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Solutions to JEE Main – 2 |JEE - 2022

PHYSICS
SECTION-1
1.(B) a  4x
vdv
 4x
dx
v x

 
vdv  4 xdx
0 0
2
v 4 x2

2 2
v2  4x 2
v 2  400
v  20 m / s
2.(C) R  L sin 
(1) T sin   mv 2 / R
(2) T cos   mg
mv 2 v2
tan    tan  
mgR ( L sin ) g
1/ 2
 Lg 
v  Lg tan 30º sin 30º   
2 3
3.(A) Force required to stop the liquid AV 2 .
4.(D)

At the time of release both ball and person B has same speed vrel  0 . According to B ball has free fall.
For A ball will move up for some time.

5.(D) Slope of x  t graph is velocity

Slope at t  8 is zero hence velocity = 0

6.(B) v y  20sin 30º  10 m /s

g 3
a y  g cos  
2
vy 10 4
Time of flight  2  2 
ay  10 3  3
 
 2 

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v 2 sin 2  v2
7.(A) H , R  sin 2
2g g
On solving
4 4
tan   so sin  
3 5
v 2 16 200 g
4  v
2 g 25 16
g
v5
2
8.(C) x  6t , x  v cos t
1 2
y  8t  5t 2 y  v sin   t  gt
2
On comparing
8  v sin 
6  v cos 
4
tan 
3
4
So, sin   v  10 m /s
5
v2
9.(B) H sin 2 
2g

For same range 1  2  90º 
2
v2 3
for 1 , h1  
2g 4
v 2 1 h1
for 2 , h2   
2g 4 3
Force external
10.(B) Common acceleration of system 
Total mass

40
 4 m /s 2
10

So N  8  4  32 N

11.(B) Max acceleration of 1 kg  f  ma

f  N  ma a  g  2m / s 2

So to move together whole system should move together with a  2m / s 2

F  5  2  10 N

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12.(C) Net force on system = 10 N

Total mass = 5 kg
10
Acceleration of system   2
5
T  10  1  2
T  12 N

13.(B) Velocity along the rope is 10cos

All velocities along rope are equal

10cos   5,    60º
3
14.(C) To avoid slipping
a  g tan 
10  10 tan 
  45º
g 1 g g 2
15.(D) a  g sin   k g cos      
2 3 2 2 3
distance  10 2m
1 g 2 2
10 2   t
2 2 3
t2  6
t  6 sec
16.(D) By constraint acceleration will not be same
ma
(1) mg  2T 
2
(2) T  mg sin 30º  ma
On solving a  0
So, acceleration of block B is a  0
17.(D) Area under v  t is displacement
1
A   100  500  25 km
2
18.(A) u  V , V f   4V , a   g , h  ?

(4V ) 2  (V ) 2  2( g ) h
15V 2
h (‘–‘ ve sign shows that displacement is downward)
2g
19.(A) v  2t
at  2
v(2)  4m / s
v2
av  16
R
atotal  (162  22 )1/2  (260)1/2  (4  65)1/2  2 65 m / s 2

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20.(C) v  4t 2
p  mv  8t 2
dp
F  16t F (t  4)  64 N
dt
SECTION-2
1.(4) Vrel  24 m /s
arel  (10  2)  12 m /s 2
 2v 
t   rel   2  2  4 sec
 arel 
2.(8) Area of F-t graph = change is momentum = 12 kg m/s
m(V f  Vi )  12 V f  8m / s

3.(16)

g( effective)  10  6  4
So, FBD of block in lift’s frame

 N  4  4  16

4.(24)
2H
Time of flight   4 as v y  0
g
Range 1  20  4  80
Range 2  40  4  160
Total distance between than  240 m
 10 x  240
x  24
5.(10) mg  N  100 g
2
mVmax
N 
R
2
mVmax
mg 
R
2
Vmax
5
20
Vmax 10m / s

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CHEMISTRY
SECTION-1
1.(C) (I) (Fluorine), (II) (Oxygen), (III) (Chlorine), (IV) (Phosphorus)
Chlorine has highest value of 1st Electron gain enthalpy (magnitude)
2.(B) H — O — N  O
0 0 0 0

3.(B)  theo  4.8 1010 1.6  108  7.68  1018 esu.cm  7.68 D
3.2
% ionic character  100  41.6%
7.68
 Z2 
4.(D) I.E.4 of Be   2 13.6  1.6  1019  J  16  13.6 1.6  1019  348.16  1019
n 
 Y  1019 J  Y  348.16
5.(D) w = work function of potassium
hc
E1   w  (0.32  1019 )
1

hc
E2   w  (0.96  1019 )
2

 1 1 
E 2  E1  hc     (0.64  10 19 )J  sec
 
 2 1 

1   2 (5000  1010 ) (4000  1010 )

h  0.64  1019   0.64  1019 J s
c(1   2 ) 3  108 (1000  1010 )

 4.27  1034 J  sec

6.(D)

7.(B) SO 24  : Central atom sp3 -hybridised hence tetrahedral.

NF3 : N  sp3 -hybridised with one lone pair hence pyramidal.
ICl3 : I  sp3d -hybridised with two lone pair hence T-shaped.
XeF4 : Xe  sp3d 2 -hybridised with two lone pairs hence square planar.

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h
8.(C) m  4mp ; q   2q p ;  =
2m q V
h h
  
2  m  q   V 2  4m p  2q p  V

h  1 1 1
P     
2  mp  qp  V p 4 2 2 2

9.(A) As the polarizing power of cation decreasing, ionic character increases.

10.(B) There is a large difference between E3 and E 4 values. Hence, number of valence electrons is 3.

h
11.(C) n = 3 ; n – l – 1 = 1  l  1; L  l (l  1) 
2
12.(B) For He (  2)

1 1 1 1  1
  R  Z2  2  2   R
 x 2   x

For Li 2 (4  3)

1 1 1 1 16  9  16x
 R  32  2  2    9    
 3 4  x  9  16  7

13.(D)
14.(D) a  0, b  5, a  b  5

h h 6.63 1034
15.(D) x  p   v    5.8 109
4 4 x  m 4  3.14  1014  9.1 1031

16.(C) Radius (x1 ) of n th orbit for H-atom  r1  n 2

If n is lower orbit, the next orbit = n + 1
and x 2  r1 (n  1) 2  r1 (n 2  2n  1)
x 2  x1  r1 (2n  1)
If n is higher orbit, then consecutive lower orbit = n – 1
and x2  r1 (n  1) 2  r1 (n 2  2n  1)
x1  x2  r1  n 2  r1 (n 2  2n  1)  r1  (2n  1)

17.(A) In isoelectronic ions, the atomic size decreases as z/e ratio increases
Ions z/e ratio
S2 16/18
Cl 17/18
 19/18
K
Ca 2 20/18

18.(C)

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19.(B) The organic compound contains 16, 4 bonds.

20.(C) 9 lone pairs.

SECTION-2

1.(33) x = 18 y=1 z = 14

2.(4) SOF4 is sp3d hybrid but contains no lone pair

SeF3 and SeOCl2 contains lone pairs in sp3 orbitals (no d-character)
XeF5 is square pyramidal with one lone pair
BrF6 sp3 d 3 hybridised is distorted octahedral containing one lone pair
TeF5 and ICl4 are sp3d 2 hybrid with one and two lone pairs respectively.

3.(1) Total energy needed to convert one Mg atom into Mg 2

(gas) ion = IE I  IE II
= 22.681 eV
 2268.1 kj mol 1
12 mg of Mg  0.5 103 mole
Amount of energy needed  2268.1  0.5  103  1.13405  1  1 kJ
4.(6)
10  4
9  4
8  4
 Total 6 spectral lines in bracket series
7  4
6  4

5  4

5.(48) 7s 5f 6d 7p  subshells to be filled in 7th period

Number of orbitals = 1 + 7 + 5 + 3 = 16
Number of electrons = 16 × 3 = 48

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MATHEMATICS
SECTION-1
1.(B) z17  z27  z37  ......z77  1
2.(D) i1!  i 2!  i 3!  i 4!  i5!  ......i(101)!
i1  i 2  i6  1  1

98
 96  i
2
3.(C) 10
 10  103  .....
   2

4 
 6 
....
n n
n
10(10  1)
 n2  n
9
4.(C) a  , b  2
r
5.(C) pr  [2(r  1)  (r  1)(2r  2)]
2
pr  r ( r  1  (r  1)( r  1)
pr  r ( r  r 2 )
pr  r 2  r 3
n
n( n  1)  2n  1 n(n  1)   4n  2  3n 2  3n  n( n  1)(3n 2  7n  2)
 pr 
2  3

2 
 n ( n  1) 
12
 
12
r 1  
n( n  1)(3n  1)(n  2)

12
6.(D) General term = (4k  3) 2  (4k  2)2  (4k  1) 2  (4k ) 2  4(8k  3) (if 4 terms are taken as terms)
5 6
S 20  32   60(8  1)
2
S 20  60  7  420
S 20  400  S19  20
( z )2 ( x  iy ) 2 x 2  y 2  2ixy
7.(A) 2
  First quadrant
z x2  y 2 x2  y2
8.(D) S n  n(n  1)( n  2)(n  3)
S n1  ( n  1)(n)( n  1)( n  2)
Tn  4n(n  1)(n  2)
1 1 1 1 
   
Tn 8  n( n  1) (n  1)(n  2) 
1
S 
16
9.(B) cos 2  i sin 2  cos   i sin 
cos 2  cos   i(sin 2  sin )
 
 3   3 3     3  i  
  2 sin sin   i 2cos sin  i 2sin  cos  i sin   2sin   e  2 2 
 2 2 2 2 2  2 2  2 
2 z  n 4i  1 4z 4i
10.(C)   
2z  n 1 2n 2  4i

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z i (1  2i )

n (1  2i)(1  2i)
z 2i

n 5
2n n
30  iy    i
5 5
2n
  30
5
n  75
11.(B) S  t  2t 2  3t 3  ....9t 9
tS  t 2  2t 3  .....8t 9  9t10
S (1  t )  t  t 2  t 3  .....t 9  9t10 { t , t 2 , t 3 .....t 9 is sum of 9th root of unity}
S (1  t )  9t10
9t
S 
(1  t )
9 9 9
S   
1  t 1  cos   i sin  2sin 20º
2
12.(C) z 1 z r
z
2 2
z  z
z z
2 2
r 1  1 r  1
r r
r  [1, 2]
z [1, 2]
22  1
13.(D) x11  1  ( x  1)( x  1 )( x   2 )......( x  10 )  (2  1 )(2   2 ).........(2  10 ) 
2  1
11  1
(  1 )(   2 ).............(  10 ) 
 1
(  1)
(2  1 )(2   2 )..........(2  10 ) (2  1) (  1)(  1) 1 1
 2   4   2
(  1 )(   2 ).................(  10 )  1 (   1)(   1)(   1)(   1)  
(  1)
2k (2k  4)(4k  1)
14.(A) 1  22  3  42  5  62......  (2k )2 
12
2 k (2 k  4)(4k  1)
1  22  3  42  ....  (2k ) 2  2k  1   (2k  1)
12
(n  1)( n  3)(2n  1)
n
12
n (  N ) 3(  N )
15.(C) a  b  c    30
2 2
  N  20
1 1 1 3 1 1 
     
p q r 2  N 

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5 3  20 
    N  36
6 2  N 
16.(B) nth row’s 1st term =
1, 2, 4, 7, 11 ……………
Tn  an 2  bn  c
n2  n  2  n  1 n2  n
nth rows last term  
2 2
n2  n  2 n2  n
 100   n  14
2 2
6 6 
2 8
3i
8
2 e 

i
 4 
  
17.(A) z   8
6 6 
 
2  ei 


4 
2 8
3  i  
 8 6    6 8 
216 ei    23 ei   
 6 4   4 6 
z 3
 16
2 2
1
z  213 ei 5  /6  13 ei 5 /6
2
 1 
z   213  13  ei 5  /6
 2 
1 (n  1) n  ( n  1) n 1 1
18.(A) Tn    
n n  1  (n  1) n n(n  1) n n 1
1 1 7
S  
3 24 24

19.(B) S n 2  Sn  ( n  2) 2
S10  S8  102
S8  S 6  82
S6  S4  62
S 4  S2  42
S10  S 2  42  62  82  102
 S10  4(12  22  32  42  52 )
20.(A) z 6  z 3  1  0
z3   or z 3  2
 2   4 
i  2k   i  2k  
3  3  3  3 
z e or z e
2 8 14  4 10  16 
i
9 ,
i
9 ,
i
9 ,
i i
9 ,e 9
i
9
10
ze e e e ,e  
9

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SECTION-2
1.(3) a p2
ar 2  p  6
p2 1

p  6 r2
p2 1
 9 or
p6 9
a  ar 2
2 5

ar 3
2
r 1 5

2r 3
2
3r  3  10r
1
r  3, r 
3
2.(6) 1  4  4i  a  2ia  ib  0
3  a  i(4  2a  b)  0
a  3 b  10
10i (1  2i)
(1  2i)  10i  
(1  2i) (1  2i)
  4  2i

2 ( a  b) 2  (b  c )2  (c  a) 2
3.(27) a  b  c2 
2
a  3n, b  3n  3, c  3n  6
2
a  b  c2  27

a b c d 2
   
4.(3) 2 3 4 9 3  4 abcd
4 2  3 4 9
AM = GM
a b c d 2
   
2 3 4 9 3 4
abcd 3
1 1 1 1  1 1 1
5.(15)  3  3  3 ........   3  3  3 .....  p
8 1 2 3  1 3 5
p
q p
8
7 p 8
q p  
8 q 7

Solutions | Page 11 JEE Main – 2 | JEE – 2022