CHEMISTRY

th
11 JEE

jklk;fud vkca/ku rFkk

vkf.od lajpuk
(CHEMICAL BONDING &
MOLECULAR STRUCTURE)

VIDYAPEETH
S E L E C T I O N H O G A Y AH I N S E
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VIDYAPEETH
p

jklk;fud vkca/ku
DPP-1
[v"Vd fu;e] ywbl izrhd] lgla;kstd vkca/k] milgla;kstd vkca/k]
vkSipkfjd vkos'k rFkk blds vuqiz;ksx]
1. In a covalent bond formation, 1. ,d lgla;kstd vkca/k fuekZ.k esa]
(A) transfer of electrons takes place (A) bysDVªkWuksa dk LFkkukUrj.k gksrk gSA
(B) equal sharing of electrons between two atoms (B) nks ijek.kqvksa ds e/; bysDVªkWuksa dk leku lk¡>k
takes place gksrk gSA
(C) electrons are shared by one atom only (C) bysDVªkWu dsoy ,d ijek.kq ds }kjk lkf>r gksrs gSA
(D) electrons are donated by one atom and shared
(D) bysDVªkWuksa dk ,d ijek.kq ds }kjk nku fd;k tkrk
by both atoms.
gS rFkk nksuksa ijek.kqvksa ds }kjk lk¡>k gksrs gSA
2. Which of the following is correct for the process of 2. fuEu esa ls dkSulk] ,d jklk;fud vkca/k ds fuekZ.k ds
formation of a chemical bond? izØe ds fy,] lgh gS?
(A) Electron-electron repulsion becomes more than (A) bysDVªkWu-bysDVªkWu izfrd"kZ.k] ukfHkd-bysDVªkWu
the nucleus-electron attraction. vkd"kZ.k dh rqyuk esa vf/kd gksrk gSA
(B) Energy of the system does not change. (B) fudk; dh ÅtkZ ifjofrZr ugh gksrh gSA
(C) Energy increases. (C) ÅtkZ c<+rh gSA
(D) Energy decreases. (D) ÅtkZ ?kVrh gSA

3. Which has incomplete octet? 3. fuEu esa ls dkSulk viw.kZ v"Bd j[krk gS?
(A) NaCl (B) AlF3 (A) NaCl (B) AlF3
(C) CsCl (D) BBr3 (C) CsCl (D) BBr3

4. Which of the following is electron-deficient? 4. fuEu esa ls dkSulk bysDVªkWu-U;wu gS?

(A) (BH3)2 (B) PH3 (A) (BH3)2 (B) PH3
(C) (CH3)2 (D) (SiH3)2 (C) (CH3)2 (D) (SiH3)2

5. How many number of penta atomic species are 5. ik¡p ijekf.od Lih'kht dh fdruh la[;k vfrla;ksth gS?
hypervalent
XeO3, XeF6, SF4, XeF4, SF6
XeO3, XeF6, SF4, XeF4, SF6
(I) (II) (III) (IV) (V) (I) (II) (III) (IV) (V)
(A) Only II & III (B) Only III & IV (A) dsoy II rFkk III (B) dsoy III rFkk IV
(C) I, II & V (D) All of these (C) I, II rFkk V (D) ;s LkHkh

6. Which one of the following contains all three- ionic, 6. fuEu esa ls dkSu vk;fud] lgla;kstd rFkk
covalent and co-ordinate bonds? milgla;kstd rhuksa vkca/k j[krk gS?
(A) NaOH (B) NaCl (A) NaOH (B) NaCl
(C) HCl (D) NaNC (C) HCl (D) NaNC
7. Which of the following doesn't obeys Lewis octet 7. fuEu esa ls dkSulk ywbl v"Vd fu;e dk ikyu ugh
rule? djrk gS?
(A) CO (B) NO3− (A) CO (B) NO3−
(C) O3 (D) NO (C) O3 (D) NO
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8. What is the formal charge on nitrogen atom in NO3− ? 8. NO3− esa ukbVªkt
s u ijek.kq ij vkSipkfjd vkos'k D;k gS\
9. In which one of the following compounds does the 9. fuEu esa ls dkSuls ;kSfxd esa dsUnzh; ijek.kq v"Vd fu;e
central atom obey the octet rule? dk ikyu djrk gS?
(A) XeF4 (B) XeOF2 (A) XeF4 (B) XeOF2
(C) SCl2 (D) AlCl3 (C) SCl2 (D) AlCl3

10. Statement-I: The formal charge of terminal nitrogen 10.
in structure CH2=N=N is –1.
Statement-II: The structure with the least number of
formal charges is more stable.
(A) Both statement I & II are correct.
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
incorrect.
(D) Statement I is incorrect while statement II is
correct.
dFku-I: lajpuk CH2=N=N esa varLFk ukbVªkt s u dk
QkWeZy vkos'k –1 gSA
dFku-II: vkSipkfjd vkos'kksa dh U;wure la[;k ;qDr
lajpuk vf/kd LFkk;h gksrh gsA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA
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DPP-2
[v"Vd fu;e] ywbl izrhd] lgla;kstd vkca/k] milgla;kstd vkca/k]
vkSipkfjd vkos'k rFkk blds vuqiz;ksx]
1. Molecule having an incomplete octet in the central atom 1. dsUnzh; ijek.kq esa viw.kZ v"Vd j[kus okyk v.kq gS&
is (A) PCl5 (B) NH3
(A) PCl5 (B) NH3
(C) BCl3 (D) H2O
(C) BCl3 (D) H2O

2. Octet rule is mostly violated in the compounds 2. fuEu esa ls fdlds }kjk fufeZr ;kSfxdksa esa v"Vd fu;e
formed by dk lokZf/kd mYya?ku gksrk gS\
(A) Alkali metals (A) {kkjh; /kkrqvksa }kjk
(B) Alkaline earth metals (B) {kkjh; e`nk /kkrqvksa }kjk
(C) p-block elements
(C) p-block rRo }kjk
(D) Transition elements
(D) laØe.k rRo }kjk

3. Which of the following species are hypervalent ? 3. fuEu esa ls dkSulh Lih'kht vfrla;ksth gS\
1. ClO−4 2. BF3 1. ClO−4 2. BF3
3. SO42– 4. CO3 2–
3. SO42– 4. CO32–
(A) 1, 2, 3 (B) 1, 3 (A) 1, 2, 3 (B) 1, 3
(C) 3, 4 (D) 1, 2 (C) 3, 4 (D) 1, 2

4. Which of the following Lewis diagram is incorrect? 4. fuEu esa ls dkSulk yqbl fp= xyr gS\

(A) Na + [ :O − Cl:]− (B) (A) Na + [ :O − Cl:]− (B)

(C) (D) (C) (D)

5. The bonds present in N2O5 are: 5. N2O5 esa mifLFkr vkca/k gS&
(A) Only ionic (A) dsoy vk;fud
(B) Covalent & coordinate (B) lgla;kstd rFkk milgla;kstd
(C) Only covalent (C) dsoy lgla;kstd
(D) Covalent & ionic (D) lgla;kstd rFkk vk;fud

6. The pair of compounds which can form a co-ordinate 6. fuEu esa ls ;kSfxdksa dk ;qXe dkSulk gS tks ,d
bond is: milgla;kstd vkca/k dk fuekZ.k dj ldrk gS&
(A) (C2H5)3 B and (CH3)3N (A) (C2H5)3 B rFkk (CH3)3N
(B) HCl and HBr (B) HCl rFkk HBr
(C) BF3 and NH3
(C) BF3 rFkk NH3
(D) (A) and (C) both
(D) (A) rFkk (C) nksuksa

7. If stability were attained with 6 electrons rather than 7. ;fn LFkkf;Ro 8 bysDVªkWuksa ds LFkku ij 6 bysDVªkWuksa ds
with 8 electrons, what would be the formula of the lkFk izkIr gksrk gS] rks LFkk;h ¶yksjkbM vk;u dk lw=
stable fluoride ion D;k gksxk\
(A) F3+ (B) F+ (A) F3+ (B) F+

(C) F– (D) F2– (C) F– (D) F2–

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8. N= N = N 8. N= N = N
(I) (II) (III) (I) (II) (III)
Calculate the formal charge of each I, II and III Øe'k% izR;sd I, II rFkk III ukbVªkt
s u ijek.kq ds
nitrogen atom respectively vkSipkfjd vkos'k Kkr dhft,A
(A) +1, –1, 0 (B) –1, –1, +1 (A) +1, –1, 0 (B) –1, –1, +1
(C) –1, +1, –1 (D) 0, –1, –1 (C) –1, +1, –1 (D) 0, –1, –1

9. What is the sum of magnitude of the formal charges 9. nh x;h lajpuk esa Øe'k% B rFkk N ij vkSipkfjd vkos'kksa
on B and N respectively in the given structure? ds ifjek.k dk ;ksx D;k gS\

10. Statement-I: The Carbon mono-oxide molecule is
electron-deficient.
Statement-II: The structure of CO involve one
coordinate bond from Oxygen to carbon.
(A) Both statement I & II are correct.
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
incorrect.
(D) Statement I is incorrect while statement II is
correct.
10. dFku-I: dkcZu eksuks&vkWDlkbM v.kq bysDVªkWu&U;wu gksrk
gSA
dFku-II: CO dh lajpuk vkWDlhtu ls dkcZu esa ,d
milgla;kstd vkca/k lfEefyr djrh gSA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA
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DPP-3
[VSEPR fl)kUr] v.kqvksa dh T;kfefr rFkk vkdkj] la;ksth vkca/k fl)kUr]
ijekf.od d{kdksa dk vfrO;kiu]
1. Choose the correct order of bond strength by 1. ijekf.od d{kdksa ds vfrO;kiu }kjk vkca/k lkeF;Z ds
overlapping of atomic orbitals lgh Øe dk p;u dhft,A
(A) 1s-1s > 1s-2s > 1s-2p (A) 1s-1s > 1s-2s > 1s-2p
(B) 2s-2s > 2s-2p > 2p-2p (B) 2s-2s > 2s-2p > 2p-2p
(C) 2s-2p > 2s-2s > 2p-2p (C) 2s-2p > 2s-2s > 2p-2p
(D) 1s-1s > 1s-2p > 1s-2s
(D) 1s-1s > 1s-2p > 1s-2s

2. Which of the following set contains species having 2. fuEu esa ls dkSulh iztkfr;ksa dk leqPp; dsUnzh; ijek.kq
same angle around the central atom? ds pkjksa vksj leku dks.k j[krk gS\
(A) SF4, CH4, NH3 (B) NF3, BCl3, NH3 (A) SF4, CH4, NH3 (B) NF3, BCl3, NH3
(C) BF3, NF3, AlCl3 (D) BF3, BCl3, BBr3 (C) BF3, NF3, AlCl3 (D) BF3, BCl3, BBr3

3. In which of the following molecules/ions all the 3. fuEu esa ls dkSuls v.kqvksa@vk;uksa esa lHkh vkca/k leku
bonds are not equal? ugha gSa\
(A) SF4 (B) SiF4 (A) SF4 (B) SiF4
(C) XeF4 (D) BF4− (C) XeF4 (D) BF4−

4. The correct order of bond angles (smallest first) in 4. H2S, NH3, BF3 rFkk SiH4 esa vkca/k dks.kksa ¼lcls igys
H2S, NH3, BF3 and SiH4 is U;wure½ dk lgh Øe gS&
(A) H2S < SiH4 < NH3 < BF3 (A) H2S < SiH4 < NH3 < BF3
(B) H2S < NH3 < BF3 < SiH4 (B) H2S < NH3 < BF3 < SiH4
(C) H2S < NH3 < SiH4 < BF3 (C) H2S < NH3 < SiH4 < BF3
(D) NH3 < H2S < SiH4 < BF3 (D) NH3 < H2S < SiH4 < BF3

5. The correct order of H – M – H bonds angle is 5. H – M – H vkca/k dks.k dk lgh Øe gS&

(A) NH3 < PH3 < SbH3 < BiH3 (A) NH3 < PH3 < SbH3 < BiH3
(B) AsH3 < SbH3 < PH3 < NH3 (B) AsH3 < SbH3 < PH3 < NH3
(C) NH3 < PH3 < BiH3 < SbH3 (C) NH3 < PH3 < BiH3 < SbH3
(D) BiH3 < SbH3 < AsH3 < PH3 (D) BiH3 < SbH3 < AsH3 < PH3

6. Select the correct order of H—M—H bond angle 6. H—M—H vkca/k dks.k ds lgh Øe dk p;u dhft,&
(A) PH3  PH4+ (B) P2H4  PH4+ (A) PH3  PH4+ (B) P2H4  PH4+
(C) PH3  NH+4 (D) PH+4  NH3 (C) PH3  NH+4 (D) PH+4  NH3

7. Compare bond angle x and y in the following 7. fuEu v.kqvksa esa vkca/k dks.k x rFkk y dh rqyuk dhft,&
molecules

(A) x>y (B) y>x (A) x>y (B) y>x

(C) x=y (D) None of these (C) x=y (D) buesa ls dkbZ ugha

8. Find the number of 90° angles in XeF5− molecules
9. Compare bond angle among H2O, OF2, OMe2 and 9.
OCl2
(A) H2O < OF2 < OMe2 < OCl2
(B) OF2 < H2O < OCl2 < OMe2
(C) OCl2 < OMe2 < H2O < OF2
(D) OCl2 < OF2 < OMe2 < H2O
10. Statement-I: Relation between (adjacent angle) 10.
FClF and FBrF bond angle in ClF3 and BrF3
molecule respectively is given byFClF < FBrF
Statement-II: Relation between (adjacent angle)
FClF and FBrF bond angle in ClF3 and BrF3
molecule respectively is given byFClF > FBrF.
(A) Both statement I & II are correct.
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
incorrect.
(D) Statement I is incorrect while statement II is
correct.
8
8. XeF5− v.kqvksa esa 90° dks.kksa dh la[;k Kkr dhft,A
H2O, OF2, OMe2 rFkk OCl2 esa vkca/k dks.k dh rqyuk
dhft,A
(A) H2O < OF2 < OMe2 < OCl2
(B) OF2 < H2O < OCl2 < OMe2
(C) OCl2 < OMe2 < H2O < OF2
(D) OCl2 < OF2 < OMe2 < H2O
dFku-I: Øe'k% ClF3 rFkk BrF3 v.kq esa FClF rFkk
FBrF vkca/k dks.k ¼fudVorhZ dks.k½ ds e/; laca/k
FClF < FBrF ds }kjk fn;k x;k gSA
dFku-II: Øe'k% ClF3 rFkk BrF3 v.kq esa FClF rFkk
FBrF vkca/k dks.k ¼fudVorhZ dks.k½ ds e/; laca/k
FClF > FBrF ds }kjk fn;k x;k gSA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA
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DPP-4
[VSEPR fl)kUr] v.kqvksa dh T;kfefr rFkk vkdkj] la;ksth vkca/k fl)kUr]
ijekf.od d{kdksa dk vfrO;kiu]
1. If y-axis is the approaching axis between two atoms, 1. ;fn y-v{k nks ijek.kqvksa ds e/; vkus okyh v{k gS rks fuEu
then which of the set of orbitals can not form the  esa ls d{kdksa dk dkSulk leqPp; lkekU;r;k nks ijek.kqvksa
bond between two atoms in general. ds e/;  vkca/k dk fuekZ.k ugha dj ldrk gS\
(A) pz – pz (B) px– px (A) pz – pz (B) px– px
(C) px – py (D) None of these (C) px – py (D) buesa ls dksbZ ugha

2. The correct order of bond angles is : 2. ca/k dks.k dk lgh Øe gS&

(A) NO−2  NO2+  NO2 (A) NO−2  NO2+  NO2
(B) NO+2  NO2−  NO2 (B) NO+2  NO2−  NO2
(C) NO2  NO+2  NO−2 (C) NO2  NO+2  NO−2
(D) NO+2  NO2  NO2− (D) NO+2  NO2  NO2−

3. Which of the following has higher bond angle? 3. fuEu esa ls dkSulk mPp vkca/k dks.k j[krk gS\
(A) H2O (B) CH4 (A) H2O (B) CH4
(C) Graphite (D) H2SO4 (C) xzsQkbV (D) H2SO4

4. The molecule having smallest bond angle is 4. U;wure vkca/k dks.k j[kus okyk v.kq gS&
(A) AsCl3 (B) SbCl3 (A) AsCl3 (B) SbCl3
(C) PCl3 (D) NCl3 (C) PCl3 (D) NCl3

5. Decreasing order of bond angle is 5. vkca/k dks.k dk ?kVrk gqvk Øe gS&

(A) BeCl2 > NO2 > SO2 (A) BeCl2 > NO2 > SO2
(B) BeCl2 > SO2 > NO2 (B) BeCl2 > SO2 > NO2
(C) SO2 > BeCl2 > NO2 (C) SO2 > BeCl2 > NO2
(D) SO2 > NO2 > BeCl2 (D) SO2 > NO2 > BeCl2

6. Which of the following is the correct representation 6. fuEu esa ls dkSulk  vkca/k ds fuekZ.k dk lgh fu#i.k gS\
of formation of  bond?

(A) +
(A) +
S P
S P

(B) +
(B) +
S P
S P

(C) +
(C) +

P P P P

(D) + (D) +

d P d P
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7. FAsF bond angle in AsF3Cl2 molecule is: 7. AsF3Cl2 v.kq esa FAsF vkca/k dks.k gS&
(A) 90° and 180° (A) 90° rFkk 180°
(B) 120° (B) 120°
(C) 90° (C) 90°
(D) 180° (D) 180°

8. Among NO3− ,CO32− ,ClO3− ,SO32− and BO3−3 the 8. NO3− ,CO32− ,ClO3− ,SO32− rFkk BO3−3 esa ls vleryh;
non-planar species are – Lih'kht gS&
(A) CO32− ,SO32− ,BO3−3 (A) CO32− ,SO32− ,BO3−3
(B) ClO3− , SO32− (B) ClO3− , SO32−
(C) NO3− , CO32− , BO3−3 (C) NO3− , CO32− , BO3−3
(D) NO3− , SO32− , BO3−3 (D) NO3− , SO32− , BO3−3

9. The compound MX4 is tetrahedral. The number of 9. ;kSfxd MX4 prq"Qydh; gksrk gS] ;kSfxd esa XMX
XMX angles in the compound is: dks.kksa dh la[;k gS&

10. Statement-I: Position of fluorine in PCl3F2 is 10. dFku-I: PCl3F2 esa ¶yksjhu dh fLFkfr nksuksa {kSfrt
identified both at equatorial positions. fLFkfr;ksa ij igpkuh tkrh gSA
Statement-II: More Electronegative atom prefers
dFku-II: vf/kd oS|qr_.kkRed ijek.kq dks vf/kd p
the orbital having more p character.
(A) Both statement I &II are correct.
y{k.k j[kus okys d{kd dks izkFkfedrk nsrs gSaA
(B) Both statement I & II are incorrect. (A) dFku-I rFkk dFku-II nksuksa lgh gSA
(C) Statement I is correct while statement II is (B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
incorrect.
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) Statement I is incorrect while statement II is
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA
correct.
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DPP-5
CO2 ,HCO2− ,CO,CO32−
[ladj.k] ifjorZu'khy la;kstdrk] cgq&vkca/k] vuqukn]
* * * * * *
1. The hybridization at carbons involved in C− C bond 1. HC  C− CH = CH2 esa C− C vkca/k esa lfEefyr
* *
in HC  C− CH = CH2 is: dkcZuksa ij ladj.k gS&
(A) sp3 – sp2 (B) sp3 – sp3 (A) sp3 – sp2 (B) sp3 – sp3
(C) sp – sp2 (D) sp – sp3 (C) sp – sp2 (D) sp – sp3

2. The hybridization of P in PO34− is same as in: 2. PO34− esa P dk ladj.k fuEu esa ls fdlds leku gksrk
(A) I in ICl−4 (B) S in SO3
gS\
(A) ICl−4 eas I (B) SO3 esa S
(C) N in NO3− (D) S in SO24−
(C) NO3− eas N (D) SO24− eas S

3. The species in which the N atom is in a state of sp 3. Lih'kht crkb;s ftlesa N ijek.kq sp ladj.k voLFkk esa
hybridization is: gksrk gSS&
(A) NO+2 (B) NO−2 (A) NO+2 (B) NO−2
(C) NO3− (D) NO2 (C) NO3− (D) NO2

4. The AsF5 molecule is trigonal bipyramidal. The 4. AsF5 v.kq f=dks.kh; f}fijkfeMh; gSA vkca/ku ds fy,
hybrid orbitals used by the As atoms for bonding are: As ijek.kqvksa ds }kjk iz;qä ladj d{kd gS&
(A) dx2 −y2 , dz2 , s, px , py (A) dx2 −y2 , dz2 , s, px , py
(B) d xy , s, px , p y , pz (B) d xy , s, px , p y , pz
(C) dx2 −y2 , s, px , py (C) dx2 −y2 , s, px , py
(D) s, px , py , pz , dz2 (D) s, px , py , pz , dz2

5. Carbon atoms in C2 (CN) 4 are: 5. C2 (CN) 4 esa dkcZu ijek.kq gS&

(A) sp-hybridized (A) sp-ladfjr
(B) 2
sp -hybridized (B) sp2 -ladfjr
(C) sp and sp2 -hybridized (C) sp rFkk sp2 -ladfjr
(D) sp, sp2 and sp3 - hybridized (D) sp, sp2 rFkk sp3 - ladfjr

6. The correct order of ‘S – O’ bond length is: 6. ‘S – O’ vkca/k yEckbZ dk lgh Øe gS&
(A) SO32−  SO42−  SO3  SO2 (A) SO32−  SO42−  SO3  SO2
(B) SO32−  SO42−  SO2  SO3 (B) SO32−  SO42−  SO2  SO3
(C) SO24−  SO32−  SO2  SO3 (C) SO24−  SO32−  SO2  SO3
(D) SO24−  SO32−  SO3  SO2 (D) SO24−  SO32−  SO3  SO2

7. The correct arrangement of the species in the 7. dkcZu rFkk vkWDlhtu ds e/; vkca/k yEckbZ ds ?kVrs
decreasing order of the bond length between carbon
gq, Øe esa bu Lih'kht dh lgh O;oLFkk gS&
and oxygen in them is
(A) CO,CO2 ,HCO2− ,CO32− (A) CO,CO2 ,HCO2− ,CO32−

(B) CO2 ,HCO2− ,CO,CO32− (B) CO2 ,HCO2− ,CO,CO32−

(C) CO32− ,HCO2− ,CO2 ,CO (C) CO32− ,HCO2− ,CO2 ,CO
(D) CO,CO32− ,CO2 ,HCO2− (D) CO,CO32− ,CO2 ,HCO2−
 12

8. How many are correct statement(s)? 8. fdrus lgh dFku gS\

As the s-character of a hybrid orbital decreases tSls gh ,d ladj d{kd dk s-vfHky{k.k ?kVrk gS&
(I) The bond angle decreases (I) vkca/k dks.k ?kVrk gSA
(II) The bond strength increases (II) vkca/k lkEFk;Z c<+rk gSA
(III) The bond length increases (III) vkca/k yEckbZ c<+rh gSA
(IV) Size of orbitals increases (IV) d{kdksa dk vkdkj c<+rk gSA

9. Which of the following statement is correct regarding 9. XeO2F2 v.kq dh lajpuk ds lUnHkZ esa fuEu esa ls dkSulk
the structure of XeO2F2 molecule? dFku lgh gS\
(A) Xe = O bonds are present in axial position (A) v{kh; fLFkfr esa Xe = O vkca/k mifLFkr gSaA
(B) All Xe—F bond lengths are identical (B) lHkh Xe—F vkca/k yEckbZ;k¡ le:i gksrh gSaA
(C) FXeF angles are 90°
(C) FXeF dks.k 90° ds gksrs gSaA
(D) Shape of the molecule is octahedral
(D) v.kq dk vkdkj v"VQydh; gksrk gSA

10. Statement-I: dsp2 hybrid orbitals are all at 90 to one
another.
Statement-II: Hybridisation is the mixing of valence
atomic orbitals of similar energy to form hybrid
orbitals which are equivalent and differ only in
orientation.
(A) Both statement I &II are correct.
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
10. dFku-I: lHkh dsp2 ladj d{kd ,d&nwljs ls 90 ij
gksrs gSaA
dFku-II: ladj.k] ladj d{kdksa ds fuekZ.k ds fy, leku
ÅtkZ ds la;kstdrk ijekf.od d{kdksa dk feJ.k gksrk
gS tks dsoy foU;kl esa rqY;kadh rFkk i`Fkd gksrs gSaA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA

incorrect (C) dFku-I lgh gS ysfdu dFku-II xyr gSA

(D) Statement I is incorrect while statement II is
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA
correct
 13

DPP-6
[ladj.k] ifjorZu'khy la;kstdrk] cgq&vkca/k] vuqukn ]
` 1. The hybridisation of carbon in diamond, graphite and 1. ghjk] xzsQkbV rFkk ,slhfVyhu esa dkcZu dk ladj.k gS&
acetylene is (A) sp3, sp2, sp (B) sp3, sp, sp2
(A) sp3, sp2, sp (B) sp3, sp, sp2
2 3
(C) sp , sp , sp (D) sp, sp3, sp2 (C) sp2, sp3, sp (D) sp, sp3, sp2

2. The hybridisation and shape of ClO3− is:
(A) sp3 and tetrahedral
(B) sp3 and triangular pyramidal
(C) sp3 and triangular planar
(D) sp3d and trigonal bipyramidal
2. ClO3− dk ladj.k rFkk vkd`fr gS&
(A) sp3 rFkk prq"Qydh;
(B) sp3 rFkk f=dks.kh; fijkfeMh;
(C) sp3 rFkk f=dks.kh; leryh;
(D) sp3d rFkk f=dks.kh; f}fijkfeMh;

3. The percentage of s-character in the hybridized 3. BF3 esa B ds ladfjr d{kdksa ds s-vfHky{k.k dh izfr'krrk
orbitals of B in BF3 is: gS&
(A) 25 (B) 50 (A) 25 (B) 50
(C) 75 (D) 33.3 (C) 75 (D) 33.3

4. The hybridization of central iodine atom in IF5, I3− 4. IF5, I3− rFkk I3+ esa dsUnzh; vk;ksMhu ijek.kq dk ladj.k
+ Øe'k% gS&
and I3 are respectively:
(A) sp3d2, sp3d, sp3 (B) sp3d, sp3d, sp3 (A) sp3d2, sp3d, sp3 (B) sp3d, sp3d, sp3
3 2 3 2
(C) sp d , sp d , sp 3
(D) sp3d, sp3d2, sp3 (C) sp3d2, sp3d2, sp3 (D) sp3d, sp3d2, sp3

5. Which of the following statements is correct?
(A) A sp3 hybrid orbitals have equal s and p
character.
(B) The bond angle decreases with the decrease of s
character of hybridized orbital.
(C) Resonance decreases the stability of a molecule.
(D) Resonance is due to delocalization of sigma
electrons.
5. fuEu esa ls dkSulk dFku lgh gS\
(A) ,d sp3 ladj d{kd cjkcj s rFkk p vfHky{k.k
j[krk gSA
(B) vkca/k dks.k ladfjr d{kd ds s vfHky{k.k dh deh
ds lkFk ?kVrk gSA
(C) vuqukn ,d v.kq ds LFkkf;Ro dks de djrk gSA
(D) vuqukn flXek bysDVªkWuksa ds foLFkkuhdj.k ds dkj.k
gksrk gSA

6. The correct increasing order of O − O bond length in 6. fuEu v.kqvksa esa O – O vkca/k yEckbZ dk lgh c<+rk gqvk
the following molecules is Øe gS&
(A) H2O2  O2  O3 (B) O3  H2O2  O2 (A) H2O2  O2  O3 (B) O3  H2O2  O2
(C) O2  H2O2  O3 (D) O2  O3  H2O2 (C) O2  H2O2  O3 (D) O2  O3  H2O2

7. Choose the incorrect option for bond strength. 7. vkca/k lkeF;Z ds fy, xyr fodYi dk p;u dhft,&
(A) 2p– 2p > 2p – 3p (A) 2p– 2p > 2p – 3p
(B) 2p– 3p > 2p – 3d (B) 2p– 3p > 2p – 3d
(C) 1s– 2p > 2s – 2p (C) 1s– 2p > 2s – 2p
(D) 2s– 2p > 3s – 3p
(D) 2s– 2p > 3s – 3p

8. Which among the following resonance structures of 8. N3– dh fuEu vuqukn lajpukvksa esa ls dkSulh lajpuk
N3– satisfies the octet rule but is ruled out as a v"Vd fu;e dks larq"V djrh gS] ysfdu ,d vuqukn
resonance structure? lajpuk ds :i esa mYya?ku djrh gS\
(I) (II) (I) (II)

(III) (IV) (III) (IV)

(A) IV only (B) I and IV only (A) dsoy IV (B) dsoy I rFkk IV
(C) I only (D) II and III only (C) dsoy I (D) dsoy II rFkk III

9. In PO34− , the sum of magnitude of formal charge on
each oxygen atom and the P-O bond order
respectively is ___
10. Statement-I: For resonance, the contributing
structures should be so that unlike charges, if any,
reside on atoms that are far apart.
Statement-II: Hybrid structure is most energetic
among various resonating structures.
(A) Both statement I &II are correct.
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
incorrect
(D) Statement I is incorrect while statement II is
correct
14
9. PO34− es,a izR;sd vkWDlhtu ijek.kq ij vkSipkfjd vkos'k
ds ifjek.k rFkk P-O vkca/k dksfV dk ;ksx gS___
10. dFku-I: vuqukn esa ;ksxnku nsus okyh lajpuk,¡ bl izdkj
gksuh pkfg, fd foijhr vkos'k nwj fLFkr ijek.kqvksa ij
vk,A
dFku-II: ladj lajpuk fofHkUu vuquknh lajpukvksa esa ls
lcls vf/kd ÅtkZ okyh gksrh gSA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA
 15

DPP-7
[MOT-leukfHkdh; f}ijek.oh; v.kqvksa ds vkf.od d{kd bysDVªkWfud foU;kl]
1. What is the bond order of He+2 ? 1. He+2 dh vkca/k dksfV D;k gS?
(A) 1.0 (B) 0.5 (A) 1.0 (B) 0.5
(C) 1.5 (D) 2.0 (C) 1.5 (D) 2.0

2. “s-p-mixing” is not observed in 2. “s-p-lfEEkJ.k” fuEu esa ls fdlesa izsf{kr ugh gksrk gS\
(A) N2 (B) N22− (A) N2 (B) N22−
(C) O22+ (D) Both (B) & (C) (C) O22+ (D) nksuksa (B) rFkk (C)

3. Which is incorrect according to MOT ? 3. MOT ds vuqlkj dkSulk xyr gS?

(A) H +2 and He+2 have same stability (A) H +2 rFkk He+2 leku LFkkf;Ro j[krs gSaA

(B) H2 is more stable than H +2
(C) He+2 may exist while He2 cannot
(D) same bond order of two species do not mean
they have same bond energy
(B) H2, H +2 ls vf/kd LFkk;h gksrk gSA
(C) He+2 dk vfLrRo gks ldrk gS tcfd He2 dk
vfLrRo ugh gks ldrk gSA
(D) nks Lih'kht dh vkca/k dksfV leku gS] bldk vFkZ
;g ugha gS fd vkca/k ÅtkZ Hkh leku gksA

4. O2 is paramagnetic, this property as for B2, can not be 4. O2 vuqpqEcdh; gksrh gS] B2 ds fy, bl xq.k dks
explained by the traditional Lewis dot structure but is ikjEifjd ywbl fcUnq lajpuk }kjk le>k;k ugh tk
evident from the MO picture. In energy level diagram ldrk gS ysfdu MO fp= ls izekf.kr gSA O22+ ds ÅtkZ
of O22+ ,13th eΘ present in Lrj vkjs[k es]a 13th eΘ fuEu esa ls fdlesa mifLFkr gksrk
gS\
(A)  2pz orbital
(A)  2pz d{kd
(B) 2py or 2px orbital (B) 2py vFkok 2px d{kd
(C) *2py or *2px orbital (C) *2py vFkok *2px d{kd
(D) *2pz orbital (D) *2pz d{kd

5. In the process of N+2 → N2 the electron is removed 5. N+2 → N2 izØe es]a bysDVªkWu ‘______’ ls gVk;k tkrk
from ‘______’ provided the x-axis is the bond gS] ;fn x-v{k vkca/k fuEkkZ.k v{k gksA
formation axis.
(A) *2p y d{kd (B) *2px d{kd
(A) *2p y orbital (B) *2px orbital
(C) 2px orbital (D)  2s orbital (C) 2px d{kd (D)  2s d{kd

6. Which of the following set of orbital results in 6. fuEu esa ls d{kdksa dk dkSulk ;qXe N.B.M.O dk fuekZ.k
N.B.M.O [If z-axis is the bond formation axis] djrk gS?
(A) pz + dxz (B) s + dyz [;fn z-v{k] vkca/k fuekZ.k v{k gS]
(C) s + dxz (D) All of these (A) pz + dxz (B) s + dyz
(C) s + dxz (D) ;s lHkh
7. How many of the following species is/are 7. fuEu esa ls fdruh Lih'kht izfrpqEcdh; gS?
diamagnetic? (I) O +2
(I) O +2
(II) O2
(II) O2
(III) O −2 (III) O −2

(IV) O22− (IV) O22−

(V) O3− (V) O3−
 16

8. Choose the correct statement: 8. lgh dFku dk p;u dhft,&

(A) Bond order of CO+ is 3.0
(B) Bond length of CO+ < bond length of CO
+
(C) Bond order of NO > bond order of CO
(D) Bond order of N −2 > bond order of N +2
(A) CO+ dh vkca/k dksfV 3.0 gksrh gSA
(B) CO+ dh vkca/k yEckbZ < CO dh vkca/k yEckbZ
(C) NO+ dh vkca/k dksfV > CO dh vkca/k dksfV
(D) N −2 dh vkca/k dksfV > N +2 dh vkca/k dksfV

9. Statement-I: The observed bond length of N2+ is 9. dFku-I: N2+ dh izsf{kr vkca/k yEckbZ] N2 dh rqyuk esa
larger than N2 while the bond length in NO is less
vf/kd gksrh gS tcfd NO dh vkca/k yEckbZ] NO+ dh
+
than in NO .
Statement-II: Bond order of NO & N2 are 2 and 3
rqyuk esa de gksrh gSA
respectively. dFku-II: NO rFkk N2 dh vkca/k dksfV Øe'k% 2 vkSj 3 gSA
(A) Both statement I &II are correct (A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) Both statement I & II are incorrect
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) Statement I is correct while statement II is
incorrect (C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) Statement I is incorrect while statement II is (D) dFku-I xyr gS ysfdu dFku-II lgh gSA
correct

10. What is the bond order of CN–? 10. CN– dh vkca/k dksfV D;k gS?
(A) 1.0 (A) 1.0
(B) 0.5 (B) 0.5
(C) 3.0 (C) 3.0
(D) 2.0 (D) 2.0

11. The bond length in O+2 , O2 , O2− and O22− follows the 11. O+2 , O2 , O2− rFkk O22− dh vkca/k yEckbZ dk Øe gS%
order
(A) O22−  O−2  O2  O2+
(A) O22−  O−2  O2  O2+
(B) O+2  O2  O−2  O22−
(B) O+2  O2  O−2  O22−
(C) O2  O2−  O22−  O2+
(C) O2  O2−  O22−  O2+
(D) O−2  O22−  O2+  O2
(D) O−2  O22−  O2+  O2
 17

DPP-8
[lgla;kstd vkca/kksa dh /kzqo.krk] f}/kzqo vk?kw.kZ] vkca/k ,UFkSYih
vFkok vkca/k fo;kstu ,UFkSYih]
1. Which of the following has the least dipole moment? 1. fuEu esa ls fdldk f}/kzqo vk?kw.kZ U;wure gksrk gS\
(A) NF3 (B) CO2
(A) NF3 (B) CO2
(C) SO2 (D) NH3
(C) SO2 (D) NH3

2. The dipole moment of is 1.5 D. The dipole 2. dk f}/kzqo vk?kw.kZ, 1.5 D gSA

moment of is : dk f}/kzqo vk?kw.kZ gksxk&

(A) 0 D (B) 1.5 D (A) 0 D (B) 1.5 D

(C) 2.86 D (D) 2.25 D
(C) 2.86 D (D) 2.25 D

3. Which has maximum dipole moment? 3. fuEu esa ls fdldk f}/kzqo vk?kw.kZ vf/kdre gksrk gS\

(A) (B) (A) (B)

(C) (D) (C) (D)

4. Which of the following molecule / ion has zero dipole 4. fuEu esa ls fdl v.kq@vk;u dk f}/kzqo vk?kw.kZ 'kwU; gksrk
moment. gS\
- -
(A) ClF3 (B) ICl2 (A) ClF3 (B) ICl2
(C) SF4 (D) None of these (C) SF4 (D) buesa ls dksbZ ugha

5. Which of the following is the correct order of dipole 5. fuEu esa ls dkSulk f}/kzqo vk?kw.kZ dk lgh Øe gS\
moment? (A) NH3 < BF3 < NF3 < H2O
(A) NH3 < BF3 < NF3 < H2O (B) BF3 < NF3 < NH3 < H2O
(B) BF3 < NF3 < NH3 < H2O
(C) BF3 < NH3 < NF3 < H2O
(C) BF3 < NH3 < NF3 < H2O
(D) H2O < NF3 < NH3 < BF3
(D) H2O < NF3 < NH3 < BF3

6. The correct order of decreasing polarity is 6. /kzqo.krk dk ?kVrk gqvk lgh Øe gS&
(A) HF > SO2 > H2O > NH3 (A) HF > SO2 > H2O > NH3
(B) HF > H2O > SO2 > NH3 (B) HF > H2O > SO2 > NH3
(C) HF > NH3 > SO2 > H2O (C) HF > NH3 > SO2 > H2O
(D) H2O > NH3 > SO2 > HF (D) H2O > NH3 > SO2 > HF
 18

7. In a polar molecule, the ionic charge is 4.8 × 10–10 7. ,d /kzqoh; v.kq esa vk;fud vkos'k 4.8 × 10–10 e.s.u gSA ;fn
e.s.u. If the inter ionic distance is 1 Å unit, then the vUrj vk;fud nwjh 1 Å bdkbZ gS] rks f}/kzqo vk?kw.kZ gS%
dipole moment is
(A) 41.8 debye (B) 4.18 debye
(A) 41.8 debye (B) 4.18 debye
(C) 4.8 debye (D) 0.48 debye (C) 4.8 debye (D) 0.48 debye

8. The dipole moment of HCl is 1.03D, if H–Cl bond 8. HCl dk f}/kzqo vk?kw.kZ 1.03D gSA ;fn H–Cl dh vkca/k
distance is 1.26 Å, what is the percentage of ionic nwjh 1.26 Å gS, H—Cl vkca/k esa vk;fud vfHky{k.k dk
character in the H—Cl bond? izfr'kr D;k gS ?

9. Statement-I: Order of dipole moment is: 9. dFku-I: f}/kzqo vk?kw.kZ dk Øe

CH3F > CH3Cl > CH3Br > CH3I.
Statement-II: CH3Cl is more polar than CH3F.
(A) Both statement I &II are correct
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
incorrect
(D) Statement I is incorrect while statement II is
correct.
CH3F > CH3Cl > CH3Br > CH3I gSA
dFku-II: CH3Cl, CH3F dh rqyuk esa vf/kd /kzqoh; gSA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA

10. Statement-I: Bond energy order: F-F > Cl-Cl.
Statement-II: Fluorine forms stronger and shorter
bond than Chlorine.
(A) Both statement I &II are correct
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
incorrect
(D) Statement I is incorrect while statement II is
correct.
10. dFku-I: vkca/k ÅtkZ dk Øe F-F > Cl-Cl gSA
dFku-II: ¶yksjhu] Dyksjhu dh rqyuk esa izcy rFkk NksVk
vkca/k fufeZr djrk gSA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA

11. Which of the following molecule is planar as well as 11. fuEu esa ls dkSulk v.kq leryh; rFkk /kzqoh; nksuksa gSa\
polar. Br Br
Br Br (A) C=C=C
(A) C=C=C Br Br
Br Br
Cl Cl
Cl Cl (B) C=C=C=C
(B) C=C=C=C H H
H H
Cl Cl Cl Cl
(C) C=C=C=C (C) C=C=C=C
Cl Cl Cl Cl
(D) None of these (D) buesa ls dksbZ ughaA
 19

DPP-9
` [vk;fud vkca/k ds fuekZ.k dh fLFkfr;k¡] tkyd ÅtkZ] /kzqo.krk
rFkk Qkt+kUl fu;e] ty;kstu ÅtkZ]
1. Which of the following is not a correct statement 1.
about an ionic compound?
(A) The higher the temperature, the more is the
solubility.
(B) The higher the dielectric constant of the
solvent, the more is the solubility.
(C) The higher the dipole moment of the solvent,
the more is the solubility.
(D) The higher the lattice energy, the more is the
solubility.
fuEu esa ls dkSulk dFku vk;fud ;kSfxd ds ckjs esa lgh
ugha gS\
(A) rkieku ftruk mPp gksxk] foys;rk mruh vf/kd
gksxhA
(B) foyk;d dk ijkoS|qr fLFkjkad ftruk mPp
gksxk] foys;rk mruh vf/kd gksxhA
(C) foyk;d dk f}/kzqo vk?kw.kZ ftruk mPp gksxk]
foys;rk mruh vf/kd gksxhA
(D) tkyd ÅtkZ ftruh mPp gksxh] foys;rk mruh
vf/kd gksxhA

2. In which of the following species the bond is non- 2. fuEu esa ls fdl Lih'kht esa vkca/k vfn'kkRed gS\
directional? (A) NCl3 (B) RbCl
(A) NCl3 (B) RbCl
(C) BeCl2 (D) BCl3
(C) BeCl2 (D) BCl3

3. CaO and NaCl have the same crystal structure and 3. CaO vkSj NaCl esa leku fØLVy lajpuk rFkk yxHkx
approximately the same ionic radii. If U is the lattice leku vk;fud f=T;k gksrh gSA ;fn NaCl dh tkyd
energy of NaCl, the approximate lattice energy of ÅtkZ U gS] rks CaO dh yxHkx tkyd ÅtkZ gS%
CaO is
(A) U/2 (B) U
(A) U/2 (B) U
(C) 2U (D) 4U
(C) 2U (D) 4U

4. The correct order of polarizability of X– is: 4. X– dh /kzqo.krk dk lgh Øe gS%

(A) F– > Cl– > Br– > I– (A) F– > Cl– > Br– > I–
(B) Cl– > F– > Br– > I– (B) Cl– > F– > Br– > I–
(C) Br– > Cl– > F– > I– (C) Br– > Cl– > F– > I–
(D) I– > Br– > Cl– > F– (D) I– > Br– > Cl– > F–

5. Which of the following order is correct for covalent 5. fuEu esa ls dkSulk Øe lgla;kstd vfHky{k.k ds fy,
character (if the cation sizes are identical in pairs)- lgh gS\ ¼;fn /kuk;u ds vkdkj] ;qXeksa esa leku gSa½
(A) NaCl < CuCl (B) CaCl2 < PdCl2 (A) NaCl < CuCl (B) CaCl2 < PdCl2
(C) RbCl < AuCl (D) All of these (C) RbCl < AuCl (D) mijksä lHkh

6. The solubility of CaSO4, BeSO4, MgSO4 and BaSO4 6. CaSO4, BeSO4, MgSO4 rFkk BaSO4 dh foys;rk dk
will follow the order Øe gS%
(A) BeSO4 > MgSO4 > CaSO4 > BaSO4 (A) BeSO4 > MgSO4 > CaSO4 > BaSO4
(B) BeSO4 > CaSO4 > MgSO4 > BaSO4 (B) BeSO4 > CaSO4 > MgSO4 > BaSO4
(C) MgSO4 > BeSO4 > CaSO4 > BaSO4 (C) MgSO4 > BeSO4 > CaSO4 > BaSO4
(D) CaSO4 > BeSO4 > MgSO4 > BaSO4 (D) CaSO4 > BeSO4 > MgSO4 > BaSO4

7. Select the correct order of stability- 7. foys;rk ds lgh Øe dk p;u dhft,&

(A) BeCO3 < CaCO3 < SrCO3 (A) BeCO3 < CaCO3 < SrCO3
(B) LiNO3 > NaNO3 > KNO3 (B) LiNO3 > NaNO3 > KNO3
(C) LiF < NaF < KF (C) LiF < NaF < KF
(D) ;s lHkh
(D) All of these
 20

8. The decreasing order of ionic nature of the following 8. fuEu ;kSfxdksa dh vk;fud izd`fr dk ?kVrk gqvk lgh
compound is: Øe gS%
(A) LiI > NaBr > KCl > CsF (A) LiI > NaBr > KCl > CsF
(B) LiI > KCl > NaBr > CsF (B) LiI > KCl > NaBr > CsF
(C) CsF > NaBr > KCl > LiI (C) CsF > NaBr > KCl > LiI
(D) CsF > KCl > NaBr > LiI (D) CsF > KCl > NaBr > LiI

9. Which of the following order is correct? 9. fuEu esa ls dkSulk Øe lgh gS\
+ + + + + +
(A) Li(aq)  Na (aq)  K(aq) ; Ionic mobility (A) Li(aq)  Na (aq)  K(aq) ; vk;fud xfr'khyrk

+ + + + + +
(B) Li(aq)  Na (aq)  K(aq) ; Hydrated size (B) Li(aq)  Na (aq)  K(aq) ; ty;ksftr vkdkj

– – – – – –
(C) F(aq)  Cl(aq)  Br(aq) ; Hydrated size (C) F(aq)  Cl(aq)  Br(aq) ; ty;ksftr vkdkj

– – – – – –
(D) F(aq)  Cl(aq)  Br(aq) ; Ionic mobility (D) F(aq)  Cl(aq)  Br(aq) ; vk;fud xfr'khyrk

10. Statement-I: HgCl2 is more covalent than ZnCl2. 10. dFku-I: HgCl2, ZnCl2 dh rqyyk esa vf/kd lgla;kstd
Statement-II: Ionisation of ZnCl2 is greater than that gksrk gSA
of HgCl2 in aq. Solution. dFku-II: tyh; foy;u esa ZnCl2 dk vk;uu HgCl2 dh
(A) Statement-I is true, Statement-II is true and rqyuk esa vf/kd gksrk gSA
Statement-II is correct explanation for (A) dFku I lR; gS] dFku II lR; gS rFkk dFku II, dFku
statement-1.
I dh lgh O;k[;k gSA
(B) Statement-I is true, statement-II is true and
(B) dFku I lR; gS] dFku II lR; gS rFkk dFku II, dFku
statement-II is NOT correct explanation for
I dh lgh O;k[;k ugha gSA
statement-I.
(C) dFku I lR; gS] dFku II vlR; gSA
(C) Statement-I is true, statement-II is false.
(D) dFku I vlR; gS] dFku II lR; gSA
(D) Statement-I is false, statement-II is true.

11. How many are incorrect order as specified? 11. fuEu esa ls fdrus Øe xyr gSa\
(1) LiH > NaH > KH > RbH > CsH (thermal (1) LiH > NaH > KH > RbH > CsH (rkih; LFkkf;Ro)
stability) (2) ZnCl2 > CaCl2 > KCl > RbCl (lgla;kstd
(2) ZnCl2 > CaCl2 > KCl > RbCl (covalent
vfHky{k.k)
character)
(3) ScN > TiC (rkih; LFkkf;Ro)
(3) ScN > TiC (thermal stability)
(4) BeSO4 > MgSO4 > CaSO4 (foys;rk)
(4) BeSO4 > MgSO4 > CaSO4 (solubility)
(5) CsO2 > RbO2 > KO2 (rkih; LFkkf;Ro)
(5) CsO2 > RbO2 > KO2 (thermal stability)
(6) F2 < Cl2 < Br2 < I2 (DoFkukad)
(6) F2 < Cl2 < Br2 < I2 (boiling point)
(7) LiF > LiCl > LiBr > LiI (xyukad)
(7) LiF > LiCl > LiBr > LiI (melting point)
(8) Ag2CO3 > Na2CO3 > Li2CO3 (rkih; LFkkf;Ro)
(8) Ag2CO3 > Na2CO3 > Li2CO3 (thermal stability)
 21

DPP-10
[gkbMªkt
s u vkca/k]
1. Weakest hydrogen bond is: 1. nqcZyre gkbMªkstu vkca/k gS:
(A) O – H ......N (A) O – H ......N
(B) O – H .....Cl (B) O – H .....Cl
(C) F – H ......F (C) F – H ......F
(D) N – H .....N (D) N – H .....N

2. Two ice cubes are pressed over each other and unite 2. cQZ ds nks VqdM+ksa dks ,d-nwljs ds Åij jxM+ dj ,d
to form one cube, which force is responsible for cQZ dk VqdM+k cuk;k tk, rks fuEu esa ls dkSulk cy
holding them together? mUgsa ijLij caf/kr j[kus ds fy, mÙkjnk;h gSa?
(A) Vander Waal's forces (A) okaMj oky cy
(B) Covalent attraction (B) lgla;kstd vkd"kZ.k
(C) Hydrogen bond formation (C) gkbMªkstu vkca/k fuekZ.k
(D) Ion-Dipole attraction (D) vk;u-f}/kzqo vkd"kZ.k

3. Which of the following molecule has intramolecular 3. fuEu esa ls fdl v.kq esa vUrjkv.kqd gkbMªkstu vkca/ku gS?
H-bonding? (A) vkWFkksZ-ukbVªksQhukWy
(A) Ortho-nitrophenol (B) vkWFkksZ-cksfjd vEy
(B) Ortho-boric acid (C) (A) rFkk (B) nksuksa
(C) Both (A) and (B)
(D) buesa ls dksbZ ugha
(D) None of these

4. Which of the following does not have hydrogen bond? 4. fuEu esa ls fdl esa gkbMªkstu vkca/k ugha gksrk gS?
(A) o–nitrophenol (A) o–ukbVªksQhukWy
(B) Liquid HF (B) nzo HF
(C) Ice (C) cQZ
(D) CH3Cl (D) CH3Cl

5. The correct order of boiling point is : 5. DoFkukad dk lgh Øe gS:

(A) HF > HCl > HBr > HI (A) HF > HCl > HBr > HI
(B) HF > HI > HCl > HBr (B) HF > HI > HCl > HBr
(C) HF > HBr > HI > HCl (C) HF > HBr > HI > HCl
(D) HF > HI > HBr > HCl (D) HF > HI > HBr > HCl

6. The hydrogen bond is strongest in 6. fuEu esa ls fdl esa gkbMªkstu vkca/k izcyre gS\
(A) Water (A) ty
(B) Ammonia (B) veksfu;k
(C) Hydrogen fluoride (C) gkbMªkstu ¶yksjkbM
(D) Acetic acid (D) ,slhfVd vEy
 22

7. In the absence of hydrogen bonding, boiling point of 7. gkbMªkstu vkca/ku dh vuqifLFkfr esa] ty dk DoFkukad
water would have been ____. gksxk-
(A)  373 K (A)  373 K
(B)  473 K (B)  473 K
(C)  0°C (C)  0°C
(D)  –80°C (D)  –80°C

8. Statement-I: A mixture of o-nitrophenol and p- 8. dFku-I: o-ukbVªksQhukWy rFkk p-ukbVªkQ

s hukWy ds ,d
nitrophenol can be separated by steam distillation. feJ.k dks Hkki vklou }kjk i`Fkd fd;k tk ldrk gSA
Statement-II: p-nitrophenol is steam volatile
dFku-II: p-ukbVªkQ
s hukWy ok"Ik'khy gS tcfd o-
whereas o-nitrophenol is not steam volatile.
ukbVªkQ
s hukWy ok"Ik'khy ugha gSA
(A) Statement-I is true, Statement-II is true and
Statement-II is correct explanation for (A) dFku-I lR; gS] dFku-II lR; gS rFkk dFku-II, dFku-I

statement- I. dh lgh O;k[;k gSA

(B) Statement-I is true, statement-II is true and (B) dFku-I lR; gS] dFku-II lR; gS rFkk dFku-II, dFku-I
statement-II is NOT correct explanation for
dh lgh O;k[;k ugha gSA
statement-I.
(C) dFku-I lR; gS] dFku-II vlR; gSA
(C) Statement-I is true, statement-II is false.
(D) Statement-I is false, statement-II is true. (D) dFku-I vlR; gS] dFku-II lR; gSA

9. Intramolecular H–bond :- 9. vUrjkv.kqd H–vkca/k :-

(A) Decreases Volatility (A) ok"i'khyrk dks de djrk gSA
(B) Increases melting point (B) xyukad esa o`f) djrk gSA
(C) Increases viscosity (C) ';kurk esa o`f) djrk gSA
(D) Increases vapour pressure (D) ok"inkc esa o`f) djrk gSA

10. Incorrect statement regarding BF2 NH2 molecule is:
(A) FBF bond angle < 120°
(B) HNH bond angle > 109°28
(C) Exhibits intermolecular H-bond
(D) Hybridization of N-atom is sp3
10. BF2 NH2 v.kq ds lEcU/k esa xyr dFku gS%
(A) FBF vkca/k dks.k < 120°
(B) HNH vkca/k dks.k > 109°28
(C) vUrjv.kqd H-vkca/k n'kkZrk gSA
(D) N-ijek.kq dk ladj.k sp3 gSA
 23

DPP-11
[gkbMªkt
s u vkca/k]
1. H2O boils at higher temperature than H2S, because it 1. H2O, H2S dh rqyuk esa mPp rki ij mcyrk gS D;ksfa d
is capable of forming: ;g cukus esa l{ke gS:
(A) Ionic bonds (A) vk;fud vkca/k
(B) Covalent bonds (B) lgla;kstd vkca/k
(C) Hydrogen bonds (C) gkbMªkstu vkca/k
(D) Metallic bonds (D) /kkfRod vkca/k

2. Which of the following has strongest intra molecular 2. fuEu esa ls fdlesa izcyre vUrjkv.kqd gkbMªkstu
hydrogen bonding: vkca/ku gS?

(A) (A)

(B) (B)

(C) (C)

(D) (D)

3. Acetic acid exists as dimer in benzene due to: 3. fdl ds dkj.k ,slhfVd vEy] csUthu esa f}yd ds #i
(A) Condensation reaction esa mifLFkr gksrk gS?
(A) la?kuu vfHkfØ;k
(B) Hydrogen bonding
(B) gkbMªkstu vkca/ku
(C) Presence of carboxyl group
(C) dkcksZfDly lewg dh mifLFkfr
(D) None of the above
(D) mijksDr esa ls dksbZ ugha

4. In which case hydrogen bond will not be observed ? 4. fuEu esa fdl fLFkfr esa gkbMªkstu vkca/k izsf{kr ugha
gksxk\
(A) H3O2–
(A) H3O2–
(B) H2O (B) H2O
(C) HF (C) HF
(D) H3O+
(D) H3O+
 24

5. Density of ice is less than that of water because of?
(A) presence of hydrogen bonding
(B) crystal modification of ice
(C) open porous structure of ice due to hydrogen
bonding
(D) different physical states of these
5. fdl ds dkj.k cQZ dk ?kuRo] ty ds ?kuRo dh rqyuk
esa de gksrk gS?
(A) gkbMªkstu vkca/ku dh mifLFkfr
(B) cQZ dk fØLVy #ikUrj.k
(C) gkbMªkstu vkca/ku ds dkj.k cQZ dh [kqyh fNfnzr
lajpuk
(D) budh fofHkUu HkkSfrd voLFkkvksa

6. The correct order of volatility is : 6. ok"i'khyrk dk lgh Øe gS–

(A) NH3 < H2O (A) NH3 < H2O
(B) p-nitro phenol < o-nitro phenol (B) p-ukbVªks QhukWy < o-ukbVªks QhukWy
(C) CH3OH > CH3 – O – CH3 (C) CH3OH > CH3 – O – CH3
(D) HF > HCl (D) HF > HCl

7. Maximum no. of hydrogen bonds formed by a water 7. cQZ esa ty v.kq }kjk fufeZr gkbMªkstu vkca/kksa dh
molecule in ice is ___ vf/kdre la[;k ___ gSA

8. The pair of molecules forming strongest hydrogen 8. izcyre gkbMªkt

s u vkca/k cukus okys v.kqvksa dk ;qXe gS%
bonds are :
(A) SiH4 rFkk SiF6
(A) SiH4 and SiF6
(B) CH3 − C − CH3 rFkk CHCl3
(B) CH3 − C − CH3 and CHCl3 ||
|| O
O
(C) H − C − OH rFkk CH3 − C − OH
(C) H − C − OH and CH3 − C − OH || ||
|| || O O
O O
(D) H2O and H2 (D) H2O rFkk H2

9. Statement-I: The boiling point of methanol is 9.
greater than methyl thiol.
Statement-II: There is intramolecular hydrogen
bonding in methanol and intermolecular hydrogen
bonding in methyl thiol.
(A) Both statement I & II are correct.
(B) Both statement I & II are incorrect
(C) Statement I is correct while statement II is
incorrect.
(D) Statement I is incorrect while statement II is
correct.
dFku-I: esFksukWy dk DoFkukad] esfFky Fkk;kWy dh rqyuk
esa vf/kd gksrk gSA
dFku-II: esFksukWy esa vUrjkv.kqd gkbMªkstu vkca/ku rFkk
esfFky Fkk;kWy esa vUrjv.kqd gkbMªkstu vkca/ku mifLFkr
gSA
(A) dFku-I rFkk dFku-II nksuksa lgh gSA
(B) dFku -I rFkk dFku -II nksu ksa xyr gS aA
(C) dFku-I lgh gS ysfdu dFku-II xyr gSA
(D) dFku-I xyr gS ysfdu dFku-II lgh gSA

10. The hydrogen bond is strongest in 10. fuEu esa ls fdl esa gkbMªkstu vkca/k izcyre gS\
(A) Water (A) ty
(B) Ammonia (B) veksfu;k
(C) Hydrogen fluoride (C) gkbMªkstu ¶yksjkbM
(D) Acetic acid (D) ,slhfVd vEy