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BG00420000 en-US A.002.1 2015-09-09

Factory filled oils - lubricants and


coolants for underground rigs;
Normal conditions
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

WARNING
IGNORING INSTRUCTIONS HAZARD!
To avoid death or injury you MUST read, understand and follow
operator's and maintenance manuals before installing, inspecting,
operating, servicing, testing, cleaning, transporting, storing,
dismantling or disposing of the product or a part or accessory of the
product. Keep this publication for future reference.

Copyright © Sandvik
ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

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Copyright © Sandvik
ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

Table of Contents

1 General ...........................................................................7
1.1 Safety instruction ................................................................................. 7
1.2 Standard first filling table .................................................................... 7

2 Motor oil ......................................................................... 9


2.1 Motor oil .................................................................................................11

3 Gearbox ..........................................................................31
3.1 Gearbox ................................................................................................. 33

4 Axles ...............................................................................41
4.1 Axles ...................................................................................................... 43

5 Hydraulics and hydrostatic transmission ...................63


5.1 Hydraulics and hydrostatic transmission .......................................... 65

6 Compressor ................................................................... 81
6.1 Technical data sheet .............................................................................81
6.2 Compressor ...........................................................................................83

7 Shank lubrication .......................................................... 99


7.1 Shank lubrication ..................................................................................101

8 Torque and rotation mechanisms ................................111


8.1 Torque and rotation mechanisms ....................................................... 113

9 Coolant ...........................................................................123
9.1 Coolant .................................................................................................. 125

10 Common grease for boom and carrier ........................131


10.1 Common grease for boom and carrier ............................................... 133

11 Air conditioner refrigerant ............................................143


11.1 Air conditioner refrigerant ................................................................... 145

12 Air conditioner oil ......................................................... 157


12.1 Air conditioner oil ................................................................................. 159

Copyright © Sandvik
ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

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Copyright © Sandvik
ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

1 GENERAL
1.1 Safety instruction
WARNING! HEALTH AND ENVIRONMENTAL HAZARD!
Skin contact and inhalation of vapours when handling fluids could
cause damage to human health.
Incorrect disposal of fluids and greases could cause damage to the
environment.
Use personal protective equipment when handling fluids and
greases, and dispose of all fluids and greases in accordance with
local regulations.

1.2 Standard first filling table


For more detailed oil and fluid recommendations, refer to the section
"Lubricants and capacities" in the maintenance manual or instruction
"Lubricant and coolant recommendations" (optional instruction).

Oil type Purpose of use


Shell Rimula R5 LE 10W-40 Motor oil
Shell Spirax S1 ATF TASA Gearbox
Shell Spirax S4 TXM Axle
Shell Spirax S2 ALS 90 Axle
Shell Naturelle HF-E 46 Hydraulics
Shell Naturelle HF-E 68 Hydraulics
Shell Tellus S2 V 68 Hydraulics, Hydrostatic transmission
Shell Corena S2 R 46 Compressor
Shell Air Tool Oil S2 A 100 Shank lubrication
Shell Spirax S3 AX 80W-90 Torque and rotation mechanisms
Univar Carcoolant 774C Coolant
Shell Gadus S2 V220 2 Common grease for boom and carrier
Genetron 134a Air conditioner refrigerant
Sanden SP-10 / SP-20 Air conditioner oil

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Normal conditions

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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

2 MOTOR OIL

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Normal conditions

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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

2.1 Motor oil

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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING

1.1 Product Identifier

Material Name : Shell Rimula R5 LE 10W-40


Product Code : 001D7308

1.2 Relevant identified uses of the substance or mixture and uses advised against

Product Use : Engine oil.

Uses Advised Against : This product must not be used in applications other than the
above without first seeking the advice of the supplier.

1.3 Details of the Supplier of the safety data sheet

Manufacturer/Supplier : Shell Deutschland Oil GmbH


Suhrenkamp 71-77
D-22335 Hamburg

Telephone : (+49) 40 6324-6255


Fax : (+49) 40 6321-051
Email Contact for : If you have any enquiries about the content of this SDS please
Safety Data Sheet email lubricantSDS@shell.com

1.4 Emergency Telephone Number

: (+49) 30 3068 6790 (Giftnotruf Berlin)

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

1999/45/EC
Hazard Characteristics R-phrase(s)
Not classified as dangerous under EC criteria.;

2.2 Label Elements

Labeling according to Directive 1999/45/EC

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

EC Symbols : No Hazard Symbol required

EC Classification : Not classified as dangerous under EC criteria.


EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.

2.3 Other Hazards

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.

Safety Hazards : Not classified as flammable but will burn.

Environmental Hazards : Not classified as dangerous for the environment.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substance

Material Name : Not applicable.

3.2 Mixtures

Mixture Description : Highly refined mineral oils and additives.

Hazardous Components

Classification of components according to Regulation (EC) No 1272/2008

Chemical Name CAS No. EC Number REACH Registration Conc.


No.
Zinc dialkyl 84605-29-8 283-392-8 01-2119493626-26 1,00 - 2,40%
dithiophosphate
Interchangeable low * * * 0,00 - 90,00%
viscosity base oil
(<20,5 cSt @40°C) *

Chemical Name Hazard Class & Category Hazard Statement


Zinc dialkyl Skin Corr., 2; Eye Dam., 1; Aquatic H315; H318; H411;
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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

dithiophosphate Chronic, 2;
Interchangeable low Asp. Tox., 1; H304;
viscosity base oil
(<20,5 cSt @40°C) *

Classification of components according to 67/548/EEC

Chemical Name CAS No. EC REACH Symbol(s) R-phrase(s) Conc.


Number Registration
No.
Zinc dialkyl 84605-29-8 283-392-8 01- Xi, N R38; R41; 1,00 -
dithiophosphate 2119493626- R51/53 2,40%
26

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346.

Refer to Ch 16 for full text of R- and H- phrases.

* contains one or more of the following CAS-numbers (REACH


registration numbers): 64742-53-6 (01-2119480375-34), 64742-
54-7 (01-2119484627-25), 64742-55-8 (01-2119487077-29),
64742-56-9 (01-2119480132-48), 64742-65-0 (01-2119471299-
27), 68037-01-4 (01-2119486452-34), 72623-86-0 (01-
2119474878-16), 72623-87-1 (01-2119474889-13), 8042-47-5
(01-2119487078-27), 848301-69-9 (01-0000020164-80).

This mixture does not contain any REACH registered


substances that are assessed to be a PBT or a vPvB.

SECTION 4. FIRST AID MEASURES

4.1 Description of First Aid Measures

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

are swallowed, however, get medical advice.


Self-protection of the first : When administering first aid, ensure that you are wearing the
aider appropriate personal protective equipment according to the
incident, injury and surroundings.
4.2 Most important : Oil acne/folliculitis signs and symptoms may include formation
symptoms and effects, of black pustules and spots on the skin of exposed areas.
both acute and delayed Ingestion may result in nausea, vomiting and/or diarrhoea.
4.3 Indication of any : Notes to doctor/physician:
immediate medical Treat symptomatically.
attention and special
treatment needed

SECTION 5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

5.1 Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
5.2 Special hazards : Hazardous combustion products may include: A complex
arising from the mixture of airborne solid and liquid particulates and gases
substance or mixture (smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
5.3 Advice for firefighters : Proper protective equipment including chemical resistant
gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

SECTION 6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. Observe the relevant local and
international regulations.

6.1 Personal Precautions, : 6.1.1 For non emergency personnel: Avoid contact with skin
Protective Equipment and and eyes.
Emergency Procedures
6.1.2 For emergency responders: Avoid contact with skin and
eyes.
6.2 Environmental : Use appropriate containment to avoid environmental
Precautions contamination. Prevent from spreading or entering drains,
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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

ditches or rivers by using sand, earth, or other appropriate


barriers.
6.3 Methods and Material : Slippery when spilt. Avoid accidents, clean up immediately.
for Containment and Prevent from spreading by making a barrier with sand, earth or
Cleaning Up other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
6.4 Reference to other : For guidance on selection of personal protective equipment
sections see Chapter 8 of this Material Safety Data Sheet. For guidance
on disposal of spilled material see Chapter 13 of this Material
Safety Data Sheet.

SECTION 7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Use the information in this data
sheet as input to a risk assessment of local circumstances to
help determine appropriate controls for safe handling, storage
and disposal of this material.
7.1 Precautions for Safe : Avoid prolonged or repeated contact with skin. Avoid inhaling
Handling vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used. Properly dispose of any contaminated rags or
cleaning materials in order to prevent fires. Keep container
tightly closed and in a cool, well-ventilated place. Use properly
labelled and closeable containers.
Product Transfer : This material has the potential to be a static accumulator.
Proper grounding and bonding procedures should be used
during all bulk transfer operations.
7.2 Conditions for safe : Store at ambient temperature.
storage, including any
incompatibilities
Refer to section 15 for any additional specific legislation
covering the packaging and storage of this product.
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
7.3 Specific end use(s) : Not applicable
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.
Storage class according to TRGS 510: 10
Fire hazard classification: B
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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this
document, it is provided for information only.

8.1 Control Parameters

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral ACGIH TWA(Inhala 5 mg/m3
ble fraction.)

Biological Exposure Index (BEI)


No biological limit allocated.

PNEC related information : Data not available

Monitoring Methods : Monitoring of the concentration of substances in the breathing


zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate. Validated exposure measurement methods
should be applied by a competent person and samples
analysed by an accredited laboratory. Examples of sources of
recommended exposure measurement methods are given
below or contact the supplier. Further national methods may be
available.

National Institute of Occupational Safety and Health (NIOSH),


USA: Manual of Analytical Methods http://www.cdc.gov/niosh/

Occupational Safety and Health Administration (OSHA), USA:


Sampling and Analytical Methods http://www.osha.gov/

Health and Safety Executive (HSE), UK: Methods for the


Determination of Hazardous Substances
http://www.hse.gov.uk/

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

Institut für Arbeitsschutz Deutschen Gesetzlichen


Unfallversicherung (IFA), Germany.
http://www.dguv.de/inhalt/index.jsp

L'Institut National de Recherche et de Securité, (INRS), France


http://www.inrs.fr/accueil

8.2 Exposure Controls


General Information : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.

Define procedures for safe handling and maintenance of


controls. Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product. Ensure appropriate selection, testing and
maintenance of equipment used to control exposure, e.g.
personal protective equipment, local exhaust ventilation. Drain
down system prior to equipment break-in or maintenance.
Retain drain downs in sealed storage pending disposal or for
subsequent recycle. Always observe good personal hygiene
measures, such as washing hands after handling the material
and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove
contaminants. Discard contaminated clothing and footwear that
cannot be cleaned. Practice good housekeeping.

Occupational Exposure Controls


Personal Protective : The provided information is made in consideration of the PPE
Equipment directive (Council Directive 89/686/EEC) and the CEN
European Committee for Standardisation (CEN) standards.
Personal protective equipment (PPE) should meet
recommended national standards. Check with PPE suppliers.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

suitable chemical protection: PVC, neoprene or nitrile rubber


gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
For continuous contact we recommend gloves with
breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same, but
recognise that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time may be acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Body protection : Skin protection not ordinarily required beyond standard issue
work clothes.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Thermal Hazards : Not applicable.

Environmental Exposure Controls


Environmental exposure : Minimise release to the environment. An environmental
control measures assessment must be made to ensure compliance with local
environmental legislation. Information on accidental release
measures are to be found in section 6.

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties


Appearance : Amber. Liquid at room temperature.
Odour : Slight hydrocarbon.
Odour threshold : Data not available
pH : Not applicable.
Initial Boiling Point and : > 280 °C / 536 °F estimated value(s)
Boiling Range
Pour point : Typical -36 °C / -33 °F
Flash point : Typical 221 °C / 430 °F (COC)
Upper / lower Flammability : Typical 1 - 10 %(V) (based on mineral oil)
or Explosion limits
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0,5 Pa at 20 °C / 68 °F (estimated value(s))
Relative Density : Typical 0,866 at 15 °C / 59 °F
Density : Typical 866 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
Solubility in other solvents : Data not available

n-octanol/water partition : > 6 (based on information on similar products)


coefficient (log Pow)
Dynamic viscosity : Data not available
Kinematic viscosity : Typical 96,5 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available
Decomposition : Data not available
Temperature
Flammability : Data not available
Oxidizing Properties : Data not available

Explosive Properties : Not classified

9.2 Other Information

Other Information : not a VOC


Volatile organic carbon : 0%
content

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.
10.2 Chemical stability : No hazardous reaction is expected when handled and stored
according to provisions.
10.3 Possibility of :
Hazardous Reactions Reacts with strong oxidising agents.
10.4 Conditions to Avoid : Extremes of temperature and direct sunlight.
10.5 Incompatible : Strong oxidising agents.
Materials
10.6 Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on Toxicological effects


Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).
Likely Routes of : Skin and eye contact are the primary routes of exposure
Exposure although exposure may occur following accidental ingestion.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin corrosion/irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Serious eye : Expected to be slightly irritating.
damage/irritation
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Respiratory or skin : For respiratory and skin sensitisation: Not expected to be a
sensitisation sensitiser.
Aspiration Hazard : Not considered an aspiration hazard.

Germ cell mutagenicity : Not considered a mutagenic hazard.


Carcinogenicity : Not expected to be carcinogenic. Product contains mineral oils
of types shown to be non-carcinogenic in animal skin-painting

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

studies. Highly refined mineral oils are not classified as


carcinogenic by the International Agency for Research on
Cancer (IARC).

Material : Carcinogenicity Classification


Highly refined mineral oil : ACGIH Group A4: Not classifiable as a human carcinogen.
(IP346 <3%)
Highly refined mineral oil : IARC 3: Not classifiable as to carcinogenicity to humans.
(IP346 <3%)
Highly refined mineral oil : GHS / CLP: No carcinogenicity classification
(IP346 <3%)

Reproductive and : Not expected to be a hazard.


Developmental Toxicity

Summary on evaluation of the CMR properties


Carcinogenicity : This product does not meet the criteria for classification in
categories 1A/1B.,
Mutagenicity : This product does not meet the criteria for classification in
categories 1A/1B.
Reproductive Toxicity : This product does not meet the criteria for classification in
(fertility) categories 1A/1B.

Specific target organ : Not expected to be a hazard.


toxicity - single exposure
Specific target organ : Not expected to be a hazard.
toxicity - repeated
exposure
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Classifications by other authorities under varying regulatory
frameworks may exist.

SECTION 12. ECOLOGICAL INFORMATION

Basis for Assessment : Ecotoxicological data have not been determined specifically for
this product. Information given is based on a knowledge of the
components and the ecotoxicology of similar products. Unless
indicated otherwise, the data presented is representative of the
product as a whole, rather than for individual component(s).
12.1 Toxicity
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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Rimula R5 LE 10W-40
Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract. Mineral oil is not expected to cause any chronic effects
to aquatic organisms at concentrations less than 1 mg/l.

12.2 Persistence and : Expected to be not readily biodegradable. Major constituents


degradability are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
12.3 Bioaccumulative : Contains components with the potential to bioaccumulate.
Potential

12.4 Mobility in Soil : Liquid under most environmental conditions. If it enters soil, it
will adsorb to soil particles and will not be mobile. Floats on
water.

12.5 Result of PBT and : This mixture does not contain any REACH registered
vPvB assesment substances that are assessed to be a PBT or a vPvB.

12.6 Other Adverse : Product is a mixture of non-volatile components, which are not
Effects expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste Treatment Methods

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 02 05 mineral-based non-
chlorinated engine, gear and lubricating oils. Classification of
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Version 1.0
Effective Date 17.10.2012
Regulation 1907/2006/EC
Safety Data Sheet

waste is always the responsibility of the end user.

SECTION 14. TRANSPORT INFORMATION

Land transport (ADR/RID):


ADR
This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

RID
This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

Inland waterways transport (ADN):


This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.
CDNI Inland Water Waste : 3411 Engine oil
Agreement

Sea transport (IMDG Code):


This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

Air transport (IATA):


This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution Category : Not applicable.
Ship Type : Not applicable.
Product Name : Not applicable.
Special Precaution : Not applicable.

Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.

SECTION 15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
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15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Other regulatory Information
Authorisations and/or : Product is not subject to Authorisation under REACh.
restrictions on use

Recommended : This product must not be used in applications other than the
Restrictions on Use above without first seeking the advice of the supplier.
(Advice Against)

Chemical Inventory Status

EINECS : All components


listed or polymer
exempt.
TSCA : All components
listed.

National Legislation

Water Pollution Class : WGK 2 - hazard to waters (appendix 2, VwVwS, preparations).

Other Information : Technische Anleitung Luft: Product not listed by name.


Observe section 5.2.5 in connection with section 5.4.9
15.2 Chemical Safety : No Chemical Safety Assessment has been carried out for this
Assessment substance/mixture by the supplier.

SECTION 16. OTHER INFORMATION

R-phrase(s)
Not classified.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

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Safety Data Sheet

CLP Hazard Statements


H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.

H411 Toxic to aquatic life with long lasting effects.

Additional Information : No Exposure Scenario annex is attached to this safety data


sheet. It is a non-classified mixture containing hazardous
substances as detailed in Section 3; relevant information from
Exposure Scenarios for the hazardous substances contained
have been integrated into the core sections 1-16 of this SDS.
Other Information

Abbreviations and : Acute Tox. = Acute toxicity


Acronyms Asp. Tox. = Aspiration hazard
Aquatic Acute = Acute hazards to the aquatic environment
Aquatic Chronic = Hazardous to the aquatic environment -
Long-term Hazard
Eye Dam. = Serious eye damage/eye irritation
Flam. Liq. = Flammable liquids
Skin Corr. = Skin corrosion/irritation
Skin Sens. = Skin sensitizer
STOT SE = Specific target organ toxicity - single exposure
STOT RE = Specific target organ toxicity - repeated exposure

ACGIH = American Conference of Governmental Industrial


Hygienists
ADR = European Agreement concerning the International
Carriage of Dangerous Goods by Road
AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits
BTEX = Benzene, Toluene, Ethylbenzene, Xylenes
CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches Institut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission

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Safety Data Sheet

EC50 = Effective Concentration fifty


ECETOC = European Center on Ecotoxicology and Toxicology
Of Chemicals
ECHA = European Chemicals Agency
EH40 WEL = UK Environmental Hygiene Guidance Note 40 -
Workplace Exposure Limit (GB only)
EINECS = The European Inventory of Existing Commercial
Chemical Substances
EL50 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
IMDG = International Maritime Dangerous Goods
INV = Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the
determination of polycyclic aromatics DMSO-extractables
KECI = Korea Existing Chemicals Inventory
LC50 = Lethal Concentration fifty
LD50 = Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LL50 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No
Observed Effect Level
OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of
Dangerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act

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TWA = Time-Weighted Average


vPvB = very Persistent and very Bioaccumulative

SDS Distribution : The information in this document should be made available to


all who may handle the product.
SDS Version Number : 1.0

SDS Effective Date : 17.10.2012

SDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
SDS Regulation : Regulation 1907/2006/EC as amended by Regulation (EU)
453/2010
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

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3 GEARBOX

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3.1 Name
Previous Gearbox
: Shell Donax TM

Shell S1 ATF TASA


Quality Type A Suffix A Automatic Transmission and Hydraulic
Fluid
Shell S1 ATF TASA is a high quality automotive transmission, power steering and
hydraulic oil mainly used for heavy-duty vehicles working in an 'off-road'
environment.

Applications Specification and Approvals


• Powershift and Industrial torque convertors
Meets the requirements of:
• Applications calling for a GM Type 'A' Suffix 'A' General Motors Type 'A' Suffix 'A'
performance fluid Mercedes-Benz Sheet 236.2
• Automatic transmission and power steering
fluid used in heavy trucks and off-road
vehicles and older passenger cars
Advice
Advice on applications not covered in this leaflet
• Hydraulic oil for certain off-road applications may be obtained from your Shell Representative.

Performance Features and Benefits Health and Safety


Guidance on Health and Safety are available on
• Oxidation & thermal stability the appropriate Material Safety Data Sheet, which
• Dispersancy can be obtained from your Shell representative.
Protect the environment
• Friction retention Take used oil to an authorized collection point. Do
• not discharge into drains, soil or water.
Shear stability
• Anti-wear & EP performance

Typical Physical Characteristics


Spirax S1 ATF TASA
Kinematic Viscosity ISO 3104
at 40°C mm2/s 40.0
at 100°C mm2/s 7.5
Viscosity Index ISO 2909 157
Density at 15°C kg/m3 ISO 12185 880
Flash Point COC °C ISO 2592 170
Pour Point °C ISO 3016 -42

These characteristics are typical of current production. Whilst future production will conform
to Shell's specification, variations in these characteristics may occur.

Shell Lubricants – 001D8294 23/02/2010


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Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Spirax S1 ATF TASA


Uses : Transmission oil.
Product Code : 001D8294

Manufacturer/Supplier : Shell Nederland Verkoopmaatschappij B.V.


Rivium Boulevard 156
2909 LK Capelle aan den IJssel
Netherlands

Telephone : (+31) 0900 202 2710


Email Contact for : If you have any enquiries about the content of this MSDS
MSDS please email lubricantSDS@shell.com

Emergency Telephone : +31 (0)10 4313233


Number

2. HAZARDS IDENTIFICATION

EC Classification : Not classified as dangerous under EC criteria.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation Description : Highly refined mineral oils and additives.

Hazardous Components

Chemical Identity CAS EINECS Symbol(s) R-phrase(s) Conc.


Barium alkenyl Xn R20/22 1,00 - 5,00 %
carboxylate
Barium 61790-48-5 263-140-3 Xn, Xi R20/22; 1,00 - 3,00 %
sulphonate R38; R53
Zinc alkyl Xi, N R38; R51/53 1,00 - 2,40 %
dithiophosphate

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
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EC R-phrases.

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Suitable Extinguishing : Foam, water spray or fog. Dry chemical powder, carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.

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7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on


this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral NL OEL TGG 5 mg/m3
[Mist.]
ACGIH TWA 5 mg/m3
[Inhalable
fraction.]

Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
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concentrations to a level which is adequate to protect worker


health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Red. Liquid at room temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.
Initial Boiling Point and : > 280 °C / 536 °F estimated value(s)
Boiling Range
Pour point : Typical -42 °C / -44 °F
Flash point : Typical 170 °C / 338 °F (COC)
Lower / upper Flammability : Typical 1 - 10 %(V) (based on mineral oil)
or Explosion limits
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0,5 Pa at 20 °C / 68 °F (estimated value(s))
Density : Typical 880 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)
Kinematic viscosity : Typical 40 mm2/s at 40 °C / 104 °F

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Vapour density (air=1) : > 1 (estimated value(s))


Evaporation rate (nBuAc=1) : Data not available

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.

12. ECOLOGICAL INFORMATION

Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic

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effects to aquatic organisms at concentrations less than 1 mg/l.


Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 02 05 mineral-based non-
chlorinated engine, gear and lubricating oils. Classification of
waste is always the responsibility of the end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

ADNR
This material is not classified as dangerous under ADNR regulations.

IMDG
This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

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Safety Data Sheet

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Not classified as dangerous under EC criteria.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.
Chemical Inventory Status
EINECS : All components
listed or polymer
exempt.
TSCA : All components
listed.

16. OTHER INFORMATION

R-phrase(s)

Not classified.
R20/22 Harmful by inhalation and if swallowed.
R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R53 May cause long-term adverse effects in the aquatic environment.

MSDS Version Number : 1.0

MSDS Effective Date : 14.12.2010

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

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4 AXLES

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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

This page is intentionally left blank

42 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

4.1 Name
Previous Axles
: Shell Donax TD

Shell Spirax S4 TXM


Premium, SAE 10W-30, Multi-functional Tractor Transmission and
Hydraulic Oil

Premium “universal tractor transmission oils” (UTTO) designed for use in transmissions,
hydraulic systems, oil immersed brakes and other ancillary systems fitted to agricultural
tractors and off-road equipment. Spirax S4 TXM is recognised by leading agricultural
equipment manufacturers and suitable for use in most modern equipment.

Applications
• Agricultural Tractors Transmissions
Spirax S4 TXM has been evaluated against the latest • OEM Recognition
requirements of leading tractor and transmission Spirax S4 TXM has been tested and approved by
manufacturers including John Deere, Massey a wide range of equipment manufacturers.
Ferguson, CNH and ZF.
• Hydraulic Systems Specification and Approvals
Spirax S4 TXM is ideally suited for hydraulic systems
of tractors and ancillary equipment. Spirax S4 TXM API Gear Performance API GL-4
is formulated using specially selected additives and Case New Holland MAT-3525
high quality base oils to provide good low M2C-134 A-D
temperature fluidity and wear protection. FNHA-2-D.201.00
John Deere JDM-J20C
• Oil Immersed Brakes
Massey-Ferguson M1143
Special friction modifying additives are included in
M1145
Spirax S4 TXM to ensure optimum performance of
Volvo WB 101
oil immersed brakes whilst minimising brake noise.
ZF TE-ML 03E, 05F, 06D, 06K,
Spirax S4 TXM is recommended for most wet brake
17E
systems fitted to agricultural tractors and off-highway
Caterpillar TO-2 (obsolete)
construction equipment.
Komatsu recommended for
Warning: Not to be used as an engine oil
use in certain
construction
Performance Features and Benefits equipment
• Enhanced Protection Clark
Excellent anti-oxidation, shear-stability, anti-wear, Recommendations
anti-corrosion and anti-foam characteristics result Spirax S4 TXM is also recommended for use in Case
from the use of the latest additive technology leading equipment where fluids meeting MS 1204, 1206,
to greater reliability and reduced down time thus 1207, 1209 or 1210 are specified.
minimising cost and maximising utilisation. Spirax S4 TXM can be used when a
• Operator Comfort SAE J 306 85W grade is recommended.
The excellent low temperature fluidity of Spirax S4
TXM, results in responsive hydraulic performance, Advice
and smooth gearshift performance, from cold starts Advice on applications not covered in this leaflet
to maximum operating temperatures. Friction may be obtained from your Shell Representative.
modifying additives help create smooth, noise-free
operation of oil immersed brakes.

Shell Lubricants –001D8246 24/02/2010


Page 1 ©
Copyright ofSandvik
2 43 (180)
ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

Health and Safety Protect the environment


Guidance on Health and Safety are available on the Take used oil to an authorized collection point. Do
appropriate Material Safety Data Sheet, which can be not discharge into drains, soil or water.
obtained from your Shell representative.

Typical Physical Characteristics


Spirax S4 TXM
SAE Viscosity grade SAE J 300 10W-30
Kinematic Viscosity ISO 3104
at 40°C mm2/s 60
at 100°C mm2/s 9.4
Viscosity Index ISO 2909 138
Density at 15°C kg/m3 ISO 12185 882
Flash Point COC °C ISO 2592 220
Pour Point °C ISO 3016 -42

These characteristics are typical of current production. Whilst future production will conform to Shell's specification,
variations in these characteristics may occur.

Shell Lubricants –001D8246 24/02/2010


44 (180) CopyrightPage 2 of
© Sandvik 2
ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Spirax S4 TXM


Uses : Transmission oil.
Product Code : 001D8246

Manufacturer/Supplier : Univar OY
Y-tunnus (Company number): 0536122-7
FI-01670
Vanha Nurmijärventie 62 E 28
Vantaa

Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : sds.fi@univareurope.com
MSDS

Emergency Telephone : 09-471 977


Number
Other Information : KT code: 35 lubricants and additivesTOL code: C Industry.

2. HAZARDS IDENTIFICATION

EC Classification : Not classified as dangerous under EC criteria.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation Description : Highly refined mineral oils and additives.

Hazardous Components

Chemical Identity CAS EINECS Symbol(s) R-phrase(s) Conc.


Zinc alkyl 68649-42-3 272-028-3 Xi R38; R52/53 1.00 - 3.00 %
dithiophosphate
Calcium R53 1.00 - 3.00 %
sulphonate

1/7
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 45 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
refined mineral oil.

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Suitable Extinguishing : Foam, water spray or fog. Dry chemical powder, carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or

2/7
Print Date 24.12.2010 MSDS_FI

46 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

other containment material. Reclaim liquid directly or in an


absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on


this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral HTP-ARVOT HTP 8H 5 mg/m3 Known Harmful
[Mist.] Concentration
(Liite 1).
ACGIH TWA 5 mg/m3
[Inhalable
fraction.]

Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
3/7
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 47 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Personal Protective : Personal protective equipment (PPE) should meet


Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Amber. Liquid at room temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.
Initial Boiling Point and : > 280 °C / 536 °F estimated value(s)
Boiling Range
Pour point : Typical -42 °C / -44 °F
Flash point : Typical 220 °C / 428 °F (COC)
Lower / upper Flammability : Typical 1 - 10 %(V) (based on mineral oil)
or Explosion limits
Auto-ignition temperature : > 320 °C / 608 °F

4/7
Print Date 24.12.2010 MSDS_FI

48 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))


Density : Typical 882 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)
Kinematic viscosity : Typical 60 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.

12. ECOLOGICAL INFORMATION

Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.

5/7
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 49 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 02 05 mineral-based non-
chlorinated engine, gear and lubricating oils. Classification of
waste is always the responsibility of the end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

ADNR
This material is not classified as dangerous under ADNR regulations.

IMDG

6/7
Print Date 24.12.2010 MSDS_FI

50 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Not classified as dangerous under EC criteria.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.
Chemical Inventory Status
EINECS : All components
listed or polymer
exempt.
TSCA : All components
listed.

16. OTHER INFORMATION

R-phrase(s)

Not classified.
R38 Irritating to skin.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.

MSDS Version Number : 1.0

MSDS Effective Date : 16.12.2010

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

7/7
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 51 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

52 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

Copyright © Sandvik 53 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Spirax S2 ALS 90


Uses : Transmission oil.
Product Code : 001D8278

Manufacturer/Supplier : Univar OY
Y-tunnus (Company number): 0536122-7
FI-01670
Vanha Nurmijärventie 62 E 28
Vantaa

Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : sds.fi@univareurope.com
MSDS

Emergency Telephone : 09-471 977


Number
Other Information : KT code: 35 lubricants and additivesTOL code: C Industry.

2. HAZARDS IDENTIFICATION

EC Classification : Not classified as dangerous under EC criteria.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation Description : Highly refined mineral oils and additives.

Hazardous Components

Chemical Identity CAS EINECS Symbol(s) R-phrase(s) Conc.


Long-chain alkyl T, C, N R22; R34; 0.10 - 0.24 %
amine R43;
R23/24;
R48/20;
R50/53
1/8
Print Date 24.12.2010 MSDS_FI

54 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
refined mineral oil.

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Suitable Extinguishing : Foam, water spray or fog. Dry chemical powder, carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.

2/8
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 55 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Prevent from spreading by making a barrier with sand, earth or


other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on


this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral HTP-ARVOT HTP 8H 5 mg/m3 Known Harmful
[Mist.] Concentration
(Liite 1).
ACGIH TWA 5 mg/m3
[Inhalable
fraction.]

Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
3/8
Print Date 24.12.2010 MSDS_FI

56 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Amber. Liquid at room temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.
Initial Boiling Point and : > 280 °C / 536 °F estimated value(s)
Boiling Range
Pour point : Typical -18 °C / 0 °F
Flash point : Typical 210 °C / 410 °F (COC)
Lower / upper Flammability : Typical 1 - 10 %(V) (based on mineral oil)
or Explosion limits

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Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Auto-ignition temperature : > 320 °C / 608 °F


Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))
Density : Typical 909 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)
Kinematic viscosity : Typical 155 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.

12. ECOLOGICAL INFORMATION

Ecotoxicological data have not been determined specifically for this product. Information given is

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
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Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

based on a knowledge of the components and the ecotoxicology of similar products.

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 02 05 mineral-based non-
chlorinated engine, gear and lubricating oils. Classification of
waste is always the responsibility of the end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

ADNR
This material is not classified as dangerous under ADNR regulations.

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

IMDG
This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Not classified as dangerous under EC criteria.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.
Chemical Inventory Status
EINECS : All components
listed or polymer
exempt.
TSCA : All components
listed.
Sensitiser not sufficient to : Contains alkylamine. May produce an allergic reaction.
classify

16. OTHER INFORMATION

R-phrase(s)

Not classified.
R22 Harmful if swallowed.
R23/24 Toxic by inhalation and in contact with skin.
R34 Causes burns.
R43 May cause sensitization by skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

MSDS Version Number : 1.0

MSDS Effective Date : 16.12.2010

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
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Factory filled oils - lubricants and coolants for underground rigs;
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Shell Spirax S2 ALS 90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

safety and environmental requirements only. It should not


therefore be construed as guaranteeing any specific property
of the product.

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5 HYDRAULICS AND HYDROSTATIC TRANSMISSION

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Shell Naturelle Fluids HF-E


5.1 Hydraulics and hydrostatic transmission
Environmentally considerate hydraulic
fluids
Shell Naturelle HF-E fluids are advanced hydraulic fluids for use in power
transmission and hydraulic systems. They are biodegradable with a low
ecotoxicity, and are particularly suited for use in environmentally sensitive
areas.
Synthetic esters, blended with specially tailored additive systems, provide
Shell Naturelle Fluids HF-E with a superior balance of lubrication performance
and compatibility with the environment.

Main Applications  Good oxidation resistance


Resists the formation of acidic products
 Heavy-duty hydraulic systems for generated when working at high operating
construction and earth moving equipment temperatures.
 Machine tool hydraulic systems  Optimum wear protection
 Hydrostatic drive gears Effective under all operating conditions,
including low and severe duty situations.
 General industrial control equipment and
hydraulic systems
Specifications, Approvals and
 Moderately rated gearboxes where an
anti-wear hydraulic oil is specified Recommendations
Shell Naturelle HF-E 32, 46 and 68 are
environmentally acceptable hydraulic fluids
Performance Features and Benefits based on synthetic esters and can be used
where ISO 15380 or VDMA 24568 HEES fluids
 Readily biodegradable are specified.
- biodegraded by >60% after 28 days
when tested in OECD 301 B (CO2 Naturelle HF-E 15 is a mixture of synthetic
evolution test) ester and vegetable oil.
 Low ecotoxicity Naturelle HF-E 32 and 46 meet the
- ‘not harmful’ to algae, invertebrates environmental requirements of Swedish
(Daphnia) and fish; EL50/LL50 >100 mg/l Standard SS 15 54 34 and are SP-listed.
when tested as water-accommodated Naturelle HF-E 15, 46 and 68 are on the
fractions in OECD 201, OECD 202 and ‘Positivliste’ and qualify for funding under the
OECD 203 German ‘Market Introduction Programme’ for
 Excellent viscosity/temperature biolubricants.
characteristics Naturelle HF-E has Eaton Vickers M-2950 S
Minimum change of viscosity with variation and I-286 S approval.
in operating temperature, giving true
‘multigrade’ characteristics. The improved anti-wear properties, and
naturally high viscosity index (VI) of Naturelle
 High shear-stability Fluids HF-E, mean that they can often be used
High shear stability ensures effective where ISO 11158 (HM/HV) and DIN 51524
lubrication and efficient system operation. Part 2 or Part 3 (HLP/HVLP) mineral oil
 Excellent corrosion protection hydraulic fluids are specified. However, bulk
Long term protection for common fluid operating temperatures should not be
construction materials, including most allowed to exceed 90°C and optimum fluid life
metals, non-metals and seal materials will be realised if operating temperatures are
such as viton and high nitrile. maintained at approximately 55°C.

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Compatibility with mineral oils and industrial adhesives may be adversely
Shell Naturelle Fluids HF-E is miscible with affected and advice should be sought from the
conventional mineral oil based hydraulic oils in respective manufacturers.
all proportions. However, in order to ensure
that the environmental properties and
performance of Naturelle HF-E are maintained, Health & Safety
the system should be drained and flushed prior
Guidance on Health and Safety are available
to fluid change over.
on the appropriate Material Safety Data Sheet
Owing to the surface wetting properties of Shell
which can be obtained from your Shell
Naturelle HF-E, if the system was previously
representative.
operated using a mineral oil hydraulic fluid,
deposits formed in the system during operation Protect the environment
may be loosened and deposited in system Take used oil to an authorised collection point.
filters. The filters should therefore be checked Do not discharge into drains, soil or water.
at regular intervals after fluid change over.
Advice
Seal & Paint Compatibility Advice on applications not covered in this
Shell Naturelle HF-E is compatible with all seal leaflet may be obtained from your Shell
materials and paints normally specified for use Representative.
with petroleum mineral oils. Certain plastics

Typical Physical Characteristics

Shell Naturelle HF-E 15 HF-E 32 HF-E 46 HF-E 68

ISO Viscosity Grade 15 32 46 68


(ISO 3348)

Colour Green Green Green Green

Kinematic Viscosity
@ 40°C cSt 14.1 31.6 42.4 64.9
100°C cSt 4.2 6.3 8.4 12.1
(ASTM D 445)

Viscosity Index 232 156 178 187


(ISO 2909)

Density @ 15°C kg/l 0.892 0.918 0.919 0.928


(ISO 12185)

Pour Point °C -54 -60 -54 -39


(ISO 3016)

Flash Point 202 236 219 226


(Cleveland Open Cup) °C
(ISO 2592)

These characteristics are typical of current production. Whilst future production will conform to Shell’s
specification variations in these characteristics may occur.

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Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Naturelle Fluid HF-E 46


Uses : Hydraulic oil
Product Code : 001A9034

Manufacturer/Supplier : oy Shell ab
(0113882-9)
Neilikkatie 17
FI-01300 Vantaa

Telephone : 0204 43 2073


Fax : 0204 43 2084
Email Contact for : If you have any enquiries about the content of this MSDS
MSDS please email lubricantSDS@shell.com

Emergency Telephone :
Number Poison Information Centre. tel 09-4711 or 09-471 977 (24h).
Stenbäckinkatu 11, 00290 Helsinki.

Other Information : KT code: 35 Lubricants and additivesTOL code: D Industry.

2. HAZARDS IDENTIFICATION

EC Classification : Not classified as dangerous under EC criteria.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. High-pressure injection under the
skin may cause serious damage including local necrosis. Used
oil may contain harmful impurities.
Signs and Symptoms : Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection. Oil
acne/folliculitis signs and symptoms may include formation of
black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation description : Blend of synthetic esters and additives.

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.

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Shell Naturelle Fluid HF-E 46
Version 1.
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Material Safety Data Sheet Regulation 1907/2006/EG

Inhalation : No treatment necessary under normal conditions of use. If


symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention. When using high
pressure equipment, injection of product under the skin can
occur. If high pressure injuries occur, the casualty should be
sent immediately to a hospital. Do not wait for symptoms to
develop. Obtain medical attention even in the absence of
apparent wounds.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically. High pressure injection injuries require
prompt surgical intervention and possibly steroid therapy, to
minimise tissue damage and loss of function. Because entry
wounds are small and do not reflect the seriousness of the
underlying damage, surgical exploration to determine the
extent of involvement may be necessary. Local anaesthetics or
hot soaks should be avoided because they can contribute to
swelling, vasospasm and ischaemia. Prompt surgical
decompression, debridement and evacuation of foreign
material should be performed under general anaesthetics, and
wide exploration is essential.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations.

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or

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Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

other containment material. Reclaim liquid directly or in an


absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point

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Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

>65 °C (149 °F)] meeting EN141.


Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturiser is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Green. Liquid at room temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.
Boiling point : > 280 °C / 536 °F estimated value(s)
Pour point : Typical -51 °C / -60 °F
Flash point : Typical 219 °C / 426 °F (COC)
Explosion / Flammability : Typical 1 - 10 %(V) (based on mineral oil)
limits in air
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))
Density : Typical 919 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)
Kinematic viscosity : Typical 46.1 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

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Factory filled oils - lubricants and coolants for underground rigs;
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Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser. May cause an allergic
skin reaction in sensitive individuals.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible. High
pressure injection of product into the skin may lead to local
necrosis if the product is not surgically removed.

12. ECOLOGICAL INFORMATION

Information given is based on product data, a knowledge of the components and the
ecotoxicology of similar products.

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract).
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Readily biodegradable.
Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 01 12 readily
biodegradable hydraulic oils. Classification of waste is always
the responsibility of the end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

ADNR
This material is not classified as dangerous under ADNR regulations.

IMDG
This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Not classified as dangerous under EC criteria.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.
EINECS : All components
listed or polymer
exempt.
TSCA : All components
listed.

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Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

16. OTHER INFORMATION

R-phrase(s)

Not classified.

MSDS Version Number : 1.

MSDS Effective Date : 05.03.2008

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EG
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Naturelle Fluid HF-E 68


Uses : Hydraulic oil.
Product Code : 001A9035

Manufacturer/Supplier : oy Shell ab
(0113882-9)
Neilikkatie 17
FI-01300 Vantaa

Telephone : 0204 43 2073


Fax : 0204 43 2084
Email Contact for : If you have any enquiries about the content of this MSDS
MSDS please email lubricantSDS@shell.com

Emergency Telephone :
Number Poison Information Centre. tel 09-4711 or 09-471 977 (24h).
Stenbäckinkatu 11, 00290 Helsinki.

Other Information : KT code: 35 Lubricants and additivesTOL code: D Industry.

2. HAZARDS IDENTIFICATION

EC Classification : Not classified as dangerous under EC criteria.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. High-pressure injection under the
skin may cause serious damage including local necrosis. Used
oil may contain harmful impurities.
Signs and Symptoms : Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection. Oil
acne/folliculitis signs and symptoms may include formation of
black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation description : Blend of synthetic esters and additives.

Hazardous Components

Chemical Name CAS EINECS Symbol(s) R-phrase(s) Conc.


Alkylated phenol 4306-88-1 224-320-7 Xi R38; R53 1.00 - 3.00 %

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Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

Additional Information : Refer to chapter 16 for full text of EC R-phrases.

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention. When using high
pressure equipment, injection of product under the skin can
occur. If high pressure injuries occur, the casualty should be
sent immediately to a hospital. Do not wait for symptoms to
develop. Obtain medical attention even in the absence of
apparent wounds.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically. High pressure injection injuries require
prompt surgical intervention and possibly steroid therapy, to
minimise tissue damage and loss of function. Because entry
wounds are small and do not reflect the seriousness of the
underlying damage, surgical exploration to determine the
extent of involvement may be necessary. Local anaesthetics or
hot soaks should be avoided because they can contribute to
swelling, vasospasm and ischaemia. Prompt surgical
decompression, debridement and evacuation of foreign
material should be performed under general anaesthetics, and
wide exploration is essential.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations.

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Version 1.
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Material Safety Data Sheet Regulation 1907/2006/EG

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker

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Version 1.
Effective Date 07.03.2008

Material Safety Data Sheet Regulation 1907/2006/EG

health, select respiratory protection equipment suitable for the


specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN141.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturiser is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Green. Liquid at room temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.
Boiling point : > 280 °C / 536 °F estimated value(s)
Pour point : Typical -39 °C / -38 °F
Flash point : Typical 226 °C / 439 °F (COC)
Explosion / Flammability : Typical 1 - 10 %(V)
limits in air
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))
Density : Typical 928 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)
Kinematic viscosity : Typical 64.9 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available

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Version 1.
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Material Safety Data Sheet Regulation 1907/2006/EG

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible. High
pressure injection of product into the skin may lead to local
necrosis if the product is not surgically removed.

12. ECOLOGICAL INFORMATION

Information given is based on product data, a knowledge of the components and the
ecotoxicology of similar products.

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract).
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Readily biodegradable.
Bioaccumulation : Contains components with the potential to bioaccumulate.

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Material Safety Data Sheet Regulation 1907/2006/EG

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 01 12 readily
biodegradable hydraulic oils. Classification of waste is always
the responsibility of the end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

ADNR
This material is not classified as dangerous under ADNR regulations.

IMDG
This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Not classified as dangerous under EC criteria.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.
EINECS : All components
listed or polymer

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Version 1.
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Material Safety Data Sheet Regulation 1907/2006/EG

exempt.
TSCA : All components
listed.

16. OTHER INFORMATION

R-phrase(s)

Not classified.
R38 Irritating to skin.
R53 May cause long-term adverse effects in the aquatic environment.

MSDS Version Number : 1.

MSDS Effective Date : 07.03.2008

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EG
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

7/7
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6 COMPRESSOR
6.1 Technical data sheet
For Shell Corena S2 R 46 technical data sheet refer to the http://
www.epc.shell.com/

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Shell Corena S2 R 46
Version 1.1
6.2 Compressor Effective Date 12.12.2012
Regulation 1907/2006/EC
Safety Data Sheet

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING

1.1 Product Identifier

Material Name : Shell Corena S2 R 46


Product Code : 001D7776

1.2 Relevant identified uses of the substance or mixture and uses advised against

Product Use : Compressor oil.

Uses Advised Against : This product must not be used in applications other than those
recommended in Section 1, without first seeking the advice of
the supplier.

1.3 Details of the Supplier of the safety data sheet

Manufacturer/Supplier : Univar OY

Y-tunnus (Company number): 0536122-7


Y-tunnus (Company number): 0536122-7
Vanha Nurmijärventie 62
Vanha Nurmijärventie 62
01670 Vantaa
01670 Vantaa

Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : sds.fi@univareurope.com
Safety Data Sheet

1.4 Emergency Telephone Number

: 09-471 977

Other Information : KT code: 35 lubricants and additivesTOL code: C Industry.

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

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Regulation 1907/2006/EC
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1999/45/EC
Hazard Characteristics R-phrase(s)
Not classified as dangerous under EC criteria.;

2.2 Label Elements

Labeling according to Directive 1999/45/EC

EC Symbols : No Hazard Symbol required

EC Classification : Not classified as dangerous under EC criteria.


EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.

2.3 Other Hazards

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.

Safety Hazards : Not classified as flammable but will burn.

Environmental Hazards : Not classified as dangerous for the environment.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substance

Material Name : Not applicable.

3.2 Mixtures

Mixture Description : Highly refined mineral oils and additives.

Hazardous Components

Classification of components according to Regulation (EC) No 1272/2008

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Regulation 1907/2006/EC
Safety Data Sheet

Chemical Name CAS No. EC Number REACH Registration Conc.


No.
Interchangeable low * * * 0.00 - 90.00%
viscosity base oil
(<20,5 cSt @40°C) *

Chemical Name Hazard Class & Category Hazard Statement


Interchangeable low Asp. Tox., 1; H304;
viscosity base oil
(<20,5 cSt @40°C) *

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346.

Refer to Ch 16 for full text of H phrases.

* contains one or more of the following CAS-numbers (REACH


registration numbers): 64742-53-6 (01-2119480375-34), 64742-
54-7 (01-2119484627-25), 64742-55-8 (01-2119487077-29),
64742-56-9 (01-2119480132-48), 64742-65-0 (01-2119471299-
27), 68037-01-4 (01-2119486452-34), 72623-86-0 (01-
2119474878-16), 72623-87-1 (01-2119474889-13), 8042-47-5
(01-2119487078-27), 848301-69-9 (01-0000020164-80).

This mixture does not contain any REACH registered


substances that are assessed to be a PBT or a vPvB.

Exposure limits apply to the following components: Highly


refined mineral oil.

SECTION 4. FIRST AID MEASURES

4.1 Description of First Aid Measures

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
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Regulation 1907/2006/EC
Safety Data Sheet

are swallowed, however, get medical advice.


Self-protection of the first : When administering first aid, ensure that you are wearing the
aider appropriate personal protective equipment according to the
incident, injury and surroundings.
4.2 Most important : Oil acne/folliculitis signs and symptoms may include formation
symptoms and effects, of black pustules and spots on the skin of exposed areas.
both acute and delayed Ingestion may result in nausea, vomiting and/or diarrhoea.
4.3 Indication of any : Notes to doctor/physician:
immediate medical Treat symptomatically.
attention and special
treatment needed
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.

SECTION 5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

5.1 Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
5.2 Special hazards : Hazardous combustion products may include: A complex
arising from the mixture of airborne solid and liquid particulates and gases
substance or mixture (smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
5.3 Advice for firefighters : Proper protective equipment including chemical resistant
gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

SECTION 6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. Observe the relevant local and
international regulations.

6.1 Personal Precautions, : 6.1.1 For non emergency personnel: Avoid contact with skin
Protective Equipment and and eyes.
Emergency Procedures
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Version 1.1
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Regulation 1907/2006/EC
Safety Data Sheet

6.1.2 For emergency responders: Avoid contact with skin and


eyes.
6.2 Environmental : Use appropriate containment to avoid environmental
Precautions contamination. Prevent from spreading or entering drains,
ditches or rivers by using sand, earth, or other appropriate
barriers.
6.3 Methods and Material : Slippery when spilt. Avoid accidents, clean up immediately.
for Containment and Prevent from spreading by making a barrier with sand, earth or
Cleaning Up other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
6.4 Reference to other : For guidance on selection of personal protective equipment
sections see Chapter 8 of this Material Safety Data Sheet. For guidance
on disposal of spilled material see Chapter 13 of this Material
Safety Data Sheet.

SECTION 7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Use the information in this data
sheet as input to a risk assessment of local circumstances to
help determine appropriate controls for safe handling, storage
and disposal of this material.
7.1 Precautions for Safe : Avoid prolonged or repeated contact with skin. Avoid inhaling
Handling vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used. Properly dispose of any contaminated rags or
cleaning materials in order to prevent fires. Keep container
tightly closed and in a cool, well-ventilated place. Use properly
labelled and closeable containers.
Product Transfer : This material has the potential to be a static accumulator.
Proper grounding and bonding procedures should be used
during all bulk transfer operations.
7.2 Conditions for safe : Store at ambient temperature.
storage, including any
incompatibilities
Refer to section 15 for any additional specific legislation
covering the packaging and storage of this product.
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
7.3 Specific end use(s) : Not applicable
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Shell Corena S2 R 46
Version 1.1
Effective Date 12.12.2012
Regulation 1907/2006/EC
Safety Data Sheet

Additional Information : Polyethylene containers should not be exposed to high


temperatures because of possible risk of distortion.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this
document, it is provided for information only.

8.1 Control Parameters

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral ACGIH TWA(Inhala 5 mg/m3
ble fraction.)

HTP- HTP 5 mg/m3 Known Harmful


ARVOT 8H(Mist.) Concentration
(Liite 1).

Biological Exposure Index (BEI)


No biological limit allocated.

PNEC related information : Data not available

Monitoring Methods : Monitoring of the concentration of substances in the breathing


zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate. Validated exposure measurement methods
should be applied by a competent person and samples
analysed by an accredited laboratory. Examples of sources of
recommended exposure measurement methods are given
below or contact the supplier. Further national methods may be
available.

National Institute of Occupational Safety and Health (NIOSH),


USA: Manual of Analytical Methods http://www.cdc.gov/niosh/

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Version 1.1
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Regulation 1907/2006/EC
Safety Data Sheet

Occupational Safety and Health Administration (OSHA), USA:


Sampling and Analytical Methods http://www.osha.gov/

Health and Safety Executive (HSE), UK: Methods for the


Determination of Hazardous Substances
http://www.hse.gov.uk/

Institut für Arbeitsschutz Deutschen Gesetzlichen


Unfallversicherung (IFA), Germany.
http://www.dguv.de/inhalt/index.jsp

L'Institut National de Recherche et de Securité, (INRS), France


http://www.inrs.fr/accueil

8.2 Exposure Controls


General Information : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.

Define procedures for safe handling and maintenance of


controls. Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product. Ensure appropriate selection, testing and
maintenance of equipment used to control exposure, e.g.
personal protective equipment, local exhaust ventilation. Drain
down system prior to equipment break-in or maintenance.
Retain drain downs in sealed storage pending disposal or for
subsequent recycle. Always observe good personal hygiene
measures, such as washing hands after handling the material
and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove
contaminants. Discard contaminated clothing and footwear that
cannot be cleaned. Practice good housekeeping.

Occupational Exposure Controls


Personal Protective : The provided information is made in consideration of the PPE
Equipment directive (Council Directive 89/686/EEC) and the CEN
European Committee for Standardisation (CEN) standards.

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Shell Corena S2 R 46
Version 1.1
Effective Date 12.12.2012
Regulation 1907/2006/EC
Safety Data Sheet

Personal protective equipment (PPE) should meet


recommended national standards. Check with PPE suppliers.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, dexterity. Always seek advice
from glove suppliers. Contaminated gloves should be replaced.
Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of a
non-perfumed moisturizer is recommended.
For continuous contact we recommend gloves with
breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same, but
recognise that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time may be acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Body protection : Skin protection not ordinarily required beyond standard issue
work clothes.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Thermal Hazards : Not applicable.

Environmental Exposure Controls


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Shell Corena S2 R 46
Version 1.1
Effective Date 12.12.2012
Regulation 1907/2006/EC
Safety Data Sheet

Environmental exposure : Minimise release to the environment. An environmental


control measures assessment must be made to ensure compliance with local
environmental legislation. Information on accidental release
measures are to be found in section 6.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties


Appearance : Light brown. Liquid at room temperature.
Odour : Slight hydrocarbon.
Odour threshold : Data not available
pH : Not applicable.
Initial Boiling Point and : > 280 °C / 536 °F estimated value(s)
Boiling Range
Pour point : Typical -33 °C / -27 °F
Flash point : Typical 230 °C / 446 °F (COC)
Upper / lower Flammability : Typical 1 - 10 %(V) (based on mineral oil)
or Explosion limits
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))
Relative Density : Typical 0.875 at 15 °C / 59 °F
Density : Typical 875 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
Solubility in other solvents : Data not available

n-octanol/water partition : > 6 (based on information on similar products)


coefficient (log Pow)
Dynamic viscosity : Data not available
Kinematic viscosity : Typical 46 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available
Decomposition : Data not available
Temperature
Flammability : Data not available
Oxidizing Properties : Data not available

Explosive Properties : Not classified

9.2 Other Information


Electrical conductivity : This material is not expected to be a static accumulator.

Other Information : not a VOC


Volatile organic compound : 0%
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Regulation 1907/2006/EC
Safety Data Sheet

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.
10.2 Chemical stability : No hazardous reaction is expected when handled and stored
according to provisions.
10.3 Possibility of :
Hazardous Reactions Reacts with strong oxidising agents.
10.4 Conditions to Avoid : Extremes of temperature and direct sunlight.
10.5 Incompatible : Strong oxidising agents.
Materials
10.6 Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on Toxicological effects


Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).
Likely Routes of : Skin and eye contact are the primary routes of exposure
Exposure although exposure may occur following accidental ingestion.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin corrosion/irritation : Expected to be slightly irritating.
Serious eye : Expected to be slightly irritating.
damage/irritation
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Respiratory or skin : For respiratory and skin sensitisation: Not expected to be a
sensitisation sensitiser.
Aspiration Hazard : Not considered an aspiration hazard.

Germ cell mutagenicity : Not considered a mutagenic hazard.


Carcinogenicity : Not expected to be carcinogenic. Product contains mineral oils
of types shown to be non-carcinogenic in animal skin-painting
studies. Highly refined mineral oils are not classified as
carcinogenic by the International Agency for Research on

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Regulation 1907/2006/EC
Safety Data Sheet

Cancer (IARC).

Material : Carcinogenicity Classification


Highly refined mineral oil : ACGIH Group A4: Not classifiable as a human carcinogen.
(IP346 <3%)
Highly refined mineral oil : IARC 3: Not classifiable as to carcinogenicity to humans.
(IP346 <3%)
Highly refined mineral oil : GHS / CLP: No carcinogenicity classification
(IP346 <3%)

Reproductive and : Not expected to be a hazard.


Developmental Toxicity

Summary on evaluation of the CMR properties


Carcinogenicity : This product does not meet the criteria for classification in
categories 1A/1B.,
Mutagenicity : This product does not meet the criteria for classification in
categories 1A/1B.
Reproductive Toxicity : This product does not meet the criteria for classification in
(fertility) categories 1A/1B.

Specific target organ : Not expected to be a hazard.


toxicity - single exposure
Specific target organ : Not expected to be a hazard.
toxicity - repeated
exposure
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Classifications by other authorities under varying regulatory
frameworks may exist.

SECTION 12. ECOLOGICAL INFORMATION

Basis for Assessment : Ecotoxicological data have not been determined specifically for
this product. Information given is based on a knowledge of the
components and the ecotoxicology of similar products. Unless
indicated otherwise, the data presented is representative of the
product as a whole, rather than for individual component(s).
12.1 Toxicity
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
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Version 1.1
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Regulation 1907/2006/EC
Safety Data Sheet

100 mg/l (to aquatic organisms) LL/EL50 expressed as the


nominal amount of product required to prepare aqueous test
extract. Mineral oil is not expected to cause any chronic effects
to aquatic organisms at concentrations less than 1 mg/l.

12.2 Persistence and : Expected to be not readily biodegradable. Major constituents


degradability are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
12.3 Bioaccumulative : Contains components with the potential to bioaccumulate.
Potential

12.4 Mobility in Soil : Liquid under most environmental conditions. If it enters soil, it
will adsorb to soil particles and will not be mobile. Floats on
water.

12.5 Result of PBT and : This mixture does not contain any REACH registered
vPvB assesment substances that are assessed to be a PBT or a vPvB.

12.6 Other Adverse : Product is a mixture of non-volatile components, which are not
Effects expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste Treatment Methods

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 02 05 mineral-based non-
chlorinated engine, gear and lubricating oils. Classification of
waste is always the responsibility of the end user.

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Regulation 1907/2006/EC
Safety Data Sheet

SECTION 14. TRANSPORT INFORMATION

Land transport (ADR/RID):


ADR
This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

RID
This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

Inland waterways transport (ADN):


This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

Sea transport (IMDG Code):


This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

Air transport (IATA):


This product is not classified as dangerous for this mode of transport. Therefore 14.1 UN
Number, 14.2 UN Proper Shipping name, 14.3 Transport hazard class(es), 14.4 Packing group,
14.5 Environmental hazards, 14.6 Special precautions for user do not apply.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution Category : Not applicable.
Ship Type : Not applicable.
Product Name : Not applicable.
Special Precaution : Not applicable.

Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.

SECTION 15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
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Version 1.1
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Regulation 1907/2006/EC
Safety Data Sheet

Other regulatory Information


Authorisations and/or : Product is not subject to Authorisation under REACh.
restrictions on use

Recommended : This product must not be used in applications other than those
Restrictions on Use recommended in Section 1, without first seeking the advice of
(Advice Against) the supplier.

Chemical Inventory Status

EINECS : All components


listed or polymer
exempt.
TSCA : All components
listed.

15.2 Chemical Safety : No Chemical Safety Assessment has been carried out for this
Assessment substance/mixture by the supplier.

SECTION 16. OTHER INFORMATION

Not classified.

CLP Hazard Statements


H304 May be fatal if swallowed and enters airways.

Additional Information : No Exposure Scenario annex is attached to this safety data


sheet. It is a non-classified mixture containing hazardous
substances as detailed in Section 3; relevant information from
Exposure Scenarios for the hazardous substances contained
have been integrated into the core sections 1-16 of this SDS.
Other Information

Abbreviations and : Acute Tox. = Acute toxicity


Acronyms Asp. Tox. = Aspiration hazard
Aquatic Acute = Acute hazards to the aquatic environment
Aquatic Chronic = Hazardous to the aquatic environment -
Long-term Hazard
Eye Dam. = Serious eye damage/eye irritation
Flam. Liq. = Flammable liquids
Skin Corr. = Skin corrosion/irritation
Skin Sens. = Skin sensitizer
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Version 1.1
Effective Date 12.12.2012
Regulation 1907/2006/EC
Safety Data Sheet

STOT SE = Specific target organ toxicity - single exposure


STOT RE = Specific target organ toxicity - repeated exposure

The standard abbreviations and acronyms used in this


document can be looked up in reference literature (e.g.
scientific dictionaries) and/or websites.

ACGIH = American Conference of Governmental Industrial


Hygienists
ADR = European Agreement concerning the International
Carriage of Dangerous Goods by Road
AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits
BTEX = Benzene, Toluene, Ethylbenzene, Xylenes
CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches Institut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission
EC50 = Effective Concentration fifty
ECETOC = European Center on Ecotoxicology and Toxicology
Of Chemicals
ECHA = European Chemicals Agency
EINECS = The European Inventory of Existing Commercial
Chemical Substances
EL50 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
IMDG = International Maritime Dangerous Goods
INV = Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the

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Regulation 1907/2006/EC
Safety Data Sheet

determination of polycyclic aromatics DMSO-extractables


KECI = Korea Existing Chemicals Inventory
LC50 = Lethal Concentration fifty
LD50 = Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LL50 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No
Observed Effect Level
OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of
Dangerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act
TWA = Time-Weighted Average
vPvB = very Persistent and very Bioaccumulative

SDS Distribution : The information in this document should be made available to


all who may handle the product.
SDS Version Number : 1.1

SDS Effective Date : 12.12.2012

SDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
SDS Regulation : Regulation 1907/2006/EC as amended by Regulation (EU)
453/2010
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

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7 SHANK LUBRICATION

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7.1 Shank lubrication


Previous Name: Shell
Torcula Oils
Shell Air Tool Oil S2 A •

RELIABLE PROTECTION
MIST LUBRICATION
Pneumatic Tool and Rock Drill Oils
Shell Air Tool Oil S2 A has been developed to meet the special
lubrication requirements of pneumatic tools, including percussion
type pneumatic tools subjected to the most arduous conditions.
They are designed to maintain high oil film strength and
effectively lubricate even the most demanding requirements of
pneumatic drill impact mechanisms as well as providing excellent
mist lubrication of general purpose air tools.

Performance Benefits
• Oil mist lubrication applications
• Reliable wear & corrosion protection Shell Air Tool Oil can also be
Shell Air Tool Oil S2 A has been used in applications requiring
developed to provide excellent mist lubrication, such as air tool
lubricity and anti-wear properties to installations commonly found in
protect percussion tools including manufacturing.
rock drills operating under arduous
conditions. • Other applications
It also provides high levels of May be used in certain gear and
corrosion protection even under bearing lubrication systems
severe water wash conditions. subject to water ingress.

The high oil film strength provides Specifications and Approvals


for excellent load carrying Meets ISO 6743-11 Types PAC and PBC
performance and increased drill life.
• Maintaining system efficiency Health and Safety
Guidance on Health and Safety is
To ensure efficient lubrication under available on the appropriate Material
the full range of operation, Shell Safety Data Sheet, which can be
Air Tool Oil S2 A has good low obtained from your Shell
temperature fluidity at low representative.
temperatures to provide consistent
lubrication and to resist oil build-
up in areas cooled by rapid air Seal & Paint Compatibility
expansion. Shell Air Tool Oil S2 A is compatible
with seal materials and paints
Shell Air Tool Oil S2 A has excellent normally specified for use with
emulsability enabling lubrication in mineral oils.
a wet environment.
Protect the Environment
Applications Take used oil to an authorised
collection point. Do not discharge
• Percussive pneumatic tools into drains, soil or water.
Suitable for a wide range of mobile Advice
percussive pneumatic tools such as Advice on applications not covered in
those used in rock drilling, mining this leaflet may be obtained from
and construction activities (e.g. your Shell representative.
jack hammers, sinkers and other air
operated tools).

Shell Lubricants
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Typical Physical Characteristics


Shell Air Tool 32 100 150 320
Oil S2 A
ISO Viscosity ISO 32 100 150 320
Grade 3448
Kinematic ISO
Viscosity 3104
at 40° C mm2/s 32 100 150 320
at 100° C mm2/s 5.6 11.5 15.1 25.0
Viscosity ISO 116 102 101 100
Index 2909
Flash Point °C ISO 208 241 246 248
COC 2592
Pour Point °C ISO -33 -24 -24 -18
3016
Density at kg/m3 ISO 873 884 887 895
15° C 12185
These characteristics are typical of current production. Whilst future production will conform
to Shell's specification, variations in these characteristics may occur.

Shell Lubricants
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Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Air Tool Oil S2 A 100


Uses : Machine oil.
Product Code : 001D7866

Manufacturer/Supplier : Univar OY
Y-tunnus (Company number): 0536122-7
FI-01670
Vanha Nurmijärventie 62 E 28
Vantaa

Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : sds.fi@univareurope.com
MSDS

Emergency Telephone : 09-471 977


Number
Other Information : KT code: 35 lubricants and additivesTOL code: C Industry.

2. HAZARDS IDENTIFICATION

EC Classification : Not classified as dangerous under EC criteria.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation Description : Highly refined mineral oils and additives.

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346.
Exposure limits apply to the following components: Highly
refined mineral oil.

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Version 1.0
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Regulation 1907/2006/EC
Safety Data Sheet

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Suitable Extinguishing : Foam, water spray or fog. Dry chemical powder, carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.

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Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on


this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral HTP-ARVOT HTP 8H 5 mg/m3 Known Harmful
[Mist.] Concentration
(Liite 1).
ACGIH TWA 5 mg/m3
[Inhalable
fraction.]

Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
3/7
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 105 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

material. If engineering controls do not maintain airborne


concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Amber. Liquid at room temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.
Initial Boiling Point and : > 280 °C / 536 °F estimated value(s)
Boiling Range
Pour point : Typical -24 °C / -11 °F
Flash point : Typical 241 °C / 466 °F (COC)
Lower / upper Flammability : Typical 1 - 10 %(V) (based on mineral oil)
or Explosion limits
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))
Density : Typical 884 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Kinematic viscosity : Typical 100 mm2/s at 40 °C / 104 °F


Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.

12. ECOLOGICAL INFORMATION

Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.

5/7
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 107 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Mobility : Liquid under most environmental conditions. Floats on water. If


it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 02 05 mineral-based non-
chlorinated engine, gear and lubricating oils. Classification of
waste is always the responsibility of the end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

ADNR
This material is not classified as dangerous under ADNR regulations.

IMDG
This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

6/7
Print Date 24.12.2010 MSDS_FI

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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Not classified as dangerous under EC criteria.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.
Chemical Inventory Status
EINECS : All components
listed or polymer
exempt.
TSCA : All components
listed.

16. OTHER INFORMATION

R-phrase(s)

Not classified.

MSDS Version Number : 1.0

MSDS Effective Date : 16.12.2010

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

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8 TORQUE AND ROTATION MECHANISMS

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Interim Technical Data Sheet

8.1 Torque and rotation mechanisms


Shell Spirax S3 AX 80W-90
High Performance, GL-5 Axle Oil for General Applications
Spirax S3 AX 80W-90 is a high performance, API GL-5 gear and axle oil for moderate
to heavily loaded on and off-road driveline applications requiring SAE 80W-90 oil.

Applications Outstanding pitting, scoring and wear


protection.
• Automotive Differentials
Automotive gear boxes, differentials, and hypoid Specification and Approvals
gear sets in motorcycle, passenger car,
commercial vehicles, off-road construction and API Service Classification GL-5
agricultural equipment. US Military MIL-L-2105D
Mercedes-Benz Sheet Approval 235.6
• General Gear Sets MAN 342 Typ M2
Ancillary equipment gear sets and some industrial ZF TE-ML 05A, 07A, 16C,
equipment. 17B, 19B, 21A

Performance Features and Benefits


Advice
• Multiple Vehicle Applications Advice on applications not covered in this leaflet
High performance fluid for API GL-5 applications may be obtained from your Shell Representative.
that may require SAE 80W-90, 90, or 80W fluids.
May be used in some SAE 75W-90 applications
where low temperature performance is not Health and Safety
needed.. Guidance on Health and Safety are available on
the appropriate Material Safety Data Sheet which
• Longer oil drain capability can be obtained from your Shell representative.
Long life additives ensure long-term protection of Protect the environment
the gears and high oxidation resistance so Take used oil to an authorised collection point. Do
providing extended drain capability. not discharge into drains, soil or water.
• Longer transmission life

Typical Physical Characteristics

Spirax S3 AX 80W-90
SAE Viscosity grade SAE J 306 80W-90
Kinematic Viscosity ISO 3104
at 40°C mm2/s 169.0
at 100°C mm2/s 16.8
Density at 15°C kg/m3 ISO 12185 900
Flash Point COC °C ISO 2592 220
Pour Point °C ISO 3016 -30

These characteristics are typical of current production. Whilst future production will conform
to Shell's specification, variations in these characteristics may occur.

Shell Lubricants – 001D8281 30/03/2010


Page 1 of 1
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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Spirax S3 AX 80W-90


Uses : Transmission oil.
Product Code : 001D8281

Manufacturer/Supplier : Univar OY
Y-tunnus (Company number): 0536122-7
FI-01670
Vanha Nurmijärventie 62 E 28
Vantaa

Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : sds.fi@univareurope.com
MSDS

Emergency Telephone : 09-471 977


Number
Other Information : KT code: 35 lubricants and additivesTOL code: C Industry.

2. HAZARDS IDENTIFICATION

EC Classification : Dangerous for the environment.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation Description : Highly refined mineral oils and additives.

Hazardous Components

Chemical Identity CAS EINECS Symbol(s) R-phrase(s) Conc.


Alkyl phosphonate Xi, N R38; R41; 0.10 - 0.90 %
R51/53
Alkyl Xi, N R36; R50/53 0.25 - 0.90 %
dithiophosphate
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114 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Long-chain alkenyl C, Xn, N R22; R35; 0.10 - 0.50 %


amine R50

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
refined mineral oil.

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Suitable Extinguishing : Foam, water spray or fog. Dry chemical powder, carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
2/8
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ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

other appropriate barriers.


Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on


this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral HTP-ARVOT HTP 8H 5 mg/m3 Known Harmful
[Mist.] Concentration
(Liite 1).
ACGIH TWA 5 mg/m3
[Inhalable
fraction.]

Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
3/8
Print Date 24.12.2010 MSDS_FI

116 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

airborne concentrations. Where material is heated, sprayed or


mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Amber. Liquid at room temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.
Initial Boiling Point and : > 280 °C / 536 °F estimated value(s)
Boiling Range
Pour point : Typical -30 °C / -22 °F
Flash point : Typical 220 °C / 428 °F (COC)

4/8
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 117 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Lower / upper Flammability : Typical 1 - 10 %(V) (based on mineral oil)


or Explosion limits
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))
Density : Typical 900 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)
Kinematic viscosity : Typical 169 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.

12. ECOLOGICAL INFORMATION

5/8
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118 (180) Copyright © Sandvik


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be harmful: LL/EL/IL50 10-100 mg/l (to
aquatic organisms) (LL/EL50 expressed as the nominal
amount of product required to prepare aqueous test extract).
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
Contains alkyl phosphate. Very toxic: LC/EC/IC50 0.1 - 1 mg/l
(to aquatic organisms)

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 13 02 05 mineral-based non-
chlorinated engine, gear and lubricating oils. Classification of
waste is always the responsibility of the end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

ADNR
This material is not classified as dangerous under ADNR regulations.

6/8
Print Date 24.12.2010 MSDS_FI

Copyright © Sandvik 119 (180)


ID: BG00420000 en-US A.002.1 2015-09-09
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

IMDG
This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Dangerous for the environment.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : R52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
EC Safety Phrases : S61 Avoid release to the environment. Refer to special
instructions/Safety data sheets.
Chemical Inventory Status
EINECS : All components
listed or polymer
exempt.
TSCA : All components
listed.

16. OTHER INFORMATION

R-phrase(s)

R22 Harmful if swallowed.


R35 Causes severe burns.
R36 Irritating to eyes.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

MSDS Version Number : 1.0

MSDS Effective Date : 16.12.2010

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
7/8
Print Date 24.12.2010 MSDS_FI

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Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet

MSDS Distribution : The information in this document should be made available to


all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

8/8
Print Date 24.12.2010 MSDS_FI

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9 COOLANT

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9.1 Coolant

Carcoolant 774C
Engine coolant
Properties

Long life and long lasting corrosion protection.


Free from nitrite, amine and phosphate.
Miscible with most other engine coolants.
Wide working temperature range.

The Carcoolant 774C is a high quality product from the leading manufacturers in
Europe.
774C is free from nitrite, amine and phosphate but contains silicate in order to give the
best possible protection against corrosion of the engines light metal parts (aluminum,
magnesium).
774C guarantees safe functionality and good protection against corrosion following
most of the occurring car manufacturer’s specifications.

Use

The cooling system should contain at least 30% engine coolant of high quality in order to
give best possible corrosion protection up to 3 years. Also during the summer months is it
important to have glycol in the cooling system. The boiling point will increase to about 105 ºC
and protects the engine against overheating.

Follow the guidance in the car manual regarding choice of engine coolant. Do not jeopardize
the function of the engine by choosing a low quality. This is most important for heavy duty
vehicles or vehicles with a high demand of reliability. The added cost of a quality engine
coolant is minimal compared to the cars total operating cost per year.

Approvals

Univar Carcoolant 774C meets the performance requirements of the relevant OEM´s

Mixing table

774 C % Freeze protection °C


10 - 4
20 -11
30 -16
40 -27
50 -38

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Typical data

Color: Blue
Contains: 1,2 – ethanediol > 90%
Is diluted with pure water

Safety

The main component in Carcoolant 774C is, like in most other engine coolants,
mono ethylene glycol that is toxic when ingested. Make sure that the products are stored
safely and prevent spillage in nature or streams.

As a precaution does the glycol contain bittrex.

Our Security Data Sheet gives you all information about labeling, environmental impact,
handling, health aspects etc. www.univar.se

Used glycol

Used glycol can be left at an approved collection point for hazardous waste. Do not pour the
glycol in the sink, in nature or in streams.

Packages

Plastic bottle, 1 liter


Plastic can, 4 liter
Plastic can, 28 kg (25 liter)
Steel drum, 235 kg (209 liter)
Container, 1135 kg (1011 liter)
Bulk

The information in this product sheet is only guiding and we reserve ourselves the right to without
further notice change text or facts

SWEDEN Univar AB DENMARK Univar A/S NORWAY Univar AS FINLAND Univar Oy


Kalendegatan 26, Marieholmsgatan 56, Gustavlundsvägen 143 Islands Brygge 43 Østensjøveien 32 Vanha Nurmijärventie 62
Box 4072 Box 48 SE-167 51 Bromma DK-2300 København S Postboks 49 FI-01670 Vantaa
SE-203 11 Malmö SE-401 20 Göteborg Sweden Denmark NO-0667 Oslo Finland
Sweden Sweden Norway
T +358 9 350 86 50
T +46 40 35 28 00 T +46 31 83 80 00 T +46 8 58 77 12 00 T +45 35 37 12 44 T +47 22 88 16 00 F +358 9 350 86 550
F +46 40 12 51 72 F +46 31 84 39 80 F +46 8 58 77 12 10 F +45 35 37 52 04 F +47 22 72 00 52 Org nr: 9600675947
Org nr: 556114-6308 Org nr: 11652328 Org nr: 00918821015 Vat nr: FI105361227
Vat nr: SE556114630801 Vat nr: DK11652328 Vat nr: NO918821015
www.univar.fi
www.univar.se www.univar.dk www.univar.no

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REVISION DATE:conditions
11.05.2010

SAFETY DATA SHEET


Carcoolant 774C

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE


COMPANY/UNDERTAKING
PRODUCT NAME Carcoolant 774C
SUPPLIER Univar
Aquarius House
6 Midpoint Business Park
Thornbury
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
sds@univareurope.com
PRODUCT NO.
NO. KY1711, KY1713, KY1714, KY1717, KY1724, KY1744
APPLICATION Coolant
Emergency Contact Number +441865 407333
(Outside Office Hours)
Hours)
Finnish Only TOL1: G453, KT1: 29
SDS No.
No. 11948

2 HAZARDS IDENTIFICATION

Harmful if swallowed.
CLASSIFICATION (1999/
1999/45)
45) Xn;R22.

3 COMPOSITION/INFORMATION ON INGREDIENTS
Name EC No.
No. CAS-
CAS-No.
No. Content Classification (67/
67/548)
548)

2-Ethylhexanoic Acid, Sodium Salt 243-283-8 19766-89-3 3% Repr. Cat. 3;R63.


Denatoniumbenzoat 223-095-2 3734-33-6 0.0005% Xn;R20/22. R52/53.
ETHANEDIOL 203-473-3 107-21-1 90% Xn;R22

The Full Text for all R-Phrases are Displayed in Section 16

COMPOSITION COMMENTS
Inhibitors

4 FIRST-AID MEASURES
INHALATION
Provide rest, warmth and fresh air. Get medical attention if any discomfort continues.
INGESTION
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Drink plenty of water. Get medical
attention immediately!
SKIN CONTACT
Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if
irritation persists after washing.

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Carcoolant 774C
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water
while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms
occur after washing.

5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
SPECIAL FIRE FIGHTING PROCEDURES
Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

6 ACCIDENTAL RELEASE MEASURES


ENVIRONMENTAL PRECAUTIONS
Do not discharge into drains, water courses or onto the ground.
SPILL CLEAN UP METHODS
Collect in containers and seal securely. Flush area clean with lots of water. Be aware of potential for surfaces to
become slippery.

7 HANDLING AND STORAGE


USAGE PRECAUTIONS
Avoid spilling, skin and eye contact.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry and cool place. Keep in original container.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name Std TWA - 8 hrs STEL - 15 min Notes

ETHANEDIOL WEL 52 104


mg/m3(Sk) mg/m3(Sk)
WEL = Workplace Exposure Limit.

INGREDIENT COMMENTS
WEL = Workplace Exposure Limits
PROTECTIVE EQUIPMENT

ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection may still be required under exceptional
circumstances when excessive air contamination exists. In case of inadequate ventilation or when the product is
heated, use suitable respiratory equipment with gas filter (type A2).
HAND PROTECTION
Use protective gloves. Nitrile.
EYE PROTECTION
Wear approved safety goggles.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.

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Carcoolant 774C
HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using
the toilet. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin
becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or
smoke.

9 PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE Liquid
COLOUR Misc. colours
ODOUR Characteristic
SOLUBILITY Soluble in water.
BOILING POINT (°C) > 165°C (ASTM D1120) MELTING POINT (°C) < - 18 °C (DIN ISO
3016)
RELATIVE DENSITY 1.122 - 1.126 g/cm³ VAPOUR PRESSURE 0,02 kPa @ 20°C
(DIN 51757) @ 20
°C
FLASH POINT (°C) > 120 °C (DIN; ISO AUTO IGNITION > 200 °C
2592) TEMPERATURE (°C)
FLAMMABILITY LIMIT - 3 FLAMMABILITY LIMIT - 15
LOWER(%)
LOWER (%) UPPER(%)
UPPER (%)

10 STABILITY AND REACTIVITY


STABILITY
Stable under normal temperature conditions.
CONDITIONS TO AVOID
Avoid contact with strong oxidisers.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

11 TOXICOLOGICAL INFORMATION
TOXIC DOSE 1 - LD 50 > 2000 mg/kg mg/kg (oral rat)
INGESTION
Harmful if swallowed.
SKIN CONTACT
May cause defatting of the skin, but is not an irritant. May be absorbed through the skin.
EYE CONTACT
No specific health warnings noted.

12 ECOLOGICAL INFORMATION
ECOTOXICITY
Not regarded as dangerous for the environment.
LC 50,
50, 96 Hrs, FISH mg/
mg/l > 100 mg/l
EC 50,
50, 48 Hrs, DAPHNIA, mg/
mg/l > 100 mg/l
IC 50,
50, 72 Hrs, ALGAE, mg/
mg/l > 100 mg/l
DEGRADABILITY
The product is easily biodegradable.

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REVISION DATE: 11.05.2010
Carcoolant 774C
Name ETHANEDIOL
50,, 96 Hrs, FISH mg/
LC 50 mg /l > 10 000 mg/l
50,, 48 Hrs, DAPHNIA, mg/
EC 50 mg /l > 10 000 mg/l
50,, 72 Hrs, ALGAE, mg
IC 50 mg//l > 10 000 mg/l
Bioaccumulation potential
The product is not bioaccumulating.
Degradability
The product is easily biodegradable.

13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.

14 TRANSPORT INFORMATION
GENERAL The product is not covered by international regulation on the transport of dangerous
goods (IMDG, IATA, ADR/RID).

15 REGULATORY INFORMATION
LABELLING

Harmful

CONTAINS ETHANEDIOL
RISK PHRASES
R22 Harmful if swallowed.
SAFETY PHRASES
S24/25 Avoid contact with skin and eyes.
S46 If swallowed, seek medical advice immediately and show this container
or label.

16 OTHER INFORMATION
REVISION DATE 11.05.2010
REV.
REV. NO./
NO./REPL
./REPL.
REPL. SDS 04
GENERATED
NO..
SDS NO 11948
SAFETY DATA SHEET STATUS
Approved.
DATE 09.02.2009
SIGNATURE KL
RISK PHRASES IN FULL
R20/22 Harmful by inhalation and if swallowed.
R22 Harmful if swallowed.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R63 Possible risk of harm to the unborn child.

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10 COMMON GREASE FOR BOOM AND CARRIER

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Technical Data Sheet

10.1 Common grease for boom and carrier


Previous Names: Shell Alvania Grease EP(LF), Retinax EP

Shell Gadus S2 V220


• Reliable Protection
High Performance Multipurpose Extreme • Multipurpose
Pressure Grease • Lithium

Shell Gadus S2 V220 greases are high quality multipurpose, extreme-pressure greases based
on a blend of high viscosity index mineral oils and a lithium hydroxystreate soap thickener and
contain extreme-pressure and other proven additives to enhance their performance in a wide
range of applications.
Shell Gadus S2 V220 greases are designed for multipurpose grease lubrication of rolling
element and plain bearings as well as hinges and sliding surfaces such as those found in
throughout most industrial and transport sectors

Applications  Operation over the temperature range -


20°C to 100°C for bearings operating at
Shell Gadus S2 V220 greases 0 are specifically
75% of the maximum rated speed (Can
designed for:
withstand up to 120°C intermittently)
 Steel mill lubrication where a softer grease
is necessary for specialised dispensing
systems.
Performance Features

 Heavy duty plain and rolling element  Outstanding load carrying capacity
bearings operating under harsh conditions Shell Gadus S2 V220 greases contain
including shock loading in wet environments special extreme-pressure additives which
enable them to withstand heavy and shock
Shell Gadus S2 V220 grease 1 is designed for: loads without failure of the lubricant film.

 Heavy duty bearings served by centralised  Improved mechanical stability


dispensing equipment This is particularly important in vibrating
environments where poor mechanical
 Extreme-pressure gear grease for stability can lead to grease softening with
applications at normal ambient temperature subsequent loss of lubrication performance
 Heavy duty plain and rolling element and leakage.
bearings operating under harsh conditions
including shock loading in wet environments  Good resistance to water wash-out
Shell Gadus S2 V220 greases have been
 Low temperature greasing applications formulated to offer resistance to water wash-
out

Shell Gadus S2 V220 greases 2 & 3  Oxidation stability


Specially selected base oil components have
are designed for: excellent oxidation resistance. Their
 Heavy duty bearings and general industrial consistency will not alter in storage and they
lubrication withstand high operating temperatures
without hardening or forming bearing
 Heavy duty plain and rolling element deposits
bearings operating under harsh conditions
including shock loading in wet environments  Anti- corrosion protection
Shell Lubricants 17/12/2010
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Technical Data Sheet

Shell Gadus S2 V220 greases have an


affinity with metal and have the ability to
protect bearing surfaces against corrosion,
even when the grease is contaminated with
water.

Performance Specifications
Meets ASTM D4950-08 LB
Meet the British Timken specification for Steel Mill
applications

Re-greasing Intervals
For bearings operating near their maximum
recommended temperatures, re-greasing intervals
should be reviewed

Health & Safety


Shell Gadus S2 V220 greases are unlikely to
present any significant health or safety hazard
when properly used in the recommended
application, and good standards of industrial
and personal hygiene are maintained.
For further guidance on Product Health & Safety
refer to the appropriate Shell Product Safety Data
Sheet.

Note
Care should be taken to ensure that the grease
does NOT come into contact with hydraulic brake
rubber components.

Shell Lubricants 17/12/2010


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Technical Data Sheet

Typical Physical Characteristics

Shell Gadus S2 V220 00 0 1 2 3

Soap Type Lithium Lithium Lithium Lithium Lithium

Base Oil Mineral Mineral Mineral Mineral Mineral

Kinematic Viscosity
@ 40°C cSt 220 220 220 220 220
100°C cSt 19 19 19 19 19
(IP 71/ASTM-D445)

Dropping Point
°C - - 180 180 180
(IP 132)

Cone Penetration
Worked @ 25°C 0.1mm 400- 355- 310- 265- 220-
(IP 50/ASTM-D217) 430 385 340 295 250

These characteristics are typical of current production. Whilst future


production will conform to Shell's specification, variations in these
characteristics may occur.

Shell Lubricants 17/12/2010


Page 3 of 3

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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010

Material Safety Data Sheet Regulation 1907/2006/EC

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Material Name : Shell Gadus S2 V220 2


Uses : Automotive and industrial grease.
Product Code : 001D8451

Manufacturer/Supplier : Univar OY

Y-tunnus (Company number): 0536122-7


Vanha Nurmijärventie 62 E 28
FI-01670
Vantaa

Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : sds.fi@univareurope.com
MSDS

Emergency Telephone : 09-471 977


Number
Other Information : KT code: 35 lubricants and additivesTOL code: C Industry.

2. HAZARDS IDENTIFICATION

EC Classification : Not classified as dangerous under EC criteria.

Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. High-pressure injection under the
skin may cause serious damage including local necrosis. Used
grease may contain harmful impurities.
Signs and Symptoms : Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection. Oil
acne/folliculitis signs and symptoms may include formation of
black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation Description : A lubricating grease containing highly-refined mineral oils and


additives.

Hazardous Components

Chemical Identity CAS EINECS Symbol(s) R-phrase(s) Conc.


Zinc alkyl 68649-42-3 272-028-3 Xi, N R38; R41; < 2.40 %
dithiophosphate R51/53

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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010

Material Safety Data Sheet Regulation 1907/2006/EC

Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
refined mineral oil.

4. FIRST AID MEASURES

General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention. When using high
pressure equipment, injection of product under the skin can
occur. If high pressure injuries occur, the casualty should be
sent immediately to a hospital. Do not wait for symptoms to
develop. Obtain medical attention even in the absence of
apparent wounds.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically. High pressure injection injuries require
prompt surgical intervention and possibly steroid therapy, to
minimise tissue damage and loss of function. Because entry
wounds are small and do not reflect the seriousness of the
underlying damage, surgical exploration to determine the
extent of involvement may be necessary. Local anaesthetics or
hot soaks should be avoided because they can contribute to
swelling, vasospasm and ischaemia. Prompt surgical
decompression, debridement and evacuation of foreign
material should be performed under general anaesthetics, and
wide exploration is essential.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Hazardous combustion products may include: A complex


mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds.
Suitable Extinguishing : Foam, water spray or fog. Dry chemical powder, carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus

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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010

Material Safety Data Sheet Regulation 1907/2006/EC

Firefighters must be worn when approaching a fire in a confined space.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.

Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Shovel into a suitable clearly marked container for disposal or
reclamation in accordance with local regulations.

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of


vapours, mists or aerosols. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling
vapour and/or mists. When handling product in drums, safety
footwear should be worn and proper handling equipment
should be used.
Storage : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labelled and closeable containers. Storage
Temperature: 0 - 50°C / 32 - 122°F
Recommended Materials : For containers or container linings, use mild steel or high
density polyethylene.
Unsuitable Materials : PVC.
Additional Information : Polyethylene containers should not be exposed to high
temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on


this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation


Oil mist, mineral ELV (FI) HTP 8H 5 mg/m3 Known Harmful
[Mist.] Concentration
(Liite 1).
ACGIH TWA 5 mg/m3
[Inhalable
fraction.]

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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010

Material Safety Data Sheet Regulation 1907/2006/EC

Additional Information : Due to the product's semi-solid consistency, generation of


mists and dusts is unlikely to occur.
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN14387.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Brown. Semi-solid at ambient temperature.


Odour : Slight hydrocarbon.
pH : Not applicable.

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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010

Material Safety Data Sheet Regulation 1907/2006/EC

Initial Boiling Point and : Data not available


Boiling Range
Dropping point : > 180 °C / 356 °F
Flash point : > 180 °C / 356 °F (COC)
Lower / upper Flammability : Typical 1 - 10 %(V) (based on mineral oil)
or Explosion limits
Auto-ignition temperature : > 320 °C / 608 °F
Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s))
Density : Typical 900 kg/m3 at 15 °C / 59 °F
Water solubility : Negligible.
n-octanol/water partition : > 6 (based on information on similar products)
coefficient (log Pow)
Kinematic viscosity : Not applicable.
Vapour density (air=1) : > 1 (estimated value(s))
Evaporation rate (nBuAc=1) : Data not available

10. STABILITY AND REACTIVITY

Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used grease may contain harmful impurities that have
accumulated during use. The concentration of such harmful
impurities will depend on use and they may present risks to
health and the environment on disposal. ALL used grease
should be handled with caution and skin contact avoided as far

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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010

Material Safety Data Sheet Regulation 1907/2006/EC

as possible. High pressure injection of product into the skin


may lead to local necrosis if the product is not surgically
removed.

12. ECOLOGICAL INFORMATION

Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.

Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
Mobility : Semi-solid under most environmental conditions. Floats on
water. If it enters soil, it will adsorb to soil particles and will not
be mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.

13. DISPOSAL CONSIDERATIONS

Material Disposal : Recover or recycle if possible. It is the responsibility of the


waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal : Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
EU Waste Disposal Code (EWC): 12 01 12 spent waxes and
fats. Classification of waste is always the responsibility of the
end user.

14. TRANSPORT INFORMATION

ADR
This material is not classified as dangerous under ADR regulations.

RID
This material is not classified as dangerous under RID regulations.

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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010

Material Safety Data Sheet Regulation 1907/2006/EC

ADNR
This material is not classified as dangerous under ADNR regulations.

IMDG
This material is not classified as dangerous under IMDG regulations.

IATA (Country variations may apply)


This material is not classified as dangerous under IATA regulations.

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.

EC Classification : Not classified as dangerous under EC criteria.


EC Symbols : No Hazard Symbol required
EC Risk Phrases : Not classified.
EC Safety Phrases : Not classified.
Chemical Inventory Status
EINECS : All components
listed or polymer
exempt.
TSCA : All components
listed.

16. OTHER INFORMATION

R-phrase(s)

Not classified.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

MSDS Version Number : 1.0

MSDS Effective Date : 30.11.2010

MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.

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11 AIR CONDITIONER REFRIGERANT

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11.1 Air conditioner refrigerant


Genetron® 134a
Introduction
Genetron® 134a (HFC-134a) has been developed by Honeywell
to serve as one of the key substitutes for CFCs and HCFCs.
Genetron® 134a is a long-term, environmentally safer, non-ozone
depleting substitute. As a refrigerant, it possesses similar energy
efficiency and capacity characteristics as R-12 and has an
intrinsically low toxicity. Genetron® 134a is the refrigerant of
choice in automobile air-conditioning. It may be used in
residential and commercial refrigeration, as well as commercial,
and industrial air-conditioning.

Physical properties Pressure/Temperature table


Component: Chemical name: Molecular formula: Temperature Pressure
HFC-134a 1,1,1,2 Tetrafluoroethane CH2FCF3 (°C) (kPa)
Molecular weight 102.03 -40.0 51
IV
Boiling point (°C) -25.9 -35.0 66
IV
Freezing point (°C) -96.6 -30.0 84
I
Critical temperature (°C) 101.06 -25.0 106
Critical pressure (kPa) 4059 -20.0 133
Critical volume I
(m3/kg) 0.002 -15.0 164
Critical density I
(kg/m3) 511.9 -10.0 201
Vapour density at boiling point (kg/m3) 5.26 -5.0 243
Liquid density III (kg/m3) 1207.0 -0.0 293
III
Liquid heat capacity (kJ/kg·°K) 1.425 5.0 350
III, IV
Vapour heat capacity (kJ/kg·°K) 0.851 10.0 415
Heat of vaporization at boiling point (kJ/kg) 216.98 15.0 488
Vapour pressure III (kPa) 665.0 20.0 572
III
Liquid thermal conductivity (W/m·°K) 0.081 25.0 665
III
Vapour thermal conductivity (W/m·°K) 0.0138 30.0 770
III
Liquid viscosity (μPa·sec) 197.9 35.0 887
Vapour viscosity III (μPa·sec) 11.8 40.0 1017
% Volatiles by volume 100 45.0 1160
Solubility of Genetron 134a in water (wt.%)
®
0.15 50.0 1318
Solubility of water in Genetron 134a (wt.%) ®
0.11
II
Flammability limits in air (vol.%) None
Auto ignition temperature (°C) 770
Ozone Depletion Potential (ODP-R11=1) 0
I
Relprop v6.01 (NIST)
II Copyright
Flame limits measured using ASTM E681 with electrically activated © Sandvik
kitchen ignition source per ASHRAE Standard 34. 145 (180)
III
ID: BG00420000 en-US A.002.1 2015-09-09
All data are at 25°C unless noted otherwise
IV
at 101.3 kPa
Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

Compatibility with plastics formulations of these materials, we The rankings in the table should be used
and elastomers recommend that compatibility testing be with caution since they are judgements
The table below is a summary of performed on the specific grade of based on limited samplings.
materials compatibility data resulting from materials under consideration when Customers should consult with the
tests performed by Honeywell and other designing new systems. This data should manufacturer or conduct further
worldwide industry organisations. be used only as a guide to the compatibility independent testing.
Since there are many different grades and of materials with Genetron 134a. ®

Compatibility with plastics and elastomers Applications


Material ®
Genetron Genetron ®
Genetron ®
Refrigeration and air-conditioning
134a 134a/PAG 134a/Polyol Esters In the automotive industry, manufacturers
Ethylene Propylene Diene Terpolymer S S S are using Genetron® 134a in the air-
Ethylene-Propylene copolymeer S S S conditioning systems of all vehicles.
Chlorosulfonated Polyethylene S Us Us
Polyisoprene S Su U Genetron® 134a has been developed for
Chlorinated Polyethylene Su Su Us a number of refrigeration applications
Neoprene (Chloroprene) S S Su including supermarket cases, walk-in
Epichlorohydrin S Su Us coolers and home refrigerators.
Polyvinylidene Fluoride and copolymer U S Us Genetron® 134a is also being used in
of Vinylidene Fluoride and some centrifugal chillers.
Hexafluoropropylene
Silicone Us S Su Genetron® 134a is suitable for both new
Polyurethane S U Su equipment and for retrofitting existing
Nitrile Su Su Su R-12 commercial refrigeration systems.
H-NBR S Su S Generally, there will be few equipment
Butyl rubber S S Su design changes necessary to optimise the
Natural rubber Su U U performance of Genetron® 134a in these
Polysulfide S U U applications. For retrofitting commercial
Nylon S Su Su refrigeration systems, refer to Genetron®
Polytetrafluoroethylene S S S 134a retrofitting guidelines.
PEEK S S S
ABS S U U
Polypropylene Su Su S Solubility of water in
Polyphenylene Sulfide Su U Su Genetron® 134a
Polyethylene Terephthalate S U S The solubility of water in Genetron® 134a
Polysulfone S Us S is shown in the graph below. This
Polyimide S Su Su solubility is comparable to that of water
Polyetherimide S Su S in Genetron® 22.
Polyphthalamide S U U
3000
Solubility of water in Genetron® 134a (in ppm)

Polyamideimide S S S
2500
Acetal S U U
2000
Phenolic S S Su
1500
Epoxy resin S S S
1000
S: Suitable
500
Su: Suitable with some exceptions
0
U: unsuitable -20 -10 0 10 20 30 40 50
Temperature (C)
Us: Unsuitable with some exceptions

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2 www.honeywell.com
Factory filled oils - lubricants and coolants for underground rigs;
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Lubricants Leak detection to high-temperature sources (such as


Genetron® 134a is being used with Use leak detectors for pinpointing leaks welding, brazing and open flames) until
polyalkylene glycol (PAG) and with polyol or for monitoring an entire room on a they have been thoroughly cleaned and
ester lubricants. Most automotive original continual basis. Leak detection is found free of vapours or liquid. Cylinders
equipment manufacturers have chosen important for refrigerant conservation, must never be exposed to welding,
specific PAG lubricants for their systems. equipment protection and performance, brazing or open flames. Exposure to high
For non-automotive applications, most reduction of emission and protection of temperatures can cause fire, explosion
compressor manufacturers are those coming in contact with the system. and decomposition of Genetron® 134a.
recommending specific polyol ester Never use air to perform leak detection. This may result in the formation of toxic
lubricants. Users should check with the or corrosive compounds.
equipment manufacturer for the
recommended lubricants for their system. Storage and handling When possible, maintenance or cleaning
Bulk and cylinder of equipment should be performed
Genetron® 134a cylinders must be clearly without entering the vessel. If a tank or
Safety marked and kept in a cool, dry and any confined space must be entered,
Honeywell recommends reading the properly ventilated storage area away then formal confined space entry
Material Safety Data Sheet (MSDS) from heat, flames, corrosive chemicals, procedures must be followed. These
before using Genetron® 134a. fumes, explosives — and be otherwise procedures require that a fully qualified
protected from damage. Under no work team be used and a confined
Toxicity circumstances should an empty cylinder space entry form be completed and
Genetron 134a can be safely used in
®
be refilled with anything other than virgin placed at the job site.
all of its intended applications, based on product. Once empty, properly close the
data developed by the Program for cylinder valve and replace the valve cap.
Alternative Fluorocarbon Toxicity Testing Return empty cylinders to your Honeywell
(PAFT 1). distributor.

Leaks Cylinders of Genetron® 134a should be


If a large release of Genetron® 134a kept out of direct sunlight, especially in
vapour occurs, the area should be warm weather. Liquid Genetron® 134a
evacuated immediately. Vapours may expands significantly when heated,
concentrate near the floor, displacing reducing the amount of vapour space left
available oxygen. Once the area is in the cylinder. Once the cylinder
evacuated, it must be ventilated using becomes liquid-full, any further rise in
blowers or fans to circulate the air at temperature can cause it to burst,
floor-level. potentially resulting in severe personal
injury. Never allow a cylinder to get
Flammability warmer than 52°C.
According to ASHRAE Standard 34,
Genetron® 134a is classified in safety Vessels, containers, transfer lines, pumps
group A1, i.e., it is nonflammable at 1 and other equipment used with
atm. pressure (101.3 kPa) and 18°C. Genetron® 134a should not be exposed

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www.honeywell.com 3
Factory filled oils - lubricants and coolants for underground rigs;
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Available literature Pressure-Enthalpy Diagram


Honeywell has a wide range of literature
available on topics including: retrofitting Genetron® 134a-SI
procedures, product specifications and
10 115 130
product descriptions.

J/kg-K

180
Please ask for Honeywell’s software

.70 k
T=-20°C -5 10 25 40 50 70 85 100 250

185
py= 1
169
package containing Refrigerant Properties,

Entro

0
114

19
Cycle Analysis and Pipe Sizing. 77.0

5
19
52.0

200
All literature and information can be found at:
35.0
www.honeywellrefrigerants.com 1

5
24.0

20
Pressure, MPa

16.0

0
21
11.0

7.0
3
kg/m
Density= 5.0

0.1
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

0.01
100 150 200 250 300 350 400 450 500 550
Enthalpy, kJ/kg

Disclaimer
Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guarantee
or warranty of any kind, express or implied. Information provided herein does not relieve the user from the responsibility of carrying out
its own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained. Statements or
suggestions concerning the use of materials and processes are made without representation or warranty that any such use is free of patent
infringement and are not recommendations to infringe any patent. The user should not assume that all toxicity data and safety measures
are indicated herein or that other measures may not be required.

Honeywell Fluorine Products


Europe B.V.
Laarderhoogtweg 18
1101 EA Amsterdam
The Netherlands

Honeywell Belgium N.V.


Haasrode Research Park,
Grauwmeer 1
B-3001 Heverlee
Belgium
Tel: +32 16-391 278
Fax: +32 16-391 277
DS134a-UK-HRE 0507-2
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Factory filled oils - lubricants and coolants for underground rigs;
Normal conditions

Safety Guidelines
Safety first Many fluorine based refrigerants can become combustible under
Safety and environmental protection begins with observing basic pressure when mixed with air and/or oil. Because of this combustibil-
precautions and following simple procedures. Honeywell Refrigerants ity potential under pressure, the refrigerants should never be mixed
Europe recommends reading the Materials Safety Data Sheet in tanks or supply lines, or allowed to accumulate in storage tanks.
(MSDS) before using any chemical products, including our full range Leak-checking should never be done with a mixture of the fluorine
of fluorine chemical products. refrigerants and air.

Inhalation Thermal stability


Please consult the MSDS for specific inhalation permissible exposure It is important to avoid exposing these chemicals to very high
limits (PEL) for the products you intend to use. temperatures. When exposed to high temperatures, such as those
found in flames, the vapours will decompose. This may produce
Toxicity toxic and irritating compounds.
The products which Honeywell offers can be safely used in all Pungent odours released will irritate the nose and throat and generally
of their intended applications when handled in accordance with force evacuation of the area. Please consult the product MSDS for
the MSDS. This is based on data developed by the Program for specific details on material compatibility and thermal stability.
Alternative Fluorocarbon Toxicity Testing (PAFTS, 1 1 1 and V), an
international consortium of which Honeywell is a charter member.
Honeywell recommends always reading the MSDS before using any Storage and handling
of its products.
Bulk and Cylinder
Skin and eye contact Different fluorine refrigerants have varying pressure ratings.
When handling refrigerants always wear safety glasses and gloves. All fluorine chemical products must be handled with careful
Also, skin should be protected. Many fluorine based refrigerants can attention to the design pressure rating of the handling equipment.
irritate the skin and eyes. In liquid form, they can freeze skin or eyes All storage shipping containers – cylinders, storage tanks, tank trailers
on contact. If contact with skin should occur, flush the exposed area or tank cars – must be appropriately designed to handle the product.
with lukewarm water until all of the chemical is removed. If there is Fluorine refrigerants must be clearly marked and kept in a cool,
evidence of frostbite, bathe in lukewarm water. Should eye contact dry and properly ventilated storage area, away from heat, flames,
occur, immediately flush with large amounts of lukewarm water for corrosive chemicals, fumes and explosives, and be otherwise
at least 15 minutes, lifting eyelids occasionally to facilitate irrigation. protected from damage. Keep cylinders out of direct sunlight,
Seek medical attention as soon as possible. especially in warm weather. Never allow a cylinder to become
warmer than 52°C. Any evidence of a leak, visual or by a leak
Leaks detector must be corrected immediately, by either stopping the
If a large release of a fluorine chemical vapour occurs, the area leak or transferring all products from the leaking container into a
should be evacuated immediately. Vapours may concentrate near secure container to allow for repairs. Cylinders should only be filled
the floor, displacing available oxygen. Once the area is evacuated, to 75% of their capacity.
it must be ventilated using blowers or fans to circulate the air at Before performing maintenance in areas where fluorine chemicals
floor-level: the lowest point possible. have accumulated, a thorough pre-job review must be done to
determine respiratory protection requirements, as well as the
Flammability other safety equipment needed. Vapours may concentrate near
Please consult the MSDS of the product to determine whether it is the floor, displacing available oxygen.
flammable. Cylinders, vessels, containers, transfer lines, pumps and other
equipment used with fluorine gases, should not be exposed to
Combustibility high¬temperature sources, such as welding, brazing and open
flames, until they have been thoroughly cleaned and found free of
vapours or liquid.

Copyright © Sandvik 149 (180)


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Available conditions
Honeywell has a wide range of literature
available on topics including: retrofitting
procedures, product specifications and
product descriptions.
Please ask for Honeywell’s software
package containing Refrigerant Properties,
Cycle Analysis and Pipe Sizing.
All literature and information can be found at:
www.honeywellrefrigerants.com

Disclaimer
Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guar-
antee or warranty of any kind, express or implied. Information provided herein does not relieve the user from the responsibility of car-
rying out its own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained.
Statements or suggestions concerning the use of materials and processes are made without representation or warranty that any
such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that all
toxicity data and safety measures are indicated herein or that other measures may not be required.

­­­Honeywell Chemicals
Honeywell Chemicals
Northern & Central Europe
Haasrode Research Park,
Grauwmeer 1
B-3001 Heverlee (Leuven)
Belgium
Tel: +32 16-391 278
Fax: +32 16-391 277

Honeywell Chemicals
Southern Europe, Middle East & Africa
Viale A. De Gasperi 19,
I-20020 Lainate MI
Italia
Tel:
150 +39
(180)02-9379 6777
SF-UK-HRE 1005-1
Copyright © Sandvik
October 2005
Fax: +39 02-9379 6761 ID:©BG00420000 en-US
2005 Honeywell A.002.1 2015-09-09
International Inc.

www.honeywell.com
Factory filled oils - lubricants and coolants for underground rigs;
Normal
SAFETY conditions
DATA SHEET
according to Regulation (EU) No. 1907/2006

HFC-134a, Genetron® 134a

Version 1.2 Revision Date 28.08.2007 Print Date 09.10.2007

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name : HFC-134a, Genetron® 134a

Use of the : Refrigerant


Substance/Preparation Propellant

Company/Undertaking Identification
Company : Honeywell Fluorine Products Europe B.V.
Laarderhoogtweg 18
1101 EA Amsterdam
Telephone : (31) 020 5656911
Telefax : (31) 020 5656600
Emergency telephone : (32) 14584545
For further information, : SafetyDataSheet@Honeywell.com
please contact:

2. HAZARDS IDENTIFICATION

Risk advice to man and the environment


Does not require a hazard warning label, but the normal safety precautions for handling of chemicals
must be observed.
Additional advice : Rapid evaporation of the liquid may cause frostbite.
High vapour concentrations can cause headaches, dizziness,
drowsiness, and nausea, and may lead to unconsciousness.
May cause cardiac arrhythmia.

See Section 11 for more detailed information on health effects and symptoms.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization

Chemical Name : 1,1,1,2-tetrafluoroethane


Formula : CF3CH2F
CAS-No. : 811-97-2

Hazardous components
Chemical Name CAS-No. EC-No. Index-No. Classification Concentration
[%]
Norflurane 811-97-2 212-377-0 <= 100

Occupational Exposure Limit(s), if available, are listed in Section 8.

4. FIRST AID MEASURES

Inhalation : Remove to fresh air.


Artificial respiration and/or oxygen may be necessary.
Call a physician immediately.

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HFC-134a, Genetron® 134a

Version 1.2 Revision Date 28.08.2007 Print Date 09.10.2007

Skin contact : Rapid evaporation of the liquid may cause frostbite.


In case of contact with liquid, thaw frosted parts with water,
then remove clothing carefully. Wash with plenty of water
Consult a physician.
Take off contaminated clothing and shoes immediately.
Wash contaminated clothing before re-use.
Eye contact : Remove contact lenses.
Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Ingestion : As this product is a gas, refer to the inhalation section.
Do not induce vomiting without medical advice.
Never give anything by mouth to an unconscious person.
Call a physician immediately.

Notes to physician
Treatment : Do not give adrenaline or similar drugs.

See Section 11 for more detailed information on health effects and symptoms.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing : The product is not flammable.


media ASHRAE 34
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Specific hazards during fire : Possibility of generating hazardous reactions during a fire due
fighting to the presence of F and Cl groups.
Heating will cause pressure rise with risk of bursting
Cool closed containers exposed to fire with water spray.
This product is not flammable at ambient temperatures and
atmospheric pressure.
However, this material can ignite when mixed with air under
pressure and exposed to strong ignition sources.
Special protective : Wear self-contained breathing apparatus and protective suit.
equipment for fire-fighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately contact emergency personnel.


Wear personal protective equipment. Unprotected persons
must be kept away.
Ensure adequate ventilation.
In case of insufficient ventilation wear suitable respiratory
equipment.
Environmental precautions : Prevent further leakage or spillage if safe to do so.
The product evaporates readily.

For personal protection see section 8.

7. HANDLING AND STORAGE

Handling
Advice on safe handling : Open drum carefully as content may be under pressure.
The product should only be used in areas from which all naked
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HFC-134a, Genetron® 134a

Version 1.2 Revision Date 28.08.2007 Print Date 09.10.2007

lights and other sources of ignition have been excluded.


Pressurized container. Protect from sunlight and do not expose
to temperatures exceeding 50 °C.
Do not pierce or burn, even after use. Do not spray on a naked
flame or any incandescent material.
Do not use in areas without adequate ventilation.
Contaminated equipment (brushes, rags) must be cleaned
immediately with water.

Storage
Further information on : Store in original container.
storage conditions Keep away from direct sunlight.
Keep containers tightly closed in a cool, well-ventilated place.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational exposure controls

Components Basis Value Control Exceeding Form of Remarks


type parameters Factor exposure
Norflurane EH40 WEL time 4.240
weighted mg/m3
average 1.000 ppm

Personal protective equipment


Respiratory protection : Remarks: In case of insufficient ventilation wear suitable
respiratory equipment.

Hand protection : Glove material: Viton (R)


Break through time: 240 min
Glove thickness: 0,7 mm
Vitoject 890
Heat insulating gloves

Eye protection : Safety glasses with side-shields conforming to EN166


Face-shield

Skin and body protection : Protective footwear

Protective measures : The Personal Protective Equipment must be in accordance


with EN standards:respirator EN 136, 140, 149; safety glasses
EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2;
gloves EN 374, safety shoes EN-ISO 20345.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Form : Liquefied gas

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HFC-134a, Genetron® 134a

Version 1.2 Revision Date 28.08.2007 Print Date 09.10.2007

Colour : colourless

Odour : weak

molecular weight : 102,02 g/mol

Safety data
Melting point/range : -101 °C

Boiling point/boiling range : -26,2 °C

Flash point : Remarks: not applicable

Auto ignition temperature : > 750 °C

Density : 1,2 g/cm3

Water solubility : 1,5 g/l

Partition coefficient: n- : log Pow 1,06


octanol/water Remarks: The product is more soluble in octanol.

Relative vapour density : 3,5

Evaporation rate : >1


Method: Compared to CCl4.

10. STABILITY AND REACTIVITY

Conditions to avoid : Heating will cause pressure rise with risk of bursting
Pressurized container. Protect from sunlight and do not expose
to temperatures exceeding 50 °C.
Do not pierce or burn, even after use. Do not spray on a naked
flame or any incandescent material.

Materials to avoid : oxidising substances


Possible incompatibility with alkali sensitive materials.
Powdered metals

Hazardous decomposition : Halogenated compounds


products Hydrogen fluoride
Carbonyl halides
Carbon oxides

Thermal decomposition : >250 °C

11. TOXICOLOGICAL INFORMATION


Acute inhalation toxicity : LC50
Species: rat
Dose: > 500000 ppm
Exposure time: 4 h
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HFC-134a, Genetron® 134a

Version 1.2 Revision Date 28.08.2007 Print Date 09.10.2007

Repeated dose toxicity : Species: rat


NOEL: 40000 ppm

Information derived from : Inhalation: May cause cardiac arrhythmia.


practical experience. Ingestion: No hazards to be specially mentioned.
Skin contact: Rapid evaporation of the liquid may cause
frostbite. Irritating to skin.
Eye contact: Irritating to eyes.
Cardiac sensitisation threshold (dog): 80000 ppm.

12. ECOLOGICAL INFORMATION

Ozone Depletion Potential : 0


(ODP)

Global warming potential : 1.300


(GWP)

Additional ecological : Accumulation in aquatic organisms is unlikely.


information

13. DISPOSAL CONSIDERATIONS

Product : Offer surplus and non-recyclable solutions to a licensed


disposal company.
Refer to manufacturer/supplier for information on
recovery/recycling.

Remarks : To present knowledge of the supplier, this product is not


regarded as hazardous waste as defined by EU Directive
91/689/EC.

Waste key for the unused : Classification: 14.06.01


product

14. TRANSPORT INFORMATION

ADR
UN Number : 3159
Description of the goods : 1,1,1,2-TETRAFLUOROETHANE
Class : 2
Classification Code : 2A
Hazard identification No : 20
Hazard Label : 2.2

IATA
UN Number : 3159
Description of the goods : 1,1,1,2-Tetrafluoroethane
Class : 2.2
Hazard Label : 2.2
Packing instruction (cargo : 200

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HFC-134a, Genetron® 134a

Version 1.2 Revision Date 28.08.2007 Print Date 09.10.2007

aircraft)
Packing instruction : 200
(passenger aircraft)

IMDG
UN Number : 3159
Description of the goods : 1,1,1,2-TETRAFLUOROETHANE
Class : 2.2
Hazard Label : 2.2
EmS Number : F-C
Marine pollutant : no

RID
UN Number : 3159
Description of the goods : 1,1,1,2-TETRAFLUOROETHANE
Class : 2
Classification Code : 2A
Hazard identification No : 20
Hazard Label : 2.2

15. REGULATORY INFORMATION

Labelling according to EC Directives 1999/45/EC


Further information : Not a hazardous substance or preparation according to EC-
directives 67/548/EEC or 1999/45/EC.
The product does not need to be labelled in accordance with
EC directives or respective national laws.

Other regulations : EU Regulation 842/2006/EC


Restricted to professional users.
For industrial use only.

16. OTHER INFORMATION

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Final determination of suitability of any
material is the sole responsibility of the user.
This information should not constitute a guarantee for any specific product properties.

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