ALLEN CHEMISTRY AT A GLANCE 33

SOLUTION 429. Density of 12.25% (w/w) H2 SO 4 solution is

1.052 g/ml then molarity of solution is :-
422. In an aqueous solution ethylene glycol has the
mass percentage (% w/w) 30% then the mole (1) 1.315 M (2) 2.63 M
fraction of ethylene glycol will be :- (3) 0.657 M (4) 1 M
(1) 0.428 (2) 0.124 430. Incorrect relationship for mole fraction is :-
(3) 0.11 (4) 0.889 (1) X < 1 (2) 0 < X < 1

423. What will be the mass percentage of resulting (3) –2 < X < + 2 (4) Always positive
solution prepared by mixing 15% (w/w) 500 g 431. 0.1 molal solution of Hg(NO 3 ) 2 freezes at
aqueous solution of urea with 25% (w/w) 400g –0.558°C. The cryoscopic constant for water
aqueous solution of it :- is 1.86 KKg mol –1 then what will be the
percentage ionisation of salt ?
(1) 18% (2) 20%
(1) 33.33% (2) 50%
(3) 25% (4) 15%
(3) 75% (4) 100%
424. What will be the molality of solution prepared
by dissolving 3.7 g propanoic acid in 80 g 432. Which of the following solution has maximum
benzene ? vapour pressure :-

(1) 0.77 m (2) 0.625 m (1) 1 N KNO3 (2) 1 N Ba(NO3)2

(3) 1 N Al2 (SO4)3 (4) 1 N Ti(NO3)4
(3) 0.045 m (4) 46.25 m
433. When HgI2 is added in KI solution. The freezing
425. If the sea water is 3.5% (w/w) aqueous solution
point of solution :-
of NaCl then its molality will be :-
(1) increases
(1) 0.598 (2) 36.27 m
(2) decreases
(3) 0.62 m (4) 0.578 m
(3) Remains unchanged
426. 10% (w/v) solution of glucose is isotonic with
(4) Can't predict
4% (w/v) solution of non-volatile solution then
molar mass of non-volatile solute will be :- 434. A solute dissociates in solution according to
reaction 2A ® 5B, If solute shows 30%
(1) 36 (2) 72 (3) 54 (4) 63
dissociation then van't Haff factor will be :-
427. The vapour pressure of mixture of toluene and
(1) 2.2 (2) 1.45 (3) 2.9 (4) 1.9
xylene at 90°C is 0.5 atm. If at this temperature
vapour pressure of pure toluene and xylene 435. An aqueous solution of urea [6% w/v] is
are 400 mm and 150 mm respectively then what isotonic with NaCl solution then mass-volume
will be the mole fraction of toluene in percentage (%w/v) of NaCl solution will be :-
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mixture? (1) 1.46% (2) 5.85%

(1) 0.08 (2) 0.92 (3) 2.92% (4) 11.7%
(3) 0.88 (4) 0.46 436. The vapour pressure of pure liquid A and liquid
428. What will be the freezing point of 0.2 molal B at 350 K are 440 mm and 720 mm of Hg. If
aqueous solution of MgBr2 ? If salt dissociates total vapour pressure of solution is 580 mm of
40% in solution and Kf for water is 1.86 KKg Hg then the mole fraction of liquid A in vapour
mol–1 phase will be :-
(1) –3.35°C (2) –0.67°C (1) 0.31 (2) 0.38
(3) –0.6°C (4) –0.45°C (3) 0.62 (4) 0.76

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34 CHEMISTRY AT A GLANCE ALLEN
437. If T1 , T2 and T3 are boiling points of component 443. Which of the follow ing relationship is
A, component B and azeotropic mixture then correct? (A ® solvent; B ® solute )
which of the following relation is correct for a
minimum boiling azeotrope :- P o - PS PBo - X B
(1) = XA (2) YB = PAo
Po
(1) T1 < T3 (2) T2 < T3
(3) T3 < T1 (4) T3 = T2 (3) PA = PAo XA (4) PS = PAo X A + PBo X A
438. Which of the following relationship is correct ?
444. What will be the osmotic pressure of 5% (w/v)
RTb2 RTb2
K
(1) b = K
(2) b = aqueous solution of urea at 17°C ?
1000 ´DVv 1000 L v
(1) 19.81 atm (2) 1.16 atm
RTf2 RTf2 ´ M
K
(3) f = K
(4) f = (3) 1.981 atm (4) 6.61 atm
1000 DH f 1000 ´ L f
445. Van't Hoff factor is 1.92 for MgI2 solution with
439. If the solubility product of CuS is 6 × 10 . –6
concentration 0.2M then the degree of
Calculate the maximum molarity of CuS is dissociation of salt at this concentration is :-
aqueous solution
(1) 46% (2) 96%
(1) 2.45 × 10 mol L
–8 –1
(3) 30.67% (4) 64%
(2) 1.5 × 10–5 mol L–1 446. The vapour pressure of any liquid shows
following change with temperature :-
(3) 3.5 × 10–2 mol L–1
(1) Exponential increase
(4) 2.45 × 10–3 mol L–1
(2) Exponential decrease
440. Which of the following 0.2m aqueous solutions
(3) Linear increase
will show minimum freezing point :-
(4) Linear decrease
(1) CaCl2 (2) K2 SO4
447. During dissolution of gas in liquid solvent :-
(3) Al(NO3)3 (4) KBr (1) Heat is released
441. For which of the following solutions observed (2) Heat is absorbed
boiling point is greater than theoretical boiling (3) No heat transfer takes place
point ?
(4) Colour of liquid solvent is always changed
(1) CHCl3 + CCl4 448. 18 g glucose (C6 H12O6 ) is added to 178.29 of
(2) CCl4 + SiCl4 H 2 O the vapour pressure of water for this
aqueous solution at 100°C.
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(3) CHCl3 + CH3COCH3

(1) 759 torr (2) 7.60 torr
(4) C6H5CH3 + C6H6
(3) 76 torr (4) 752.4 torr
442. The boiling point of solution obtained by
449. The solubility of gases in liquid is maximum
dissolving 0.51 g anthracene in 35 g
at :-
chloroform increases by 0.32°C then what will
(1) Low temperature and low pressure
be the molar mass of anthracene if for
chloroform Kb = 3.9 K Kg mol–1 :- (2) Low temperature and high pressure
(3) High temperature and high pressure
(1) 175.2 (2) 177.6
(3) 178.6 (4) 182.3 (4) High temperature and low pressure

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 ALLEN CHEMISTRY AT A GLANCE 35
450. If solubility of vinyl chloride (g) is 0.09 M at 456. Which of the following will have maximum
STP then value of henry's constant will be :- depression in freezing point?
(1) 0.0016 bar (2) 617.284 bar (1) 0.5 M Li2SO4
(3) 6.17 × 10–2 bar (4) 308.642 bar
(2) 1M KCl
451. Which of the following statement is incorrect:-
(3) 0.5 M BaCl2
(1) In solution of volatile liquids partial pressure
(4) 1M Al2(SO4)3
of any component is directly proportional
to its mole fraction in solution. 457. 1.00 g of a non electrolyte solute is dissolved
(2) Components of azeotropic mixture can be in 50g of benzene which lowers the freezing
separated in pure form using fractional point of benzene by 0.40K. The freezing point
distillation depression constant of benzene is 5.12 K kg
(3) Total vapour pressure of solution of binary mol–1. Find the molar mass of the solute
volatile liquids, decreases on increasing (1) 206 g mol–1 (2) 226 g mol–1
mole fraction of less volatile component.
(3) 246 g mol–1 (4) 256 g mol–1
(4) At a given pressure, higher the value of
KH, the lower is the solubility of the gas in 458. At 40°C the vapour pressure of pure benzene
the liquid. and toluene are 160 mmHg and 60 mmHg
452. What will be the osmotic pressure of 0.03 N respectively. If equimolar above liquids are mixed
solution of Aluminium sulphate solution at at same temperature to form an ideal solution. Then
27°C? If in solution salt dissociates 90% :- vapour pressure of solution will be
(1) 0.566 atm (2) 0.677 atm (1) 140 mm of Hg
(3) 3.399 atm (4) 4.065 atm (2) 110 mm of Hg
453. What will be the amount of ice separated on (3) 220 mm of Hg
cooling solution of 40g ethylene glycol in 400g (4) 100 mm of Hg
water upto –9.3° C ?
459. Dissolving 120 g of urea (mol wt = 60) in
(Kf for water is 1.86 K Kg mol–1) :-
1000 g of water gave a solution of density
(1) 177.78 g (2) 129.03 g 1.15 g mL–1. The molarity of the solution is
(3) 222.22 g (4) 270.97 g
(1) 1.78 M (2) 2.00 M
454. Which one of the following solution has
(3) 2.05 M (4) 2.22 M
maximum vapour pressure at 27°C temperature ?
460. A binary liquid solution is prepared by mixing
(1) 1M Na2SO4 (2) 1 M AlCl3
n-heptane and ethanol which one of the
(3) 1M KBr (4) 1M MgCl2
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following statement is correct regarding the

455. At 298 K, 1000 cm of a solution containing
3 behaviour of the solution?
4.34 g of solute shows osmotic pressure of (1) the solution formed is an ideal solution
2.55 atm. What is the molar mass of solute? (2) the solution is non-ideal, showing positive
(R = 0.0821 L atm K–1 mol–1) deviation from Raoult's law
(1) 41.64 g mol–1 (3) the solution is non ideal showing negative
(2) 82.73 g mol–1 deviation from Raoult's law

(3) 58.31 g mol–1 (4) n-heptane shows positive deviation while

ethanol shows negative deviation from
(4) 91.65 g mol–1
Raoult's law
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36 CHEMISTRY AT A GLANCE ALLEN
461. What is the g-molecular mass of a nonionizing 468. A solution of a substance containing 1.05 g
solid if 10 g of this solid dissolved in 100 g per 100 mL was found to be isotonic with
of water, forms a solution which froze at 3% w/v glucose solution. The molecular mass
–1.22 °C? (Kf = 1.86 K kg mol–1) of substance is
(1) 265 g/mol (2) 152 g/mol (1) 31.5 (2) 6.3 (3) 630 (4) 63
(3) 130g/mol (4) 65g/mol 469. The vapour pressure of benzene at 90°C is
462. At 293 K, vapour pressure of pure benzene is 1020 torr. A solution of 5g of a solute in 58.5 g
75 mm of Hg and that of pure toluene is benzene has vapour pressure 990 torr. The
22 mm of Hg. The vapour pressure of the molecular mass of the solute is
solution which contains 20 mol% benzene and
(1) 78.2 (2) 178.2
80 mol % toluene is
(3) 200 (4) 220
(1) 32.6 mm Hg (2) 64.4 mm Hg
(3) 97 mm Hg (4) 3.26 mm Hg 470. Which of the following has minimum freezing
point
463. The vapour pressure of pure liquid solvent is
0.80 atm. When a non-volatile substance (Z) (1) 0.1M K2Cr2O7 (2) 0.1M NH4Cl
is added to the solvent, its vapour pressure (3) 0.1M BaSO4 (4) 0.1M Al2(SO4)3
drops to 0.6 atm. What the mole fraction of the 471. What is the correct sequence of osmotic
substance (Z) in the solution
pressure of 0.01 M aq solution of
(1) 0.75 (2) 0.50
(a) Al2(SO4 )3 (p1 ) (b) Na3 PO4 (p2 )
(3) 0.25 (4) 0.33
(c) BaCl 2(p3 ) (d) Glucose (p4 )
464. What will be normality of "20V H 2 O 2 "
Choose the correct option.
solution?
(1) 1.78 N (2) 3.56 N (1) p4 > p2 > p3 > p1 (2) p3 > p4 > p2 > p1

(3) 10N (4) 0.28 N (3) p3 > p4 > p1 > p2 (4) p1 > p2 > p3 > p4

465. Which of the following solution have highest 472. A solution contains nonvolatile solute of
boiling point. (Assume all salts completely molecular mass M2. Which of the following can
dissociate) be used to calculate the molecular mass of
(1) 0.1M Al2(SO4)3 (2) 0.1M BaCl2 solute in terms of asmotic pressure.

(3) 0.1M glucose (4) 0.1M AlCl3

æ m2 ö æ m ö RT
466. What will be the freezing point (in °C) of (1) M 2 = ç ÷ VRT (2) M 2 = ç 2 ÷
è p ø è V ø p
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solution obtained by dissolving 0.1 g

potassium ferricyanide (mol wt = 329) in 100 æ m2 ö æ m2 ö p
g water. If Kf for water is 1.86 K kg mol–1 (3) M 2 = ç ÷ pRT (4) M 2 = ç ÷
è V ø è V ø RT
(1) –2.3 × 10–2 (2) –5.7 × 10–2
473. Normal saline solution is
(3) –5.7 × 10–3 (4) –1.2 × 10–2
467. The van't Hoff factor for 0.1M Ba(NO 3 ) 2 (1) 1N salt solution
solution is 2.74. The degree of dissociation is (2) 0.9% mass/volume NaCl solution
(1) 91.3% (2) 87% (3) 1N NaCl solution
(3) 100% (4) 74% (4) Normal salt solution
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 ALLEN CHEMISTRY AT A GLANCE 37
474. A certain substance ‘A’ tetramerises in water to 481. A solution of benzoic acid dissolved in ben-
the extent of 80%. A solution of 2.5g of A in zene will show a molecular mass closer to -
100g of water lowers the freezing point by (1) 122 (2) 244
0.3°C. The molar mass of A is -
(3) 61 (4) 366
(1) 122 (2) 31 (3) 244 (4) 62
475. Compound PdCl4.6H2O is a hydrated complex; DTb
482. Ratio of k of 10 gm of AB2 & 14 gm A2B in
1molal aqueous solution of it has freezing point b

269.28K. Assuming 100% ionization of 100 gm of solvent in their respective solution

complex, calculate the molecular formula of (AB2 & A 2 B both are non - electrolytes) is
the complex (Kf for water = 1.86 K kg mol–1) -
mol
(1) [Pd(H2O)6 ]Cl 4 1 kg in both case. Hence atomic wt. of A and
(2) [Pd(H2 O)4 Cl2 ]Cl 2 .2H2 O
B are respectively.-
(3) [Pd(H2O)3Cl3 ]Cl.3H2 O
(1) 100, 40 (2) 60, 20
(4) [Pd(H2 O)2 Cl4 ]4H2 O
(3) 20, 60 (4) None of these
476. Which pair shows a contraction in volume on
mixing along with evolution of heat- - 483. A solution X of A and B contains 30 moles %
of A & is in equilibrium with its vapour that
(1) CHCl3 + C6H6 (2) H2O + HCl
contains 40 mole % of B. the ratio of V.P of
(3) H2O + HNO3 (4) All
pure, A & B will be -
477. Decimolar solution of potassium ferricyanide,
(1) 2 : 7 (2) 7 : 2
K3[Fe(CN)6] has osmotic pressure of 3.94atm
(3) 3 : 4 (4) 4 : 3
at 27°C. Hence percent ionisation of the solute
is - 1 1
(1) 10% (2) 20% 484. The plots of Y Vs X (Where XA & YA aree
A A

(3) 30% (4) 40% the mole fraction of liquid A in liquid & vap.
478. A complex containing K ,Pt (IV) and Cl is
+ –
phase) is linear with slope & intercepts
100% ionised giving i = 3. Thus, complex is - respectively. -
(1) K2 [PtCl4 ] (2) K2 [PtCl6 ]
PA0 PA0 - PB0 PB0 PA0 - PB0
(3) K3 [PtCl5 ] (4) K[PtCl3] (1) & (2) P 0 & P 0
PB0 PB0 A A
479. If pKa = – log Ka = 4, and Ka = Ca2 then van’t
Hoff factor for weak monobasic acid when PB0 PA0 - PB0 PB0 PB0 - PA0
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(3) & (4) &

C = 0.01 M is - PA0 PB0 PA0 PB0
(1) 0.01 (2) 1.02
485. A mixture of two volatile liquids A and B for 1
(3) 1.10 (4) 1.20
and 3 moles respectively has V.P. of 300 mm
480. In which case van’t Hoff factor is maximum? - at 27°C. If one mole of A is further added to
(1) KCl, 50% ionised this solution, the vapour pressure becomes 290
(2) K2SO4 40% ionised mm at 27°C. The vapour pressure of pure A is-
(3) FeCl3,30% ionised (1) 250mm (2) 316mm
(4) SnCl4, 20% ionised (3) 220mm (4) 270mm

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38 CHEMISTRY AT A GLANCE
486. If liquid A and B form ideal solution, then :-
(1) DGmix = 0
(2) DHmixing = 0
(3) DGmix = 0, DSmix = 0
(4) DSmix = 0
487. Which of the following liquid pairs shows a
positive deviation from Raoult's law?-
(1) Water - hydrochloric acid
(2) Benzene - methanol
(3) Water - nitric acid
(4) Acetone - chloroform
488. Benzene and toluene form nearly ideal
solutions. At 20°C, the vapour pressure of
benzene is 75 torr and that of toluene is
22 torr. The partial pressure of benzene at 20°C
for a solution containing 78 g of benzene and
46 g of toluene in torr is -
(1) 25 (2) 50
(3) 53.5 (4) 37.5
489. Vapour pressure of pure benzene is 119 torr and
that of toluene is 37.0 torr at the same
temperature. Mole fraction of toluene in
vapour phase which is in equilibrium with a
solution of benzene and toluene having a mole
fraction of toluene 0.50, will be :
(1) 0.137 (2) 0.205
(3) 0.237 (4) 0.435
490. Consider separate solution of 0.500 M
C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250 M
KBr(aq) and 0.125 M Na3 PO 4 (aq) at 25°C.
Which statement is true about these solutions,
assuming all salts to be strong electrolytes ?
(1) 0.125 M Na 3 PO 4 (aq) has the highest
osmotic pressure.
(2) 0.500 M C 2 H 5OH (aq) has the highest
osmotic pressure.
(3) They all have the same osmotic pressure.
(4) 0.100 M Mg3(PO4)2 (aq) has the highest
osmotic pressure.
ALLEN
491. The vapour pressure of acetone at 20°C is
185 torr. When 1.2 g of non-volatile substance
was dissolved in 100 g of acetone at 20°C, its
vapour pressure was 183 torr. The molar mass
(g mol–1) of the substance is :
(1) 128 (2) 488
(3) 32 (4) 64
492. An aqueous solution of a salt MX2 at certain
temperature has a van't Hoff factor of 2. The
degree of dissociation for this solution of the
salt is :
(1) 0.50 (2) 0.80
(3) 0.67 (4) 0.33
493. The freezing point of benzene decreases by
0.45°C when 0.2 g of acetic acid is added to
20 g of benzene. If acetic acid associates to
form a dimer in benzene, percentage
association of acetic acid in benzene will be :-
(Kf for benzene = 5.12 K kg mol–1)
(1) 64.6% (2) 80.4%
(3) 74.6% (4) 94.6%
494. Which statement about the composition of
vapour over an ideal 1 : 1 molar mixture of
benzene and toluene is correct ? Assume the
temperature is constant at 25°C.
Vapour pressure date (25°C)
Benzene 75 mm Hg
Toluene 22 mm Hg
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(1) The vapour will contain higher percentage
of benzene
(2) The vapour will contain higher percentage
of toluene
(3) The vapour will contain equal amount of
benzene and toluene
(4) Not enough information is given to make
a prediction
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 ALLEN CHEMISTRY AT A GLANCE 39
495. A solute 'S' undergoes a reversible trimerization 499. The solubility of N2 in water at 300 K and 500
when dissolved in a certain solvent. The boiling torr partial pressure is 0.01 g L–1. The solubility
point elevation of its 0.1 molal solution was (in g L–1) at 750 torr partial pressure and 300K
found to be identical to the boiling point is :
elevation in case of a 0.08 molal solution of a (1) 0.02 (2) 0.005
solute which neither undergoes association nor (3) 0.015 (4) 0.0075
dissociation. To what percent had the solute 'S' 500. 12g of a nonvolatile solute dissolved in 108g
undergone trimerization ? of water produces the relative lowering of
(1) 30% (2) 40% vapour pressure of 0.1. The molecular mass of
the solute is :
(3) 50% (4) 60%
(1) 60 (2) 80
496. Consider a binary mixture of voltile liquids. If
(3) 40 (4) 18
a XA = 0.4 the vapour pressure of solution is
CHEMICAL KINETICS
580 torr then the mixture could be (p°A = 300
torr, p°B = 800 torr) :- 501. Which of the following rate law expression
represent zero order reaction :-
(1) CHCl3–CH 3 COCH3
(1) K(A)3/2 (B)–1 (C)1/2
(2) C6H5 Cl–C 6 H5 Br
(2) K(A)o (B)2
(3) C6 H6–C6 H5 CH3
(3) K(A)1/2 (B)1/2 (C)–1
(4) nC6 H14 –nC7 H16
(4) K(A)2 (B)1
497. A 20.0 mL sample of CuSO 4 solution was
502. The ratio of t0.875 and t0.75 for first order reaction:-
evaporated to dryness, leaving 0.967 g of
(1) 4 : 3 (2) 3 : 2
residue. What was the molarity of the original
solution ? (Cu = 66.5) :- (3) 2 : 1 (4) 1 : 2
503. The correct expression for Arrehenius equation:-
(1) 48.4 M (2) 0.0207 M
(3) 0.0484 M (4) 0.303 M E
(1) lnk = lnA -
RT
498. Two solutions S 1 and S 2 containing 0.1M
NaCl(aq.) and 0.08M BaCl2(aq.) are separated (2) ke - E / RT = A
by semipermeable membrane. Which among
the following statement(s) is/are correct - E
(3) log k = log A - 2.303
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RT
S1 S2
(4) K = A -1e -E / RT
0.1M NaCl 0.08M BaCl2
504. For every 10°C increase in temperature the rate
SPM becomes twice. If the temperature increases
(1) S1 and S2 are isotonic from 10°C to 100°C then rate increases ....
(2) S 1 is hypertonic and S 2 is hypotonic times :-
(3) S 1 is hypotonic and S 2 is hypertonic (1) 400 (2) 512
(4) Flow of NaCl will take place from S1 to S2 (3) 112 (4) 614

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40 CHEMISTRY AT A GLANCE ALLEN
505. The specific rate of reaction for the first order
509. In a reaction N 2( g ) + 3H 2( g ) ® 2NH 3( g ) rate of
reaction depends upon :-
appearance of NH3 is 2.5 × 10–4 mol L–1 sec–1
(1) pressure
then rate of reaction and rate of disappearance
(2) temperature of H2 respectively is:-
(3) concentration of reactant (1) 3.75 × 10–4 , 1.25 × 10–4
(4) concentration of the product (2) 1.25 × 10–4 , 2.5 × 10–4
(3) 1.25 × 10–4 , 3.75 × 10–4
506. The rate contant for zero order reaction is
(4) 5 × 10–4 , 3.75 × 10–4
3 × 10 –2 mol L –1 sec –1 . After 25 sec. If the
510. Rate of formation of SO3 in this reaction is
concentration of reactant is 0.5M then initial
concentration of the reactant is :- 1.6 × 10–3 kg/min
2SO2+O2 ® 2SO3 then rate of decomposition of
(1) 1 M (2) 1.25 M
SO2(g) is :-
(3) 0.5 M (4) 0.75 (1) 1.6 × 10–3 kg/min
(2) 8 × 10–4 kg/min
1
507. The plot of ln K versus is linear with slope (3) 3.2 × 10–3 kg/min
T
(4) 1.28 × 10–3 kg/min
of:- 511. Calculate the order of the reaction with respect
to A and B :-
Ea Ea
(1) - (2) + A B Rate
R R
(mol/l) (mol/l)
0.05 0.05 1.2× 10–3
Ea Ea
(3) - (4) 0.10 0.05 2.4 × 10–3
2.303R 2.303R
0.05 0.10 1.2 × 10–3
508. For a first order gaseous reaction A ® 2B+C, (1) 1 and 0 (2) 1 and 1
initial pressure is Pi and total pressure after time (3) 0 and 1 (4) none of these
't' is P t then expression of rate constant:- 512. The rate law of reaction A + 2B ® product is
given by
2.303 2Pi
(1) K = log
3Pi - Pt
r = K(A)2 (B)1. If A is taken in excess the order
t of the reaction will be :-
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(1) zero (2) 1

2.303 æ 2Pi ö
(2) K = log ç ÷ (3) 2 (4) 3
t è 2Pt - Pi ø
513. The half life for the first order reaction
A ¾® B + C is 24 hrs. starting with 20g of A
2.303 æ Pi ö how many grams of A will remain after
(3) K = log ç ÷ 72 hours. :-
t è Pi - Pt ø
(1) 1.25 g (2) 0.63 g
(4) None of these (3) 1.77 g (4) 2.5 g

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 ALLEN CHEMISTRY AT A GLANCE 41
514. Rate of reaction increases with temperature :- 521. The t1/2 of a reaction is halved as the initial
(1) for any reaction concentration of the reactant is doubled then
(2) for exothermic reaction only order of reaction :-
(3) for endothermic reaction only (1) 1 (2) 0
(4) for none (3) 2 (4) 3
515. If concentration of reactant is increased by 522. For this reaction
2 times then K becomes :-
N 2( g ) + 3H 2( g ) ® 2NH3(g)
K K
(1) ln (2) (3) 2K (4) K
2 2 d ( NH 3 ) d ( H2 )
The relation beteween and – is :-
516. K is rate constant at temp T then value of dt dt
lim logK is equal to :-
T®¥
d ( NH 3 ) 1 d ( H2 )
(1) A/2.303 (2) A (1) =-
dt 3 dt
(3) 2.303 A (4) log A
517. The activation energy for a chemical reaction d ( NH 3 ) 2 d ( H2 )
(2) + =-
depends upto :- dt 3 dt
(1) Temperature
(2) Nature of reacting species d ( NH 3 ) 3 d ( H2 )
(3) + =-
dt 2 dt
(3) Concentration of the reacting species
(4) Collision frequency d ( NH 3 ) d (H2 )
(4) =-
518. For an endomermic reaction, energy of dt dt
activation is Ea and enthalpy of reaction is DH
523. Activation energy of the reaction
(both of these in KJ/mol ) The value of Ea will
A ® B –52KCal is 128KCal. then activation
be :-
energy of the reaction B ® A will be :-
(1) equal to zero (2) less than DH
(1) –76 KCal (2) +76 KCal
(3) equal to DH (4) more than DH
(3) –180 KCal (4) +180 KCal
519. For a reaction r = K[A] 3/2
then unit of rate of 524. For a reaction rate = K(A) 1/2 (B) 2 . If
reaction and rate constant respectively :- concentration of A and B are increased by factor
(1) molL–1 s–1, mol–1/2 L1/2 s–1 of 4 and 2 respectively then rate is changed by
the factor of :-
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(2) mol–1 L–1 s–1, mol–1/2 L1/2 s–1

(1) 4 (2) 6
(3) molL–1s–1, mol+1/2 L1/2 s–1
(3) 8 (4) None of these
(4) mol, mol+1/2 L1/2 s
525. The reaction 2A+B ® product follows the
520. The rate of first order reaction is 1.5 × 10–2 mol
mechanism :-
L–1 min–1 at 0.5M concentration of the reactant.
The half life of the reaction is :- 2A ƒ A2(fast)
A2+B ® P(slow)
(1) 7.53 min (2) 0.383 min
The order of the reaction is
(3) 23.1 min (4) 8.73 min
(1) 1.5 (2) 3 (3) 1 (4) 2

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42 CHEMISTRY AT A GLANCE ALLEN
526. Which of following is correct for zero order 531. The half life of a first order reaction is 6 hour.
and first order (a ® Initial cencentration) :- How long will it take for the concentration of
reactant to change from 0.8 M to 0.25 M?
1
(1) t1/2 µ a, t1/2 µ (2) t1/ 2 µ a, t1/ 2 µ a o
(1) 1.07 hour (2) 5.1 hour
a
(3) 2.7 hour (4) 10.07 hour
1 532. The concentration of a reactant in solution
(3) t1/ 2 µ a o , t1/ 2 µ a (4) t1/ 2 µ a, t1/ 2 µ
a2 decreases from 0.5 M to 0.25 M in 5 hours and
from 1.0 M to 0.25 M is 10 hours. The order of
527. Which of following represents the expression
the reaction will be
3
for th life of first order reaction :- (1) 2 (2) 1 (3) 3 (4) 0
4
533. Which of the following is the correct
K 4 2.303 3 expression for Arrhenius equation?
(1) log (2) log
2.303 3 K 4
K2 Ea æ 1 1 ö
(1) ln K = R ç T - T ÷
2.303 2.303 1 è 1 2 ø
(3) log4 (4) log3
K K
K2 E a æ T1T2 ö
528. The rate constant for first order reaction whose (2) log K = 2.303 ç T - T ÷
1 è 2 1 ø
half life is 480 sec. :-
(1) 1.44 × 10–3 sec–1 K2 Ea æ 1 1 ö
(3) ln K = 2.303R ç T - T ÷
(2) 1.44 sec–1 1 è 1 2 ø

(3) 0.72 × 10–3 sec–1

K2 E a æ T2 - T1 ö
(4) 2.88 × 10–3 sec–1 (4) K = 2.303R ç T T ÷
1 è 1 2 ø

534. For a first order reaction A®B, the time taken

529. to reduce to 1/4 of initial concentration is
10 min. The time required to reduce to 1/16 of
initial concentration will be
For this parallel first order reaction then find (1) 10 min
out percentage of B = ? (2) 20 min
(1) 40% (2) 60% (3) 50% (4) 90% (3) 4.46 min
530. consider the plots for a reaction nA ® B + C (4) 2.24 min
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These plots respectively correspond to the 535. For the reaction, 2N 2 O 5 ®4NO 2 + O 2 rate
reaction order and rate constant are 1.02 × 10–4 M sec–1 and
3.4 × 10–5 sec–1 respectively, the concentration
t1/2 t1/2 t1/2 of N2O5, at that time will be
[A] [A] 1/[A]® (1) 1.732 M
(I) (II) (III) (2) 3M
(1) 0,1,2 (2) 1,2,3 (3) 1.02 × 10–4 M
(3) 1,0,2 (4) None of these (4) 3.5 × 105M

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 ALLEN CHEMISTRY AT A GLANCE 43
536. For the reaction N2O5(g) ®N2O4 (g) + ½O2(g) 542. The half life period and initial concentration for
a reaction are as follows:
initial pressure is 114 mm and after 20 seconds
the pressure of reaction mixture becomes Initial concentration 350 540 158
133 mm then the average rate of reaction will t½ 425 275 941
be order of reaction is–
(1) 1.9 atm S –1
(1)2 (2) 1 (3)0 (4) 4
(2) 8.75 × 10–3 atm S–1 543. The activation energy for the reaction–
(3) 2.5 × 10–3 atm S–1 1
H2 O2 ¾¾® H2O + O2
2
(4) 6.65 atm S–1
is 18 K cal/mol at 300 K. calculate the fraction
537. Reaction A+B ®C+D is started with 1M of each of molecules of reactonts having energy equal
A and B and follows the rate law to or greater than activation energy?
r = k[A]1/2[B]1/2 Anti log (–13.02) = 9.36 × 10–14
What is the time taken for the concentration of (1) 9.36 × 10–14 (2) 1.2 × 10–12
A to drop to 0.1M (K = 2.303 × 10–3 sec–1)
(3) 4.2 × 10–16 (4) 5.2 × 10–15
(1) 57 sec (2) 100 sec
544. A first order reaction is 50% completed in
(3) 434 sec (4) 1000 sec
20 minutes at 27°C and 5 minutes at 47°C. The
538. 75% of a first order reaction was found to energy of activation of the reaction is–
complete in 32 minute. When will 50% of the
(1)43.85 KJ (2)55.14 KJ
same reaction will complete
(3)11.97 KJ (4) 6.65 KJ
(1) 24 min (2) 16 min
545. The accompanying figure depicts the change
(3) 8 min (4) 4 min
in concentration of species X and Y for the
539. Half lives of a first order and zero order are reaction X ® 3Y as a function of time the point
same. Then the ratio of the initial rates of the of intersection of the two curves represents.
first order reaction to that of zero order reaction
is [initial conc. of reactant = 1 Molar] (1) t1/2
Concentration

(1) 1/0.693 (2) 2 × 0.693 1

X
(2) t3/4
(3) 2/0.693 (4) 6.93
Y
540. The rate of reaction is expressed (3) t1/4 0 Time

1 d [ C] 1 d [D] 1 d [ A ] -d [ B] (4) Data insufficient to predict

+ =- =+ =
2 dt 3 dt 4 dt dt
546. For the reaction N2(g) + 3H2(g) ® 2NH3(g)
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the reaction is under certain conditions of temperature and

(1) 4A + B ®2C +3D partial pressure of the reactants, the rate of
(2) B + 3D ® 4A + 2C formation of NH3 is 0.001 kg lit–1 h–1. The rate
(3) A+B® C+D of conversion of H2 under the same condition
is ..... kg lit–1 h–1.
(4) B+D® A+C
541. Rate constant for first order reaction is (1) 0.001 kg lit–1 h–1
5.78 × 10–5 sec –1. What percentage of initial (2) 0.0015 kg lit –1 h–1
reactant will react in 10 hours?
(3) 0.00017 kg lit –1 h–1
(1)12.5% (2) 25% (3) 87.5% (4) 75%
(4) 0.0017 kg lit –1 h–1
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44 CHEMISTRY AT A GLANCE ALLEN
547. For a first order reaction - 550. For an exothermic chemical process occurring
in two steps as follows
(1) the degree of dissociation is equal to e–kt
(i) A + B ® X (slow)
(2) a plot of reciprocal concentration of the (ii) X ® AB (fast)
reactant vs time gives a straight line the process of reaction can be best described
by :
(3) the time taken for the completion of 75%
reaction is thrice the t 1/2 of the reaction

(4) the pre-exponential factor in the Arrhenius P.E.

X
equation has the dimension of time, T–1 A+B
AB
(1)
548. In the following reaction : xA ¾® yB (reaction coordinate)
R.C.

é d[A] ù é d[B] ù
log ê- ú = log ê ú + 0.3010
ë dt û ë dt û
P.E. X
where –ve sign indicates rate of disappearance
(2) AB
of the reactant. Thus, x : y is : A+B

R.C.
(1) 1 : 2 (2) 2 : 1

(3) 3 : 1 (4) 3 : 10

549. If for a reaction in which A(g) converts to B(g) P.E.

X
A+B
the reaction carried out at const. V & T results (3) AB
into the following graph.
R.C.

PB

Partial P.E.
Pressure X AB
(4)
PA A+B

o R.C.
Time ®
551. Arrhenius equation may be written as :–
(1) then the reaction must be A(g) ® 3B(g)
and is a first order reaction d Ea
(1) (ln K) = –
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dT RT
(2) then the reaction must be A(g) ® 3B(g)
and is a second order reaction d Ea
(2) (ln K) = –
dT RT 2
(3) then the reaction must be A(g) ® 3B(g)
and is a zero order reaction d Ea
(3) (ln K) = +
dT RT 2
(4) then the reaction must be A(g) « 3B(g)
and is a first order reaction d Ea
(4) (ln K) =
dT RT

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 ALLEN CHEMISTRY AT A GLANCE 45
552. Consider the reaction : 556. In the reaction : P + Q ¾¾
® R+S
+ –
Cl2(aq) + H2S(aq) ® S(s) + 2H (aq) + 2Cl (aq) the time taken for 75% reaction of P is twice
The rate equation for this reaction is the time taken for 50% reaction of P. The
concentration of Q varies with reaction time
rate = k[Cl2][H2S]
as shown in the figure. The overall order of
Which of these mechanisms is/are consistent
the reaction is
with this rate equation ?
A. Cl2 + H2S ® H+ + Cl– + Cl+ + HS– (slow) [Q]0
+ – + –
Cl + HS ® H + Cl + S(fast) [Q]
B. H2S Û H+ + HS– (fast equilibrium)
Cl2 + HS– ® 2Cl– + H+ + S(slow) Time
(1) A only (2) B only (1) 2 (2) 3 (3) 0 (4) 1
(3) Both A and B (4) Neither A nor B 557. For the reaction 2A + B ® C + D, the following
553. For the first order reaction, which is not correct kinetic data were obtained in three separate
2N2O5(g) ¾® 4NO2(g) + O2(g) experiments, all at 298 K.

(1) the concentration of the reactant decreases Initial Initial Initial rate of
Concentration Concentration formation of C
exponentially with time. (A) (B) (mol L–S–)
(2) the half-life of the reaction decreases with
0.1M 0.1M 1.2 × 10 –3
increasing temperature.
0.1M 0.2M 1.2 × 10–3
(3) the half-life of the reaction depends on the
initial concentration of the reactant. 0.2M 0.1M 2.4 × 10–3

(4) the reaction proceeds to 99.6% completion

d[C] d[C]
in eight half-life duration. (1) = k[A] [B]2 (2) = k[A]
dt dt
554. Reaction rate between two substances A and B
is expressed as following : rate = k[A]n [B]m If d[C] d[C]
(3) = k[A] [B] (4) = k[A]2 [B]
the concentration of A is doubled and dt dt

concentration of B is made half of initial 558. The reaction of ozone with oxygen atoms in
concentration, the ratio of the new rate to the the presence of chlorine atoms as a catalyst can
earlier rate will be :- occur by a two step process shown below :

1 O3(g) + Cl× (g) ® O2(g) + ClO× (g) ......(i)

(n–m)
(1) m + n (2) (3) 2 (4) n – m
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2( m + n ) ki = 5.2 × 109 L mol–1s–1

555. An organic compound undergoes first-order ClO× (g) + O× (g) ® O2(g) + Cl× (g)
decomposition . The time taken for its kii = 2.6 × 1010 L mol–1s–1 ....(ii)
decomposition of 1/8 and 1/10 of its initial The closest rate constant for the overall reaction
concentration are t1/8 and t1/10 respectively. What O3(g) + O× (g) ® 2O2(g) is :
(1) 3.1 × 1010 L mol–1s–1
[t ]
is the value of 1/8 ´ 10 ? (take log102 = 0.3)
t 1/10 (2) 2.6 × 1010 L mol–1s–1
(3) 5.2 × 109 L mol–1s–1
(1) 4 (2) 5 (3) 15 (4) 2
(4) 1.4 × 10 20 L mol–1s–1

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46 CHEMISTRY AT A GLANCE ALLEN
559. Decomposition of hydrogen peroxide as per 563. The half-life period for a reaction at initial
concentrations of 0.5 and 1.0 mol L –1 are
1
following reaction H2O2 ® H2 O + O2 ; 200 sec and 100 sec respectively. The order
2
of the reaction is -
follows a first order reaction. In fifty minutes
(1) 0 (2) l
the concentration of H2O2 decreases from 0.5
(3) 2 (4) 3
to 0.125 M in one such decomposition. When
564. Consider the data given below for hypothetical
the concentration of H2O2 reaches 0.05 M, the
reaction A ® X.
rate of formation of O2 will be :-
Time (sec) Rate (mol L–1 sec. -1 )
(1) 1.34 × 10–2 M min–1
0 1.60 × l0–2
(2) 6.93 × 10–2 M min–1 10 I.60 × l0–2
(3) 6.93 × 10–4 M min–1 20 1.60 × 10–2
(4) 2.66 L min–1 at STP 30 1.60 × 10–2
560. Two reactions R 1 and R 2 have identical pre- From the above data, the order of reaction is-
exponential factors. Activation energy of R 1 (1) 1 (2) 0
–1 (3) 2 (4) Unpredictable
exceeds that of R2 by 10 kJ mol . If k1 and k2
are rate constants for reactions R 1 and R 2 565. For a first order reaction A ® products, the
respectively at 300 K, then ln(k2/k1) is equal to:- concentration of [A] is reduced from 1M to
(R = 8.314 J mol–1K–1) 0.125 M in one hour, the t1/2 of this reaction
(in sec) is :-
(1) 8 (2) 12
(1) 600 (2) 300
(3) 6 (4) 4
(3) 1200 (4) 0.693/1200

k 350 566. For a zero order reaction, the plot of dissociated

561. > 1 , 1f this means that - concentration (x) vs time is linear with -
k 340
(1) +ve slope and zero intercept
(1) Rate increases with the rise in temperature (2) –ve slope and zero intercept
(2) Rate decreases with rise in temperature (3) +ve slope and non-zero intercept
(4) –ve slope and non-zero intercept
(3) Rate does not change with rise in
temperature 567. The rate of reaction at 273 K is R0. The rate
of reaction at 313 K will be (Assuming
(4) None of the above temperature coefficient equal to 2) -
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562. A radioactive isotope decomposes according (1) 16 R0 (2) 64 R0

to the first order with half life period of 15 hrs. (3) R 0 /32 (4) R 0 /16
80% of the sample will decompose in - 568. At 100°C, the gaseous reaction A ® 2B + C
(1) 15 × 0.8 hr. is found to be of first order. Starting with pure
A, if at the end of 10 min, the total pressure
(2) 15 × (log 8) hr.
of the system is 176 mm and the end of reaction,
(3) 15 × (log5 / log2) hr. (or 34.83) hr. it is 270 mm, the partial pressure of A at the
(4) 15 × 10/8 hr. end of 10 min is :-
(1) 94 mm (2) 43 mm
(3) 47 mm (4) 176 mm
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 ALLEN CHEMISTRY AT A GLANCE 47

569. If for two reaction Ea1 > E a2 & TC1 & TC2 are 575. If E A+2 / A = –0.30 V and E oA+3 / A+2 = 0.40 V, the
o

temperature coefficient respectively, then standard Emf of the reaction : A + 2A+3 ® 3A+2
which of the following is correct :- will be :-
(1) TC1 >TC2 (2) TC 1 < TC 2 (1) 0.30 V (2) 0.40 V
(3) TC1 = TC 2 (4) None of these (3) 0.70 V (4) 0.10 V
570. H 2 gas is adsorbed on metal surface like 576. The equilibrium constant of the reaction :
tungsten. This follows ...... order reaction at
Zn(s) + 2Ag+(aq) ® Zn2+(aq)+ 2Ag(s) ; E° = 1.50V
high pressure.
at 298 K is
(1) Third (2) Second
(1) 2.6 × 1049 (2) 8.7 × 1051
(3) Zero (4) First
(3) 6.1 × 1030 (4) 6.6 × 1050
571. t 1/4 can be taken as the time taken for the
concentration of a reactant to drop to 3/4 of 577. On the basis of the following E° values, the
its initial value. If the rate constant for a first strongest oxidising agent is :-
order reaction is K, t1/4 can be written as :- K++e– ® K E0 = –2.923 V
(1) 0.29/K (2) 0.10/K Mg+2 + 2e– ® Mg Eo = –2.337 V
(3) 0.75/K (4) 0.69/K (1) K+ (2) Mg+2
572. The Ea of a reaction in the presence of a catalyst
(3) K (4) Mg
is 4.15 kJ mol–1 and in the absence of catalyst
is 8.3 kJ mol–1. What is the slope of the plot M
578. The equivalent conductance of solution of
20
1 a weak monobasic acid is 10 S cm 2 /eq. and
of ln k vs in the absence of catalyst :-
T at infinite dilution is 200 S cm 2 /eq.
The dissociation constant of this acid is :-
(1) +l (2) –l
(1) 1.25 × 10–4
(3) +1000 (4) –1000
573. For a certain reaction of order 'n' the time for (2) 1.25 × 10–5
(3) 1.25 × 10–6
2- 2
half change t1/2 is given by : t1 / 2 = ´ C1/0 2 (4) 6.26 × 10–4
K
where K is rate constant and C0 is the initial 579. Given Fe+2 + 2e– ® Fe(s) E° = – 0.447V
concentration. The value of n is :- Fe+2 ® Fe+3+e– E° = – 0.771V
(1) 1 (2) 2 (3) 0 (4) 0.5 Find E° for the reaction Fe+3 + 3e– ® Fe(s)
ELECTROCHEMISTRY (1) 0.34 V (2) –0.041V
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574. A hypothetical electrochemical cell is shown (3) +0.39 V (4) –0.47 V

below
Pt ( s ) | A 2 (1atm ) | A - ( xM ) ||B+ ( yM ) | B ( s )
The emf measured is 0.30V. The cell reaction is :-
(1) A2 + 2B+ ® 2A– + 2B
(2) A2 + 2e– ® 2A– ; 2B+ + 2e– ® 2B
(3) The cell reaction cannot be predicted
(4) 2A– + 2B+ ® A2 + 2B
580. An increase in molar conductance of a strong
electrolyte with dilution is mainly due to :-
(1) Increase in number of ions
(2) Increase in ionic mobility of ions
(3) 100% ionisation of electrolyte at normal
dilution
(4) Increase in both i.e. number of ions and
ionic mobility of ions.

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48 CHEMISTRY AT A GLANCE ALLEN
581. For the reduction of silver ions with copper 586. Standard electrode potential of three metals A,B
metals, the standard cell potential was found and C are –1.5V, 0.8V and –2.7V respectively.
to be + 0.40V at 25°C. The value of standard The reducing power of these metals will be :-
Gibb's energy DG° will be (F = 96500 C mol–1):- (1) B > C > A (2) B > A > C
(1) –70 KJ (2) –77.2 KJ (3) C > A > B (4) A > B > C
(3) –88 KJ (4) +90KJ 587. A solution contains Cr , Cr+3 and I– ions. This
+2

582. Which relation of emf of an electrochemical solution was treated with iodine at 35°C.
cell is correct :- E° for Cr +3 / Cr +2 is –0.41V and E° for
(1) emf of cell = oxidation potential of anode – I2/2I– = 0.536V, The favourable redox reaction
reduction potential of cathode is :-

(2) emf of cell = oxidation potential of anode +
reduction potential of cathode
(3) emf of cell = reduction potential of anode +
reduction potential of cathode
(4) All of these
583. Which of the following expression correctly
represents the equivalent conductance at
(1) Cr+2 will be oxidised to Cr+3
(2) Cr+3 will be reduced to Cr+2
(3) There will be no redox reaction
(4) I– will be oxidised to I2
588. Limiting molar conductivity of CH3 COOH
(i.e. Lm0(CH COOH) is equal to :-
3

(1) L + L mo ( CH3COONa ) - L om (NaOH)

o
infinite dilution of Ca3 (PO4)2 Given L oCa +2 and m ( CH3COOH )

L oPO-3 are the equivalent conductance at infinite

(2) L m ( CH3COONa ) + L m ( HCl ) - L m (NaCl)
o o o
4

dilution of the respective ions :-

( ) (3) L m ( CH3COONa ) + L m ( NaCl ) - L m (NaOH)

o o o
(1) L Ca +2 + L PO-43
o o
(2) L Ca+2 + L PO4-3 ´ 6
o o

1 o 1 (4) L m ( NaOH ) + L m ( NaCl ) - L m (CH3COONa)

o o o
L Ca +2 + L oPO -3 (4) 3L Ca+2 + 2L PO4-3
o o
(3)
2 3 4

584. If the E ocell for a given reaction has a positive 589. The weight of copper (At wt=63.5) displaced
value, then which of the following gives the by a quantity of electricity which displaces
correct relationship for the values of DG° and Keq:- 5600 ml of O2 at STP will be :-

(1) DG o < 0 ; K eq < 1 (1) 63.5 g (2) 31.75 g

(3) 15.875 g (4) 127 g
(2) DG o > 0 ; K eq > 1
590. When 0.1 mole Cr2O7–2 is reduced then quantity
(3) DG > 0 ; K eq < 1
o
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of electricity required to reduced Cr2 O 7-2 to Cr+3

(4) DG o < 0 ; K eq > 1 completely is :-
585. Standard electrode potential Au+3/Au couple is (1) 9650 C (2) 96500 C
1.428 V and that for Na+/Na couple is –2.714 V. (3) 57900 C (4) 54900 C
These two couples in their standard state are 591. A device that converts energy of combustion
connected to make a cell. The cell potential of fuel like hydrogen and methane directly into
will be :- electrical energy is known as :-
(1) 4.142 (2) 1.286 V (1) Electrolytic cell (2) Dynamo
(3) –1.286 V (4) 3.376 V (3) Ni-Cd cell (4) Fuel cell
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 ALLEN CHEMISTRY AT A GLANCE 49
592. Aqueous solution of which of the following 599. A solution of CuSO 4 is electrolysed for
compounds is the best conductor of electric 10 minutes with a current of 1.5 amperes. What
current :- is the mass of copper deposited at the cathode ?
(1) CH 3COOH (2) C 12 H22 O11 (Molar mass of Cu = 63.5 g/mol)
(3) H2 C2 O4 (4) NaOH (1) 0.492g (2) 0.325g
593. The pressure of H2 required (in bar) to make (3) 0.873g (4) 0.296g
the potential of H2-electrode zero in pure water 600. The conductance is the :-
at 25°C is :- (1) Reciprocal of specific resistance
(1) 10 –14
(2) 10 –7
(3) 10 +14
(4) 10 +7
(2) Reciprocal of resistance
594. The number of electrons delivered at the (3) Reciprocal of current
cathode during electrolysis by a current of (4) Reciprocal of concentration
2 ampere in 120 seconds is 601. The ion which has lowest ionic mobility in
(charge on electron = 1.6 × 10 –19
C) :- aqueous solution :-
(1) 3.75 × 1020 (2) 7.48 × 1020 (1) Li+ (2) Na+ (3) K+ (4) Rb+

(3) 1.5 × 1021 (4) 3 × 1020 602. An electric current of 100 ampere is
passed through a molten liquid of
595. The molar conducitviy of a 0.1 mol/dm 3
sodium chloride per 5 hours. Calculate the
solution of KNO3 with electrolytic conductivity
volume of chlorine gas liberated at the
of 4 × 10–3 Scm–1 at 298 K is :-
electrode at NTP :-
(1) 11.52 Scm2 mol–1 (2) 20 Scm2 mol–1
(1) 208.91 L (2) 310 L
(3) 40 Scm2 mol–1 (4) 13.48 Scm2 mol–1 (3) 40.8 L (4) 150.2 L
596. The resistance of conductivity cell containing 603. Zn can displace :-
0.001 M KCl solution at 298 K is 1500 ohm. (1) Mg+2 from its aqueous solution
What is the cell constant if the conductivity of
(2) Cu+2 from its aqueous solution
0.001 M KCl solution at 298 K is 0.146 × 10–3 S cm–1
(3) Na+ from its aqueous solution
(1) 0.419 cm–1 (2) 0.219 cm–1 (4) Al+3 from its aqueous solution
(3) 0.45 cm –1
(4) 0.75 cm –1
604. Which of the following is incorrect regarding
597. Calculate the DG° of the following reaction :- salt bridge solution ?
Fe (aq) + Ag (aq) ® Fe (aq) + Ag(s)
+2 + +3 (1) Solution must be of strong electrolyte
(2) Solution should be inert towards both
E 0Ag+ / Ag = 0.8V E 0Fe +3 / Fe +2 = 0.77V
electrodes
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(1) –2895 J mol–1 (3) Size of cation and anions of salt should be
(2) –3845 J mol–1 much different
(4) Salt bridge solution is prepared in gelatin
(3) –1874 J mol–1
or agar-agar to make it semi solid.
(4) –375 J mol–1
605. Cell reaction during discharging of lead storage
598. Calculate the emf of the cell
battery at cathode is :-
Fe(s) + 2H+(1M) ® Fe+2 (0.001M) + H2/(g),1atm) (1) Pb+SO4–2 – 2e– ® PbSO4
(Given : E Fe +2 / Fe = -0.44V )
0 (2) PbSO4 + 2e– ® Pb+SO4–2
(3) PbO2 + SO4–2 + 4H+ + 2e– ® PbSO4 + 2H2O
(1) 0.215 V (2) 0.38 V
(4) PbSO4 + 2H2O ® PbO2 + SO4–2 + 4H+ + 2e–
(3) –0.48V (4) 0.5285 V
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50 CHEMISTRY AT A GLANCE ALLEN
606. The efficiency of fuel cell is given by :- 613. The strongest oxidising agent among the
species having SRP values of
DG DG DS DH
(1) (2) (3) (4) In+3 (E0 = –1.34 V), Au+3 (E0 = 1.4V),
DS DH DG DG
Hg+2 (E0 = 0.86 V) and Cr+3 (E=–0.74V) is
607. On electrolysis of dilute sulphuric acid using
(1) Cr+3 (2) Au+3 (3) Hg+2 (4) In+3
platinum electrode, the product obtained at the
anode will be :- 614. Given the standard electrode potential

(1) hydrogen (2) oxygen (a) K+/K = – 3.02 V

(3) sulphur dioxide (4) hydrogen sulphide (b) Cu+2/Cu = + 0.34 V

608. Which metal will dissolve if the cell works (c) Hg+2/Hg = 0.92 V
Cu|Cu2+ || Ag+ | Ag:- (d) Cr+3/Cr = – 0.74 V
(1) Cu (2) Ag Decreasing order of reducing power of these
(3) Both 1 & 2 (4) None of these element is

609. On the basis of the electrochemical theory of (1) a > b > c > d (2) a > d > c > b
aeueous corrosion, the reaction occuring at the (3) a > d > b > c (4) c > b > d > a
cathod is :- 615. Calculate Ecell of the reaction
(1) O2 + 4H+ + 4e– ¾® 2H2O(l) Mg(s) + 2Ag+ ® Mg+2 + 2Ag(s)
(2) Fe(s) ¾® Fe+2(aq) + 2e– (0.0001M) (0.100M)
(3) Fe+2 ¾® Fe+3(aq) + e– If E0cell = 3.17 V
(4) H2(g) + 20H–(aq) ¾® 2H2O(l) + 2e– (1) –2.96 V (2) +2.96V
610. When lead storage battery is charged it acts (3) 3.38 V (4) – 3.38 V
as :- 616. Which of the following statements is correct
(1) Fuel cell (2) Electrolytic cell for an electrolytic cell?
(3) Galvanic cell (4) Concentration cell (1) electrons flow from cathode to anode
611. The zinc acts as sacrifical or cathodic protection through external battery
to prevent rusting of iron because :- (2) electrons flow from cathode to anode within
(1) E oOP of Zn < E oOP of Fe the electrolytic solution
(3) Migration of ions along with oxidation
(2) E oOP of Zn > E oOP of Fe
reaction at cathode and reduction reaction
(3) E o
of Zn = E o
of Fe at anode
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OP OP
(4) migration of ions along with reduction
(4) Zn is cheaper than Fe
reaction at cathode and oxidation reaction
612. The molar conductivity of 0.01 M solution of
at anode
weak acid is 16.6 W –1 cm 2 mol –1 . Its molar
617. In an electrolysis of acidulated water, 4.48 L
conductivity at infinite dilution is 390.7 W–1 cm2
of hydrogen at STP was produced by passing
mol–1. The degree of dissociation of weak acid
a current of 2.14 A. For how many hours was
is
the current passed?
(1) 0.24 (2) 0.42
(1) 4 (2) 3
(3) 0.042 (4) 0.024
(3) 6 (4) 5

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 ALLEN CHEMISTRY AT A GLANCE 51
618. When a dilute aq. solution of Li 2 SO 4 is 623. Consider the following electrode potentials
electrolysed, the products formed at the anode Mg+2 + 2e– ® Mg E0 = – 2.37V
and cathode are respectively?
V+2 + 2e– ® V E0 = – 1.18 V
(1) H2 and O2 (2) O2 and Li Cu+2 + e– ® Cu+ E0 = 0.15 V
(3) SO2 and H2 (4) O2 and H2 Which of the following reactions will proceed
from left to right spontaneously?
619. Based on the data given below, the correct
order of reducing power is (1) Mg+2 + V ® Mg + V2+
(2) Mg+2 + 2Cu+ ® Mg+2Cu+2
Fe3+(aq) + e– ® Fe2+(aq); E0 = + 0.77 V
(3) V+2 + 2Cu+® V + 2Cu+2
Al3+(aq) + 3e– ® Al(s); E0 = – 1.66 V
(4) V + 2Cu+2 ® V2+ + 2Cu+
Br2(aq) + 2e– ® 2Br–(aq); E0 = + 1.08 V
624. A metal bucket is to be electroplated by using
(1) Br < Fe < Al
– 2+
ZnCl 2 as an electrolyte. How many moles of
(2) Fe2+ < Al < Br– zinc are deposited in 20 min by a constant
current of 10A?
(3) Al < Br– < Fe2+
(1) 0.01 (2) 0.03
(4) Al < Fe2+ < Br–
(3) 0.06 (4) 0.10
620. How much time is required for complete 625. The quantity of electricity required to release
decomposition of 4 mol water using current of 112 cm3 of hydrogen at STP from acidified
4 Ampere? water is
(1) 96500 sec (1) 0.1F (2) 1F
(2) 3.85 × 104 sec (3) 965C (4) 96500C

(3) 1.93 × 105 sec 626. If E 0Au + / Au = 1.69V and E 0Au 3+ / Au = 1.40V then
(4) 2.92 × 105 sec 0
the value of E Au +3 / Au + will be
621. The amount of metal deposited at cathode on
passing electric current of 0.75 ampere in (1) 0.19V (2) 2.945 V
aqueous ferric sulphate solution for 30 minutes, (3) 1.255 V (4) 1.19 V
will be (atomic weight of Fe = 56) 627. Given the standard electrode potential
(1) 0.00435 g (2) 0.261 g K+/K = – 2.93V, Ag+/Ag = 0.80 V
Hg2+/Hg = 0.79V; Mg2+/Mg = –2.37V,
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(3) 0.783 g (4) 0.522g

Cr3+/Cr = – 0.74V
622. Pt |H 2 (1atm )|H (0.001M)||H
+ +
(0.1M)|H 2
Correct order of their reducing power is –
(1atm)|Pt
(1) Ag > Hg > Cr > Mg > K
what will be the value of Ecell for this cell (2) K > Mg > Cr > Hg > Ag
(1) 0.1182 V (2) – 0.1182 V (3) K > Cr > Mg > Ag > Hg
(3) 0.0591 V (4) – 0.0591 V (4) Cr > Mg > K > Hg > Ag

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52 CHEMISTRY AT A GLANCE
628. The conductivity of Electrolytic solutions depends
on-
(1) Size of the ions produced and their solvation
(2) The nature of the solvent and its viscosity
ALLEN
634. The molar ionic conductances at infinite
dilution of K+ and SO42– are 73.5 and 160 Scm2
mol–1 respectively. The molar conductance of
solution of K2SO4 at infinite dilution will be

(3) temperature (1) 233.5 (2) 307

(4) All of the above (3) 153.5 (4) 467

629. Which statement is incorrect about cell constant 635. How many seconds, 0.2 A current should be
passed to deposit 40%, Cu from 200 ml of
(1) Cell constant depends on the distance
0.5M CuSO4 solution ?
between the electrodes and their area of cross
section (1) 38600 sec (2) 42100 sec

(2) The dimension of cell constant is length –1 (3) 28200 sec (4) 10500 sec

(3) The cell constant G* = Rk
(4) None of the above
630. The volume of hydrogen gas liberated at STP
when a current of 5.36 ampere is passed
through dil. H2SO4 for 5 hours will be
636. When a solution containing Zn++ and Cu++ is
electrolysed. Cu++ is deposited at cathode why.
(1) (S.R.P.)Zn++ > (S.R.P.)Cu++
(2) (S.R.P.)Zn++ < (S.R.P.)Cu++

(1) 5.6L (2) 11.2L

(3) (S.O.P.) Zn ++ < (S.O.P.)Cu ++
(3) 16.8L (4) 22.4L
631. The electrolysis of silver nitrate solution is (4) (S.R.P.)H2O > (S.R.P.)Cu ++
carried out using silver electrods. Which the
637. For half reaction
following reaction occurs at the anode?
(1) Ag ® Ag+ + e– MnO4- + 5eΘ + 8H + ® Mn ++ + 4H 2 O

(2) Ag+ + e– ® Ag then Nerst equation for ERP is :-

(3) 2H2O ® 4H+ + O2 + 4e–
8
– – 0.059 éë MnO-4 ùû éë H + ùû
(4) 4OH ® 2H2 + O2 + 4e (1) E MnO- / Mn 2+ =E +0
log
4
5 éë Mn 2 + ùû
632. The equilibrium constant (K) for the reaction
Fe2+(aq) + Ag+(aq) ® Fe3+(aq) + Ag(s) will be
éë Mn ++ ùû [ H 2 O ]
4
GivenE°(Fe3+/Fe2+) = 0.77V; 0.059
(2) E MnO4- / Mn 2+ =E -0
log
E°(Ag+/Ag) = 0.80V 5 éë MnO -4 ùû
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(1) 100 (2) 3.16

(3) 10 (4) 0.5 éë Mn ++ ùû
(3) E MnO-4 / Mn 2+ = E - 0.059 ´ 5 log
0

633. The ionization constant of a weak electrolyte éë MnO 4- ùû éë H + ùû

8

is 25 × 10– 6 while the equivalent conductance

of its 0.01M solution is 19.6 Scm 2 eq–1. The
8
equivalent conductance of the electrolyte at 0.059 é MnO 4- ùû éë H + ùû
(4) E MnO-4 / Mn 2+ =E +0
log ë
infinite dilution (in Scm2 eq–1) will be 7 éë MnO 4- ùû [ H 2 O]
4

(1) 250 (2) 196 (3) 392 (4) 384

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638. Aqueous soln of AuCl3 , CuSO4 & AgNO3 are 645. Which is correct for an electrolytic cell ?
connected in series, when 3F charge is passed (1) ECell < 0 (2) ECell > 0
then calculate ratio of moles of metals deposited
(3) DG = 0 (4) Both (2) and (3)
on cathod.
646. A quantity of electricity required to reduce
(1) 2 : 3 : 6 (2) 3 : 4 : 5
12.3 gm of nitrobenzene to aniline arising 50%
(3) 1 : 3 : 5 (4) None current efficiency is :-
639. Why density of electrolyte in lead storage (1) 115800 C (2) 579000 C
battery decreases as it is discharge.
(3) 231600 C (4) 289500 C
(1) Only Pb reacts with H2SO4
647. How many columbs are required for the
(2) Only PbO2 reacts with H2SO4 oxidaion of 1 mol of H2O2 to O2 ?
(3) H2 SO4 is formed (1) 9.65 × 104 C (2) 93000 C
(4) Pb and PbO2 both reacts with H2 SO4 (3) 1.93 × 105 C (4) 19.3 × 102 C
640. Which of the following has highest resistance 648. Which of the following equility holds good for
during the passage of current? the strong electrolytes ?
(1) 1 N NaCl (2) 0.1 N NaCl
(1) Ù = Ù0 as C ® 1
(3) 2N NaCl (4) 0.05 N NaCl
641. 0.36 gram of a metal is deposited on the (2) Ù = Ù0 as C ® 0
electrode. When 1.2 A current is passed for 15 (3) Ù = Ù0 as C ® ¥
min. though its salt. At weight of metal is 96.
(4) Ù = Ù0 as C ® b
What will be its valency.
(1) 2 (2) 3 (3) 4 (4) 1 649. The quantity of electricity required to reduce
642. If Hg is used as cathode is the electolysis of 0.05 mole of MnO-4 to Mn+2 in acidic medium
aqueous NaCl solution, the ions discharged at would be :-
cathode are :-
(1) 0.01 F (2) 0.05 F
(2) H+ (2) Na+
(3) 0.15 F (4) 0.25 F
(3) OH– (4) Cl–
643. Which metal will dissolve if the cell works SURFACE CHEMISTRY
Cu|Cu++ || Ag+|Ag 650. Bredig arc method cannot be used to prepare
colloidal solution of which of the following :-
(1) Cu
(1) Pt (2) Ag (3) Au (4) Fe
(2) Ag
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651. Which one of the following is correctly

(3) both 1 and 2 matched:-
(4) No metal will dissolve (1) Emulsion - curd (2) Foam - mist
644. Passage of three faraday of charge through (3) Aerosol - smoke (4) Sol - cake
aqueous solution of AgNO3, CuSO4, Al(NO3)3 652. The protecting power of Lyophilic colloidal sol
and NaCl respectively will deposited metals at is expressed in terms of :-
cathode in the molar ratio : (1) Coagulation value
(1) 1 : 2 : 3 : 1 (2) 6 : 3 : 2 : 6 (2) Gold number

(3) 6 : 3 : 0 : 0 (4) 3 : 2 : 1 : 0 (3) Critical micelle concentration

(4) Oxidation number
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