2. CHEMICAL KINETICS - DPP - 2 ANS

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JEE EXPERT
CHEMISTRY (DAILY PRACTICE PROBLEMS) DPP - 02
TOPIC : CHEMICAL KINETICS
ANSWER
(1.) 1350 (2.) 130 (3.) 1
(4.) 333 (5.) 75 (6.) 3.98
(7.) 60 (8.) 84297.48 (9.) 100
(10.) 26 (11.) 81 (12.) 526
(13.) 52 (14.) 50 (15.) 14
(16.) 10 (17.) 108 (18.) 2
(19.) 27 (20.) 3 (21.) 10
(22.) 106 (23.) 1 (24.) 7
(25.) 4 (26.) 658 (27.) 1
(28.) 0 (29.) 4 (30.) 16
(31.) 2 (32.) 45 (33.) 47
(34.) 154 (35.) 1 (36.) 0
(37.) 200 (38.) 4 (39.) 166
(40.) 59 (41.) 16 (42.) 75
(43.) 1 (44.) 216 (45.) 1
(46.) 2 (47.) 2 (48.) 2
(49.) 165 (50.) 100 (51.) 8
(52.) 40 (53.) 1 (54.) 3
(55.) n=2 (56.) 2 (57.) 15
(58.) 2520 (59.) 17 (60.) 623
JEE EXPERT Pvt Ltd., 16/71 C, Near Income Tax Office, Civil Lines, Kanpur . Mob- 9919447742/43; Web: www.jeeexpert.com
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EXPLANATION
1 a0
ln
t1 K 0.4a0
(1.) 
t2 1 a0
ln
K 0.1a0
10
ln 540 log10  log4 540 1  0.6 540
540
 4     0.4  t 2  540  1350sec
t2 ln10 t 2 log10 t2 1 t2 0.4
(2.) 1 30
E a  300 kJ mol1
E a E a'

T T
(Since rate of catalyzed and uncatalysed reaction is same)
'
300 Ea , f

600 300
E 'a,f  150
20  150
20  150  E 'a,b
E 'a,b  130
(3.) Only option (B) is correct as order cannot be determined
(4.) 333
ΔFeSO 4 10  8.8 1.2
 
Δt 30  60 1800
From given equation :

1 ΔFeSO 4 1
6 Δt
   Rate of production of Fe2  SO 4 3
3

3 1.2
Rate of production of Fe 2  SO 4 3  
6 1800
1
  103
3
1000
  106
3
 333.33 106
(5.) 75
(6.) 3.98
Using Arrehenius equation
K  Ae  Ea / RT
Assuming A (pre - exponential factor remains same)
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k  E  1 1 
 ln  400   a   
 k 300  R  300 400 
 1 60  Ea 100
 ln     
 40 1  R 300  400
3 Ea
 ln   0.4
2 1200 R
 Ea 0.4 1200 8.3 3984 J / mol
Ea  3.984 kJ / mol
 3.98 kJ / mol
(7.) 60
st
Time for completion of 75% of a order reaction = 90 min
1
 Half life, t 1   t 3
2
2 4
90
  45 min
2
0.693
Rate constant, K  min1
45
Time for completion of 60% of the reaction,
2.303 10
t 60%  log
K 4
2.303  45
 1  0.6  60
0.693
(8.) 84297.48
 k  Ae  E / RTa
Assuming A and Ea to be temperature independent.

k 2 Ea  1 1 
ln    
k1 R  T1 2 
T
E  1 1 
 ln5  a   
R  300 315 
1.6094  8.314  300  315
 Ea 
15
 84297.48 J / mol
(9.) 100.00
Ea

k  Ae RT
Assuming A and Ea to be independent of temperature
k 2 Ea  1 1 
ln    
k1 R  T1 2 
T
Ea  1 1 
ln3.555    
8.314  303 313 
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1.268  8.314  303  313
 Ea 
10
 99980.7 99.98 kJ / mol
(10.) 26
For a 1st order reaction
a
kt  ln 0
at
1 a
t40%  4
ln 0
3.3  10 0.6a0
104 10
 ln sec
3.3 6
104  0.51
 min 25.8 min
3.3  60
 26
(11.) 81
t  0 Sucrose
t  9hr a x
0.693 1
k hr H
3.33
2.303 H
k log
t ax
H
0.693  9
1
3.33  2.303log10  
f 
1
log10    81
f 
(12.) 526
k  Aee  E
a
/RT
Ea 1
logk  logA  
2  303R T
E a
From given graph : slope  10000 
2.303R
k2 Ea  1 1 
 log    
k1 2.303R  T1 2
T
104  1 1 
log 5  10000   
10  500 T2 
10000
 1  20 
T2
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10000
 T2   526.3  526 K
19
(13.) 52
K Ea  1 1 
log 2    
K1 2.303R  1T 2T
Ea  1 1 
log5  
2.303  8.314  300 325 

0.7  2.303  8.314  300  325
Ea  J mol1
25
1
 52271 J 52.271 kJ mol  52
(14.) 50
X Y
ΔE  ( Ea ) f  ( Ea )b
20  30  ( Ea )b
 ( Ea )b  50 kJ
(15.) 14
Energy of activation, E a  80.9 kJ mol1
Temperature of reaction, T  700 K
Fraction of molecules having enough energy to react  e  Ea / RT  e  x
E 80900
 x a   13.9 14
RT 8.31 700
(16.) 10
k Ea  1 1 
log 2    
k1 2.303R  T1 2
T
k1 ( at 200 K) ?
k2 ( at 300 K) 1 103 s1
1 103 11.488 103  1 
log  1
k1 2.303  8.314  600 
1103
 10
k1
k1  10  10 5 s1
(17.) 108
Initially :  A0    B0   a
After time ' t ' min :  A  16  B
 A   A0  ek t
A
 B   B0  ek t
B
 a  e  k At  16ae  kB t
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 e k A k B  t  16
  k B  k A  t  ln16
 1 1 
 ln2    t  4ln2
 18 54 
54  18  4
t  108min
36
(18.) 2
A   Products
Rate constant of a first order is given as
2.303 [ A]0
k log
t [ A]t
2.303 100
 log
570 32
3 1
 2  10 s
(19.) 27
2 A B2  2 B
rate  [A]2  B2    PA 
2
P 
B2
Now, if volume is reduced by a factor of 3 , then P is increased by a factor of 3 .

 1
 V  
 P

rate   3PA  3PB2
2

 27PA2  PB2
Rate increases by 27 times the previous rate.
(20.) 03
Rate  r   k[NO]x  Cl2 
y
From run (2) and (3)

 r0 3 (0.20) x (0.20) y

 r0 2 (0.10) x (0.20) y
1.40
 2x   22
0.35
 x 2
From run (1) and (2)
 r0 2 (0.10) x (0.20) y

 r0 1 (0.10) x (0.10) y
0.35
 2y
0.18
 y  1  r  k [NO ]2  Cl2 
1
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 Overall order of reaction  2  1  3
(21.) 10
The given reaction to be first order, then
ln2
ln 1000   t
t1/2
1ln 1000 
t
ln2
 10 min
(22.) 106
Rate  k [Amount of virus ]
1 1
k ln 
( 10% of virus is inactivated )
1min 0.9
 2.303 1  0.954
 0.1059
 105.9  10 3
 106  10 3 min1 (nearest integer)
(23.) 1
1
a 0  50 mol L
1
at  10 mol L
1 50
K  2.303log
120 10
 0.01341
 1.34  10 2 min1
x  1.34  1 (nearest integer)
(24.) 7
For the first order reaction
[R]0
Kt  ln
R 
K  60  ln
 2.4 10  2
1.6 10  2
 2.303   log3  log2

 2.303  0.477  0.301
K  6.7  10 3 min1
For 1st order reaction
Rate  k [Reactant ]
A  [A]0 ekt
0.693
t1 
2
k
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(25.) 4
AB
Increase in concentration of B
Average rate
Time
1
0.2 mol L

0.5hr
 0.4  4  10 1 mol L 1 1
h
(26.) 658
t  0 A  B2
t  100min1  x
2 x  0.2  x  0.1
1 [ A]0
k  ln
t  A
ln2
k
t1
ln2 1 1
 ln
t1 100 0.9
t1 ln2  100
   600  700  min*
1 ln10  ln9
2
(depending on value of log3 )
(27.) 1
2NOg  2H2 g  N 2 g  2H2O g
Rate  k[NO] H2 
x y
  8 10 
x y
7  10 9  k 8  10 5 5
 k  24  10   8  10 
x y
2.1 108 5 5
Now dividing (ii) by (i)

x
2.1 10 8  24  10 5 
 5 
7  10 9  8  10 
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3  3x
 x 1
Similarly,
y
8.4  108  32  105 
 
2.1 108  8  105 
 y 1
Order of reaction w.r.t. NO is 1.
(28.) 0
Kf
 PtCl4 

 H 2 O   Pt  H 2 O  Cl3   Cl 
2
Kb
d  PtCl4  
2

   K  PtCl 2   K  Pt H O Cl    Cl  
f  4 b   2  3   
dt  

5
K 4.8 10
KC  f  3
 2  102
K b 2.4 10
(29.) 4
2 K2 Cr2 O7  8H2 SO4  3C2 H6 O
 2Cr2 SO4 3  3C2 H4O2  2 K2 SO4  11H2 O
1 d  C 2 H 6 O  1 d  Cr2  SO 4 3 
Rate   
3 dt 2 dt
d  Cr2  SO 4 3 
 2.67 mol min1
dt
d  C 2 H 6 O  3 d  Cr2  SO 4 3 
 
dt 2 dt
3
  2.67  4 mol min1
2
(30.) 16
k1  6.36  10 3 s1 1T 700k
E a  209 kJ / mol
k 2  x  10 6 s1 T 600k
2
k 2 Ea  1 1 
ln    
k1 R  T1 2 
T
 x 106  209 103  1 1 
log  3 
   
 6.36 10  8.31 2.303  700 600 

log x  10 6  4.79 
x  10  1.62  10 5
6
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x  16.2  16  Nearest integer

(31.) 2
For first order reaction
t75%  2  t50%
A
 kt  ln 0 (for first order reaction)
A
A
t  A 0
At 50%
2
 kt 50%  ln2
A
t  A 0
At 75%
4
 kt75%  ln4
(32.) 45
(33.) 47
log10 K  20.35 
 2.47 10 
3
T
Ea
logK  logA 
2.303RT
Comparing (i) and (ii),
Ea 2.47  103

2.303RT T
Ea  2.47  10  2.303  8.314
3
 47293.44 J mol1
 47.2934 kJ mol1
(34.) 154
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Ea
lnk  lnA 
RT
Ea
 Slope of the graph    18.5
R  103
1
 Ea  18.5 8.31 1000 154 kJ mol
(35.) 1
1   d  A  1   d  B   1   d  C  
Rate       
r1  dt  r2  dt  r3  dt 
1  d  D 
  
r4  dt 
d  D r4  d  B 
  
dt r2  dt 
r4 3

r2 2
d  B  r2  d  A  r2
   2
dt r1  dt  r1
r2  2r1
r4  1.5r2  3r1
d  C
 1 m moldm3 sec1
dt
d  D
 9 m moldmmec1
dt
d  D r4 d  C r
   4 9
dt r3 dt r3
r4  9r3  3r1
 r1  3r3
3r3 A  6r3 B  r3C  9r3 D
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1
 rate of reaction   9 m moldm3 sec1
9
3 1
 1 m moldm sec
(36.) 0
1
t1/2 
 P0 
n 1
 t1/2 1  P0 2
n 1

 t1/2 2  P0 1n 1
n 1
340  27.8 
 
170  55.5 
n 1
1
2 
2
2  (2)1 n
1 n  1
n0
(37.) 200
at initially
A B
11
mole mole
after 100 s
1 1
2 4
after 200 s
1 1
4 16
Ans. 200 seconds
(38.) 4
K  Ea  Ea
ln 
K RT
10  103

8.314  300
K 100
ln 
K 8.314  3
K
 e4
K
x4
(39.) 166
2 104
Ink 33.24
T
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Ea
  2 104
R
Ea  2  10 4  8.3
 166 kJ / mol
(40.) 59
T1  300 K
(Rate constant)
K 2  2 K1 , on increase temperature by 9 K
T2  309 K
Ea  ?
K Ea  T2  T1 
log 2   
K1 2.3R  T2  T1 
Ea  9 
log2 
2.3  8.3  309  300 

0.3  309  300  2.3  8.3
Ea 
9
 58988.1 J / mole
 59kJ / mole
(41.) 16
A
 kt  ln 0
A
ln2 A0
t67%  ln
t1 0.33 A0
2
log2 1
t67%  log
t1 0.33
2
t67%  1.566t1/2
x  15.66
Nearest integer  16
(42.) 75
2.303 A
 log 0
t A
0.693 2.303 A
 log 0
200 83 A
A
 0.75
A0
Hence, percentage of original activity remaining after 83 days is 75%
(43.) 1
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 K  532611  1 1 
log  310     
 K300  8.3  300 310
K 310
 103  K 300  1 10 3  K 310
K300
(44.) 216
 Ea
k  Ae RT
Ea 26000

RT T
Ea  26000  8.314
 216164 J
 216 kJ
(45.) 1
t1/2  A  240 s when P  500 torr
t1/2  A  4min  4  60  240 sec when P  250
torr
If means half-life is independent of concentration of reactant present.
 Order of reaction  1
(46.) 2
For first order reaction,
lnA  lnA0  kt
Hence Slope   k
 k  3.465  10 4
0.693
k
t1/ 2
0.693
3.465  104 
t1/2
t1/ 2  2  10 5 s
(47.) 2
1
t1/ 2 
a0 
n 1
t1/2  100seca 0  0  5
t1/ 2  50seca 0  1
n 1
100  1 
 
50  0  5 
 2  (2)n 1
n 1  1
n2
(48.) 2
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Let the rate of reaction  r  is as
r  K[NO]n  H 2 
m
From 1st data

0.135  K [40]n  (65.6) m
From 2nd data
0.033  K (20.1)n  (65.6)m  2
On dividing equation (1) by equation (2)
n
0.135  40 
 
0.033  20.1 
4  (2) n
 n 2
 Order of reaction w.r.t. NO is 2 .
(49.) 165
A  B
Reactant
0.693
k  165  106 s1
70  60
 x  165
(50.) 100
0.693
t1/ 2  t1/ 2 given 0.3010
K
0.693
K
0.3010
K 2.30
K
2.303
log 0
A 
t At 
A0  initial concentration of reactant
At  concentration of reactant at time t
2.303 
2.303 A 
log 0
2  At 
2  log
 A0 
 At 
A0
100 
At
(51.) 8
| 26 | P a g e
20
Slope 
5
E
lnk  lnA  a
RT
E a 20 20R
  E  8calmol1
R 5 5
(52.) 40
Rate   X]1  Y]0
Rate  k  X 
From Exp I and II,
4  103  L   0.2 
1 0
   
2  103  0.1   0.1 
2  (10 L)1 .
Hence L  0.2 mol / L
From Exp III and IV,
M  103  0.4   0.4 
0
  
2  103  0.1   0.2 
M M 8
4 M 8   40
2 L 0.2
(53.) 1
1
kt  ln
1 X
0.693 1
100   ln
30 1 X
1 1
2.303  2.303log   10
1 X 1 X
9
 1  10  10X X   0.9  g
10
Amount ofX remaining   1X
 1  0.9  0.1 g
 1101  g
| 27 | P a g e
(54.) 3
(55.) As unit of rate constant is (conc. )1n time 1

 Lmol1  1  n 1
n  2
(56.) t1/2  T50  30 min
T75  2t1/2  30  2  60 min
(57.) 15
K 300 Ea  1 1 
(58.) log    
K200 2.3 8.314 1T 2T
0.05 Ea  1 1 
log   
0.03 2.305  8.314  200 300 
Ea  2519.88 J Ea  2520 J
Co Co
C 
2n 32
n  5
(59.) t  5t1/2
5  0.693 0.693
 
20 4
 0.17325 min 17.325 102 min.
(60.) A  B  P
t 0 7 g
tt 2 g
at constant volume
2.303 [A]
t  log 0
K [ A]t
2  303 7
 3
log
2  01110 2
2  303  0  544

2  011103
 622.989
 623

2. CHEMICAL KINETICS - DPP - 2 ANS

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2. CHEMICAL KINETICS - DPP - 2 ANS

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| 11 | P a g e

Assuming A and Ea to be temperature independent.

Now, if volume is reduced by a factor of 3 , then P is increased by a factor of 3 .

From run (2) and (3)

 2.303   log3  log2

Now dividing (ii) by (i)

From 1st data

(55.) As unit of rate constant is (conc. )1n time 1

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