NEET

Lakshya NEET (2025)

Physical Chemistry
DPP: 7
Chemical Kinetics

Q1 For a reaction, activation energy Ea = 0 and (A) 256 times (B) 512 times
6 −1
the rate constant at 200 K is 1.6 × 10 s . (C) 64 times (D) 128 times
The rate constant at 400 K will be [Given that
−1 Q6 Rate of reaction (r) is plotted against
gas constant R = 8.314 J K mol−1 ]
temperature (T) for an enzyme catalyzed
(A) 3.2 × 104 s−1
reaction. Which of the following is correct
(B) 1.6 × 106 s−1
representation?
(C) 1.6 × 103 s−1
(A)
(D) 3.2 × 106 s−1

Q2 The addition of a catalyst during a chemical

reaction alters which of the following
quantities?
(A) Enthalpy
(B) Activation energy
(C) Entropy (B)
(D) Internal energy

Q3 The activation energy of a reaction can be

determined from the slope of which of the
following graphs?
(A) ln k vs T1
(B) lnTk vs 1T (C)
(C) ln k vs T
(D) lnT k vs T

Q4 What is the activation energy for a reaction if

its rate doubles when the temperature is raised
from 20∘ C to 35∘ C ?
−1 −1
(R = 8.314 J mol K )
(D)
(A) 34.7 kJ mol −1
(B) 15.1 kJ mol −1
(C) 342 kJ mol −1
(D) 269kJ mol −1

Q5 In a zero-order reaction, for every 10∘ C rise of

temperature, the rate is doubled. If the
temperature is increased from 10∘ C to 100∘ C,
Q7 The rate of the reaction,2NO + Cl2 → 2NOCl
the rate of the reaction will become
is given by the rate equation, rate

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= k[NO]2 [Cl2 ]. The value of the rate constant of enzyme, then rate of reaction obtained is
can be increased by 10−6 times, the activation energy of reaction in
(A) increasing the temperature the presence of enzyme is.
(B) increasing the concentration of NO (A) 6/RT
(C) increasing the concentration of the Cl2 (B) P is required
(D) doing all of these (C) different from Ea obtained in laboratory
(D) can't say anything
Q8 The rate constants k1 and k2 for two different
reactions are 1016 ⋅ e−2000/T and Q12 How enzymes increases the rate of reactions?
15 −1000/T
10 ⋅ e , respectively. The temperature (A) By lowering activation energy
at which k1 = k2 is (B) By increasing activation energy
(A) 2000 K (C) By changing equilibrium constant
1000
(B) K
2.303
(D) By forming enzyme substrate complex
(C) 1000 K
Q13 For a reaction, temperature coefficient = 2 , if
(D) 2000 K
2.303 the temperature is increased from 25∘ C to
Q9 Consider figure and mark the correct option. 35∘ C, then, calculate the activation energy (in
kJ ) of the reaction.
(A) 52.8 kJ
(B) 70 kJ
(C) 100 kJ
(D) 0 kJ

(A) Activation energy of forward reaction is Q14 For reaction: A → B, the rate constant
E1 + E2 and product is less stable than k 1 = A 1 (e−Ea1 /RT
) and for the reaction
reactant. X → Y , the rate constant k2 = A2 (e−Ea2/RT ).
(B) Activation energy of forward reaction is E1 + If A1 = 109 , A2 = 1010 and
E2 and product is more stable than Ea1 = 1200cal/mol and Ea2 = 1800cal/mol,
reactant. then the temperature at which k1 = k2 is
(C) Activation energy of both forward and (Given R = 2cal/K − mol )
backward reaction is E1 + E2 reactant is (A) 300 K
more stable than product. (B) 300 × 2.303 K
(D) Activation energy of backward reaction is (C) 300 K
2.303
E1 and product is more stable than (D) None of these
reactant.
Q15 The activation energies of the forward and
Q10 The activation energy for a simple chemical backward reactions in the case of a chemical
reaction AB is Ea in forward direction.The reaction are 30.5 and 45.4 kJ/mol
activation energy for reverse reaction respectively. The reaction is
(A) is negative of Ea (A) exothermic
(B) is always less than Ea (B) endothermic
(C) can be less than or more than Ea (C) neither exothermic nor endothermic
(D) is always double of Ea (D) independent of temperature

Q11 When a biochemical reaction is carried out in

laboratory, outside the human body in absence

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Answer Key
Q1 (B) Q9 (A)

Q2 (B) Q10 (C)

Q3 (A) Q11 (C)

Q4 (A) Q12 (A)

Q5 (B) Q13 (A)

Q6 (B) Q14 (C)

Q7 (A) Q15 (A)

Q8 (B)

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