4 fom (E) q arr jap EVISU DY ODE UVIAL WE COR PLIPEDL)) ) is im OWED 4 SUBJECT: CHEMISTRY (043 Ces? ; ‘ial Te Maximum Marks : 70 Aes ao Aare =m Bc cc Bae eae yo wr hin ae 1 Fee e ee eR CEC ORR Re Si aL al Cee Re CRE te ee ed) Dee ee RCC eae Cee ee ee eel COM Re kc ee ke ek ca CORR ck MR i ei (ii) eee ER ee Renal au Ce Ree hk ee ee eee Re CeCe 0) Ce Re RR CUR Cad GENERAL INSTRUCTIONS: ere eee ee eee ena Rc he ene @ This question paper contains 33 questions. All questions are compulsory. (ii) This question paper is divided into five sections — A, B, C, D and E. eee SES ett ee heer ee ae di) ) re (iv) _ In Section B - Question No.17 to 21 are Very Short Answer (VSA) type questions, carrying 2 ee eee OME ere OR eee eS Cas eee eer ed om (vi) In Section D ~ Question No.29 to 30 are Case study based questions, carrying 4 marks each. (vii) In Section E - Question No.31 to 33 are Long Answer (LA) type questions, carrying 5 marks oom : ; “(vili) There is no overall choice. However, an intemal choice has been provided in 1 question in RS eee eer ee eer Et etn ernest (ix) Use of Calculators and log tables are not allowed. oreeerereete’ PCS AE Na a —bene , ee Pefated er ere en fe eer eh Se ET SiR oe ee oe eee Tests] SRR ec ae CS (Omeee) is mens Re CRBC R Ree CR Ce (@) Mg Oe Ga (© Na ‘ (d) Nat See eT ee ee Cee en OO eee Occ Rc cc Me Ge © tt ppt fiver aed ora: aie ot cia aftr eH a GN) Se RE CR eee ae ee ; ON CMa (o) feria aaien Wen © Fe Ae CL (COME DE Cc See 7 COM id we (OME CMaSECTION-A BU ar DCSE ee Ce CCR Re ee la peta 16x1=16 See VCC po DUE MMe Osan ee Cem oR ioa:() The oxidation state of oxygen in H;O, is : ji ; 4 7 1 A (b) +2 F; (Ome A @ +1 Which of the following atom or ion have the largest size? a Ng Ben eae © Na (CONC eee eC nee Oe Ca eee Re mC Rony d FOE rd : (@)__ Ais limiting reagent and B is excess reagent PT eM ee Cera tiraetss —“(c)__ Both reacts completely, hence no limiting reagent CMP ESE OCR ce eas PC Sa Coo Tue t et ct sa (a) Principal quantum number {b) — Azimuthal quantum number oe (c) Magnetic quantum number (COMES SORT CLUno nag Es Packet of energy is called : (a) Electron (Oe acon a Bat) (COMER Sosa9. 1. ' eee ae es i! Os ee i On LS oe ore ec (b) sp? [ORE @ dsp? (ORE orones be ees H,0,, (Ree rne Oe aes cleo ORE Soe REE ce @ beineie Gr Oa OES Loan 5 ola ch. ek kee. COM oT (OM cee © sad - 3, af - 13 (CVS a Ue) Dee eC i ie) @ 1s (OES (Cera eee SR (@) B>A€>Mg>K © 2» (b+) A£>Mg>B>K (©) Mg> Aé>K>B @ K>Mg> ag>BSO Ceca (CO Essig is vo (©) Molality (a) Allofthe above Which of the following hybridization have maximum bond angle? 4 7 () sp q Ss re Goan ; z= @) i CS Which of the following is not an example of redox reaction? Or Mts: Maneo NES: Revny + (OE COMES COREE RECT > 2K, % wa Saar) SOMME ORC DES: EO REES = Sone E 1700) eee Cee kr com CR creck Cc aT Le aa2 (a) _Period-04, group-11 (OM eC CU s ee (OMB Ones SEs OME Sco et) ASO Moe BOO este Te Cs tL) @ 1s re © 2» (Ce a a“ \ pce erase tatod eS ela Cu Oe eee SR ome m mtg 7s (a) B>A>Mg>K (UES Eee 1 Cea Sa) (CN eave Vis) : _ aeSra Roa Bolo g teem Cnt sya Oc CEEOL Be Pg (0) Molality @ __ Allof the above Re OR CEO UCE Sorc UCC E san aad 2 ee 5 (ORS a a ee laa Me e ‘ } ( i i @ dsp’ A Which of the following is not an example of redox reaction? (COMER OnE: OEE XONTNED ¢ hOlt) + OME ROME S COMED EEOC 2 wi 2K yy + Fy 7 2KF iP CE OACCR ES COPIES: Coan eiiny In terms of period an d group where would you locate the element with Z=29? aC) sos ea Pee (b) Period-07, group-11 (©). Period-03, group-13 YL @__ Period-02, group-09 BU NO Moa Ceo nates Ole es ssl) Ce @ Is cy (© 2p @ 4 aa Cea cee aCe ett cug moans ticketed Sal @) B> Al>Mg>K (OES Ces E84 Ps aaa COME eae ES) eee a] BoE aw” sy ER COED eto) ca ORCA CC Ce 2) @ 1 () 5 ©) 0 (Cn) ; ee ey Rk be a 8 Foc ee ew Oy OR kk ee er ae re cea ORC ee ee Se UO oe al OM EC ee em Cay OR CO kee me eT ONO Ramee eee ca SC ee See SOR rfregert (a) te Ac mm ta BS re a ae one te B ap ages SC eRe ki ee R ai a ko nines culsee ce ester ea eee eR Per TEE Cnr ee rt ee al (Oe the other labelled as Reason (R). Select the correct answer Pee Chae the codes (a), (b), (c) and (d) as given below : a COMER CUM Coot CO CUES cco (OR CRC eas COC motes CRM EUT Ra Paci 0 (b) Both Assertion (A) and Reason (R) are true, but Reason (R) is not Pees PCOS ey Cran Cls PRT e Sn recor Ea (@ Assertion (A) is false, but Reason (R) is true. “Assertion (A) : 2Mg, +Ozq > 2Mg0,, reaction is an example of disproportination. pe OPS DU ce ls ead the reactions in which same species gets Pr nN Cac eu ec eg “Assertion (A) : The density of a gas A is three times that of gas B. Then molecular mass Ra Seas Cee iS pt 5 Reason (R) : Greater the molecular mass of gas, greater is its density.TS eae eo a ry ce eed AT (A): SAO ong arr eg WHE rent fer re Se eee RCLESS ce het bee ce ae RS er oe a) (a) cea ees of ico ere acorn ©) Re ec et lL Soi dy ORE A Ron ©) NaBH, ee ee PR OR cea aad) [O)ee ret 5 sertion (A) : Both BF; and PF; do not obey octet rule. eee Reason (R) : Both are electron deficient molecules. : 16. Assertion (A) Photoelectric effect is easily given by cesium metal: FeneRC SEROUS oat tc tc a SECTION-B ‘This section contains 5 questions with internal choice in one question: Pe oiled PORE ROU Le Rae 2 marks each. 17. (@)~ What mass of CaO will be obtained by PE Khon POL aaa PR ter mtcnd i (oreo Wie econ OE TOO co ROR USES C Cnc ome 7 SMe RUE SCC Pears R ag Peo Race Olid Rates en r vee ok ae td Loa ores i asa in O; molecule. —~~ 2 oy See Bec yee ne a s MnO, (s) + BrO3(aq.) re (Basic Medium) s) 4) eee Rte ie aan 26. Explain the following : 3 ) Sst e Ren curtinm sh teh ee wan eS a] (b) Orbital (c)~ Electromagnetic spectrum a 27. The first Ionization Enthalpies (IE,) and Second Ionization Enthalpies (IE2) of a few Soren Cannel . ape TE; oA (KJ/mot) (KJ/moe) te EEE a Eos cy 520 7300 Gl 0 ea 2 co EEK) Fa ecco @ @ PD) () anoble gas OM ame)Pa ri COMICS OMC LR Bcc Bee (0) TH TE (x) Se Ree H H Thome ee ORS oe ee cc ee 2) (O) SR Re eae eee ee emer beMe Aa NIE Rous OR AR Re ne ec oe ae ee SR Re ek ee ee nd é iid] CORR ec os PCC CLE che 2 RRR RRR Ree ‘agg free A en at air thor ed be ae ah atom eae PR kr ee ae Sd RSME Ch) ee @ Ch ke SS mol CRMC LICE Mime co)i cae a! ae Hom an Rex ae sCEcsH | Tk eae er aek: | ete ne @ What do you understand by polar Setar aes a (©). ° Arrange the following molecules in the Cece Cam ee \g ig H,0,CH,,NH; ? ete _ G SECTIOI The following questions are case study based Perr Pe oop er choice and carries 4 marks each. Read the passage carefully and answer the COcCoRen soa Bee eee Ce ce OTC aeRO RON a CoRR ee Ree Cerca sconce moles is called solute whereas the component in which solute is dissolved and present in ee eave Oe Rear crete sao tence ee weer sg “of solvent or solution is called concentration of the solution. Amount of solute can be ee te OCR UC en ANAS Coe ey Cees ce ECR Caan OC ee LOSS ke RRL ae Tees COO eo (a) Why does molality and mole fraction are preferred over molarity to determine Pere R Oe noesy 3 r a Fs 82 PU a oe Rr kc eR RR Cae Ces ts Pea cd (c) Calculate PCA EN aa gor net ed COST aos ceca n TD) OR Bs fervancicm Cp icCait Raid astm The definite relative arrangement of the bonded atoms in a molecule is known as Peta ees Ree a Cae UES ioe eel eas Fee Rete ene OR Ra OCC CMa Aaa a - pair repulsion) theory and hybridization. VSEPR theory is based on the repulsion amone Pe Core Rs es lone pairs) present around the central metal atom. ‘These pair of electrons tend to occupy such position in space Peters CCE Pree Rh oa ks Hybridisation is based on mixing of atomic ee COR ao ‘This results in the formation of new equivalent orbital of same shape and energy called Py reted Ps CMe Cass pin sCed forse cmuCas Pore OLS Pest el mC i Teast it re ST oan Fircat Cee of overlap gives tomers of formation a bela a ee = a a oa jor of Wl Cia ce Pra kasi v7Rly “4 rae ccm Ck ae i SIC) (CS) SR Me cd a EA 3) ‘ cls ii ee ee ee re ry hak rial neoahy palh Se CRS Nabe aiibahac hia cereal aie RCRA Rd CN mc RR Ee Ee Se cl ee ee ee cece er Pie eee ee See Be RRR RRR Ra Rie Nee eRe Re ee Ren ee ee Le Ue ieaeiaa eT kk eel Tce dlec. Cee See ee CE cee eee cra ) eS en fet ee | Ok ccc men Sc eee ; a aca Fe ars 3 ev atari mer th ee men s aed ar att we wee 8 ates ory 31. (a) RRC eee A (0) ok ee econ rene Fev aen Pre © wa eee] @) ee ee eter ne er Re ee So CERES as cay : Ey pee EoPeg ea a cee ea ee F Re eee ae aT acu i , Ae OR Pe Be eae ee ma : 7 according to VSEPR theory ; q f ‘oe B= , 7 aa la jpn DAR cme ae CL ek ce CL ui . Dime eye Vane ee Ff (c) Name the covalent bond formed by axial overlapping of atomic orbital H (d) Define hybridization. OR Senn ee Re CL SECTION-E - De Rn long answer questions carries Fe ee ad DNs Reta ne 49 io) , Sit ee re Sead ree aL LU iti —. wg | io ee le Gig St aa on a en a Cee oe Dee a Pen ie ce a pean Pye Be aad en ec a) XI-CHEMISTRY-E rTcco) cls Leo Fay 3 feet ) eee 107 2a oRteer aif See) Oe ee 10) - ea RES ay | PC. er ae aA Oe eee ee el (COM Ce Re L ed Gil) He) sty a1 afer i 1 CORE REE (OMT (Comme es ce Se ey FRC Re SME R CROLL Ba iS Se RR ke eal Fmd De eRe a ee Reka e ) ® ace wen HH A IF fet #7 a cco ee eg ©) bee Pd Pt Perec Oe IOR Ong zi (@) Out ofthe following subshells which is having ere eel (b) Define threshold energy. (©) A photon of wavelength 4.0 x 1077 m Cee ee ; of metal being 2.13 eV, Calculate : amie MMR R SSC NCS) (COMB UCa Sutra ramea ttre eny Zo OC RE Sia) (@ — Give reason for the following statements : pi A (i) O-nitrophenol is steam volatile while P-nitrophenol is not. COMIN ECR Cc Cocrat URN Tae (iii) He molecule does not exist. Dear oe ene olor os @__ SF oP; /, ES Zi n am (e BrFs a OR (a) Explain why Np has greater Pen eee C UCL while O2 has Seed ee Ree than O}. (b) Define Prete eee tito east POMS ono nC coon Re cee ad Reser 5 ME Css i Deena caeee acs Ree econ any 5 an a pee© ee Saal = @ (AICECH,0) py cS ceo C) hho r eco ee @ Oak eee ee Hs 0) aie CNR ee ee : ) ihe. on’ a in) oe ae ORB ee Sc ampound. a sa Pratt aise i oa a a aN ery Peon wf LE a cant OCs een Dd Pea ucu Pr POR or ar oak : aa Lea 4 toys pan Coe Peep sk nao Bota) FeCl d Pyar ere kek Cad CCE ee Fi rl PRC ora te Se ec ety Sa Eited electroneg' Tanda oi Oe Re eae enthalpies. Pets electron Pe enthalpy than F. CRO NTO como of nitrogen is higher than oxygen- ae