1.

SiCl4  4H2 O  H4 SiO4  4HCl

PCl5  4H2 O  H3PO4  5HCl
BCl3  3H2 O  B  OH3  3HCl

2. Br Br

Br NH3 NH3 Cl
IV IV
Pt Pt and more stereo isomers are possible.
NH3 NH3
Cl Cl
Cl Br
(Optically active) (Optically inactive)
cis trans

3. SiH4  4H2 O 
 SiO2 .2H2 O  4H2
2Al  2NaOH  2H2 O  2NaAlO2  3H2
Zn  H2 SO4  ZnSO4  H2
XeF6  3H2O  XeO3  6HF

6. B.O. of H2 = I
1
B.O. of H2 
2

7. With NH3, CH3NH2 and (CH3)2NH, (BH2)(BH2L2) is formed.

9. Ag+, Pb2+ and Bi3+ form corresponding thiosulphate.

10. P4  3NaOH  3H2 O  3NaH2PO2  PH3


4Na2 SO3   3Na2 SO4  Na2S

4H3PO3   3H3PO4  PH3

11. Due to maximum 1, 3-diaxial interaction.

12. O O
H C H
O O (highly stable anion).
13. OH OH
Br Br
Br H O
2 2
   CO2

COOH Br

14.

OH I CF 3 
 CF3  HOI  CHF3  IO

15. (A) SO 3H HO 3S



 


HO 3S SO 3H
(B) Due to tautomerism the product will become racemic mixture.
(C) CH3 CH3
H3C CH3
H Br Br H
C C  
H H Br H H Br

CH3 CH3
16. All are stronger than carbonic acid.

17. O O

 CH3 3 C C OCH3 OH  CH3 3 C C O  CH3 OH

20. 1, 2-addition does not yield syn-brominated product.

3R
21. CV  (for monoatomic gas)
2
We know q  E  W
 q
q  nCV  T     
 2
q
nT 
2CV
q q 3R
C    2CV  2   3R
nT q / 2CV 2

22.
M  
O 2  Metallic oxide O2  
80 gm 20 gm 100 gm
No. of equivalents of M = no. of equivalents of O2
 80 20
 
E 8
80  8
E   32
20

24. pH of aqueous solution of salt of weak acid and weak base is given by
1
pH  7  pK a  pK b 
2

25. H2 and O2 are produced at cathode and anode respectively.

At cathode:
2H2 O  2e  H2  2OH
2F 1 mol
At anode:
2H2 O  O2  4H  4e
1
mol 2F
2
Total volume of gases = 22.4 L H2
+11.2 L O2
33.6 L

26. s-orbital is spherically symmetrical.

30. Due to strong H-bond between acetone and chloroform, vapour pressure is less than that of ideal
solution.