ATOMIC STRUCTURE,

QUIZ FIITJEE STOICHIOMETRY & PERIODIC

PROPERTIES
Single correct choice type

1. de-Broglie wavelength of an electron in the first Bohr orbit of H-atom is

o o
(A) 1.7 A (B) 3.3 A
o o
(C) 6.8 A (D) 5.5 A

2. The maximum limiting labelling of oleum is approximately?

(A) 200% (B) 163.5%
(C) 122.5% (D) 180%

3. In a titration, H2O2 is oxidised to O2 by MnO4 in acidic medium. If 24 ml H2O2 requires 16ml

of 0.1M MnO4 , then the volume strength of H2O2 will be:
(A) 0.167 (B) 1.89
(C) 3.72 (D) 0.93

4. Which of the following order is correct?

(A) Li < Na < K < Rb < Cs (melting point)
(B) Li > Na > K > Rb > Cs (density)
(C) Be > Mg > Ca > Sr > Ba (ionization energy)
(D) Be < Mg < Ca < Sr < Ba (melting point)

5. The element with atomic number 56 belongs to

(A) s-Block element (B) p-Block element
(C) d-Block element (D) f-Block element

6. Which is correct among the following?

(A) Li < Na < K < Rb < Cs (according to density)
(B) B < Al < Ga < In < T (according to atomic radii)
(C) BF3  BCl3  BBr3  BI3  acidic nature 
(D) LiF > NaF > KF > RbF> CsF (solubility)

7. For following electron gain enthalpies

(i) O  g   e  O   g  egH1  141 kJ / mol
(ii) O   g   e  O 2  g   egH2
(iii) O  g   2e  O 2  g   egH   egH1   egH2
Identify correct statements:
(A) egH2 is more negative than egH1
(B)  egH for reaction (iii) will be negative
(C) egH2 will be positive
(D)  egH1 and  egH2 have almost same value

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8. Consider the graph between  and Z. If OX = 1 and Z = 52 then the frequency  of the
element is




45o
O
Z

(A) 2500 Hz (B) 2501 Hz

(C) 2600 Hz (D) 2601 Hz

Paragraph for Question Nos. 9 and 10

Imagine a universe in which the four quantum numbers can have the same possible values as in our
universe except the angular momentum quantum number "  " can have integral values of 0, 1, 2, 3
…….n (instead of 0, 1, 2……….(n -1) and magnetic quantum numbers “m” can have integral values
of     1 to 0 to    1 instead of  to 0 to   .

9. Electronic configuration of the element with atomic number 25, based on the above
assumption is.
(A) 1s 2 ,1p 6 ,2s2 ,1d10 ,2p5 (B) 1s 2 ,1p10 ,2s 2 ,1d11
(C) 1s3 ,1p9 ,2s3 ,2p9 ,3s1 (D) 1s 6 ,1p10 ,2s6 ,2p3

10. Based on above assumption magnetic moment of the element with atomic number 18 is
(A) 24 B.M. (B) 8 B.M.
(C) Zero B.M. (D) 15 B. M.

Multiple correct choice type

11. The correct statement for 2pz orbital is/are

3/2 3/2
Z  Zr  Z  Zr 
(A) n,,m      e2r /2a cos    (B) n,,m     2   e2r /2a
a  a  a  a 
(C) xy plane is nodal plane (D) 2pz ungerade orbital

12. Which set of quantum numbers is/are not consistent with the theory?
1 1
(A) n  2,   0, m  1, s   (B) n  2,   0, m  0, s  
2 2
1 1
(C) n  1,   1, m  0, s   (D) n  3,   3, m  3, s  
2 2

13. Which of the following is/are correct option for 2s orbital?

3/2
1  Z  Zr  Zr /2ao
(A) It has 1 radial node (B) R    e
2 6  ao  ao
1/2
Zr  3 
(C) At radial node, 2 (D) Angular function of 2s    cos 
ao  4 

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14. Out of the following, which is not correct match for radial
probability of finding the electron of 2s orbital?
(A) A  H , B  He  , C  Li 2 
(B) A  He  , B  H , C  Li 2
(C) A  Li 2 , B  He  , C  H
(D) A  Li 2 , B  H , C  He

Stem Type
Question Stem for Question Nos. 15 and 16
Question Stem

x and y .
15. Calculate distance between x and y (in units of a0) for Li+2 ion __?

16. Calculate ratio of y to x (in units of a0) for Be+3 ion __?

Question Stem for Question Nos. 17 and 18

Question Stem
Consider the given plot of KEmax against frequency    of incident light.

(Graph not to scale)

19.86
K.Emax(Joules)

13.24

6.62

1.0 2.0 3.0 4.0

Frequency ' ' (in Hz)

Here, frequency '  ' is to be multiplied by 1015 and maximum kinetic energy (KEmax) to be
multiplied by 1019 .
The work function of the metal be ‘x’ eV.
Planck’s constant  h   6.62  1034 J.s and speed of light (c) = 3  108 m / sec .

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 Let, electronic charge  e   1.6  1019 Coulamb .
If a light radiation of wavelength 100 nm is allowed to strike surface of the metal (taken in the
experiment for which above graph has been plotted), then, maximum speed of photoelectron
ejected is found to be y  106 m / s .

17. The value of ‘x’ is________

18. The value of ‘y’ is_______

Question Stem for Question Nos. 19 and 20

Question Stem
Photons
Metal A 
4.25 eV
 Maximum KE of ejected electron is TA in eV  ; and de  Broglie wave length   A
Photons
Metal B 
4.20 eV
 Maximum KE of ejected electron is TB  in eV  ; and de  Broglie wave length  B
If B  2 A and TB  TA  1.50 eV then

19. Work function of A is_______

20. TB  _______

Question Stem for Question Nos. 21 and 22

Question Stem
One litre solution contains 10.6 g of Na2CO3 and 4 g NaOH. Adding of HCl into the solution allows
following reactions.
Na2CO3  HCl   NaHCO3  NaCl
NaHCO3  HCl 
 NaCl  CO2  H2O
NaOH  HCl   NaCl  H2O
When the above solution mixture is treated with HCl in presence of phenolphthalein indicator, 300
mL of HCl solution is needed.

x = The concentration of HCl solution in mol L–1 unit

y = n-factor of Na2CO3 in presence of phenolphthalein indicator

21. The value of x is

22. The value of y is

Question Stem for Question Nos. 23 and 24

Question Stem

Brass is a mixture of 90% Cu (63.5) and 10% Zn (65.0). HNO3 reacts with brass according to the
following reactions:
Cu  4H  2NO3  2NO 2  Cu2   2H2 O
4Zn  10H  NO3  NH4  4Zn2   3H2 O

23. What volume (in mL) of 3.0 M HNO3 can react with 15.0 g of brass?

24. What volume (in L) of NO2 gas at N.T.P. would be produced?

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 Question Stem for Question Nos. 25 and 26
Question Stem
An aqueous solution of 10 moles of KIO3 is treated with an excess of KI solution. This is done in
acidic condition and liberates I2, which is consumed in 20 litres of sodium thiosulphate solution.
strength of hypo solution  100
Here, x 
2
1
and y = milliequivalents of I2 × nf of I2 obtained from reaction between KI and KIO3  .
40

25. The value of x is__________

26. The value of y is__________

Numerical Type

27. According to Moseley’s equation: v  a  Z  b  , the graph between v vs Z is given below.

The frequency v (in sec–1) for atomic number (Z) = 52 is:
1

v
45o
O Z

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