SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)

Exam Dt. 30-03-2024

Chemistry

PART - A
SINGLE ANSWER CORRECT:
1.  H 2 + I 2 . The reaction mixture on titration
0.96 g of HI were heated to attain equilibrium 2HI 
requires 15.7 ml of N/10 Hypo solution. Calculate degree of dissociation of HI
a) 0.418 b) 0.209 c) 0.267 d) 0.836
1.b

Sol: 2HI 

 H 2 + I2 .
0.96
Mole at t =0 0 0
128
7.5  103
x x
Moles at equilibrium 7.5  10 3  x
2 2
meq of I2 formed at equilibrium = meq of Hypo used for reaction mixture.
 WI2  1
   1000 = 15.7 
 E  10
W 3
  of Z2 = 15.7  10
E
1.57  10 3
Mole of I2 formed = = 0.785  10 3
2
x
= 0.785  103
2
x = 1.57  103
1.57  103
Degree of dissociation of HS = = 0.209
7.5  10 3

2. In an inert gas, the number of d, s and p electrons are x, y and z respectively. If x  z  y , then
select the correct statement about inert gas.
a) Period number of inert gas is 5 b) Period number of inert gas is 4
c) x  20 d) y  10
2.b

Sol: Inert gas is 38 Kr

y  8, z  18, x  10

3. In the following molecular/ions

O +2 , O 22 , C 22 , N 22 , N 24
Which one is paramagnetic and has highest bond length?
a) O +2 b) C2 2 c) N 22 d) N 2 4
3.c
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)
Exam Dt. 30-03-2024

Sol. Molecule / ion Number of unpaired electron Bond order Magnetic character
O 2 2 1 1.5 Dia
O +2 1 2.5 Para
2
N 2 2 2 Para
C2 2 0 3 Dia
4
N 2 0 1 Dia
1
Bond length 
Bond order
4. The equation of state for 1 mole of Ne and 1 mole of Xe is given as P(V-b) = RT, at temperature T.
(b = vandar Waals constant) Compressibility factor Z vs P curve is given as
Z
II
I

P
a) Curve I – Ne b) Curve II – Xe
c) Curve I – Xe d)Cannot be predicted
4.b
Sol. P  V  b  = RT
PV  b = RT
Divide by RT
PV bP
 =1
RT RT
 b 
Z  1  P
 RT 
Slope  b  size of atom.

5. Difference between the radii of 2nd and 3rd orbits of He + is R1. The difference between the radii of
3rd and 4th orbits of Li +2 is R 2 . Find R1 / R 2
21 10 14 15
a) b) c) d)
10 21 15 14
5.d

n2
Sol. rn = r0
Z
r0 2
R = rn 2  rn1 =
Z
 n 2  n12 
r0
He+ , R1 =   32  2 2  ……..(i)
2
r
Li +2 , R 2 = 0   42  32  …..…(ii)
3
R 1 3 5 15
=  =
R 2 2 7 14
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)
Exam Dt. 30-03-2024

6. Acidic strength order of compounds is given below. Identify incorrect option.

COOH COOH COOH
COOH
NO 2
a)  b) >

F Cl NO 2
OH OH
OH OH
NO 2
c) > d) 

OH
NO 2 OH
6.d

OH
OH

>  Correct acidic strength 

Sol. OH
OH
I effect increases acidic nature
 M effect decreases acidic nature
 pK a  9.44
 pK a  9.96 
7. Which of the following is correct order of reactivity towards EAS?
NO 2
Cl

a) > >

COCH 3 CH3 OH

b) < <

c) < <
N
N
H
CH3 CH3 CH3

d) > >

OH CHO CH3
7.b
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)
Exam Dt. 30-03-2024
Cl
NO 2
Sol. a) > >

c) > >
N
N
H
CH3 CH3 CH3

d) > >

OH CH3 CHO

8. Major product formed when

is treated with dilute sulphuric acid is.

OH

a) b) c) d)
OH
HO OH
8.c


H
 
 

Sol:

H 2O

OH

9. Choose the incorrect statementabout the following alkenes is

K  L
a) Alkene [K] is more stable than alkene [L].
b) Hydrogenation of achiral alkene [K] will give chiral product.
c) Hydrogenation of achiral alkene [L] will give achiral product.
d) The two alkenes [K] and [L] are structural isomers.
9.b
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)
Exam Dt. 30-03-2024

Sol. Alkene [K] has 8  Hydrogens.

Alkene [L] has 2  Hydrogens.
H 2 / Ni
 

achiral
H 2 / Ni
 

achiral
This is achiral alkene

10. Which of the following is NOT the chain isomer of

H3C CH3

H2C CH3
H3C CH2 H2C CH3
a) b)
H2C CH3 H3C CH3
H3C CH3 H2C CH2
c) d)
H3C CH3 H3C CH3
10.d

Sol. Option d has longest chain of 5C-atom which is same as in the compound given
H3C CH3 5 4 1
3 H2C CH2
2 2
H2C CH3
1 4 5 H C 3 CH
3 3

PART-C
INTEGER ANSWER TYPE:

1. Two transparent glass flasks ‘A’ and ‘B’ of volume 13.2 litre and 26.4 litre respectively are
connected by a tube of negligible volume andfitted with a stopcock. Flask ‘A’ contains 32gm
CH 4  g  while flask ‘B’ is filled with 71 gm of Cl 2  g  both at 336 K. The assembly is irradiated by
sunlight, when stopcock is opened. Assuming that CCl4  liq  and HCl(g) are the products and yield
of the process is 50%. Find the final pressure in the container (in atm). [R = 0.0821 atm – lit
mol1K 1; consider negligible volume of CCl4  l  ]
1.2

Sol. CH 4  g  + 4Cl2  g  
 CCl4  l  + 4HCl  g  ;
Moles 2 1
Reacted at 50% yield 0.125 0.5
Left 1.875 (mole) 0.5 (mole) 0.5 mole
PV = nRT
P  39.6 = 2.875  0.0821  336
P = 2 atm
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)
Exam Dt. 30-03-2024

HBr
"A"

KMnO 4 Conc.
2. Isobutane   
H 2 SO 4

Peroxide
"B"
HBr
If ‘X’ is the locant of Br(as per IUPAC) in “A” and ‘Y’ is the locant of methyl group (as per IUPAC)
in “B” what is the value of X + Y?
2.4

OH Br
KMnO 4 Con. HBr
 
H 2SO 4
   

Sol. HBr  Br Position 2 

ROOR
A

Br

 B
X = 2, Y = 2.
3. Among BF3 , N  SiH 3 3 , N  CH 3 3 , O SiH 3 2 , CF3 , CCl3 . The number of molecules or molecular
ions which have back bonding is
3.4
Sol: BF3 , N  SiH 3 3 , O SiH 3  2 , CCl3 have back bonding.

4. Among the molecules CH 4 , PCl5  g  , PBr5  g  , PCl3F2 , ClF3 , CO 2 , SF4 , SF2Cl2 , CCl4 , SCl 4 and
H 2O. The number of molecules having different bond lengths are
4.6

Sol. In trigonalbipyramid geometry axial bonds are longer than equatorial bonds. Thus,
PCl5 , PBr5 , PCl3F2 , SF4 , SF2Cl2 , SCl4 have different bond lengths.

5. 10 mL of H2 A (weak diprotic acid) solution is titrated against 0.1 M NaOH. pH of the solution is
plotted against volume of strong base added and following observation is made.

If pH of the solution at first equivalence point is pH1 and at second equivalence point is pH 2 .
Calculate the value of  pH 2  pH1  at 250 C. (Given for H2 A pka1 = 4.6, pka 2 = 8 and log 25 = 1.4)
5.4
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)
Exam Dt. 30-03-2024

Sol. H 2 A + NaOH 
 NaHA + H 2 O 

0.1 M  20 ml

NaHA + NaOH   Na 2 A + H 2 O
At first equivalence point NaHA salt a formed
pka1  pka 2
pH1 =
2
 pH1 = 6.3
At second eq. point Na 2A salt is present
1 1
pH 2 = 7 + pka 2 + logc
2 2
1 1
= 7 + 4 + log
2 25
= 10.3
 pH 2  pH1 = 4
2m mol
c=
50 ml
6. A certain mass of anhydrous oxalic acid is converted into H2 O, CO2 and CO, on heating in the
presence of H 2SO4 . The CO formed reacts completely with iodinepentoxide to liberate iodine. The
iodine thus liberated required 200 ml of 0.2 N thiosulphate. The mass (in g) of oxalic acid taken was
6.9


Sol. H 2 C 2 O 4 
H 2SO 4
 CO + CO 2 + H 2O
100m mol 100m mol

5CO + I 2 O5 
 I2 + 5CO 2
100m mol 20m mol

I2 + Na 2S2 O3  Na 2S4O6 + NaI

40 meq, 200 ml  0.2 N
nf = 2 40meq
20 m mol
Mass of oxalic acid = 100  103 mol  90g / mol
= 9 g.

7. In the compound hydrated borax

i) Number of B  O  B bonds is ‘x’
ii) Number of B  B bonds is ‘y’
iii) Number of sp 2 hybridized B atom is ‘z’
Calculate the value of x + y + z
7.7

HO
-
B
O O
Sol. 2Na 
HO B O B OH
O - O
B
OH
x = 5, y = 0, z = 2
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-2)
Exam Dt. 30-03-2024

8. Number of Cl atoms which is / are directly bonded to each beryllium in BeCl2  s  is:
8.4

Cl Cl Cl
Sol. Be Be Be Be
Cl Cl Cl
Polymeric structure