or tubing
tubing.
Like most production chemistry problems, they pose a safety issue through loss
of operability of check valves, safety valves or, in severe cases, tree valves. To
predict the scaling potential of reservoir aquifer water
water, a representative water
sample is required.
This requires that an appraisal or exploration well deliberately produces water,
and that any contaminants such as completion or drilling fluids are also analyzed
so that interference is backed out.
The water chemistry of hydrocarbon bearing reservoirs is highly variable, ranging
f
from very llow iion strength
t th tto high
hi h salinity
li it bbrines
i containing
t i i a wide
id range off
various ions.
Prevention and mitigation:
1. Mitigate or prevent scale in formation by using formation water instead of
seawater,
2. Scale Inhibitor
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 41
Scales
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 42
2.1. Scale Types
The equilibrium that existed for so long is then upset on a geologically
diminutive timescale during the production phase of the field
development.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 43
¾ Calcite (CaCO3)
– Formed due to the presence of calcium ions
and bicarbonate ions in the produced water
– Pressure changes may cause precipitation
¾ Barite (BaSO4)
– Generally formed when there is co-
production of formation water (Ba2+) and
injection water (SO4-)
Barite
Anhydrite
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 44
Barium sulphate scale
deposition
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 45
SScale‐inhibitor
l i hibit chemicals
h i l may b be continuously
ti l iinjected
j t d th
through
haddownhole
h l
injection point in the completion, or periodic squeeze treatments may be
undertaken to place the inhibitor in the reservoir matrix for subsequent
commingling with produced fluids
fluids.
Some scale‐inhibitor systems integrate scale inhibitors and fracture
treatments into one step,
step which guarantees that the entire well is treated
with scale inhibitor. In this type of treatment, a high‐efficiency scale inhibitor
is pumped into the matrix surrounding the fracture face during leakoff.
It adsorbs to the matrix during pumping until the fracture begins to produce
water. As water passes through the inhibitor‐adsorbed zone, it dissolves
sufficient inhibitor to prevent scale deposition
deposition. The inhibitor is better placed
than in a conventional scale‐inhibitor squeeze, which reduces the
retreatment cost and improves production.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 46
Downhole chemical injection examples
Downhole chemical
injection examples
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 47
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 48
Scale Inhibitors
SScale
l inhibitors
i hibit preventt undesirable
d i bl buildup
b ild on your equipment.
i t Appropriate
A i t
treatment by NCP Scale Inhibitors will extend the life of industrial equipment
and provide optimal process conditions.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 49
Biocides
Combination Scale & Corrosion Inhibitors
Corrosion Inhibitors
Emulsion Breakers
Encapsulated Scale & Corrosion Inhibitors
Foamers & Foam Controll
H2S Scavengers
Hydrate Inhibitors
Paraffin Control & Asphaltene Inhibitors
Paraffin Inhibitors
Scale Inhibitors
Scale Inhibitor Squeezes
Surfactants
Water Clarifiers
Calcium Naphthenate Inhibitors
Hydrotesting & Subsea Preservation
Drag Reducers
Example:
http://www.champ‐tech.com/onec_prod_scal.asp for scale inhibitor
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 50
2.3.2.Reason for Scale Control: Tubing Damage
• Tubing ID Restriction
¾ C
Constrained
t i d production
d ti Scale Deposition in Tubing
¾ Often layered with scale, wax, asphaltene, FeS - Layer
etc.
B S04 Layer
BaS0 L
• Completion components
blocked with scale Under-deposit Corrosion
¾ Gas
G Lift MMandrels
d l
¾ SSSV Asphaltene layer
¾ Nipples, ..etc
H2S Pitting
g Corrosion
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 51
Scale
S
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 52
3. Deposition within Porous Formation
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 53
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 54
Organic Deposits
Organic deposits are heavy hydrocarbons (paraffins or asphaltenes) that
precipitate as the pressure or temperature is reduced.
Th are typically
They t i ll located
l t d in
i the
th tubing,
t bi perforations
f ti or formation.
f ti
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 55
Organic Deposits ,…
3 Tar:
3.
Tar is simply an asphaltene or other heavy‐
heavy‐oil deposit. It cannot be
removed by acid or mutual solvents. Removal requires dispersion in an
aromatic solvent, and energy is typically necessary to achieve removal.
4 Resins :
4.
(Peptizing agent, dissolved in oil, help suspend asphaltene in oil)
5. Wax:
A combined deposit of paraffins, asphaltenes, resins, mixed with clays,
sand,
d and
dddebris
b i (di
(dissolved
l d iin oil)
il)
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 56
3.2. Asphaltenes
¾ Organic materials consisting of aromatic and naphthenic ring compounds
containing nitrogen, sulfur and oxygen molecules. The asphaltene fraction of
crude is defined as the organic part of the oil that is not soluble in straight‐chain
solvents such as pentane or heptane.
¾ For example, in matrix acidizing, iron ions in solution favor the precipitation of
asphaltene deposits.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 57
Asphaltenes, …
Asphaltene: Facts
¾ Aromatic/Napthenic based hydrocarbons
¾ Polar ( Simply +ve
ve and –ve
ve end charged)
¾ Can contain elements (O, S, N) and metals(Fe, Cu, Ni)
¾ Amorphous (no structure)
¾ Insoluble in crude oil
¾ Not the same as paraffin
¾ Present throughout the oil and gas Industry
Asphaltene Precipitation
Generally totally UNRELATED to the amount of asphaltene that is
physically in the oil and is commonly motivated by:
¾ Reductions in temperature and pressure
¾ Contact with h lean
l or rich
h hydrocarbon
h d b gases andd CO2
¾ Contact with non‐equilibrium oils
¾ Contact with various acids (pH shift)
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 58
Example of an asphaltene molecule structure.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 59
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 60
Asphaltene Deposition Environment Example.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 61
Asphalt Tars
Aggregate of condensed Polycycllic Aromatic ring
Molecular weight
6 to 20 aromatic rings
Specific gravity
gra it = 1.2
12
Black, sticky to hard solid
Colloidally dispersed in crude oils
Burns with black sootyy flame
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 62
3.2.2. Factors Governing Asphaltene Deposition
¾ SSolubility
l bilit and
dD Deposition
iti
¾ Low molecular‐weight solvents
¾ L surface
Low f ttension
i organic i liquids
li id
¾ Iron contamination
¾ pH effects
ff
¾ Pressure
¾ Addition of paraffinic crudes
¾ Injection of cold fluids or hot oiling
¾ Flow through porous media
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 63
Asphaltene Deposits
¾H d coal‐like
¾Hard l lik ddeposits
it
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 64
3.3. Paraffin Deposition Mechanisms
¾P
Precipitated
i it t d paraffins
ffi are attracted
tt t d tot crystal
t l growth
th sites
it ((and
d
other paraffins)
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 65
Paraffin Precipitation
p
Paraffin is most often precipitated by a temperature change. The temperature
point where the lattice of the paraffin begins to grow is called the cloud point.
Once a crude oil reaches the cloud point
point, paraffin crystals establish a nucleation
site to which more paraffin crystals will adhere.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 66
3.3.2. Factors Governing Paraffin Deposition
1. Temperature
p ,
2. Ratio of solvent to solute,
3
3. Pressure exerted on the solution,
solution
4. Amount of gas in solution,
5. Presence of water, sand and other organic compounds,
6. p
Action of resins and asphaltenes, and
7. Surface roughness.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 67
Paraffin inhibitors must be introduced into the oil before the oil cools
to its cloud point.
point In additional, asphaltene composition should be
determined before treatment because it can reduce the
effectiveness of the paraffin inhibitor.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 68
Paraffin Control
A set of techniques used to prevent or considerably reduce paraffin
deposition.
P
Paraffin
ffi control
t l might
i ht iinvolve
l ththe ffollowing
ll i options:
ti
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 69
A downhole tool, generally run on slikline, used to remove paraffin and soft
wax deposits from the internal wall of production tubulars and completion
equipment.
equipment
Chemical dissolvers can also be effective. Aromatic solvents such as xylene and
toluene can be highly effective and will also remove wax deposits. Xylene and
toluene are toxic and have a low flash point (xylene 821 F, toluene 431 F).
Some of the dissolvers will adsorb onto the asphaltene deposits, effectively
increasing the deposit volume, but also considerably softening it for easier
removal.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 70
4. Characteristics of Organic Deposits
Paraffins Asphaltenes
• Precipitate upon cooling and • Destabilized by drastic
pressure reduction
d i temperature changes, low pH or
high pH fluids and Ferric ions
ions.
• Waxy, may be tacky or brittle.
brittle
• Black sticky
sticky‐‐to
to‐‐hard solid or
• Burn with a clean flame slushy mass.
mass.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 72
Sludge
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 73
6. Summary
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 74
7. Appendix and Case Studies : Lecture 4
1 Th
1. The contents
t t for
f the
th Course
C in
i the
th Curriculum
C i l off the
th
faculty, English and Arabic,
2. Example of Scale inhibitors material [Gyptron®] and
accepta Products.
3. Example of corrosion inhibitors material [Cortron® ]
p
from Champion Technologies
g Company.
p y
4. Smart Pigs ‐ application project on 9‐mile pipeline
systems
5. dbrSOLIDS software brochure: Predicting precipitation
points; Schlumberger.
Schlumberger
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 75
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 76
2. In The Arabic Curriculum
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 77
Proposed References
1
1. Oskui Reza : “Petroleum
Oskui, Petroleum Fluid Properties
Properties,” Core Laboratories,
Laboratories Western Atlas International,
International
1993.
2. McCain, W. D. : “The Properties of Petroleum Fluids, 2nd Edition,” Penn well Publishing
Company Tulsa
Company, Tulsa, Oklahoma
Oklahoma, 1990
1990.
3. Burcik, E. J. : “Properties of Petroleum Reservoir Fluids,” International Human Resources
Development Corporation (IHRDC), Boston, 1979.
4
4. Pedersen
Pedersen, K K. SS., and Christensen
Christensen, P
P. LL. : “Phase
Phase Behavior of Petroleum Reservoir Fluids
Fluids,” CRC
Press, Taylor & Francis Group, Boca Raton, 2007.
5. Danesh, Ali, : “PVT and Phase Behaviour of Petroleum Reservoir Fluids,” Elsevier, 1998.
6
6. Ahmed Tarek : “Hydrocarbon Phase Behavior
Ahmed, Behavior,”” Gulf Publishing Company
Company, Houston
Houston, Texas
Texas,
1989.
7. Ahmed, Tarek : “Equations of State and PVT Analysis, Applications for Improved Reservoir
Modeling ” Gulf Publishing Company
Modeling, Company, Houston
Houston, Texas
Texas, 2007
2007.
8. rd
Ahmed, Tarek : “Reservoir Engineering, Handbook, 3 Edition,” Elsevier, 2006.
9. Ahmed, Tarek : “Reservoir Engineering, Handbook, 2nd Edition,” Butterworth‐Heinemann, a
member of the Reed Elsevier groupgroup, 2001
2001.
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 78
Thanks For Your
Attention
February 22, 2010 Reservoir Fluids Properties ‐ PTE232, Dr. Adel Salem Lectures 1 ‐ 4: Page: 79