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Tsi12C ww Tenkasi District Common Examinations
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Third Revision Test February 2023

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5-03-303 3
Time Allowed: 3.00 Hours
Standard.12
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aa Choose CHEMISTRY
PARTa
ss a
AAl a
l a Maximum Marks: 70
I. the correct
d
electolytic refiningaa
answer:
daa aadd
15x1=155
1) In the
a) Pure copper
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.b).Impure
of copper, which oneof the
following P
..P
is used as anode?
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copper c) Carbon rod d) Platinum electrode
2) Assertion Aqueous solution of
potash Alum is acidic
Reason
sulphate undergo hydrolysis
a) Both assertion and reason are true and reason is the correct
of assertion explanation

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b)
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Both assertion and reason are true but reason is not the
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correct explanation

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Assertion is true but reason is false.N
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d) Both assertion and reason are false
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3) ColumnI
P P aa dd Column II
P Padd
a
I. Fluorine
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w . .B]Strong Oxidizing agent w
w ..
A] Identification of coloured metal ion

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II. Borax
III. Aluminium

t t
M. Sulphur
a) C
I lai D
D] Most abundant element
N
A

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sa
) B A D C

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aa B D A
a s
a aa
s
C

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4) The catalytic behaviour of transition metals and their compounds is ascribed
da

mainly due to

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.. P
a) their magnetic behaviour
ww P
.. P
b) their unfilled d orbitals

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) their ability to adopt variable oxidation states d) their chemical reactivity
5) Formula of tris(ethane-1,2-diamine) iron (11) phosphate
Pa

a) [Fe(CH3-CH(NH,),),](PO), b) [Fe(H,N-CH-CH-NH2),)](PO,)
[Fe(HN-CH-CH,-CH,-NH,),1(P0,)2 d) [Fe(H,N-CH-CH,-NH2),],(Po,)
eet t t t
6) The number of close packed spheres is 'n'. The number of tetrahedral voids
ee
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.N generated is equal to
a) n b) 2n
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c) 2n2 d) 3n
aa aa
w.

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7) If the initial concentration of the reactant is doubled, the time for half
a dd
reaction is also doubled. Then the order of the reaction is
b) aa aa
a) zero
ww P
.. P one c) Fraction
ww P
.. P d) none

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8) Dissociation constant of NH,OH is 1.8x10-5 the hydrolysis.constant of NH,CI
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would be
a) 1.8x10-19 b) 5.55x10-10 c)5.55x10-5 d) 1.8x10-5

9) Faradays constant is defined as

a) charge carried by 1 electron
eet t b) charge carried by one mole of electrons e et t
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c) charge required to deposit one mole of substance
aa 10) a a aa
d) charge carried by 6.22x1010 electrons
s s
The blue colour of water in the sea is due to

P aa
light
P
Scattering of blue dbyd water molecules
P Padd
a
a)
b) w
w . . by
sky
Reflection of blue by sea water
w
w..
c)
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Refraction of blue light
d) Adsorption
by w
w
of other colours, except the blue colour
with periodic acid
gives
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the impurities in sea water
water molecules

11) HOCH,CH-OH on heating

a) methanoic acid b) glyoxa c) methanol d) CO2

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12) Which one of the following pairs is not correcly matched?
Reducing agent Name of the reaction

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a] Zn/Hg/Con.HCI Clemension reduction
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b] LiAlIH Wolf-Kishner's reduction

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Rosenmund's reduction
d SnCl/Con.HCI
a a aa Stephen's reduction
dd-N-C-CH-CH
CH
a
13) IUPAC name for the .
ww P
. P
amine: CH,
ww . P
.P
ww w w
a) 3-Bimethylamino-3-methyl
w w
wwpentane
penÉaDe b) 3(N,N-Triethyl)-3-amino
c) 3-N,N-trimethylpentanamine d) N,N-dimethyl-3-methyl-pentan-3 amine
14) Which one given below is a non reducting sugar?

et
e t a) glucose b) sucrose
eet
c) maltose
t d) lactose

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15) The medicinal value of a drug is measured in terms of its

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a) De oxyribose b) gold number c)Therapeutic index d) equilibrium constant
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a as saaPART B

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16) Define Calcination.
P Paa dd
Answer ANY SIX.Q.No. 24 is compulsory:

P Pa
6x2=122

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17) What is Zeigler - Natta catalyst? Mention its uses.
ww. .
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w SiVAKU MAR, M,w
w
wwb/w isotropy and anisotropy R RAeo MAtiwwoPsS
18) Define Ambidentate ligand.
19) Distinguish
lai
20) Define buffer index (B)
21) Gas in gas colloid does not. Why?
22) How you prepared benzoic acid using Grignard reagent?
d

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sa
23) How is chloropicrin prepared?
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24) The half life of the homogeneous gaseous reaction SO,Cl2 >S02 Cl which

ss l
aa a
l a
obeys first order kinetic is 8.0 minutes. How long will it take for the

a dd
a a a
concentration of S0,Cl, to be reduced to 1% of the initial value?
a
da

PART C
Answer ANY SIX. Question.P
. P No. 33 is
. P
. P
25) Write a note
ww ww properties the element p-block.wwww
on
compulsory:
anomalous of first
6x318
26) Mention the ww field,
consequences
27) In an Octahedral draw the
of
figure
lanthanoid
contraction.
to show
splitting
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of d-orbitais.
Pa

28) The dissociation of water is an endothermic

29) What is intercalation? reaction. Why?
t t
30) Write Tollen's Reagent Test.
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31) Name the vitamins whose deficiency cause (i) Cheilosis
32) What are bio-degradable polymers? Give an
aa l a
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a (i) Ber-Beri
w.

example..
dd a s
a] Oxidation of ethanol into acetic acids
33) Identify the enzyme catalyst in the following
a reactions
c] Hydrolysis of urea
. P
. Pa a . . Pa
b]Hydrolysis of starch into maltose
P
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Answer ALL the

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questions:
34) a) Explain the zone refining. b)
c) Differentate lanthanide and actinides.
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Write any 3 uses of borax.
5x5-25

d) Explain the properties of inter halogen

35) a) What are the assumptions of Werner compounds.
eet t Theory? (OR)
b) Differentate frenkal and schotty defect?
e et t
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36) a) Integrated
aa ala
rate law for a first order reaction.
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Write any two examples for zero order reactions.
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d)
aa
Define electro chemicala a
c) Derive Ostwald dilution law.
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37) a) Derive
.P. P
ww1st Law.
expression
an
equivalent
for Nernst
equation
ww. P
. P
c) Describe ww
b) Explain Faraday's
ww reaction theory catalysis.
adsorption of
(OR)
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d) Explain tyndall
w
w effect.
38) a) Carbylamine b) Preparation of Urotropine
c) Write short note on peptide bond? (OR)
d) What is vulcanization (cross linking) of
eet t rubber?
eet t
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