Carbonyl

IUPAC naming
Isomerism
 General formula and structure

• Molecular formula: • Molecular formula:

• IUPAC name: propanal • IUPAC name: propanone
• Number of pi bond: • Number of pi bond:
• Number of sigma bond: • Number of sigma bond:
• Bond angle for carbonyl carbon: • Bond angle for carbonyl carbon:
 IUPAC naming for aldehyde (p.152)

CH(CH3)2CH(CH3)CH2CH(OH)CHO
 IUPAC naming for aldehyde (p.152)
Answers

4-ethyl-2,3-dimethylhexanal
3-chloro-4-ethyl-2-methylhept-2-enal

CH(CH3)2CH(CH3)CH2CH(OH)CHO
2-hydroxyl-4,5-dimethylhexanal

2-bromo-4-ethyl-2,3-dimethylhexanal
 IUPAC Naming for ketone p.152

CH(CH3)2CH(CH3)COCH2CH2CH3
 IUPAC Naming for ketone p.152
Answer

4-ethyl-2-methylheptan-3-one 5-ethyl-2-hydroxyl-4-methylheptan-3-one

CH(CH3)2CH(CH3)COCH2CH2CH3

5,6-dimethylheptan-4-one

2-bromo-4-ethyl-1-hydroxyl-2-methylhexan-3-one
Isomerism in aldehyde
Q: Name each isomer
 Isomerism in aldehyde
Answer
butanal Butan-2-one

2-methylpropanal
 Isomerism in ketone
Q1: Name each isomer
Q2: Identify optical isomers
 Isomerism in ketone
Answer

Pentan-2-one Pentan-3-one
pentanal

2-methylbutanal 3-methylbutanal 2,2-dimethylpropanal

3-methylbutan-2-one