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carbohydrate
carbohydrate
How is the number of possible isomers of a B) Equal to 2n, where n is the number of asymmetric carbon atoms
compound determined? Explanation: The number of possible isomers of a compound is determined by the formula 2n,
A) Equal to the number of carbon atoms where n represents the number of asymmetric carbon atoms, showcasing the relationship
B) Equal to 2n, where n is the number of asymmetric between asymmetric carbon and isomerism.
carbon atoms
C) Equal to the molecular weight
D) Equal to the number of hydrogen atoms
E) Equal to the number of oxygen atoms
Why has glyceraldehyde been chosen as the C) Due to its simplicity and one asymmetric carbon atom
reference carbohydrate to represent the structure of Explanation: Glyceraldehyde has been chosen as the reference carbohydrate to represent the
all other carbohydrates? structure of all other carbohydrates due to its simplicity and possession of one asymmetric
A) Due to its sweetness carbon atom, making it an ideal model for understanding carbohydrate structure.
B) Due to its abundance in nature
C) Due to its simplicity and one asymmetric carbon
atom
D) Due to its complex structure
E) Due to its role in energy storage
What is the role of the substance in the structure of E) It is widespread as a constituent of RNA and nucleotides
RNA and nucleotides? Explanation: The substance is widely present as a constituent of RNA and nucleotides,
A) It is an intermediate in uronic acid pathway playing a crucial role in their structure and function.
B) It is an important metabolite in hexose
monophosphate shunt
C) It is an important metabolite in glycolysis
D) It is an intermediate in the structure of
polysaccharides
E) It is widespread as a constituent of RNA and
nucleotides
Where is the substance found as a constituent? C) In both plant polysaccharides and animal glycoproteins
A) Only in animal glycoproteins Explanation: The substance is found as a constituent in both plant polysaccharides and
B) Only in plant polysaccharides animal glycoproteins, highlighting its widespread presence and importance in biological
C) In both plant polysaccharides and animal structures.
glycoproteins
D) Only in fruits
E) Only in heart muscle
What is the substance's role in the function of C) It is involved in the function of glycoproteins
glycoproteins? Explanation: The substance plays a role in the function of glycoproteins, indicating its
A) It is an intermediate in uronic acid pathway significance in the biological activity and structure of these molecules.
B) It is an important metabolite in hexose
monophosphate shunt
C) It is involved in the function of glycoproteins
D) It is an intermediate in the structure of
polysaccharides
E) It is an important metabolite in glycolysis
What determines whether a sugar is a D- or C) The spatial orientation of -H and -OH groups on the carbon atom
L-isomer? Explanation: The spatial orientation of -H and -OH groups on the carbon atom adjacent to the
A) The number of carbon atoms terminal primary alcohol carbon determines whether the sugar is a D- or L-isomer, providing a
B) The presence of a primary alcohol group key characteristic for distinguishing between the two isomers.
C) The spatial orientation of -H and -OH groups on
the carbon atom
D) The presence of a ketone group
E) The type of glycosidic bond
C) Optical activity
D) Low melting point
E) High stability
What are epimers in the context of B) Isomers with different configurations around a specific carbon atom
monosaccharides? Explanation: Epimers are monosaccharides that differ in their configuration around a specific
A) Isomers with the same configuration around a carbon atom, other than the anomeric carbon. This distinction is important in understanding
specific carbon atom the structural and functional differences between monosaccharides.
B) Isomers with different configurations around a
specific carbon atom
C) Isomers with the same arrangement of -OH
groups
D) Isomers with different arrangements of -OH
groups
E) Isomers with the same arrangement of -COOH
groups
What is the significance of the interconversion of E) It contributes to the structural and functional diversity of monosaccharides
epimers? Explanation: The interconversion of epimers contributes to the structural and functional
A) It leads to the formation of disaccharides diversity of monosaccharides, allowing for the generation of distinct monosaccharide isomers
B) It results in the production of polysaccharides with unique properties and roles in biological processes.
C) It allows for the conversion of glucose to fructose
D) It facilitates the conversion of galactose to
mannose
E) It contributes to the structural and functional
diversity of monosaccharides
What is the structural relationship between C) They are all mirror images of each other
D-aldoses shown in Fischer projection? Explanation: The structural relationship between D-aldoses shown in Fischer projection
A) They are all linear structures indicates that they are mirror images of each other, highlighting their stereochemical
B) They are all cyclic structures arrangement and the concept of enantiomers.
C) They are all mirror images of each other
D) They are all enantiomers
E) They are all epimerases
A) Hydrolysis which is a process that involves the conversion of one epimer into another, highlighting the
B) Oxidation significance of these enzymes in altering the stereochemistry of molecules.
C) Reduction
D) Epimerization
E) Isomerization
How is the configuration of glucose conveniently C) By both Fischer formulae and Haworth projection formulae
represented? Explanation: The configuration of glucose is conveniently represented either by Fischer
A) By Fischer formulae only formulae or by Haworth projection formulae, providing different visual representations of its
B) By Haworth projection formulae only structure.
C) By both Fischer formulae and Haworth projection
formulae
D) By Ball-and-stick model
E) By Lewis structure
What are the cyclic forms of glucose known as? A) a-D-glucopyranose and c-D-glucofuranose
A) a-D-glucopyranose and c-D-glucofuranose Explanation: The cyclic forms of glucose are known as a-D-glucopyranose and
B) a-D-glucopyranose and p-D-glucofuranose c-D-glucofuranose, which are depicted by a six-membered ring pyranose and a
C) a-D-glucopyranose and b-D-glucofuranose five-membered ring furanose, respectively.
D) a-D-glucofuranose and b-D-glucopyranose
Question Answer
What is the definition of mutarotation? A) The change in the specific optical rotation representing the interconversion of a and p
A) The change in the specific optical rotation anomers
representing the interconversion of a and p anomers Explanation: Mutarotation is defined as the change in the specific optical rotation representing
B) The conversion of glucose to fructose the interconversion of a and p anomers of glucose, which have different optical rotations and
C) The formation of glycosidic bonds differ in certain physical and chemical properties.
D) The conversion of pyranose to furanose
E) The intermolecular hydrogen bonding of glucose
molecules
What is the term for the two forms of glucose shown B) Anomers
in Fig. 2.6? Explanation: The two forms of glucose shown in Fig. 2.6 are referred to as anomers, which
A) Isomers are a specific type of epimer that differ in configuration only at the anomeric carbon.
B) Anomers Understanding these forms is crucial in comprehending the structural and functional properties
C) Polymers of glucose.
D) Monomers
E) Dimers
What is the term for the structure of glucose shown A) Pyranose form
in Fig. 2.7? Explanation: The structure of glucose shown in Fig. 2.7 represents the pyranose form, which
A) Pyranose form is a six-membered ring structure. Understanding the distinction between pyranose and
B) Furanose form furanose forms is essential in comprehending the structural diversity of carbohydrates.
C) Aldehyde form
D) Ketone form
E) Ester form
What is the term for the process shown in Fig. 2.6? C) Mutarotation
A) Isomerization Explanation: The process shown in Fig. 2.6 is mutarotation, which involves the
B) Polymerization interconversion between the alpha and beta anomers of a sugar. Understanding this process
C) Mutarotation is crucial in elucidating the dynamic nature of carbohydrate structures.
D) Hydrolysis
E) Oxidation
Question Answer
What is mutarotation in the context of glucose? B) The interconversion of glucose anomers in an equilibrium mixture
A) The conversion of glucose to fructose Explanation: Mutarotation in the context of glucose refers to the interconversion of glucose
B) The interconversion of glucose anomers in an anomers (s and p forms) in an equilibrium mixture, leading to a balanced distribution of these
equilibrium mixture forms. This process is depicted in Figure 9.2.6 and is a significant aspect of glucose
C) The conversion of glucose to sucrose chemistry.
D) The conversion of glucose to furanose
E) The linear form of glucose
What is the predominant form of glucose in aqueous C) The p form due to its stability
solution and why? Explanation: In aqueous solution, the p form of glucose is more predominant due to its stable
A) The linear form due to its stability conformation. This stability leads to a higher proportion of the p-anomer in the equilibrium
B) The furanose form due to its stability mixture, as mentioned in the provided content.
C) The p form due to its stability
D) The s form due to its stability
E) The open chain form due to its stability
What is tautomerization in the context of D) The process of shifting a hydrogen atom from one carbon atom to another to produce
monosaccharides? enediols
A) The conversion of glucose to fructose Explanation: Tautomerization in the context of monosaccharides refers to the process of
B) The interconversion of glucose anomers in an shifting a hydrogen atom from one carbon atom to another to produce enediols. This process
equilibrium mixture is significant in the chemistry of sugars, particularly in alkaline solutions, as mentioned in the
C) The conversion of glucose to sucrose provided content.
D) The process of shifting a hydrogen atom from one
carbon atom to another to produce enediols
E) The conversion of glucose to furanose
What type of ring conversion occurs in fructose A) Conversion from six-membered to five-membered ring
during mutarotation? Explanation: During mutarotation, fructose undergoes a conversion from a six-membered
A) Conversion from six-membered to five-membered pyranose ring to a five-membered furanose ring until an equilibrium is attained. This ring
ring conversion is a notable aspect of fructose's mutarotation, as outlined in the provided content.
B) Conversion from five-membered to six-membered
ring
C) Conversion from pyranose to furanose ring
D) Conversion from furanose to pyranose ring
E) Conversion from alpha to beta form
What is the reducing property of sugars attributed A) Free aldehyde or keto group of anomeric carbon
to? Explanation: The reducing property of sugars is attributed to the free aldehyde or keto group
A) Free aldehyde or keto group of anomeric carbon of anomeric carbon, which allows them to act as reducing agents in various chemical
B) Presence of oxygen atoms reactions.
C) High salinity content
D) Alkaline pH level
E) Presence of reducing agents
What is the result of the Lobry de Bruyn-von C) Formation of a common intermediate enediol
Ekenstein transformation when applied to glucose, Explanation: The Lobry de Bruyn-von Ekenstein transformation results in the formation of a
fructose, and mannose? common intermediate, known as enediol, for glucose, fructose, and mannose, demonstrating
A) Formation of gluconic acid a shared chemical reaction among these sugars.
B) Production of glucuronic acid
C) Formation of a common intermediate enediol
D) Reduction of cupric ions
E) Formation of a yellow precipitate
What is the reducing action of sugars attributed to in E) Free aldehyde or keto group of anomeric carbon
the laboratory tests? Explanation: In laboratory tests, the reducing action of sugars is attributed to the free
A) Presence of reducing agents aldehyde or keto group of anomeric carbon, which is the basis for employing tests such as
B) High temperature Benedict's, Fehling's, and Barfoed's to identify this property.
C) Alkaline medium
D) Formation of gluconic acid
E) Free aldehyde or keto group of anomeric carbon
What is the role of enediols in reducing cupric ions of E) Reduction of cupric ions
copper sulphate? Explanation: Enediols reduce cupric ions (Cu2+) of copper sulphate to cuprous ions (Cu+),
A) Formation of a yellow precipitate resulting in the reduction of the cupric ions, which is a chemical reaction that forms a yellow
B) Production of glucuronic acid precipitate.
C) Formation of gluconic acid
D) Formation of a common intermediate enediol
E) Reduction of cupric ions
Question Answer
What pathological conditions can be caused by the C) Cataract and peripheral neuropathy
accumulation of sorbitol and dulcitol in tissues? Explanation: The accumulation of sorbitol and dulcitol in tissues can lead to pathological
A) Hypertension conditions such as cataract, peripheral neuropathy, and nephropathy, as mentioned in the text.
B) Diabetes
C) Cataract and peripheral neuropathy
D) Osteoporosis
E) Asthma
What is the chemical basis of the Molisch test for C) Condensation with phenolic compounds
carbohydrates? Explanation: The Molisch test for carbohydrates is based on the condensation of furfurals,
A) Formation of furfurals formed from the dehydration of monosaccharides, with phenolic compounds, resulting in the
B) Dehydration of monosaccharides formation of colored products.
C) Condensation with phenolic compounds
D) Osazone formation
E) Hydrolysis of polysaccharides
B) Furfurals react with other compounds, resulting in the formation of glycosidic bonds.
C) Osazones
D) Polysaccharides
E) Hemiacetal or hemiketal forms
What is the nomenclature of glycosidic bonds based B) Linkages between the carbon atoms and the status of the anomeric carbon
on? Explanation: The nomenclature of glycosidic bonds is based on the linkages between the
A) Linkages between the nitrogen atoms carbon atoms and the status of the anomeric carbon. For example, the bond between C1 of
B) Linkages between the carbon atoms and the ²-galactose and C4 of glucose is named as ²(1!’4) glycosidic bond.
status of the anomeric carbon
C) Linkages between the phosphate groups
D) Linkages between the sulfur atoms
E) Linkages between the oxygen atoms
What are the products formed when one or more D) Amino sugars
hydroxyl groups of monosaccharides are replaced by Explanation: Amino sugars, such as D-glucosamine and D-galactosamine, are formed when
amino groups? one or more hydroxyl groups of monosaccharides are replaced by amino groups. These
A) Sugar acids amino sugars are important constituents of heteropolysaccharides, highlighting their
Question Answer
What type of glycosidic linkage holds the glucose B) (1!’6) glycosidic linkage
units together in isomaltose? Explanation: In isomaltose, the glucose units are held together by (1!’6) glycosidic linkage,
A) (1!’4) glycosidic linkage distinguishing its structural arrangement from other disaccharides.
B) (1!’6) glycosidic linkage
C) (1!’2) glycosidic linkage
D) (1!’3) glycosidic linkage
E) (1!’5) glycosidic linkage
C) Inversion
D) Transition
E) Alteration
What are polysaccharides primarily concerned with? A) Energy production and storage
A) Energy production and storage Explanation: Polysaccharides primarily serve two important functions: structural support and
B) Protein synthesis storage of energy, making them crucial for energy production and storage in living organisms.
C) Nucleic acid formation
D) Lipid metabolism
E) Enzyme activation
What distinguishes the structure of polysaccharides A) They are linear and branched polymers
from proteins and nucleic acids? Explanation: Unlike proteins and nucleic acids, polysaccharides exhibit both linear and
A) They are linear and branched polymers branched polymer structures, which is a key distinction in their composition and arrangement.
B) They are only linear polymers
C) They are only branched polymers
D) They are composed of different monomers
E) They are not polymers
What is the composition of amylose and amylopectin C) Amylose has a (1 + 4) glycosidic linkages and amylopectin has a (1 -> 6) glycosidic bonds
in terms of glycosidic linkages? at the branching points
A) Amylose is branched and amylopectin is linear Explanation: Amylose is a long unbranched chain with (1 + 4) glycosidic linkages, while
B) Both are linear polymers amylopectin is a branched chain with (1 -> 6) glycosidic bonds at the branching points,
C) Amylose has a (1 + 4) glycosidic linkages and illustrating their structural differences and functional roles.
amylopectin has a (1 -> 6) glycosidic bonds at the
branching points
D) Amylose has a (1 -> 6) glycosidic bonds at the
branching points and amylopectin has a (1 + 4)
glycosidic linkages
E) Both are branched polymers
Question Answer
On which type of glycosidic bonds does amylase act C) (1 -> 4) glycosidic bonds
specifically? Explanation: Amylase acts specifically on (1 -> 4) glycosidic bonds, which are present in
A) (1 -> 2) glycosidic bonds starch and are crucial for the hydrolysis of this polysaccharide into dextrins, maltose, and
B) (1 -> 3) glycosidic bonds glucose units.
C) (1 -> 4) glycosidic bonds
D) (1 -> 5) glycosidic bonds
E) (1 -> 6) glycosidic bonds
Why can cellulose not be digested by mammals, A) Due to lack of cellulase enzyme
including humans? Explanation: Cellulose cannot be digested by mammals, including humans, due to the lack of
A) Due to lack of cellulase enzyme the enzyme cellulase, which is required to break the p-glycosidic bonds present in cellulose.
B) Due to lack of amylase enzyme This inability to digest cellulose highlights its importance as a major constituent of fiber in
C) Due to lack of lipase enzyme human nutrition.
D) Due to lack of protease enzyme
E) Due to lack of maltase enzyme
D) Heparin
E) Glucuronic acid
What role does hyaluronic acid serve in joints? B) Lubricant and shock absorbent
A) Energy production Explanation: Hyaluronic acid serves as a lubricant and shock absorbent in joints, contributing
B) Lubricant and shock absorbent to the smooth movement and cushioning of the joint structures, which is essential for proper
C) Structural support joint function.
D) Immune defense
E) Waste removal
What is the primary function of fructose found in the D) Energy source for sperms
semen? Explanation: Fructose found in the semen is abundantly utilized by the sperms for energy,
A) Energy storage emphasizing its crucial role in providing energy for the motility and function of sperms.
B) Hormone production
C) Cell structure
D) Energy source for sperms
E) Blood clotting
What is the primary role of cellulose in human C) Decreasing the intestinal absorption of glucose and cholesterol, and increasing bulk of
nutrition? feces to avoid constipation
A) Energy storage Explanation: Cellulose plays a significant role in human nutrition by decreasing the intestinal
B) Hormone production absorption of glucose and cholesterol, and increasing the bulk of feces to prevent
C) Decreasing glucose absorption constipation, underscoring its importance in digestive health and overall well-being.
D) Increasing cholesterol absorption
E) Preventing constipation
What is the function of hyaluronidase of bacteria in A) Better penetration of sperm into the ovum
animal tissues? Explanation: Hyaluronidase of bacteria aids in the invasion of animal tissues, facilitating better
penetration of sperm into the ovum. This enzyme plays a crucial role in the reproductive
process.
Question Answer
What is the function of Hyaluronic acid in the body? B) Serves as a lubricant and shock absorber
A) Acts as an anticoagulant Explanation: Hyaluronic acid functions as a lubricant and shock absorber in the body,
B) Serves as a lubricant and shock absorber contributing to the maintenance of tissue structure and promoting joint health.
C) Promotes wound healing
D) Helps to maintain the structure of blood vessel
walls
E) Keeps cornea transparent
Where is Chondroitin sulfate primarily found in the B) Cartilage, bone, skin, blood vessels
body? Explanation: Chondroitin sulfate is primarily found in cartilage, bone, skin, and blood vessels,
A) Blood vessel valves playing a key role in maintaining the structural integrity of these tissues.
B) Cartilage, bone, skin, blood vessels
C) Connective tissue, synovial fluid, vitreous humor
D) Heart valves
E) Cartilage, cornea, connective tissues
What is the primary function of Dermatan sulfate in E) Maintains the shapes of tissues
the body? Explanation: Dermatan sulfate primarily maintains the shapes of tissues such as blood vessel
A) Acts as an anticoagulant valves, heart valves, and skin, contributing to their structural integrity and function.
B) Serves as a lubricant and shock absorber
C) Promotes wound healing
D) Helps to maintain the structure of blood vessel
walls
E) Maintains the shapes of tissues
What is the difference between keratan sulfate and A) Different sugar composition
chondroitin sulfate? Explanation: The difference between keratan sulfate and chondroitin sulfate lies in their sugar
A) Different sugar composition composition. Keratan sulfate consists of alternating units of D-galactosamine and
B) Different sulfate content N-acetylglucosamine 6-sulfate, while chondroitin sulfate consists of repeating units of
C) Different protein content N-acetylgalactosamine and glucuronic acid 4-sulfate.
D) Different temperature requirements
E) Different geographical distribution
C) Keratan sulfate
D) Dermatan sulfate
E) Hyaluronic acid
What is the role of glycoproteins in blood group D) Determining blood group types
antigens? Explanation: The carbohydrate content of glycoproteins plays a determinant role in blood
A) Energy production group antigens, contributing to the determination of blood group types.
B) Cell communication
C) Structural support
D) Determining blood group types
E) Hormone regulation
What is the role of antifreeze glycoproteins in fish? B) Lowering the freezing point of water
A) Enhancing swimming ability Explanation: Antifreeze glycoproteins in fish lower the freezing point of water and interfere
B) Lowering the freezing point of water with the crystal formation of ice, allowing the fish to survive in cold environments.
C) Promoting crystal formation of ice
D) Regulating body temperature
E) Improving oxygen absorption
How are carbohydrates broadly classified? A) Into monosaccharides, oligosaccharides, and polysaccharides
Explanation: Carbohydrates are broadly classified into three groups: monosaccharides,
oligosaccharides, and polysaccharides, based on their molecular structure and complexity.
What are the most common reducing disaccharides A) Lactose and maltose
among oligosaccharides? Explanation: Among the oligosaccharides, the most common reducing disaccharides are
lactose (milk sugar) and maltose (malt sugar), which are important components in various
biochemical reactions and metabolic processes.
What are polysaccharides composed of? B) Polymers of monosaccharides or their derivatives, held together by glycosidic bonds
Explanation: Polysaccharides are composed of polymers of monosaccharides or their
derivatives, held together by glycosidic bonds, which are crucial for the structural and
functional properties of various biological molecules.
What are the carbohydrate reserves of plants and C) Starch and glycogen
animals respectively? Explanation: Starch and glycogen are the carbohydrate reserves of plants and animals
respectively, serving as essential energy storage molecules and playing a vital role in the
metabolism of these organisms.