1. CHEMICAL KINETICS - DPP - 1 ANS

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JEE EXPERT
CHEMISTRY (DAILY PRACTICE PROBLEMS) DPP - 01
TOPIC : CHEMICAL KINETICS
ANSWER
(1.) 2 (2.) 1 (3.) 3 (4.) 3 (5.) 2
(6.) 1 (7.) 4 (8.) 1 (9.) 1 (10.) 1
(11.) 4 (12.) 1 (13.) 1 (14.) 2 (15.) 1
(16.) 3 (17.) 3 (18.) 2 (19.) 1 (20.) 2
(21.) 4 (22.) 4 (23.) 3 (24.) 4 (25.) 4
(26.) 3 (27.) 3 (28.) 1 (29.) 2 (30.) 4
(31.) 1 (32.) 1 (33.) 4 (34.) 4 (35.) 2
(36.) 1 (37.) 2 (38.) 2 (39.) 2 (40.) 3
(41.) 4 (42.) 3 (43.) 1 (44.) 3 (45.) 3
(46.) 1 (47.) 2 (48.) 1
JEE EXPERT Pvt Ltd., 16/71 C, Near Income Tax Office, Civil Lines, Kanpur . Mob- 9919447742/43; Web: www.jeeexpert.com
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EXPLANATION
(1.) 2
Clearly, if Ea  0, K is temperature independent
if Ea  0, K increase with increase in temperature if Ea  0, K decrease with increase in temperature
(2.) 1
r  K  A]1  B ]1
0.1  K(20)1 (0.5)1
0.40  K(x)1 (0.5)1
0.80  K(40)1 (y)1
From (i) and (ii)
x  80
From (i) and (iii)
y2
1  a  1  100 
(4.) t10%  ln  ln 
K  a x K  90
2.303
t10%   log10  log9 
K
2.093
t10%    0.04 
K
Similarly
1  100 
t 90%  ln  
K  10 
2.303
t 90% 
K
t 90% 1
  25
t10% 0.04
a
e kt 
ax
ax
 e  kt
a
x
1   e  kt
a
 
x  a 1  e  kt
   1  e 
x  kt
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(5.) Answer (2)
ln2
t1/ 2 
k
2.303  0.301
 k
6.93
2.303  a 
Also, t  
log 
k  a  0.99a 
2.303  1 
 t  6.93log 
2.303  0.301  0.01 
 46.05 minutes
(6.) Answer (1)
Rate depends only on slow step
(7.) Answer (4)
a 2
K  1
2t 1 2  1
2
C0  C t 0.5  0.25
t   0.25 h
K 1
(8.) Answer (1)
k1  k 2 e
E a1 /RT
.
 Ea1 / RT  E / RT
k1  Ae , k2  Ae a2
E a1 2E a1
lnk1  Ink 2  
RT RT
k1
e
E a1 /RT
k2
k1  k 2 e
E a1 /RT
(9.) Answer (1)

(10.) Answer (1)
k Ea  1 1   1 1 
log 2     Ea   
k1 2.303R  T1 2
T  300 310
0.301 2.303  8.314  300  310
log2 
2.303  8.314
10
Ea 

53600Jmol 1 or 53.6kJmol1
(11.) Answer (4)
2 A B  C D
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1 d  A d  B
Rate of Reaction 
2 dt dt
d C  d  D
 
dt dt
Let rate of Reaction  k  A]x  B ] y
d C
Or,  k  A]x  B]y
dt
Now from table,
1.2  103  k 0.1]x  0.1]y
1.2  103  k  0.1]x  0.2]y
2.4  10 3  k  0.2]x  0.1]y
Dividing equation (i) by (ii)
1.2 103 k 0.1]  0.1]
x y
 
1.2 103 k 0.1]x  0.2] y
k  0.1]x  0.2]y
y
1
1  
2
y0
Now Dividing equation (i) by (iii)
1.2 103 k 0.1]  0.1]
x y
 
2.4 103 k 0.2]x  0.1]y
1 x
1 1
    
2 2
 x 1
d C 
Hence  k  A]1  B]0 .
dt
(12.) Answer (1)
Higher order greater than 3 for reaction is rare because there is low probability of simultaneous collision
of all the reacting species.
(13.) Answer (1)
0.693
Rate  K  H 2 O 2    0.05
25
1 0.693
Rate of formation of H 2 O 2    0.05
2 25
 6.93  10 4 mol min1
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(14.) Answer (2)

 Ea1 / RT
k1  Ae
 Ea2 / RT
k2  Ae
k2 1
 Ea  Ea 
 e RT 1 2
k1
k Ea  Ea2
ln 2  1
k1 RT
10 103
 4
8.314  300
(15.) Answer (1)
Assume the order of reaction with respect to acetaldehyde is x .
Condition-1 :
Rate  k  CH3 CHO
x
1  k[363  0.95]x
1  k[344.85]x
Condition-2 :
0.5  k[363  0.67]x
0.5  k[243.21]x
x
1  344.85 
   2  (1.414)
x
0.5  243.21 
x2
(16.) Answer (3)
From experiment I and II, it is observed that order of reaction w.r.t. 3 is zero.
From experiment II and III,

1.386  102  0.2 
 
6.93  103  0.1 
1
Rate K[A] 1
6.93 103  K  0.1

K  6.93  10 2
For 2 A B products
[A]0
2Kt  ln
 A
0.693
t1/2 
2 K
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0.693
 5
6.93 102  2
(17.) Answer (3)
r  K  A]x  B ] y
r2
 2x  2 y  8  x  y  3
r1
r3
 2x  2  x  1
r1
 y 2
(18.) Answer (2)
K  Ae  Ea / RT
So, as Ea increases, K decreases.
and as T increases, K increases.
(19.) Answer (1)
C  O 2   CO 2 No catalyst
Ostwald process :
Pt / Rh
4NH 3  5O 2   4NO  6H 2 O
Haber's process
Fe
N 2  3H 2 
 2NH 3
(20.) Answer (2)
k
A2  1  2 A
k 1
1 d A
  k 1[ A]2  k1  A2 
2 dt
d A
 2k 1[ A]2  2k1  A2 
dt
d A
  2k1  A2   2k1 [ A] 2
dt
(21.) Answer (4)
k  Ae  Ea / RT
E
lnk  lnA  a
RT
1
For Ink versus , slope   y
RT
 y  E a
 Ea  y
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(22.) Answer (4)

For the reaction 2X  B , follow zeroth order
Rate equation is
2Kt  [A]0   A
For the half-life
[A]0
2Kt 
2
0.2
K
2 2 6
1
K Mhr 1
120
 time required to reach from 0.5M to 0.2M
2Kt  [A]0   A
t   0.5  0.2  60
 18 hour
(23.) Answer (3)
Rate constant of decomposition of X  0.05 g / year From unit of rate constant, it is clear that the
decomposition follows zero order kinetics.
For zero order kinetics,
X  [X]0  kt
5  2.5
 t
0.05
2.5
  50 years
0.05
(24.) Answer (4)
E
lnK  lnA  a
RT
E
Slope  a  4606 K
R
 K  E  T T 
ln  2   a  2 1 
 K1  R  1T 2T
4606 100 

400  500
 2.303
K 
 log  2   1
 K1 
K2
 10
K1
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 K 2  10 K1
 10 5  10
 10 4 s1
(25.) Answer (4)
2 A B P
Rate  k  A]x  B ] y
Exp-1, 0.045  k  0.05]x  0.05]y
Exp-2, 0.090  k  0.1]x  0.05]y
Exp-3, 0.72  k 0.2]x  0.1] y  (iii)
Divide equation (i) by equation (ii)
x
0.045  1 
    x 1
0.090  2 
Divide equation (i) by equation (iii)
y 1
0.045  0.05   0.05 
   
0.72  0.1   0.2 
2 y
1 1
     y2
2 2
Rate law  k  A]1  B ]2 .
(26.) Answer (3)
A 
k1
 B 
k2
C
d  B
 k1  A  k 2  B  0
dt
k1  A
 B 
k2
(27.) Answer (3)
Graph-(i) : In[Reactant] vs time is linear Hence, 1st order
Graph-(ii) : [Reactant] vs time is linear Hence, zero order
(28.) Answer (1)
Activation enthalpy to form C is 5 kJ more than that to form D .
(29.) Answer (2)
dN
When drug is administered bacterial growth is given by  5 N2
dt
N N
 0  1  5tN 0 . Thus 0 increases linearly with t .
Nt Nt
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(30.) Answer (4)
K Ea  1 1 
log 2    
K1 2.303R 1T 2T
1 Ea  1 1 
log 4
   
2.5  10 8.314  2.303  600 800 
Ea 200
3.6  
8.314  2.303 600  800
E a  165.4 kJ / mol
 166 kJ / mol
(31.) Answer (1)
xA  yB
 dA 1 dB
 
xdt y dt
dA dB x
 
dt dt y
  dA   dB  x
log    log    log  
 dt   dt   y
x
2
y
The reaction is of type 2A  B .
(32.) Answer (1)
2 N2 O5  4NO2  O2
1 d  N 2 O5  1 d  NO 2  d  O 2 
rate   
2 dt 4 dt dt
Since, instant of finding rate of formation of NO 2 is not mentioned, hence
Δ  N 2 O5   2.75  3  0.25
  Mmin1
Δt 30 30
Δ  NO 2  Δ  N 2 O 5 
  2
Δt Δt
0.25
 2
30
 1.67  10 2 Mmin 1
(33.) Answer (4)
 N  H O
2
kf
keq   2 2 2 2
kb  H 2  [NO]
Rearranging
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kb  N2  H2 O
2
k f [ NO ]  H 2  
2
H2 
on comparing R f and Rb at equilibrium,
 N 2  H 2O
2
Rb  kb
H2 
(34.) Answer (4)
The rate constant of a reaction is given by
The rate constant in presence of catalyst is given by
k  Ae  Ea / RT
'
k  E '  E  / RT
e a a
k
106  e
 
 Ea'  Ea / RT
ln10 6

E '
a  Ea 
RT
E  Ea  6  2.303 RT
'
a
(35.) Answer (2)

Ea
logk  logA 
2.303RT
Ea
Slope  
2.303R
So correct order of activation energies  Ec  Ea  Ed  Eb
(36.) Answer (1)
Rate of reaction at 700 K in the absence of catalyst  Rate of reaction at 500 K in the presence of
catalyst
 Ea    Ea c  30 kJ / mole
 Rate is same
 Rate constant will also be same
(Assuming same value of pre exponential factor)
 Ea   Ea  c
 
R  700 R  500
 5Ea  7  Ea c  7  Ea  30
 2 Ea  210  Ea  105 kJ / mol
 Activation energy in the presence of catalyst  105  30  75 kJ / mol
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(37.) Answer (2)
For reaction 1
rate  K  t  BuBr 
for reaction 2
rate  K  t  BuBr   OH  
Reaction 1 is independent of concentration of OH  where as reaction 2 is dependent on concentration of
OH 
Hence changing the concentration of base will have no effect on reaction 1
(38.) Answer (2)
Rate  k  A]a  B ]b
6 103  k(0.1)a (0.1) b
2.4  103  k(0.1)a (0.2)b
1.2  103  k (0.2) a (0.1)b
Solving eq (1), (2) and (3), we get
a  1, b  2
6 103  k(0.1)1 (0.1) 2
from (1)
k6
7.2 102  6( x)1 (0.2) 2  x  0.3
2.88 102  6(0.3)1 ( y ) 2  y  0.4
(39.) Answer (2)
Zero order reaction has complex mechanism. Zero order reaction is a multistep reaction.
(40.) Answer (3)
3
2 A 3 B C  3P
2
1 dn A 1 dn B 1 dn C
rate   
2 dt 3 dt 3 / 2 dt
dn A 2 dn B 4 dn C
 
dt 3 dt 3 dt
(41.) Answer (4)
ln2
 A A0 e kt k
t1/ 2
ln 2
 t  1 1 
4 B A0 e 300 ln 2  t
 ln 2
[given 0A 0 B , A 4 B ]e 4  180 300 
t 900sec
 t
B  B0 e 180
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(42.) Answer (3)
Ea
 Ea
K  Ae RT
lnK  lnA 
RT
Ea 103 E 10
lnK  lnA   3a  
103 RT 10 R 5
Ea
  2  103
R
 Ea  2 R kJ / molR
(43.) Answer (1)
Rate  k[ A]n
log[ Rate ]  logk  nlog  A
slope  n [n is order of the reaction]
 Correct sequence for the order of the reaction is d  b  a  c
(44.) Answer (3)
Rate  k[ A]n
(mol / L)1
 k(mol / L) n
s
k  (mol / L)1 n s 1
 mol1 n Ln 1 s1
(45.) Answer (3)
Since, half life is independent of the initial
concentration of AB2 . Hence, reaction is "First
Order".
2.303log2
k
t1/ 2
2.303log2 2.303 100
 log
t1/2 t 100  80 
2.303  0.3 2.303
 log5
200 t
t  467 s
(46.) Answer (1)
To minimize contamination, use freshly prepared starch solution to determine end point. As KI is used in
excess to consume all the H 2 O 2 the concentration of sodium thiosulphate solution is less than KI
solution. After appearance of blue colour record the time immediately.
(47.) Fact base.
(48.) (A) Physisorption  20  40 kJ / mol and Chemisorption  80  240 kJ / mol
(B) Physisorption is multi-layered and chemisorption is unimolecular layered.
(C) In heterogeneous catalysis, medium and catalyst are in different phases.
(D) Chromatography uses adsorption to purify/separate mixtures.

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(9.) Answer (1)

(14.) Answer (2)

6.93 103  K  0.1

(22.) Answer (4)

(35.) Answer (2)

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