ATOMIC STRUCTURE, STOICHIOMETRY

QUIZ FIITJEE & PERIODIC PROPERTIES

1. How many moles of electrons weight one Kg.

1
(A) 6.023  1023 (B)  10 31
9.108
6.023 1
(C)  10 54 (D)  10 8 .
9.108 9.108  6.023

2. For an electron with n = 3 has only one radial node. The orbital angular momentum of
electron will be
h
(A) 0 (B) 6
2
h  h 
(C) 2 (D) 3 
2  2 

3. The de-Broglie wavelength of a 66kg mass skiing down KufriHill in Shimla at 1  103 msec-1
(A) 1  10-36m (B) 1  10-37m
-38
(C) 1  10 m (D) 1  10-39m

4. For a d-electron, the orbital angular momentum is

(A) 2 h (B) h
(C) 6 h (D) 2h

5. For the reaction A + 2B  C + 3D, 5 moles of A and 8 moles of B will produce
(A) 5 moles of C (B) 4 moles of C
(C) 8 moles of C (D) none

6. The mole fraction of SO 2 if equal weight of CH 4 , O 2 and SO 2 are present in the mixture
1 1
(A) (B)
2 5
1 1
(C) (D)
7 9

7. Maximum number of atoms are present in

(A) 10 gm of NH3 (B) 8 gm CH4
(C) 20 gm of CO2 (D) 30 gm of N2O

8. The oxidation state of oxygen in HOF is

(A) 0 (B) 1
(C) 2 (D) +1

9. The number of moles of Na 2 SO 3 required to react exactly with 1 mole of KMnO 4 in acidic
medium will be
5 2
(A) (B)
2 5
3 2
(C) (D)
2 3

10. Which of the following is an example of disproportionation reaction ?

(A) I2  Na 2 S 2 O 3  NaI  Na 2 S 4 O 6
(B) Cl 2  H 2 O  HCl  HOCl
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 (C) H 2 C 2 O 4  KMnO 4  H 2 SO 4  K 2 SO 4  MnSO 4  H 2 O  CO 2
(D) C  O 2  CO 2

11. Which of the following can behave both as an oxidizing as well as reducing agent ?
(A) K 2 Cr2 O 7 (B) H 2 S
(C) I 2 (D) H 2 SO 4

12. The equivalent weight of NaN 3 , If it is oxidized to HNO 3 is

M M
(A) (B)
3 6
M M
(C) (D)
9 16

13. The amount of unreacted KMnO4 left, when 100 gm of KMnO4 is allowed to react with 100
gm of H2C2O4 is
(A) 10 gm (B) 12.5 gm
(C) 29.8 gm (D) completely consumed

14. The oxidation state of C in HCHO is

(A) +2 (B) 2
(C) +1 (D) 0

15. For the reaction,

P + 3 Q  R + 2S
3 moles of P and 7 moles of Q will produce
(A) 4.66 moles of S (B) 7 moles of R
(C) 6 moles of R (D) 3.5 moles of S

16. For electrons in forbitals, the orbital angular momentum is

h h h h
(A) 3 (B) 9 (C) 12 (D) 15
2 2 2 2

17. 5.6 ltr of SO2 is mixed with 5.6 ltr of H2S at N.T.P, weight of Sulphur obtained
(A) 2 gm (B) 4 gm (C) 8 gm (D) 12 gm

18. Vapour density of a substance depends upon

(A) pressure (B) temperature
(C) amount of the substance (D) none of the above

19. The minimum amount of H2C2O4 required to react exactly with 3.16 gm of KMnO4 is
(A) 4.5 gm (B) 8 gm (C) 16 gm (D) 12 gm

20. Which set of quantum numbers (n, l, m, s) represents the outermost electron in a gaseous
aluminium atom?
1 1
(A) 2, 1, 0, + (B) 2, 1, 1, +
2 2
1 1
(C) 3, 0, 0, + (D) 3, 1, 1, +
2 2

21. The wave number of first line of Balmer series of hydrogen is 15200 cm –1. The wave number
of the first line of Li2+ ion is
(A) 15200 cm–1 (B) 60800 cm–1
–1
(C) 76000 cm (D) 136800 cm–1

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22. Which of the following transition between energy levels in the hydrogen atom produces the
fourth line of the second series in the Hydrogen spectrum?
(A) n 2  5  n1  1 (B) n 2  4  n 1  1
(C) n 2  6  n 1  2 (D) n 2  5  n 1  2

23. Splitting of spectral lines when atoms are subjected to strong electric field is called:
(A) Zeeman effect (B) Stark effect
(C) Decay (D) Disintegration

24. Which of the following quantum numbers represent impossible arrangements?

(A) n = 2, l = 1, m = 0, s = –1/2 (B) n = 4, l = 3, m = 2, s = +1/2
(C) n = 3, l = 2, m = 3, s = +1/2 (D) n = 4, l = 3, m = 3, s = +1/2

Paragraph for question nos. 25 – 26

Unlike the main group elements, the transition elements contain incomplete penultimate shell as
well as incomplete valence shell. Most of the elements are paramagnetic due to presence of
unpaired electrons. The magnetic moment due to electron spin is calculated by the formula :
  n  n  2  B.M.
Where  = Magnetic moment
n = No. of unpaired electrons
B.M. = Bohr magneton (the unit of )

Fe is a transition element which atomic number is 26.

Answer the following questions on the basis of above write up.

25. Which of the following ions has the highest value of magnetic moment?
(A) Fe2+ + (B) Fe3+
4+
(C) Fe (D) Fe+

26. How many electrons of Fe have l = 1?

(A) 10 (B) 18
(C) 12 (D) 8

Multiple correct choice type

27. The electronic configuration [Ar] 3d6 can be attributed to

(A) Co3+ (B) Zn2+
2+
(C) Mn (D) Ni+4

28. Which of the following pair of species have identical value of spin-only magnetic moment?
(A) Fe and Fe2+ (B) Fe+ and Fe3+
2+ 4+
(C) Fe and Fe (D) Fe and Fe3+
29. In which of the following compound(s) does chlorine exhibit positive oxidation state?
(A) ICl (B) KClO3
(C) ClF3 (D) OCl2
30. According to Aufbau principle, which quantum number(s) is/are used to decide the filling up
of electrons in atomic orbitals?
(A) principal quantum no (B) Azimuthal quantum no
(C) Magnetic quantum no (D) Spin quantum no

31. Which of the following statement(s) is/are correct for the following reaction?
NH4 2 Cr2O7  
 Cr2O3  N2  4H2O
(A) It is an intramolecular redox reaction
(B) The n-factor of (NH4)2Cr2O7 is 6
(C) It is a decomposition reaction
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 (D) ‘N’ atom is oxidized from 3 oxidation state to +3 oxidation state

32. The first ionization energy of which of the following atom(s) is/are higher than that of
potassium?
(A) Li (B) Na
(C) Mg (D) Be

33. In which of the following option, the electronegativity of the left side atom is higher than that
of the right side atom?
(A) N, S (B) Cl, O
(C) F, Cl (D) S, P

34. Which of the following quantum number(s) may be correct for the unpaired electron of
aluminum?
(A) n = 3 (B) l = 1
1
(C) m = 1 (D) s  
2
Matrix match type

35. Match the electrons mentioned in Column - I with their quantum numbers mentioned in
Column - II
Column – I Column – II
(A) Valence electron of sodium (P) n = 3
(B) The highest energetic electron of (Q) n = 2
aluminium
(C) The unpaired electron of fluorine (R)  = 0
(D) The 11th electron of magnesium (S) =1

Numerical Type

36. The radius of the second orbit of a hydrogen like species is 0.529 A. What is the atomic
number of the species?
37. How many moles of KMnO4 can completely oxidize five moles of C2O24 ions in acidic
medium?
MnO 4  C2O24  H 
 Mn2  CO2  H2O

38. How many gram of NaOH should be added to 400 mL of 0.5 N HCl for complete
neutralization?

39. What is the sum of the principal quantum numbers of two orbits of H-atom, between which
an electron transition produces a visible radiation having the longest wavelength?

40. What is the sum of the number of unpaired electrons present in an atom and a molecule of
oxygen in ground state?

41. How many maximum number of electrons of nitrogen atom will have the spin quantum
1
number equal to  ?
2

42. 26 g of a metal M (At mass = 52) is completely oxidized by 800 mL of 0.5 M acidified
solution of KMnO4. If the oxidation number of the metal after oxidation is +x, the value of ‘x’
would be:

43. What is the orbital angular momentum of the valence electron of calcium in J s unit?

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